Retention of radionuclides in sol–gel surrogate nuclear explosive debris
Tóm tắt
Sol–gel vitrification can be used to rapidly produce solid, vitreous materials to support nuclear forensics research. This work investigates three sol–gel synthetic approaches’ ability to retain fission products within the glass as a function of drying temperature. Eight of the ten fission products studied were quantitatively retained (less than 5% losses) at temperatures up to 600 °C for glasses prepared using an acidic catalyst and at temperatures up to 300 °C for glasses prepared using a basic catalyst. Both systems show partial loss of ruthenium and complete loss of iodine at temperatures above 300 and 100 °C, respectively.