Solid carbon production and recovery from high temperature methane pyrolysis in bubble columns containing molten metals and molten salts

Carbon - Tập 151 - Trang 181-191 - 2019
Nazanin Rahimi1, Dohyung Kang1, John Gelinas1, Aditya Menon1, Michael J. Gordon1, Horia Metiu2, Eric W. McFarland1
1Department of Chemical Engineering, University of California, Santa Barbara, CA, 93106-5080, USA
2Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA 93106-9510, USA

Tài liệu tham khảo

Guéret, 1997, Methane pyrolysis: thermodynamics, Chem. Eng. Sci., 52, 815, 10.1016/S0009-2509(96)00444-7 Abánades, 2011, Experimental analysis of direct thermal methane cracking, Int. J. Hydrogen Energy, 36, 12877, 10.1016/j.ijhydene.2011.07.081 Li, 2011, Methane decomposition to COx-free hydrogen and nano-carbon material on group 8–10 base metal catalysts: a review, Catal. Today, 162, 1, 10.1016/j.cattod.2010.12.042 Steinberg, 1999, Fossil fuel decarbonization technology for mitigating global warming, Int. J. Hydrogen Energy, 24, 771, 10.1016/S0360-3199(98)00128-1 Serban, 2003, Hydrogen production by direct contact pyrolysis of natural gas, Energy Fuels, 17, 705, 10.1021/ef020271q Plevan, 2015, Thermal cracking of methane in a liquid metal bubble column reactor: experiments and kinetic analysis, Int. J. Hydrogen Energy, 40, 8020, 10.1016/j.ijhydene.2015.04.062 Parkinson, 2019, Levelized cost of CO2 mitigation from hydrogen production routes, Energy Environ. Sci., 10.1039/C8EE02079E Kevorkian, 1960, The decomposition of methane in shock waves1, J. Phys. Chem., 64, 964, 10.1021/j100837a002 Kozlov, 1962, Single-pulse shock tube studies on the kinetics of the thermal decomposition of methane, Combust. Flame, 6, 253, 10.1016/0010-2180(62)90103-7 Dunker, 2006, Production of hydrogen by thermal decomposition of methane in a fluidized-bed reactor—effects of catalyst, temperature, and residence time, Int. J. Hydrogen Energy, 31, 473, 10.1016/j.ijhydene.2005.04.023 Suelves, 2009, Effects of reaction conditions on hydrogen production and carbon nanofiber properties generated by methane decomposition in a fixed bed reactor using a NiCuAl catalyst, J. Power Sources, 192, 35, 10.1016/j.jpowsour.2008.11.096 Corbella, 2006, Characterization and performance in a multicycle test in a fixed-bed reactor of silica-supported copper oxide as oxygen carrier for chemical-looping combustion of methane, Energy Fuels, 20, 148, 10.1021/ef050212n Ashcraft, 2012, Modeling fast biomass pyrolysis in a gas–solid vortex reactor, Chem. Eng. J., 207, 195, 10.1016/j.cej.2012.06.048 Jin, 2013, Preparation of activated carbon supported Fe–Al2O3 catalyst and its application for hydrogen production by catalytic methane decomposition, Int. J. Hydrogen Energy, 38, 10373, 10.1016/j.ijhydene.2013.06.023 Liao, 1998, Dissociation of methane on different transition metals, J. Mol. Catal. A: Chem., 136, 185, 10.1016/S1381-1169(98)00050-8 Matamala, 1985, Carburization and decarburization kinetics of iron in CH4—H2 mixtures between 1000–1100° C, Mater. Chem. Phys., 12, 313, 10.1016/0254-0584(85)90102-6 Stoppel, 2017, Carbon dioxide free production of hydrogen Zhang, 2014, Comparative study of bimetallic Pt-Sn catalysts supported on different supports for propane dehydrogenation, J. Mol. Catal. A: Chem., 381, 138, 10.1016/j.molcata.2013.10.007 Nagaoka, 2001, Carbon deposition during carbon dioxide reforming of methane—comparison between Pt/Al2O3 and Pt/ZrO2, J. Catal., 197, 34, 10.1006/jcat.2000.3062 Reshetenko, 2003, Carbon capacious Ni-Cu-Al2O3 catalysts for high-temperature methane decomposition, Appl. Catal. A: General, 247, 51, 10.1016/S0926-860X(03)00080-2 Geißler, 2015, Experimental investigation and thermo-chemical modeling of methane pyrolysis in a liquid metal bubble column reactor with a packed bed, Int. J. Hydrogen Energy, 40, 14134, 10.1016/j.ijhydene.2015.08.102 T. Daniel, Production of hydrogen. 1931, Google Patents. Upham, 2017, Catalytic molten metals for the direct conversion of methane to hydrogen and separable carbon, Science, 358, 917, 10.1126/science.aao5023 Yoshida, 2016, Direct observation of formation behavior of metal emulsion in Sn/salt system, Metall. Mater. Transact. B, 47, 2498, 10.1007/s11663-016-0679-9 Tostmann, 1993, Rapid solidification of microemulsions of liquid alloys in molten salts, J. Non-Crystall. solids, 156, 551, 10.1016/0022-3093(93)90019-T Song, 2017, Influence of bottom bubbling rate on formation of metal emulsion in Sn–Sb–Cu alloy and molten salt system, ISIJ Int., 57, 236, 10.2355/isijinternational.ISIJINT-2016-528 Song, 2010, Influence of bottom bubbling condition