CO2 hydrogenation to methanol over CuO-ZnO-ZrO2 catalyst prepared by polymeric precursor method
Tóm tắt
A series of CuO-ZnO-ZrO2 catalysts were synthesized by the polymeric precursor method, and characterized by X-ray diffraction (XRD), N2 physisorption, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), temperature-programmed reduction with H2 (H2-TPR), reactive N2O adsorption, and adsorption of H2 and CO2 followed by temperature-programmed desorption (H2-TPD, CO2-TPD) techniques. The catalytic performances of all samples for methanol synthesis from hydrogenation of CO2 were evaluated under the experimental condition of 240 °C, 3 MPa, and SV = 1800–6000 mL·gcat−1·h−1. The effects of the calcination temperature on physicochemical and catalytic properties of all catalysts were investigated. The results indicate that the catalyst prepared under 400 °C calcination possesses the smallest Cu crystallites, largest metallic Cu surface area, and thus exhibits the highest methanol yield.
Tài liệu tham khảo
Gao P, Li F, Zhao N, Xiao F, Wei W, Zhong L, Sun Y (2013) Influence of modifier (Mn, La, Ce, Zr and Y) on the performance of Cu/Zn/Al catalysts via hydrotalcite-like precursors for CO2 hydrogenation to methanol. Appl Catal A 468:442–452
Arena F, Italiano G, Barbera K, Bonura G, Spadaro L, Frusteri F (2009) Basic evidences for methanol-synthesis catalyst design. Catal Today 143:80–85
Jones JP, Surya Prakash GK, Olah GA (2014) Electrochemical CO2 reduction: recent advances and current trends. Isr J Chem 54:1451–1466
Olah GA, Goeppert A, Prakash GKS (2008) Chemical recycling of carbon dioxide to methanol and dimethyl ether: from greenhouse gas to renewable, environmentally carbon neutral fuels and synthetic hydrocarbons. J Org Chem 74:487–498
Olah GA (2013) Towards oil independence through renewable methanol chemistry. Angew Chem Int Ed 52:104–107
Karelovic A, Ruiz P (2015) The role of copper particle size in low pressure methanol synthesis via CO2 hydrogenation over Cu/ZnO catalysts. Catal Sci Technol 5:869–881
Jadhav SG, Vaidya PD, Bhanage BM, Joshi JB (2014) Catalytic carbon dioxide hydrogenation to methanol: a review of recent studies. Chem Eng Res Des 92:2557–2567
Li C, Yuan X, Fujimoto K (2014) Development of highly stable catalyst for methanol synthesis from carbon dioxide. Appl Catal A 469:306–311
Chang K, Wang T, Chen JG (2017) Hydrogenation of CO2 to methanol over CuCeTiOx catalysts. Appl Catal B 206:704–711
Natesakhawat S, Ohodnicki Jr PR, Howard BH, Lekse JW, Baltrus JP, Matranga C (2013) Adsorption and deactivation characteristics of Cu/ZnO-based catalysts for methanol synthesis from carbon dioxide. Top Catal 56:1752–1763
Frei E, Schaadt A, Ludwig T, Hillebrecht H, Krossing I (2014) The influence of the precipitation/ageing temperature on a Cu/ZnO/ZrO2 catalyst for methanol synthesis from H2 and CO2. ChemCatChem 6:1721–1730
Arena F, Barbera K, Italiano G, Bonura G, Spadaro L, Frusteri F (2007) Synthesis, characterization and activity pattern of Cu-ZnO/ZrO2 catalysts in the hydrogenation of carbon dioxide to methanol. J Catal 249:185–194
Guo XM, Mao DS, Lu GZ, Wang S, Wu GS (2010) Glycine-nitrate combustion synthesis of CuO-ZnO-ZrO2 catalysts for methanol synthesis from CO2 hydrogenation. J Catal 271:178–185
Li L, Mao DS, Yu J, Guo XM (2015) Highly selective hydrogenation of CO2 to methanol over CuO-ZnO-ZrO2 catalysts prepared by a surfactant-assisted co-precipitation method. J Power Sour 279:394–404
Witoon T, Kachaban N, Donphai W, Kidkhunthod P, Faungnawakij K, Chareonpanich M, Limtrakul J (2016) Tuning of catalytic CO2 hydrogenation by changing composition of CuO–ZnO–ZrO2 catalysts. Energy Convers Manag 118:21–31
