Highly active and selective Cu-ZnO based catalyst for methanol and dimethyl ether synthesis via CO2 hydrogenation

Fuel - Tập 239 - Trang 1125-1133 - 2019
Shoujie Ren1, Weston R. Shoemaker2, Xiaofeng Wang2, Zeyu Shang2, Naomi Klinghoffer3, Shiguang Li3, Miao Yu4, Xiaoqing He5,6, Tommi A. White5, Xinhua Liang2
1Department of Chemical and Biochemical Engineering, Missouri University of Science and Technology, Rolla, MO, 65409, United States
2Department of Chemical and Biochemical Engineering, Missouri University of Science and Technology, Rolla, MO 65409, United States
3Gas Technology Institute, 1700 South Mount Prospect Road, Des Plaines, IL 60018, United States
4Department of Chemical and Biological Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180, United States
5Electron Microscopy Core Facility, University of Missouri, Columbia, MO 65211, United States
6Department of Mechanical and Aerospace Engineering, University of Missouri, Columbia, MO 65211, United States

Tài liệu tham khảo

Hu, 2013, Thermal, electrochemical, and photochemical conversion of CO2 to fuels and value-added products, J CO2 Util, 1, 18, 10.1016/j.jcou.2013.03.004 Song, 2006, Global challenges and strategies for control, conversion and utilization of CO2 for sustainable development involving energy, catalysis, adsorption and chemical processing, Catal Today, 115, 2, 10.1016/j.cattod.2006.02.029 Liu, 2015, Using carbon dioxide as a building block in organic synthesis, Nature Commun, 6, 5933, 10.1038/ncomms6933 Saeidi, 2014, Hydrogenation of CO2 to value-added products: a review and potential future developments, J CO2 Util, 5, 66, 10.1016/j.jcou.2013.12.005 Tilak, 2018, Process integration of calcium looping with industrial plants for monetizing CO2 into value-added products, Carbon Resour Convers, 1, 191, 10.1016/j.crcon.2018.07.004 Alvarez, 2017, Challenges in the greener production of formates/formic acid, methanol, and DME by heterogeneously catalyzed CO2 hydrogenation processes, Chem Rev, 117, 9804, 10.1021/acs.chemrev.6b00816 Bonura, 2014, Catalytic behaviour of a bifunctional system for the one step synthesis of DME by CO2 hydrogenation, Catal Today, 228, 51, 10.1016/j.cattod.2013.11.017 Erena, 2005, Effect of operating conditions on the synthesis of dimethyl ether over a CuO-ZnO-Al2O3/NaHZSM-5 bifunctional catalyst, Catal Today, 107–108, 467, 10.1016/j.cattod.2005.07.116 Aguayo, 2005, Deactivation and regeneration of hybrid catalysts in the single-step synthesis of dimethyl ether from syngas and CO2, Catal Today, 106, 265, 10.1016/j.cattod.2005.07.144 Kattel, 2017, Catalysis active sites for CO2 hydrogenation to methanol on Cu/ZnO catalysts, Science, 355, 1296, 10.1126/science.aal3573 Guo, 2011, CO2 hydrogenation to methanol over Cu/ZnO/ZrO2 catalysts prepared via a route of solid-state reaction, Catal Commun, 12, 1095, 10.1016/j.catcom.2011.03.033 Hong, 2002, CO2 hydrogenation to methanol over Cu/ZnO/Al2O3 catalysts prepared by a novel gel-network-coprecipitation method, Catal Lett, 82, 37, 10.1023/A:1020531822590 Li, 2014, Development of highly stable catalyst for methanol synthesis from carbon dioxide, Appl Catal A: Gen, 469, 306, 10.1016/j.apcata.2013.10.010 Kim, 2003, The preparation and characterisation of Pd-ZnO catalysts for methanol synthesis, Top Catal, 22, 319, 10.1023/A:1023596524663 Liang, 2009, Carbon nanotube-supported Pd-ZnO catalyst for hydrogenation of CO2 to methanol, Appl