on metal emulsion formation in lead-salt system, ISIJ Int., 50, 1539, 10.2355/isijinternational.50.1539 Natsui, 2016, Temperature dependence of behavior of interface between molten Sn and LiCl–KCl eutectic melt due to rising gas bubble, Metall. Mater. Trans. B, 47, 1532, 10.1007/s11663-016-0618-9 Riedewald, 2015, Novel waste printed circuit board recycling process with molten salt, MethodsX, 2, 100, 10.1016/j.mex.2015.02.010 Adachi, 1988, Extraction of lanthanide elements and bismuth in molten lithium chloride-liquid bismuth-lithium alloy system, J. Nucl. Sci. Technol., 25, 789, 10.1080/18811248.1988.9735926 Bradwell, 2012, Magnesium–antimony liquid metal battery for stationary energy storage, J. Am. Chem. Soc., 134, 1895, 10.1021/ja209759s Chow, 1993 V.A. Maroni, Process for Recovering Tritium from Molten Lithium Metal. 1976, Google Patents. Journée, 2014 Lofstrom, 2013 Natsui, 2014, Multiphase particle simulation of gas bubble passing through liquid/liquid interfaces, Mater. Trans., 55, 1707, 10.2320/matertrans.M2014245 Lin, 1994, Modeling of metallurgical emulsions, Metall. Mater. Transact. B, 25, 855, 10.1007/BF02662767 Greene, 1991, Bubble induced entrainment between stratified liquid layers, Int. J. Heat Mass Trans., 34, 149, 10.1016/0017-9310(91)90182-E Chevrier, 2000, X-ray fluoroscopy observations of bubble formation and separation at a metal-slag interface, Metall. Mater. Trans. B, 31, 537, 10.1007/s11663-000-0159-z Han, 2003, Bubble bursting phenomenon in gas/metal/slag systems, Metall. Mater. Trans. B, 34, 525, 10.1007/s11663-003-0020-2 Han, 2003, Mechanisms of iron entrainment into slag due to rising gas bubbles, ISIJ Int., 43, 292, 10.2355/isijinternational.43.292 Deng, 1990, Mass transfer of sulfur from liquid iron into lime-saturated CaO-Al2O3-MgO-SiO2 slags, Steel Res., 61, 438, 10.1002/srin.199000376 He, 1990, A model study of droplet generation in the BOF steelmaking, ISIJ Int., 30, 305, 10.2355/isijinternational.30.305 Reiter, 1992, Characteristics of entrainment at liquid/liquid interfaces due to rising bubbles, ISIJ Int., 32, 57, 10.2355/isijinternational.32.57 Chung, 2000, Dynamic and equilibrium interfacial phenomena in liquid steel-slag systems, Metall. Mater. Transact. B, 31, 957, 10.1007/s11663-000-0072-5 Feiterna, 2000, Iron drop ejection into slags by bursting gas bubbles, Steel Res., 71, 61, 10.1002/srin.200005691 Reiter, 1992, Observations of physical phenomena occurring during passage of bubbles through liquid/liquid interfaces, ISIJ Int., 32, 50, 10.2355/isijinternational.32.50 Cahn, 1999 Baumli, 2008, Wettability of carbon surfaces by pure molten alkali chlorides and their penetration into a porous graphite substrate, Mater. Sci. Eng. A, 495, 192, 10.1016/j.msea.2007.11.093 Baumli, 2008, Wettability of carbon surfaces by molten alkali chloride mixtures Hui, 2009, Synthesis criterion for a metal chloride-graphite intercalation compound by a molten salt method, New Carbon Mater., 24, 18, 10.1016/S1872-5805(08)60032-3 Stoppel, 2017, Carbon dioxide free production of hydrogen, 228 Haynes, 2012, Density of molten elements and representative salts López-de-Uralde, 2010, Automatic morphological categorisation of carbon black nano-aggregates Long, 2013, Carbon black vs. black carbon and other airborne materials containing elemental carbon: physical and chemical distinctions, Environ. Pollut., 181, 271, 10.1016/j.envpol.2013.06.009 Clague, 1999, A comparison of diesel engine soot with carbon black, Carbon, 37, 1553, 10.1016/S0008-6223(99)00035-4 Patel, 2012, Morphology, structure and chemistry of extracted diesel soot—Part I: transmission electron microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy and synchrotron X-ray diffraction study, Tribol. Int., 52, 29, 10.1016/j.triboint.2012.03.004 Pawlyta, 2016, Transmission electron microscopy (TEM) as a tool for identification of combustion products: application to black layers in speleothems Buchholz, 2003, Mechanism for the growth of multiwalled carbon-nanotubes from carbon black, Carbon, 41, 1625, 10.1016/S0008-6223(03)00110-6 Doherty, 2003, Solid-state synthesis of multiwalled carbon nanotubes, J. Mater. Res., 18, 941, 10.1557/JMR.2003.0129 Kamali, 2013, Molten salt corrosion of graphite as a possible way to make carbon nanostructures, Carbon, 56, 121, 10.1016/j.carbon.2012.12.076 Wichterle, 2010, Breakup of gas bubbles rising in molten metals, Steel Res. Int., 81, 356, 10.1002/srin.200800135 Yokoya, 1998, Removal of inclusion through bubble curtain created by swirl motion in submerged entry nozzle, ISIJ Int., 38, 1086, 10.2355/isijinternational.38.1086