An internally consistent thermodynamic data set for phases of petrological interest

Journal of Metamorphic Geology - Tập 16 Số 3 - Trang 309-343 - 1998
T. J. B. Holland1, Roger Powell1
11  Department of Earth Sciences, University of Cambridge, Cambridge CB2 3EQ, UK (email: [email protected]), 2 School of Earth Sciences, University of Melbourne, Parkville, Victoria 3052, Australia

Tóm tắt

The thermodynamic properties of 154 mineral end‐members, 13 silicate liquid end‐members and 22 aqueous fluid species are presented in a revised and updated data set. The use of a temperature‐dependent thermal expansion and bulk modulus, and the use of high‐pressure equations of state for solids and fluids, allows calculation of mineral–fluid equilibria to 100 kbar pressure or higher. A pressure‐dependent Landau model for order–disorder permits extension of disordering transitions to high pressures, and, in particular, allows the alpha–beta quartz transition to be handled more satisfactorily. Several melt end‐members have been included to enable calculation of simple phase equilibria and as a first stage in developing melt mixing models in NCKFMASH. The simple aqueous species density model has been extended to enable speciation calculations and mineral solubility determination involving minerals and aqueous species at high temperatures and pressures. The data set has also been improved by incorporation of many new phase equilibrium constraints, calorimetric studies and new measurements of molar volume, thermal expansion and compressibility. This has led to a significant improvement in the level of agreement with the available experimental phase equilibria, and to greater flexibility in calculation of complex mineral equilibria. It is also shown that there is very good agreement between the data set and the most recent available calorimetric data.

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Tài liệu tham khảo

10.1007/BF00373328

10.1093/petrology/23.2.215

10.2475/ajs.263.6.494

10.1016/0016-7037(91)90022-W

10.2475/ajs.267.3.285

10.2475/ajs.277.5.585

10.1007/BF00311034

10.1093/petrology/28.2.389

10.1007/s004100050216

Baker J., 1995, Thermal expansion of scapolite., American Mineralogist, 79, 878

10.2138/am-1996-5-615

Baker J., 1994, Standard thermodynamic properties of meionite, Ca4Al6Si6O24CO3, from experimental phase equilibria., American Mineralogist, 79, 478

10.1029/JB091iB07p07505

10.1029/JB094iB06p07621

10.1093/petrology/29.2.445

Berman R. G., 1987, Development of models for multicomponent melts: analysis of synthetic systems. In:, Reviews in Mineralogy, 17, 405

10.1130/MEM97-p97

10.2475/ajs.280.9.907

10.1029/JB087iB08p07073

10.1016/0012-821X(80)90098-9

10.1007/BF00371195

10.2138/am-1995-3-404

10.1007/978-1-4612-3128-8_7

10.2475/ajs.s4-40.236.161

BowmanA. F.1975;An investigation of Al2SiO5phase equilibrium utilizing the scanning electron microscopeMS thesis University of Oregon Eugene Oregon USA.

10.1029/JB074i008p02089

10.1016/0012-821X(83)90071-7

10.1016/0016-7037(84)90198-4

10.2475/ajs.270.1.54

10.2475/ajs.274.8.902

10.1007/BF00203057

Carey J. W., 1992, The molar enthalpy of dehydration of cordierite., American Mineralogist, 77, 930

Carman J. H., 1974, Synthetic sodium phlogopite and its two hydrates: Stabilities, properties and mineralogic implications., American Mineralogist, 59, 261

10.1007/BF00206796

Carpenter M. A., 1994, Thermodynamics of non‐convergent cation ordering in minerals, II: spinels and the orthopyroxene solid solution., American Mineralogist, 79, 1068

Carpenter M. A., 1994, Thermodynamics of non‐convergent cation ordering in minerals, III: order parameter coupling in K‐feldspar., American Mineralogist, 79, 1084

Carrington D. P., 1995, Partial melting and phase relations in high‐grade metapelites: an experimental petrogenetic grid in KFMASH system., Contributions to Mineralogy and Petrology, 120, 270, 10.1007/BF00306508

