Cold programming of epoxy-based shape memory polymer

Ferrera DA. Shape memory polymer intravascular delivery system with heat transfer medium. U.S. Patent 6,224,610, issued May 1, 2001. Lendlein, 2002, Biodegradable, elastic shape-memory polymers for potential biomedical applications, Science, 296, 1673, 10.1126/science.1066102 Kelch, 2007, Shape-memory polymer networks from oligo [(ε-hydroxycaproate)-co-glycolate]dimethacrylates and butyl acrylate with adjustable hydrolytic degradation rate, Biomacromolecules, 8, 1018, 10.1021/bm0610370 Metcalfe, 2003, Cold hibernated elastic memory foams for endovascular interventions, Biomaterials, 24, 491, 10.1016/S0142-9612(02)00362-9 Lendlein A, Langer R. Self-expanding device for the gastrointestinal or urogenital area. U.S. Patent filed June 29, 2006; Application 10/546,092. Meng, 2007, Morphology, phase separation, thermal and mechanical property differences of shape memory fibres prepared by different spinning methods, Smart Mater Struct, 16, 1192, 10.1088/0964-1726/16/4/030 Mu, 2018, Shape memory polymers for composites, Compos Sci Technol, 160, 169, 10.1016/j.compscitech.2018.03.018 Charlesby, 1960, 198 Lan, 2008, Improving the electrical conductivity by forming Ni powder chains in a shape-memory polymer filled with carbon black, Electroact. Polym. Actuators Devices, 6927 Chen, 2009, The characteristics and in vivo suppression of neointimal formation with sirolimus-eluting polymeric stents, Biomaterials, 30, 79, 10.1016/j.biomaterials.2008.09.006 Benett, William J., Peter A. Krulevitch, Abraham P. Lee, Milton A. Northrup, and James A. Folta. Miniature plastic gripper and fabrication method. No. US 5609608. Lawrence Livermore National Lab.(LLNL), Livermore, CA (United States), 1997. McKnight, 2008, Large strain variable stiffness composites for shear deformations with applications to morphing aircraft skins, Behav. Mech. Multifunct. Compos. Mater., 6929 Yin, 2009, Structural shape sensing for variable camber wing using FBG sensors, Sensors Smart Struct. Technol. Civil, Mech. Aerosp. Syst., 7292, 72921H Rodriguez, 2011, Linear/network poly (ε-caprolactone)blends exhibiting shape memory assisted self-healing (SMASH), ACS Appl Mater Interfaces, 3, 152, 10.1021/am101012c Wornyo, 2007, Nanoindentation of shape memory polymer networks, Polymer (Guildf), 48, 3213, 10.1016/j.polymer.2007.03.029 Liu, 2007, Review of progress in shape-memory polymers, J Mater Chem, 17, 1543, 10.1039/b615954k Liu, 2017, Stimulus methods of multi-functional shape memory polymer nanocomposites: a review, Compos Part A Appl Sci Manuf, 100, 20, 10.1016/j.compositesa.2017.04.022 Meng, 2009, A review of shape memory polymer composites and blends, Compos Part A Appl Sci Manuf, 40, 1661, 10.1016/j.compositesa.2009.08.011 Lendlein, 2002, Shape-memory polymers, Angew Chemie Int Ed, 41, 2034, 10.1002/1521-3773(20020617)41:12<2034::AID-ANIE2034>3.0.CO;2-M Leng, 2011, Shape-memory polymers and their composites: stimulus methods and applications, Prog Mater Sci, 56, 1077, 10.1016/j.pmatsci.2011.03.001 Tobushi, 1992, Mechanical properties of shape memory polymer of polyurethane series: basic characteristics of stress-strain-temperature relationship. JSME Int Journal Ser 1, Solid Mech, Strength Mater, 35, 296 Pieczyska, 2009, Thermomechanical properties of shape memory polymer subjected to tension in various conditions, Quant Infrared Thermogr J, 6, 189, 10.3166/qirt.6.189-205 Keihl MM, Bortolin RS, Sanders B, Joshi S, Tidwell Z. Mechanical properties of shape memory polymers for morphing aircraft applications. Smart Struct. Mater. 2005 Ind. Commer. Appl. Smart Struct. Technol., vol. 5762, 2005, p. 143–51. Safranski DL, Griffis JC. Mechanical properties of shape-memory polymers for biomedical applications. Shape Mem. Polym. Biomed. Appl., Elsevier; 2015, p. 9–33. Sokolowski, 2007, Advanced self-deployable structures for space applications, J Spacecr Rockets, 44, 750, 10.2514/1.22854 Sun, 2015, Mechanical properties of shape memory polymer composites enhanced by elastic fibers and their application in variable stiffness morphing skins, J Intell Mater Syst Struct, 26, 2020, 10.1177/1045389X14546658 Xiao, 2015, Shape memory polymers with high and low temperature resistant properties, Sci Rep, 5, 14137, 10.1038/srep14137 Sun, 2012, Stimulus-responsive shape memory materials: a review, Mater Des, 33, 577, 10.1016/j.matdes.2011.04.065 Wang, 2017, The study of thermal, mechanical and shape memory properties of chopped carbon fiber-reinforced tpi shape memory polymer composites, Polymers (Basel), 9, 594, 10.3390/polym9110594 Vijayan PP. Mechanical Properties of Shape-Memory Polymers, Polymer Blends, and Composites. Shape Mem. Polym. Blends Compos., Springer; 2020, p. 199–217. Li, 2011, Thermomechanical behavior of thermoset shape memory polymer programmed by cold-compression: testing and constitutive modeling, J Mech Phys Solids, 59, 1231, 10.1016/j.jmps.2011.03.001 Abishera, 2016, Reversible plasticity shape memory effect in carbon nanotubes reinforced epoxy nanocomposites, Compos Sci Technol, 137, 148, 10.1016/j.compscitech.2016.10.030 Xie, 2011, Recent advances in polymer shape memory, Polymer (Guildf), 52, 4985, 10.1016/j.polymer.2011.08.003 Zhang, 2016, Reversible plasticity shape memory polymers: key factors and applications, J Polym Sci Part B Polym Phys, 54, 1295, 10.1002/polb.23916 Xie, 2009, Facile tailoring of thermal transition temperatures of epoxy shape memory polymers, Polymer (Guildf), 50, 1852, 10.1016/j.polymer.2009.02.035 Liu, 2004, High thermal conductivity shape memory polymers. ANTEC 2004-Annual Tech, Conf. Proc., 3080 Li, 2016, Cold, warm, and hot programming of shape memory polymers, J Polym Sci Part B Polym Phys, 54, 1319, 10.1002/polb.24041 Feldkamp, 2010, Effect of the deformation temperature on the shape-memory behavior of epoxy networks, Macromol Mater Eng, 295, 726, 10.1002/mame.201000035