Catal B, 88, 315, 10.1016/j.apcatb.2008.11.018 Xu, 2016, Methanol synthesis from CO2 and H2 over Pd/ZnO/Al2O3: catalyst structure dependence of methanol selectivity, Appl Catal A: Gen, 514, 51, 10.1016/j.apcata.2016.01.006 Bahruji, 2016, Pd/ZnO catalysts for direct CO2 hydrogenation to methanol, J Catal, 343, 133, 10.1016/j.jcat.2016.03.017 Jiang, 2015, Bimetallic Pd-Cu catalysts for selective CO2 hydrogenation to methanol, Appl Catal B: Environ, 170, 173, 10.1016/j.apcatb.2015.01.010 Jadhav, 2014, Catalytic carbon dioxide hydrogenation to methanol: a review of recent studies, Chem Eng Res Des, 92, 2557, 10.1016/j.cherd.2014.03.005 Budiman, 2013, Design and preparation of high-surface-area Cu/ZnO/Al2O3 catalysts using a modified co-precipitation method for the water-gas shift reaction, Appl Catal A: Gen, 462, 220, 10.1016/j.apcata.2013.05.010 Ladera, 2013, Catalytic valorization of CO2 via methanol synthesis with Ga-promoted Cu-ZnO-ZrO2 catalysts, Appl Catal B: Environ, 142, 241, 10.1016/j.apcatb.2013.05.019 Toyir, 2015, Ga-promoted copper-based catalysts highly selective for methanol steam reforming to hydrogen; relation with the hydrogenation of CO2 to methanol, Int J Hydrogen Energy, 40, 11261, 10.1016/j.ijhydene.2015.04.039 Qu, 2014, Shape effect of Pd-promoted Ga2O3 nanocatalysts for methanol synthesis by CO2 hydrogenation, J Phys Chem C, 118, 24452, 10.1021/jp5063379 Behrens, 2013, How to prepare a good Cu/ZnO catalyst or the role of solid state chemistry for the synthesis of nanostructured catalysts, Z Anorg Allg Chem, 639, 2683, 10.1002/zaac.201300356 Sun, 1997, A novel process for the preparation of Cu/ZnO and Cu/ZnO/Al2O3 ultrafine catalyst: structure, surface properties, and activity for methanol synthesis from CO2+H2, J Catal, 167, 92, 10.1006/jcat.1997.1554 Schumann, 2014, Synthesis and characterisation of a highly active Cu/ZnO: Al catalyst, ChemCatChem, 6, 2889, 10.1002/cctc.201402278 Behrens, 2012, The active site of methanol synthesis over Cu/ZnO/Al2O3 industrial catalysts, Science, 336, 893, 10.1126/science.1219831 Spencer, 1999, The role of zinc oxide in Cu/ZnO catalysts for methanol synthesis and the water–gas shift reaction, Top Catal, 8, 259, 10.1023/A:1019181715731 An, 2017, Confinement of ultrasmall Cu/ZnOx nanoparticles in metal–organic frameworks for selective methanol synthesis from catalytic hydrogenation of CO2, J Am Chem Soc, 139, 3834, 10.1021/jacs.7b00058 Palomino, 2017, Hydrogenation of CO2 on ZnO/Cu (100) and ZnO/Cu (111) catalysts: role of copper structure and metal–oxide interface in methanol synthesis, J Phys Chem B, 122, 794, 10.1021/acs.jpcb.7b06901 Lunkenbein, 2015, Formation of a ZnO overlayer in industrial Cu/ZnO/Al2O3 catalysts induced by strong metal–support Interactions, Angew Chem, 127, 4627, 10.1002/ange.201411581 Witoon, 2018, Enhanced activity, selectivity and stability of a CuO-ZnO-ZrO2 catalyst by adding graphene oxide for CO2 hydrogenation to methanol, Chem Eng J, 334, 1781, 10.1016/j.cej.2017.11.117 Tursunov, 2017, Methanol synthesis from the catalytic hydrogenation of CO2 over CuO–ZnO supported on aluminum and silicon oxides, J Taiwan Inst Chem E, 78, 416, 10.1016/j.jtice.2017.06.049 Bahmani, 2016, Preparation of high performance nano-sized Cu/ZnO/Al2O3 methanol synthesis catalyst via aluminum hydrous oxide sol, Appl Catal A: Gen, 520, 178, 10.1016/j.apcata.2016.04.018 Siriworarat, 2017, Production of methanol from carbon