10.1016/0016-7037(93)90126-H

10.1007/BF00202300

10.1007/BF00307751

10.2138/am-1995-3-410

10.1016/0016-7037(75)90150-7

10.1016/0016-7037(78)90267-3

10.1016/0016-7037(83)90266-1

Chatterjee N. D., 1976, Margarite stability and compatibility relations in the system CaO‐Al2O3‐SiO2‐H2O as a pressure‐temperature indicator., American Mineralogist, 61, 699

10.1007/BF00372834

10.1007/BF00371407

10.1093/petrology/14.2.185

10.1007/BF00375213

10.1007/BF00381295

Chopin C., 1983, Magnesiocarpholite and magnesiochloritoid: Two index minerals of pelitic blueschists and their preliminary phase relations in the model system MgO‐Al2O3‐SiO2‐H2O., American Journal of Science, 283, 72

ChopinC.&SobolevN. V.1995;Principal mineralogical indicators of UHP in crustal rocks. In:Ultrahigh Pressure Metamorphism(eds Coleman R. G. & Wang X.) pp. 96–131Cambridge University Press

Chou I. M., 1978, Calibration of oxygen buffers at elevated P and T using the hydrogen fugacity sensor., American Mineralogist, 63, 690

Christy A. G., 1992, A 27Al and 29Si MAS NMR and infrared spectroscopic study of Al‐Si ordering in natural and synthetic sapphirine., American Mineralogist, 77, 8

Circone S., 1992, Substitution of Al in phlogopite: High temperature solution calorimetry, heat capacities, and thermodynamic properties of the phlogopite‐eastonite join., American Mineralogist, 77, 1191

10.1130/MEM97-p345

10.1127/ejm/3/3/0485

10.1007/BF00205262

ComodiP.&ZanazziP. F.1994High pressure structural study of muscovite.IMA 16th General Meeting Pisa abstracts 79–80

10.2138/am-1996-7-805

10.2138/am-1997-1-208

Connolly J. A. D., 1985, Experimental and thermodynamic analysis of prehnite., EOS, 66

10.1007/BF00321754

10.1127/ejm/7/4/0883

10.1016/0016-7037(93)90612-Z

10.1016/0022-4596(83)90122-6

Dickenson M. P., 1986, A garnet‐chlorite geothermometer., Geological Society of America Abstracts with Programs, 18

10.1524/zkri.1973.138.138.41

10.1029/94JB02917

Doroshev A. M., 1974, Upper pressure limit of stability of sapphirine., Doklady Akad Nauk SSSR, 219, 136

10.2138/am-1996-1-207

Duffy C. J., 1979, Phase equilibria in the system MgO‐MgF2‐SiO2‐H2O., American Mineralogist, 64, 1156

Engi M., 1983, Equilibria involving Al‐Cr spinel: Mg‐Fe exchange with olivine. Experiments, thermodynamic analysis, and consequences for geothermometry., American Journal of Science, 283, 29

10.1086/626866

10.2475/ajs.264.1.37

10.2138/am-1995-7-801

Evans B. W., 1976, Stability of chrysotile and antigorite in the serpentine multisystem., Schweizerische Mineralogische Petrologische Mitteilungen, 56, 79

10.1016/0016-7037(92)90296-U

10.1007/BF00372150

10.1063/1.324598

10.1063/1.327451

10.1007/BF00308271

Finger L. W., 1976, The thermal expansion of diopside to 800 °C and a refinement of the crystal structure at 700 °C., American Mineralogist, 61, 303

10.1007/BF00371325

10.1007/BF00376633

10.1007/BF01187144

Frantz J. D., 1982, Electrical conductances and ionization constants of salts, acids and bases in aqueous solutions at temperatures to 600 °C and pressures to 4000 bars., American Journal of Science, 284, 611

10.2475/ajs.284.6.651

10.1016/0016-7037(79)90114-5

10.1007/BF00371708

Ghiorso M. S., 1995, Chemical mass transfer in magmatic processes IV. A revised and internally consistent thermodynamic model for the interpretation and extrapolation of liquid‐solid equilibria in magmatic systems at elevated temperatures and pressures., Contributions to Mineralogy and Petrology, 119, 197, 10.1007/BF00307281

10.1029/JB085iB12p06949

Goldsmith J. R., 1985, The hydrothermal melting of low and high albite., American Mineralogist, 70, 924

Goldsmith J. R., 1977, Scapolite‐plagioclase stability relations at high pressures and temperatures in the system NaAlSi3O8‐CaAl2Si2O8‐CaCO3‐CaSO4., American Mineralogist, 62, 1063

