Grain growth of nanocrystalline cryomilled Fe-Al powders

R. J. Perez1, H. G. Jiang2, E. J. Lavernia3, C. P. Dogan4
1Material & Processes Engineering Space System Division, Boeing, Downey
2Los Alamos National Laboratory, Los Alamos
3the Department of Chemical Engineering and Materials Science, University of California, Irvine, Irvine
4the United States Bureau of Mines, Albany

Tóm tắt

Nanocrystalline Fe-xAl (x=0, 2.6, or 10 wt pct) powders have been prepared using cryogenic mechanical alloying (cryomilling). The extremely low rate of diffusion of Al in Fe at the process temperature (−196 °C) effectively limits dissolution of Al in the nanocrystalline αFe grains. Thermal stability against grain growth in the cryomilled Fe-Al mixtures is found to be much greater than that of identically prepared pure nanocrystalline Fe. Heat treatment of the cryomilled Fe-Al materials results in a highly inhomogeneous distribution of grain size and microchemistry. The observed thermal stability is evaluated in terms of Zener pinning, solute drag, and chemical ordering mechanisms.

Tài liệu tham khảo

C. Suryanarayana: Int. Mater. Rev., 1995, vol. 40, pp. 41–64. M. Gell: Mater. Sci. Eng., 1995, vol. A204, pp. 246–51. H. Gleiter: Nanostruct. Mater., 1992, vol. 1, pp. 1–19. J. Weissmuller: Nanostruct. Mater., 1993, vol. 3, pp. 261–72. C.E. Krill, R. Klein, S. Janes, and R. Birringer: Mater. Sci. Forum, 1995, vols. 179–181, pp. 443–48. J.C. Rawers: J. Mater. Synth. Proc., 1995, vol. 3, pp. 69–79. C. Bansal, Z.Q. Gao, and B. Fultz: Nanostruct. Mater., 1995, vol. 5, pp. 327–36. B. Fultz, L.B. Hong, Z.Q. Gao, and C. Bansal: in Synthesis and Processing of Nanocrystalline Powder, D.L. Bourell, ed., TMS, Warrendale, PA, 1996, pp. 249–62. M.J. Luton, C.S. Jayanth, M.M. Disko, S. Matras, and J. Vallone: Multicomponent Ultrafine Microstructures, Materials Research Society symposium Proceedings, L.E. McCandlish, D.E. Polk, R.W. Siegel, and B.H. Kear, ed. Materials Research Societ Pittsburgh, PA, 1989, pp. 79–86. K. Boylan, D. Ostrander, U. Erb, G. Palumbo, and K.T. Aust: Scripta Metall., 1991, vol. 25, pp. 2711–16. C.S. Smith: Trans. AIME, 1949, vol. 9, pp. 15–51. R.J. Perez, B. Huang, and E.J. Lavernia: Nanostruct. Mater., 1996, vol. 7, pp. 565–72. H.P. Klug and L.E. Alexander: X-ray Diffraction Procedures, John Wiley & Sons, New York, NY, 1974, pp. 661–65. J.S. Benjamin and T.E. Volin: Metall. Trans. A, 1974, vol. 5, pp. 1929–34. W.B. Pearson: A Handbook of Lattice Spacings and Structures of Metals and Alloys, Pergamon, Oxford, United Kingdom, 1967, pp. 935 and 1300. T.R. Malow and C.C. Koch: in Synthesis and Processing of Nanocrystalline Powder, D.L. Bourell, ed., TMS, Warrendale, PA, 1996, pp. 33–44. T. Zak, O. Scheeweiss, Z. Cochnar, and A. Buchal: Mater. Sci. Eng., 1991, vol. A141, pp. 73–78. K. Wolski, G.L. Caer, P. Delcroix, R. Fillit, F. Thevenot, and J.L. Coze: Mater. Sci. Eng., 1996, vol. A207, pp. 97–104. E. Bonetti, G. Scipione, G. Valdre, G. Cocco, R. Frattini, and P.P. Macri: J. Appl. Phys., 1993, vol. 74, pp. 2053–57. E. Bonetti, G. Valdre, S. Enzo, G. Cocco, and I. Soletta: Nanostruct. Mater., 1993, vol. 2, pp. 369–75. T.B. Massalski: Binary Alloy Phase Diagrams, ASM INTERNATIONAL, Materials Park, OH, 1990, pp. 147–49. F. Cardellini, G. Mazzone, and M.V. Antisari: Acta Mater., 1996, vol. 44, pp. 1511–517. Z.G. Liu, J.T. Guo, L.L. He, and Z.Q. Hu: Nanostruct. Mater., 1994, vol. 4, pp. 787–94. S. Enzo, R. Frattini, R. Gupta, P.P. Macri, G. Principi, L. Schiffini, and G. Scipione: Acta Mater., 1996, vol. 44, pp. 3105–13. C.P. Dogan, J.C. Rawers, R.D. Govier, and G. Korth: Nanostruct. Mater., 1994, vol. 4, pp. 631–44. K. Tsuchiya: Ph.D. Dissertation, Northwestern University, Evanston, IL, 1991. K. Wolski, F. Thevenot, and J.L. Coze: Mater. Sci. Eng., 1996, vol. A207, pp. 105–14. E.A. Brandes and G.B. Brook: Smithells Metals Reference Book, Butterworth-Heinemann, London, 1992, pp. 8–23. C.L. Briant: Phil. Mag. Lett., 1996, vol. 73, pp. 345–49. P. Lejcek and S. Hofmann: Crit. Rev. Solid State Mater. Sci., 1995, vol. 20, pp. 1–85. K. Ishida: J. Alloys Compounds, 1996, vol. 235, pp. 244–49. B. Ralph: Materials Science and Technology, 1990, vol. 6, pp. 1139–44. H.C. Fiedler: Metall. Trans. A, 1977, vol. 8A, pp. 1307–12. G.J. Fan, W.N. Gao, M.X. Quan, and Z.Q. Hu: Mater. Lett., 1995, vol. 23, pp. 33–37. H. Warlimont and G. Thomas: Met. Sci. J., 1970, vol. 4, pp. 47–52. D.G. Morris and S. Gunther: Acta Mater., 1996, vol. 44, pp. 2847–59.