In Situ Modification of Metal–Organic Frameworks in Mixed‐Matrix Membranes

Angewandte Chemie - International Edition - Tập 54 Số 31 - Trang 9029-9032 - 2015
Michael S. Denny1, Seth M. Cohen1
1Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093 USA

Tóm tắt

AbstractProcessable films of metal–organic frameworks (MOFs) have been long sought to advance the application of MOFs in various technologies from separations to catalysis. Herein, MOF–polymer mixed‐matrix membranes (MMMs) are described, formed on several substrates using a wide variety of MOF materials. These MMMs can be delaminated from their substrates to create free‐standing MMMs that are mechanically stable and pliable. The MOFs in these MMMs remain highly crystalline, porous, and accessible for further chemical modification through postsynthetic modification (PSM) and postsynthetic exchange (PSE) processes. Overall, the findings here demonstrate a versatile approach to preparing stable functional MMMs that should contribute significantly to the advancement of these materials.

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Tài liệu tham khảo

 

10.1002/anie.200300636

10.1002/adma.201002854

10.1039/B618320B

10.1002/9783527635856.ch15

 

10.1126/science.1230444

10.1021/cr200190s

10.1002/anie.200906491

10.1002/ange.200906491

10.1021/cr200167v

10.1039/B511962F

10.1016/j.ces.2014.10.007

 

10.1016/j.micromeso.2012.03.012

10.1021/ie202038m

10.1039/C4CS00159A

10.1039/C4CS00437J

10.1016/j.micromeso.2009.11.035

10.1021/ja407665w

10.1002/pssr.201004200

10.1021/cr200304e

 

10.1016/j.memsci.2009.07.051

10.1016/j.memsci.2010.06.017

10.1016/j.memsci.2011.10.003

10.1016/j.seppur.2011.06.037

10.1002/anie.201403978

10.1002/ange.201403978

10.1002/anie.201500207

10.1002/ange.201500207

 

10.1039/c3ta10766c

10.1021/ie400149e

10.1021/cr200179u

 

10.1016/j.memsci.2008.01.005

10.1002/cphc.201100583

 

10.1002/adfm.201002529

10.1002/adma.201301626

10.1021/ja2002428

10.1021/ja8057953

10.1126/science.283.5405.1148

 

10.1126/science.1116275

10.1021/ja906198y

 

10.1021/ja0276974

10.1002/anie.200705607

10.1002/ange.200705607

10.1073/pnas.0602439103

10.1039/c0cc02990d

 

10.1002/anie.201104383

10.1002/ange.201104383

10.1016/j.memsci.2011.08.042

10.1021/ma902303e

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Angewandte Chemie - International Edition

Tập 54 Số 31

9029-9032

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