10.1127/ejm/9/1/0175

Greenwood H. J., 1967, Wollastonite: Stability in H2O‐CO2 mixtures and occurrence in a contact‐metamorphic aureole near Salmo, British Columbia, Canada., American Mineralogist, 52, 1669

GrevelK.‐D.FockenbergT.WunderB.&BurchardM.1994;Experimental determination of the equilibrium curve 2 diaspore=corundum+H2O to high pressures and modified thermodynamic data for diaspore.Terra Nova Abstract Supplement 20

GrundyH. D.&BrownW. L.1974;A high temperature X‐ray study of low and high plagioclase feldspars. In:The Feldspars(eds MacKenzie W. S. & Zussman J.) pp. 162–173Proceedings of a NATO Advanced Study Institute. University of Manchester Press

Guggenheim S., 1987, Muscovite dehydroxylation: high‐temperature studies., American Mineralogist, 72, 537

10.1093/petrology/15.3.455

Hackler R. T., 1989, Experimental determination of Fe and Mg exchange between garnet and olivine and estimation of Fe‐Mg mixing properties in garnet., American Mineralogist, 74, 994

10.2475/ajs.257.9.656

10.2475/ajs.254.4.239

Harlov D. E., 1992, Experimental determination of the reaction 2 magnetite+2 kyanite+4 quartz=2 almandine+O2 at high pressure on the magnetite‐hematite buffer., American Mineralogist, 77, 558

Harlov D. E., 1993, Reversal of the metastable kyanite+corundum+quartz and andalusite+corundum+ quartz equilibria and the enthalpy of formation of kyanite and andalusite., American Mineralogist, 78, 594

HarrisonR. J.1997;Magnetic properties of the magnetite‐spinel solid solutionPhD thesis University of Cambridge.

Haselton H. T., 1988, Stability of muscovite in HCl‐KCl solutions: tetrahedral site disorder., EOS, 69

10.1029/GL005i009p00753

Haselton H. T., 1984, Low temperature heat capacities of CaAl2SiO6 glass and pyroxene and thermal expansion of CaAl2SiO6 pyroxene., American Mineralogist, 69, 481

10.1016/0016-7037(87)90270-5

Hawthorne F. C., 1993, The crystal chemistry of staurolite: I. Crystal structure and site occupancies., Canadian Mineralogist, 31, 551

Hazen R. M., 1976, Effects of temperature and pressure on the crystal structure of forsterite., American Mineralogist, 61, 1280

10.1007/BF00202099

Hazen R. M., 1978, The crystal structures and compressibilities of layer minerals at high pressure. II. Phlogopite and chlorite., American Mineralogist, 63, 293

10.1016/0022-3697(81)90074-3

Hazen R. M., 1989, The crystal chemistry of andradite and pyrope: revised procedures for high‐pressure diffraction experiments., American Mineralogist, 74, 352

Hazen R. M., 1988, Compressibility of sodalite and scapolite., American Mineralogist, 73, 1120

Helgeson H. C., 1978, Summary and critique of the thermodynamic properties of rock‐forming minerals., American Journal of Science, 278

Hemingway B. S., 1984, Heat capacity and thermodynamic functions for gehlenite and staurolite: With comments on the Schottky anomaly in the heat capacity of staurolite., American Mineralogist, 69, 307

Hemingway B. S., 1986, Akermanite: Phase transitions in heat capacity and thermal expansion, and revised thermodynamic data., Canadian Mineralogist, 24, 425

10.2113/gsecongeo.75.2.210

10.1180/minmag.1988.052.368.17

Hensen B. J., 1972, Phase relations involving pyrope, enstatitess, and sapphiriness in the system MgO‐Al2O3‐SiO2., Carnegie Institution of Washington Yearbook, 71, 421

Hewitt D. A., 1975, Stability of the assemblage phlogopite‐calcite‐quartz., American Mineralogist, 60, 391

10.2475/ajs.278.5.715

Hewitt D. A., 1975, Physical properties of some synthetic Fe‐Mg‐Al trioctahedral biotites., American Mineralogist, 60, 854

