On the formulation of rheological equations of state

The Royal Society - Tập 200 Số 1063 - Trang 523-541 - 1950
J. G. Oldroyd1
1Courtaulds Limited, Research Laboratory, Maidenhead, Berks.

Tóm tắt

The invariant forms of rheological equations of state for a homogeneous continuum, suitable for application to all conditions of motion and stress, are discussed. The right invariance properties can most readily be recognized if the frame of reference is a co-ordinate system convected with the material, but it is necessary to transform to a fixed frame of reference in order to solve the equations of state simultaneously with the equations of continuity and of motion. An illustration is given of the process of formulating equations of state suitable for universal application, based on non-invariant equations obtained from a simple experiment or structural theory. Anisotropic materials, and materials whose properties depend on previous rheological history, are included within the scope of the paper.

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Tài liệu tham khảo

Boltzmann L., 1876, Ann. Phys. Chem. (Poggendorff), Erganzungsband, 7, 624

10.1051/anphys/192510030251

Buggers J. M. 1935 First report on viscosity and plasticity chap. 1. Royal Netherlands Academy of Sciences.

Frdhlich H., 1946, Proc. Roy, Soc. A, 185, 415

Hencky H. 1925 Z.angew. Math. Mech.

Jeffreys H. 1931 Cartesian tensors chap. vm . Cambridge University Press.

Mumaghan F. D., 1937, Amer, J. Math., 59, 235

10.2307/2372342

Reiner M. 1949 Deformation and flow pp. 321-325. London: Lewis.

Rivlin R. S., 1948, Proc. Roy, Soc. A, 193, 260

Volterra V. 1909 R.C. Accad. Lincei (5) 18 295 577.

Weissenberg K. 1947 Nature 159 310.

Weissenberg K., 1948, Proc. Int. Rheological Congr. Holland, 1, 29

various liquids and has been attributed by him to a combination of viscous and elastic

properties giving rise to a tensile stress in the direction of the streamlines (<?><£'>0 as in

material B). [Note added 29 October 1949.] Reiner (1948 1949) regards the effect observed by Weissenberg

as a manifestation of cross-elasticity a term used of materials in which a single applied shear

stress gives rise to elastic strains in all directions. On the other hand Rivlin (1948) has shown

in detail how the same phenomenon could arise in a non-Newtonian viscous liquid exhibiting

no elasticity but is mistaken in suggesting that elastic properties could not be a contributory

cause. (His argument is that the 'time derivatives of the stress components *which occur in the

equations of state of an elastic liquid vanish in a steady state of flow so that the equations of

state are then indistinguishable from those of an inelastic liquid. In fact the simplest equations

of state representing elastico-viscous behaviour must be expressible as equations relating the

rate-of-strain tensor the stress tensor and the convected derivative of the stress tensor.

In a steady state partial time derivatives in an Eulerian system of reference vanish but the

convected derivative of the stress tensor does not vanish and does not reduce to an algebraic

combination of the stress and rate-of-strain tensors. Therefore an elastico-viscous liquid will in

general behave differently from any inelastic viscous liquid even in steady-state experiments.)