Binding Fe2O3 nanoparticles in polydopamine-reduced graphene as negative electrode materials for high-performance asymmetric supercapacitors

Springer Science and Business Media LLC - Tập 21 - Trang 1-12 - 2019
Jinjun Tian1,2, Yan Xue2, Xinping Yu1, Yuanchao Pei1, Hucheng Zhang1, Jianji Wang1
1Collaborative Innovation Centre of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, China
2School of Biological and Chemical Engineering, Nanyang Institute of Technology, Nanyang, China

Tóm tắt

Ternary composite with immobilization of Fe2O3 nanoparticles (NPs) onto porous polydopamine-reduced graphene oxide framework, abbreviated as Fe2O3@PDA-RGO, was fabricated via a simple, scalable and cost-efficient hydrothermal reaction. The as-prepared 3D Fe2O3@PDA-RGO nanocomposite provides a specific surface area of 119.9 m2 g-1 on account of the well-dispersed Fe2O3 NPs (~35 nm) onto the PDA-RGO sheets as spacer. When applied as a special faradic electrode material in negative potential region, Fe2O3@PDA-RGO can offer 169 mA h g-1 (609 F g−1) at 1 A g-1. The fabricated AC//Fe2O3@PDA-RGO asymmetric supercapacitor (ASC) delivers an energy density of 35.8 W h kg-1 (0.94 mW h cm-3) at 800 W kg-1 (21 mW cm-3) and an outstanding cyclic stability (75.7% capacity retention after 10,000 cycles). The good performance of Fe2O3@PDA-RGO in single-electrode and ASC manifests the potential the ternary composite in energy storage devices.

Tài liệu tham khảo

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