10.1007/BF01164520

10.2113/gsecongeo.77.4.798

10.1007/BF00373769

10.2475/ajs.271.2.97

10.1007/BF00371011

10.1007/BF00398778

10.2138/am-1995-5-612

10.1007/BF00371551

Holland T. J. B., 1984, Stability relations of ortho‐ and clinozoisite., Natural Environment Research Council Progress Report for Research, 6, 185

10.1007/BF00399373

Holland T. J. B., 1989, The dependence of entropy on volume for silicate and oxide minerals: a review and a predictive model., American Mineralogist, 74, 5

10.1038/320151a0

10.1111/j.1525-1314.1985.tb00325.x

10.1111/j.1525-1314.1990.tb00458.x

10.1007/BF00306484

Holland T. J. B., 1992, Plagioclase feldspars: activity‐composition relations based upon Darken’s Quadratic Formalism and Landau theory., American Mineralogist, 77, 53

10.2138/am-1996-11-1214

10.2138/am-1996-11-1215

10.1111/j.1525-1314.1985.tb00328.x

10.1007/s004100050198

HollandT. J. B.BakerJ. M.&PowellR.1998;Mixing properties and activity–composition relationships of chlorites in the system MgO‐FeO‐Al2O3‐SiO2‐H2O.European Journal of Mineralogy(in press)

10.2138/am-1996-3-408

Holm J. L., 1966, The thermodynamic properties of the aluminum silicates., American Mineralogist, 51, 1608

10.1007/BF00390149

10.1127/ejm/7/2/0353

10.1093/petrology/9.1.40

Huckenholz H. G., 1971, Andradite stability relations in the CaSiO3‐Fe2O3 join up to 30 kb., Neues Jahrbuch für Mineralogie Abhandlungen, 114, 246

10.1016/0016-7037(75)90183-0

10.1007/BF00998337

10.1016/0031-9201(74)90094-6

Ivaldi G., 1988, Crystal structure at 25 and 700° of magnesiochloritoid from a high pressure assemblage (Monte Rosa)., American Mineralogist, 73, 358

10.1016/0031-9201(76)90096-0

Jacobs G. K., 1981, Devolatilisation equilibria in H2O‐CO2 and H2O‐CO2‐NaCl fluids: an experimental and thermodynamic evaluation at elevated pressures and temperatures., American Mineralogist, 66, 1135

Jamieson H. E., 1984, The distribution of Mg and Fe2+ between olivine and spinel at 1300 °C., American Mineralogist, 69, 283

10.1007/BF00376758

10.2475/ajs.294.5.593

10.1038/304622a0

Jenkins D. M., 1991, Experimental Determination of the Pressure‐Temperature Stability Field and Thermochemical Properties of Synthetic Tremolite., American Mineralogist, 76, 458

Johannes W., 1968, Experimentelle Bestimmung von Gleichgewichtsbeziehungen im System MgO‐CO2‐H2O., Neues Jahrbuch für Mineralogie Monatshefte, 112, 15

10.1007/BF00373389

10.1029/JB093iB02p01063

10.1080/00206818209451044

10.1007/BF00371390

Kerrick D. M., 1984, The andalusite‐sillimanite equilibrium revisited., Geological Society of America Abstracts with Programs, 16

KhodakovskyI. L.WestrumE. F.&HemingwayB. S.1990;CODATA International Geothermodynamic Tables. Guidelines and a set of prototype tables

King E. G., 1967, Thermodynamic properties of forsterite and serpentine., United States Bureau of Mines Report of Investigations, 6962, 4320

Kiseleva I. A., 1990, Thermodynamic properties of alkali feldspars., Geokhimiya, 3, 406

Koziol A. M., 1993, On the stability of siderite., EOS, 74

10.2138/am-1995-11-1214

KoziolA. M.&NewtonR. C.1997;Experimental determination of the reaction: magnesite+enstatite=forsterite+CO2in the range 6–25 kbar and 700–1100 °C and the enthalpy of formation of forsterite.American Mineralogist (in press)

10.1007/BF00307328

Krupka K. M., 1985, Low‐temperature heat capacities and derived thermodynamic properties of anthophyllite, diopside, enstatite, bronzite and wollastonite., American Mineralogist, 70, 249

Krupka K. M., 1985, High‐temperature heat capacities and derived thermodynamic properties of anthophyllite, diopside, dolomite, enstatite, bronzite, talc, tremolite and wollastonite., American Mineralogist, 70, 261

