A novel hyperbranched aromatic polyamide containing bithiazole: Synthesis, metal complexation and magnetic properties

Science in China Series B: Chemistry - Tập 54 - Trang 320-325 - 2011
NengWen Ding1, WeiHong Lin1, WeiLin Sun1, ZhiQuan Shen1
1Key Laboratory of Macromolecule Synthesis and Functionalization, Ministry of Education, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, China

Tóm tắt

Based on the polycondensation of bifunctional 2,2′-diamino-4, 4′-bithiazole(DABT) and trifunctional 1,3,5-benzenetricarbonyl trichloride (BTC), a novel hyperbranched aromatic polyamide PBD was synthesized with excellent solubility and good thermal stability. The structure of the polymer was confirmed by FT-IR and 1H NMR spectrum. The calculated degree of branching of our product was 52%. By exploring the influence of several different solvent systems, the yield of the polymer increased in the solvent system of DMAc/LiCl. Two kinds of metal complexes were obtained by chelation of the polyamide with Cu2+ and Ni2+, and the metal contents of the complexes were determined by complexometric titration. The magnetic behaviors of the complexes were examined as a function of magnetic field strength at 5 K, and as a function of temperature (5–300 K) at a magnetic field strength of 2.4 × 106 A/m. The results indicated that the complexes were soft ferromagnetic materials with Curie-Weiss temperature at 102 K and 53 K, respectively.

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