dioxide using palladium-copper-zinc loaded on MCM-41: comparison of catalysts synthesized from flame spray pyrolysis and sol-gel method using silica source from rice husk ash, J Clean Prod, 142, 1234, 10.1016/j.jclepro.2016.07.099 Witoon, 2016, Tuning of catalytic CO2 hydrogenation by changing composition of CuO–ZnO–ZrO2 catalysts, Energy Convers Manage, 118, 21, 10.1016/j.enconman.2016.03.075 Bansode, 2014, Towards full one-pass conversion of carbon dioxide to methanol and methanol-derived products, J Catal, 309, 66, 10.1016/j.jcat.2013.09.005 Bonura, 2016, Catalytic features of CuZnZr-zeolite hybrid systems for the direct CO2-to-DME hydrogenation reaction, Catal Today, 277, 48, 10.1016/j.cattod.2016.02.013 Frusteri, 2017, Direct CO2-to-DME hydrogenation reaction: new evidences of a superior behaviour of FER-based hybrid systems to obtain high DME yield, J CO2 Util, 18, 353, 10.1016/j.jcou.2017.01.030 Aguayo, 2007, Kinetic modeling of dimethyl ether synthesis in a single step on a CuO-ZnO-Al2O3/gamma-Al2O3 catalyst, Ind Eng Chem Res, 46, 5522, 10.1021/ie070269s Sierra, 2010, Deactivation kinetics for direct dimethyl ether synthesis on a CuO-ZnO-Al2O3/gamma-Al2O3 Catalyst, Ind Eng Chem Res, 49, 481, 10.1021/ie900978a Ateka, 2016, Performance of CuO–ZnO–ZrO2 and CuO–ZnO–MnO as metallic functions and SAPO-18 as acid function of the catalyst for the synthesis of DME co-feeding CO2, Fuel Process Technol, 152, 34, 10.1016/j.fuproc.2016.05.041 Fichtl, 2015, Kinetics of deactivation on Cu/ZnO/Al2O3 methanol synthesis catalysts, Appl Catal A: Gen, 502, 262, 10.1016/j.apcata.2015.06.014 Bonura, 2018, Acidity control of zeolite functionality on activity and stability of hybrid catalysts during DME production via CO2 hydrogenation, J CO2 Util, 24, 398, 10.1016/j.jcou.2018.01.028 Abu-Dahrieh, 2012, Activity and deactivation studies for direct dimethyl ether synthesis using CuO–ZnO–Al2O3 with NH4ZSM-5, HZSM-5 or γ-Al2O3, Chem Eng J, 203, 201, 10.1016/j.cej.2012.07.011 Baltes, 2008, Correlations between synthesis, precursor, and catalyst structure and activity of a large set of CuO/ZnO/Al2O3 catalysts for methanol synthesis, J Catal, 258, 334, 10.1016/j.jcat.2008.07.004 Liao, 2011, Morphology dependent interactions of ZnO with Cu nanoparticles at the materials’ interface in selective hydrogenation of CO2 to CH3OH, Angew Chem Int Ed, 50, 2162, 10.1002/anie.201007108 Arena, 2007, Synthesis, characterization and activity pattern of Cu–ZnO/ZrO2 catalysts in the hydrogenation of carbon dioxide to methanol, J Catal, 249, 185, 10.1016/j.jcat.2007.04.003 Schumann, 2016, Cu, Zn-based catalysts for methanol synthesis: on the effect of calcination conditions and the part of residual carbonates, Appl Catal A: Gen, 516, 117, 10.1016/j.apcata.2016.01.037 Uslu, 2008, Pre-treatment technologies, and their effect on international bioenergy supply chain logistics. Techno-economic evaluation of torrefaction, fast pyrolysis and pelletisation, Energy, 33, 1206, 10.1016/j.energy.2008.03.007 Sun, 1999, Deactivation of Cu/ZnO/Al2O3 methanol synthesis catalyst by sintering, Ind Eng Chem Res, 38, 3868, 10.1021/ie990078s Erena, 2008, Deactivation of a CuO-ZnO-Al2O3/gamma-Al2O3 catalyst in the synthesis of dimethyl ether, Ind Eng Chem Res, 47, 2238, 10.1021/ie071478f Lorenzut, 2011, Hydrogen production through alcohol steam reforming on Cu/ZnO-based catalysts, Appl Catal B: Environ, 101, 397, 10.1016/j.apcatb.2010.10.009