Lager G. A., 1978, High‐temperature study of six olivines., American Mineralogist, 63, 365

Laird J., 1982, Amphiboles in metamorphosed basaltic rocks. In: Amphiboles,, MSA Reviews in Mineralogy, 9, 113

Laird J., 1989, Chlorites: Metamorphic petrology. In: Hydrous phyllosilicates (exclusive of micas),, MSA Reviews in Mineralogy, 19, 405

10.1016/0016-7037(87)90368-1

Lange R. A., 1990, Thermodynamic properties of silicate liquids with emphasis on density, thermal expansion and compressibility. In: Modern methods of igneous petrology: understanding magmatic processes (eds Nicholls, J. & Russel, J. K.):, MSA Reviews in Mineralogy, 24, 25

Lange R. A., 1986, Phase transitions in leucite KAlSi2O6, orthorhombic KAlSiO4, and their iron analogues (KFeSi2O6, KFeSiO4)., American Mineralogist, 71, 937

10.1127/ejm/4/2/0219

10.1007/BF00320980

10.1093/petrology/29.1.93

Levien L., 1981, High pressure crystal structure and compressibility of coesite., American Mineralogist, 66, 324

Lindsley D. H., 1983, Pyroxene thermometry., American Mineralogist, 68, 477

10.1007/BF00389814

10.1093/petrology/12.2.379

10.1007/BF00399649

10.1016/0024-4937(71)90122-8

10.1093/petrology/14.3.381

10.1007/BF00202988

10.1016/0016-7037(85)90044-4

10.1007/s004100050118

10.1007/BF00310470

10.1111/j.1525-1314.1997.00011.x

10.1016/0031-9201(70)90088-9

10.1016/0016-7037(94)90214-3

10.1007/BF00687196

Markgraf S. A., 1985, High‐temperature refinements of calcite and magnesite., American Mineralogist, 70, 590

MartensR.RosenhauerM.&GehlenV. K.1982;Compressibilities of carbonates. In:Researches in Geoscience(ed. Schreyer W.) pp. 215–222Schweizerbart’sche Verlagsbuchhandlung Stuttgart

10.2138/am-1996-5-608

MassonneH‐J.1995;Experimental and petrogenetic study of UHPM. In:Ultrahigh Pressure Metamorphism(eds Coleman R. G. & Wang X.) pp. 33–95Cambridge University Press

10.1007/BF00375235

10.1127/ejm/1/3/0391

McCormick T. C., 1989, Compressibility of omphacite to 60 Kbar: role of vacancies., American Mineralogist, 74, 1287

10.1007/BF00371235

Miller Ch., 1986, Alpine high‐pressure metamorphism in the Eastern Alps., Schweitzerische Mineralogische und Petrologische Mitteilungen, 66, 139

10.1007/BF00311979

10.1007/BF00309252

Mirwald P. W., 1979, Der Wassergehalt von Mg Cordierit zwischen 500 und 800 °C sowie 0, 5, und 11 kbar., Fortschritte der Mineralogie, 57, 462

Moecher D. P., 1990, Experimental investigation of andradite and hedenbergite equilibria employing the hydrogen sensor technique, with revised estimates of ΔfG for andradite and hedenbergite., American Mineralogist, 75, 1327

Moore P. B., 1969, The crystal structure of sapphirine., American Mineralogist, 54, 31

Moore P. B., 1972, Atomic arrangement of merwinite, Ca3Mg[SiO4]2, an unusual dense‐packed structure of geophysical interest., American Mineralogist, 57, 1355

10.1007/BF00310912

10.1007/BF00371177

10.1016/0016-7037(76)90162-9

10.1016/0016-7037(80)90107-6

Nell J., 1989, Thermodynamic properties in a multicomponent solid solution involving cation disorder: Fe3O4‐MgFe2O4‐FeAl2O4‐MgAl2O4 spinels., American Mineralogist, 74, 1000

Nelson D. O., 1993, Inferred limits to the oxidation of Fe in chlorites: a high‐temperature single‐crystal X‐ray study., American Mineralogist, 78, 1197

Newton R. C., 1993, Standard thermodynamic properties of almandine., Canadian Mineralogist, 31, 391, 10.3749/1499-1276-31.2.391