Angelo L, Kobl K, Tejada LMM, Zimmermann Y, Parkhomenko K, Roger A (2015) Study of CuZnMOx oxides (M = Al, Zr,Ce,CeZr) for the catalytic hydrogenation of CO2 into methanol. C R Chim 18:250–260
Guo XM, Mao DS, Lu GZ, Wang S, Wu GS (2011) CO2 hydrogenation to methanol over Cu/ZnO/ZrO2 catalysts prepared via a route of solid–state reaction. Catal Commun 12:1095–1098
Guo XM, Mao DS, Lu GZ, Wang S, Wu GS (2009) Combustion synthesis of CuO-ZnO-ZrO2 catalysts for the hydrogenation of carbon dioxide to methanol. Catal Commun 10:1661–1664
Vijayakumar M, Inaguma Y, Mashiko W, Crosnier MPL, Claude B (2004) Synthesis of fine powders of Li3xLa2/3-xTiO3 perovskite by a polymerizable precursor method. Chem Mater 16:2719–2724
Farhadi-Khouzani M, Fereshteh Z, Loghman-Estarki MR, Razavi RS (2012) Different morphologies of ZnO nanostructures via polymeric complex sol–gel method: synthesis and characterization. J Sol-Gel Sci Technol 64:193–199
Dang HT, Le TK (2016) Precursor chain length dependence of polymeric precursor method for the preparation of magnetic Fenton-like CuFe2O4-based catalysts. J Sol-Gel Sci Technol 80:160–167
Giraldi TR, Arruda CC, da Costa GM, Longo E, Ribeiro C (2009) Heterogeneous Fenton reactants: a study of the behavior of iron oxide nanoparticles obtained by the polymeric precursor method. J Sol-Gel Sci Technol 52:299–303
Choudhary N, Verma MK, Sharma ND, Sharma S, Singh D (2018) Superparamagnetic nanosized perovskite oxide La0.5Sr0.5Ti0.5Fe0.5O3 synthesized by modified polymeric precursor method: effect of calcination temperature on structural and magnetic properties. J Sol-Gel Sci Technol 86:73–82
Guo XM, Mao DS, Lu GZ, Wang S (2013) The influence of ZnO on the performance of CuO-ZrO2 for methanol synthesis via CO2 hydrogenation. J Shanghai Inst Technol (Nat Sci) 13:259–262
Huang C, Mao DS, Guo XM, Yu J (2017) Microwave-assisted hydrothermal synthesis of CuO-ZnO-ZrO2 as catalyst for direct synthesis of methanol by carbon dioxide hydrogenation. Energy Technol 5:2100–2107
Bonura G, Cordaro M, Cannilla C, Arena F, Frusteri F (2014) The changing nature of the active site of Cu-Zn-Zr catalysts for the CO2 hydrogenation reaction to methanol. Appl Catal B 152-153:152–161
Batyrev ED, Van den Heuvel JC, Beckers J, Jansen WPA, Castricum HL (2005) The effect of the reduction temperature on the structure of Cu/ZnO/SiO2 catalysts for methanol synthesis. J Catal 229:136–143
Fujita S, Moribe S, Kanamori Y, Kakudate M, Takezawa N (2001) Preparation of a coprecipitated Cu/ZnO catalyst for the methanol synthesis from CO2—effects of the calcination and reduction conditions on the catalytic performance. Appl Catal A 207:121–128
Chen DW, Mao DS, Guo XM, Yu J (2018) CO2 hydrogenation to methanol over CuO–ZnO–TiO2–ZrO2: a comparison of catalysts prepared by sol-gel, solid-state reaction and solution–combustion. J Sol-Gel Sci Technol 86:719–730
Han YT, Yang PC, Meng XH, Yan JS, Wang HY (2013) Preparation and characterization of hierarchical porous TiO2/γ-Al2O3 composite support. Acta Pet Sin 29:785–790
Bagherzadeh SB, Haghighi M, Rahemi N (2017) Novel oxalate gel coprecipitation synthesis of ZrO2-CeO2-promoted CuO-ZnO-Al2O3 nanocatalyst for fuel cell-grade hydrogen production from methanol: Influence of ceria-zirconia loading. Energy Convers Manag 134:88–102
Ajamein H, Haghighi M, Shokrani R, Abdollahifar M (2016) On the solution combustion synthesis of copper based nanocatalysts for steam methanol reforming: effect of precursor, ultrasound irradiation and urea/nitrate ratio. J Mol Catal A 421:222–234
Amadine O, Essamlali Y, Fihri A, Larzek M (2017) Effect of calcination temperature on the structure and catalytic performance of copper-ceria mixed oxide catalysts in phenol hydroxylation. RSC Adv 7:12586–12597
