Robust, Self‐Healing Superamphiphobic Fabrics Prepared by Two‐Step Coating of Fluoro‐Containing Polymer, Fluoroalkyl Silane, and Modified Silica Nanoparticles

Advanced Functional Materials - Tập 23 Số 13 - Trang 1664-1670 - 2013
Hua Zhou1, Hongxia Wang1, Haitao Niu1, Adrian Gestos1, Tong Lin1
1Australian Future Fibres Research and Innovation Centre, Deakin University, Geelong, VIC 3216, Australia

Tóm tắt

AbstractA robust, superamphiphobic fabric with a novel self‐healing ability to autorepair from chemical damage is prepared by a two‐step wet‐chemistry coating technique using an easily available material system consisting of poly(vinylidene fluoride‐co‐hexafluoropropylene), fluoroalkyl silane, and modified silica nanoparticles. The coated fabrics can withstand at least 600 cycles of standard laundry and 8000 cycles of abrasion without apparently changing the superamphiphobicity. The coating is also very stable to strong acid/base, ozone, and boiling treatments. After being damaged chemically, the coating can restore its super liquid‐repellent properties by a short‐time heating treatment or room temperature ageing. This simple but novel and effective coating system may be useful for the development of robust protective clothing for various applications.

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Tài liệu tham khảo

10.1126/science.1207115

10.1126/science.1148326

10.1039/b602486f

10.1002/ange.200704694

10.1002/adma.201002689

10.1002/adma.200306281

10.1002/adma.200501961

10.1021/nl8037272

10.1039/b717734h

10.1146/annurev.matsci.38.060407.132434

10.1002/adma.201100410

10.1002/adma.201003129

10.1021/jp052691x

10.1002/adfm.200800755

10.1002/adma.201002614

10.1021/la300281q

10.1002/anie.201001258

10.1039/C0CC04066E

10.1002/adma.201200184

10.1002/anie.201105069

10.1039/B714352D

10.1021/la0344682

10.1016/j.cplett.2007.11.033

10.1002/adma.201200807