10.1007/BF01132006

OlingerB. W.1977;Compression of forsterite (Mg2SiO4) and enstatite (MgSiO3). In:High‐pressure Research. Applications in Geophysics(eds Manghnani M. H. & Akimoto S. I.) pp. 325–334Academic Press New York

O’Neill H. St. C., 1987, Free energies of formation of NiO, CoO, Ni2SiO4, and Co2SiO4., American Mineralogist, 72, 280

St. O’Neill H. C., 1987, Quartz‐fayalite‐iron and quartz‐fayalite‐magnetite equilibria and the free energy of formation of fayalite (Fe2SiO4) and magnetite (Fe3O4)., American Mineralogist, 72, 67

O’Neill H. St. C., 1988, Systems Fe‐O and Cu‐O: thermodynamic data for the equilibria Fe‐‘‘FeO’’, Fe‐Fe3O4, Fe3O4‐Fe2O3, Cu‐Cu2O, and Cu2O‐CuO from emf measurements., American Mineralogist, 73, 470

10.1007/BF00371872

10.1016/0016-7037(88)90185-8

10.1021/j100317a049

10.1002/gj.3350050110

10.1007/BF00223322

10.1007/BF00310614

10.2138/am-1995-9-1015

10.1007/s004100050176

10.2138/am-1996-3-407

10.1007/s004100050129

PerchukL. L.&Lavrent’evaI. V.1983;Experimental investigation of exchange equilibria in the system cordierite‐garnet‐biotite. In:Kinetics and Equilibrium in Mineral Reactions (ed. Saxena S. K.) pp. 199–240Springer Verlag

10.1007/BF00348956

10.1016/0016-7037(80)90177-5

Peterson J. W., 1990, Experimental biotite‐quartz melting in the KMASH‐CO2 system and the role of CO2 in the petrogenesis of granites and related rocks., American Mineralogist, 75, 1029

10.1016/0016-7037(82)90056-4

PoirierJ.‐P.1991;Introduction to the Earth’s Interior. Cambridge University Press Cambridge

10.1016/0016-7037(79)90026-7

10.1111/j.1525-1314.1985.tb00324.x

10.1111/j.1525-1314.1988.tb00415.x

Powell R., 1993, On the formulation of simple mixing models for complex phases., American Mineralogist, 78, 1174

Powell R., 1993, The applicability of least squares in the extraction of thermodynamic data from experimentally bracketed mineral equilibria., American Mineralogist, 78, 107

10.1111/j.1525-1314.1998.00157.x

10.1007/BF00375219

PutnisA.1992;Introduction to Mineral Sciences. Cambridge University Press Cambridge

10.1021/j100848a050

Ralph R. L., 1984, Compressibility and crystal structure of andalusite at high pressure., American Mineralogist, 69, 513

RaoB.&JohannesW.1979;Further data on the stability of staurolite+quartz.Neues Jahrbuch für Mineralogie Monatshefte 437–447

Reeder R. J., 1986, High‐temperature crystal chemistry of dolomite., American Mineralogist, 71, 775

10.1007/BF00372220

10.1029/93GL02507

10.1063/1.1743415

10.1093/petrology/9.3.467

10.2475/ajs.266.7.515

10.2475/ajs.267.3.259

10.1029/90JB02172

10.1007/978-1-4612-2842-4_4

10.1127/ejm/3/3/0475

10.1016/S0016-7037(97)00103-8

RobieR. A.&HemingwayB. S.1995;Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105Pascals) pressure and at higher temperatures.United States Geological Survey BulletinNo. 2131

RobieR. A.BethkeP. E.&BeardsleyK. M.1967;Selected X‐ray crystallographic data molar volumes and densities of minerals and related substances.United States Geological Survey BulletinNo. 1248

RobieR. A.HemingwayB. S.&FisherJ. R.1978;Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105Pascals) pressure and at higher temperatures.United States Geological Survey BulletinNo. 1452

Robie R. A., 1982, Heat capacities and entropies of Mg2SiO4, Mn2SiO4, and Ca2SiO4 between 5 and 380 K., American Mineralogist, 67, 470

10.1016/0016-7037(87)90271-7

Rosenberg P. E., 1967, Subsolidus relations in the system CaCO3‐MgCO3‐FeCO3 between 350 and 550 °C., American Mineralogist, 52, 787