Xiao J, Mao DS, Guo XM, Yu J (2015) Effect of TiO2, ZrO2, and TiO2-ZrO2 on the performance of CuO-ZnO catalyst for CO2 hydrogenation to methanol. Appl Surf Sci 338:146–153
Wang G, Mao DS, Guo XM, Yu J (2018) Enhanced performance of the CuO-ZnO-ZrO2 catalyst for CO2 hydrogenation to methanol by WO3 modification. Appl Surf Sci 456:403–409
Chalorngtham J, Witoon T, Dumrongbunditkul P, Chareonpanich M, Limtrakul J (2016) CO2 hydrogenation to methanol over Cu/ZrO2 catalysts: effects of zirconia phases. Chem Eng J 293:327–336
Natesakhawat S, Lekse JW, Baltrus JP, Ohodnicki Jr PR, Howard BH, Deng XY, Matranga C (2012) Active sites and structure–activity relationships of copper–based catalysts for carbon dioxide hydrogenation to methanol. ACS Catal 2:1667–1676
Zhan H, Li F, Gao P, Zhao N, Xiao F, Wei W, Zhong L, Sun Y (2014) Methanol synthesis from CO2 hydrogenation over La-M-Cu-Zn-O (M = Y, Ce, Mg, Zr) catalysts derived from perovskite-type precursors. J Power Sour 251:113–121
Bando KK, Sayama K, Kusama H, Okabe K, Arakawa H (1997) In–situ FT–IR study on CO2 hydrogenation over Cu catalysts supported on SiO2, A12O3, and TiO2. Appl Catal A 165:391–409
Din IU, Shaharun MS, Subbarao D, Naeem A (2015) Synthesis, characterization and activity pattern of carbon nanofibers based copper/zirconia catalysts for carbon dioxide hydrogenation to methanol: Influence of calcinations temperature. J Power Sour 274:619–628
Bell AT (2001) Molecular design of highly active methanol synthesis catalysts. Stud Surf Sci Catal 136:13–19
Guo XM, Mao DS, Lu GZ, Wang S, Wu GS (2011) The influence of La doping on the catalytic behavior of Cu/ZrO2 for methanol synthesis from CO2 hydrogenation. J Mol Catal A 345:60–68
Arena F, Mezzatesta G, Zafaana G, Trunfio G, Frusteri F, Spadaro L (2013) How oxide carriers control the catalytic functionality of Cu-ZnO system in the hydrogenation of CO2 to methanol. Catal Today 210:39–46
Bonura G, Arena F, Mezzatesta G, Cannilla C, Spadaro L, Frusteri F (2011) Role of the ceria promoter and carrier on the functionality of Cu-based catalysts in the CO2-to-methanol hydrogenation reaction. Catal Today 171:251–256
An B, Zhang J, Cheng K, Ji P, Wang C, Lin W (2017) Confinement of ultrasmall Cu/ZnOx nanoparticles in metal–organic frameworks for selective methanol synthesis from catalytic hydrogenation of CO2. J Am Chem Soc 139:3834–3840
Arakawa H, Dubois JL, Sayama K (1992) Selective conversion of CO2 to methanol by catalytic hydrogenation over promoted copper catalyst. Energy Convers Manag 33:521–528
An X, Li J, Zuo Y, Zhang Q, Wang D, Wang J (2007) A Cu/Zn/Al/Zr fibrous catalyst that is an improved CO2 hydrogenation to methanol catalyst. Catal Lett 118:264–269
Din IU, Shaharun MS, Naeem A, Tasleem S, Johan MR (2018) Carbon nanofibers based copper/zirconia catalysts for carbon dioxide hydrogenation to methanol: Effect of copper concentration. Chem Eng J 334:619–629
Ma Y, Sun Q, Wu D, Fan WH, Zhang YL, Deng JF (1998) A practical approach for the preparation of high activity Cu/ZnO/ZrO2 catalyst for methanol synthesis from CO2 hydrogenation. Appl Catal A 171:45–55
Jung KT, Bell AT (2002) Effects of zirconia phase on the synthesis of methanol over zirconia-supported copper. Catal Lett 80:63–68
Witoon T, Bumrungsalee S, Chareonpanich M, Limtrakul J (2015) Effect of hierarchical meso–macroporous alumina-supported copper catalyst for methanol synthesis from CO2 hydrogenation. Energy Convers Manag 103:886–894
Lei H, Nie RF, Wu GQ, Hou ZY (2015) Hydrogenation of CO2 to CH3OH over Cu/ZnO catalysts with different ZnO morphology. Fuel 154:161–166