Ross N. L., 1992, High‐pressure structural study of dolomite and ankerite., American Mineralogist, 77, 412

10.1016/0016-7037(88)90179-2

10.1016/0016-7037(87)90013-5

10.1029/JB083iB01p00335

10.1093/petrology/21.3.441

10.1007/BF00307565

10.1016/0012-821X(94)00080-8

Schreyer W., 1969, High pressure phases in the system MgO‐Al2O3‐SiO2‐H2O., American Journal of Science, 267, 407

10.1007/BF01166805

10.1086/627958

10.1007/s004100050221

10.1016/0016-7037(86)90321-2

ShearerJ. A.1973;Thermochemistry of the garnets and some related compoundsUnpublished PhD thesis Department of Chemistry University of Chicago USA.

10.1016/0016-7037(88)90181-0

10.1130/MEM97-p75

10.1007/s004100050175

Smyth J. R., 1975, High‐temperature crystal chemistry of fayalite., American Mineralogist, 60, 1092

Skrok V., 1994, Die Stabilität von Lawsonit, CaAl2(OH)2.H2O, bei Drücken bis zu 50 kbar., European Journal of Mineralogy, 6

10.1007/BF00381840

10.1007/BF00307271

10.1029/JB081i014p02453

Sueno S., 1973, The high‐temperature crystal chemistry of tremolite., American Mineralogist, 58, 649

Sueno S., 1976, Orthoferrosilite: High temperature crystal chemistry., American Mineralogist, 61, 38

10.1016/0016-7037(91)90157-Z

10.1016/S0016-7037(97)00009-4

TakedaH.&MorosinB.1975;Comparison of observed and predicted structural parameters of mica at high temperatures.Acta Crystallographica B.31 2444–2452

10.1016/0016-7037(91)90158-2

10.1127/ejm/4/3/0487

10.1111/j.1525-1314.1997.1501050.x

10.2475/ajs.269.3.267

10.2475/ajs.271.1.79

10.1007/BF00310641

10.1029/JB078i029p06893

10.2475/ajs.263.10.886

10.1111/j.1525-1314.1992.tb00109.x

10.1007/BF00306647

10.1007/BF00371870

VoigtR.&WillG.1981;Das System Fe2O3–H2O unter hohen Drucken.Neues Jahrbuch für Mineralogie Monatshefte 89–96

10.1007/BF00283228

10.2475/ajs.277.10.1315

Walther J. V., 1983, The extraction‐quench technique for determination of the thermodynamic properties of solute complexes: application to quartz solubility in fluid mixtures., American Mineralogist, 68, 731

10.1093/petrology/27.2.541

Wechsler B. A., 1984, Crystal structure of ilmenite (FeTiO2) at high temperature and at high pressure., American Mineralogist, 69, 176

10.1016/0016-7037(66)90109-8

10.2138/am-1995-5-603

10.2475/ajs.281.8.1091

10.1016/0016-7037(89)90383-9

Winter J. K., 1979, Thermal expansion and high‐temperature crystal chemistry of the Al2SiO5 polymorphs., American Mineralogist, 64, 573

Winter J. K., 1979, A high‐temperature structural study of high albite, monalbite and the albite‐monalbite phase transition., American Mineralogist, 64, 409

Wood B. J., 1976, The reaction phlogopite+quartz=enstatite+sanidine+H2O. Progress in Experimental Petrology,, 3rd NERC report, 6, 17

10.1007/BF00320977

Wunder B., 1993, Synthesis, stability and properties of Al2SiO4(OH)2: a fully hydrated analogue of topaz., American Mineralogist, 78, 285

10.1029/94GL00026

Zhang L., 1992, Compressibility of grunerite., American Mineralogist, 77, 480

Zharikov V. A., 1969, High temperature mineral equilibria in the system CaO‐SiO2‐CO2., Geochemistry International, 6, 853

Zheng J., 1996, In situ X‐ray observations of the coesite‐stishovite transition: reversed phase boundary and kinetics., Physics and Chemistry of Minerals, 23, 1

Zhu H., 1994, Enthalpy of formation of wollastonite (CaSiO3) and anorthite (CaAl2Si2O8) by experimental phase equilibrium measurements and high‐temperature solution calorimetry., American Mineralogist, 79, 134