Dimethyl ether production from CO2 rich feedstocks in a one-step process: Thermodynamic evaluation and reactor simulation

Chemical Engineering Journal - Tập 294 - Trang 400-409 - 2016
Marcello De Falco1, Mauro Capocelli1, Gabriele Centi2
1Unit of Process Engineering, Department of Engineering, Università Campus Bio-Medico di Roma, via Álvaro del Portillo 21, 00128 Rome, Italy
2University of Messina and INSTM/CASPE, Dipartimento di Chimica Industriale ed Ingegneria dei Materiali, V.le F. Stagno D’Alcontres 31, 98166 Messina, Italy

Tài liệu tham khảo

Naik, 2011, Synthesis of DME from CO2/H2 gas mixture, Chem. Eng. J., 167, 362, 10.1016/j.cej.2010.12.087 Azizi, 2014, Dimethyl ether: a review of technologies and production challenges, Chem. Eng. Proc., 82, 150, 10.1016/j.cep.2014.06.007 Goeppert, 2014, Recycling of carbon dioxide to methanol and derived products – closing the loop, Chem. Soc. Rev., 43, 7995, 10.1039/C4CS00122B Lanzafame, 2014, Catalysis for biomass and CO2 use through solar energy: opening new scenarios for a sustainable and low-carbon chemical production, Chem. Soc. Rev., 43, 7562, 10.1039/C3CS60396B Centi, 2013, Catalysis for CO2 conversion: a key technology for rapid introduction of renewable energy in the value chain of chemical industries, Energy Env. Sci., 6, 1711, 10.1039/c3ee00056g Fleisch, 2012, Introduction and advancement of a new clean global fuel: the status of DME developments in China and beyond, J. Nat. Gas Sci. Eng., 9, 94, 10.1016/j.jngse.2012.05.012 Park, 2014, Applicability of dimethyl ether (DME) in a compression ignition engine as an alternative fuel, Energy Conv. Manag., 86, 848, 10.1016/j.enconman.2014.06.051 Laosiripojana, 2014, Synthetic fuel production from the catalytic thermochemical conversion of carbon dioxide, 215 Tian, 2015, Methanol to olefins (MTO): from fundamentals to commercialization, ACS Catal., 5, 1922, 10.1021/acscatal.5b00007 Migliori, 2014, Kinetic analysis of methanol to dimethyl ether reaction over H-MFI catalyst, Ind. Eng. Chem. Res., 53, 14885, 10.1021/ie502775u Sun, 2014, Catalysis chemistry of dimethyl ether synthesis, ACS Catal., 4, 3346, 10.1021/cs500967j Peral, 2015, Optimal Production of dimethyl ether from switchgrass-based syngas via direct synthesis, Ind. Eng. Chem. Res., 54, 7465, 10.1021/acs.iecr.5b00823 Frusteri, 2015, Stepwise tuning of metal-oxide and acid sites of CuZnZr-MFI hybrid catalysts for the direct DME synthesis by CO2 hydrogenation, Appl. Catal. B: Env., 176–177, 522, 10.1016/j.apcatb.2015.04.032 Liu, 2014, Gasoline from Coal via DME with electricity co-production and CO2 capture, Energy Proc., 63, 7367, 10.1016/j.egypro.2014.11.773 Kim, 2012, Design modification study on DME direct synthesis technology, Computer-Aided Chem. Eng., 31, 790, 10.1016/B978-0-444-59507-2.50150-5 Ampelli, 2015, CO2 utilization: an enabling element to move to a resource-and energy-efficient chemical and fuel production, Philos. Trans. R. Soc. London A, 373, 20140177, 10.1098/rsta.2014.0177 Perathoner, 2014, CO2 recycling: a key strategy to introduce green energy in the chemical production chain, ChemSusChem, 7, 1274, 10.1002/cssc.201300926 Tokay, 2012, Dimethyl ether synthesis over alumina based catalysts, Chem. Eng. J., 184, 278, 10.1016/j.cej.2011.12.034 Diban, 2014, Improved performance of a PBM reactor for simultaneous CO2 capture and DME synthesis, Ind. Eng. Chem. Res., 53, 19479, 10.1021/ie503663h Huang, 2015, An experimental study on single-step dimethyl ether (DME) synthesis from hydrogen and carbon monoxide under various catalysts, Int. J. Hydrogen Energy, 40, 13583, 10.1016/j.ijhydene.2015.07.168 Qin, 2015, Experimental and theoretical study of the intrinsic kinetics for dimethyl ether synthesis from CO2 over Cu–Fe–Zr/HZSM-5, AIChE J., 61, 1613, 10.1002/aic.14743 Witoon, 2015, Direct synthesis of dimethyl ether from CO2 hydrogenation over Cu–ZnO–ZrO2/SO42−–ZrO2 hybrid catalysts: effects of sulfur-to-zirconia ratios, Catal. Sci. Technol., 5, 2347, 10.1039/C4CY01568A Oyola-Rivera, 2015, CO2 hydrogenation to methanol and dimethyl ether by Pd–Pd2Ga catalysts supported over Ga2O3 polymorphs, J. CO2 Util., 9, 8, 10.1016/j.jcou.2014.11.003 Zhang, 2015, A conceptual design by integrating dimethyl ether (DME) production with tri-reforming process for CO2 emission reduction, Fuel Proc. Technol., 131, 7, 10.1016/j.fuproc.2014.11.006 Mao, 2014, Dimethyl ether synthesis from syngas over the admixed Cu/ZnO/Al2O3 catalyst and alkaline earth oxide-modified HZSM-5 zeolite, Energy Technol., 2, 882, 10.1002/ente.201402071 Frusteri, 2015, Multifunctionality of Cu–ZnO–ZrO2/H-ZSM5 catalysts for the one-step CO2-to-DME hydrogenation reaction, App. Catal. B: Env., 162, 10.1016/j.apcatb.2014.06.035 Zhang, 2014, V-modified CuO–ZnO–ZrO2/HZSM-5 catalyst for efficient direct synthesis of DME from CO2 hydrogenation, Catal. Commun., 55, 49, 10.1016/j.catcom.2014.05.026 Pontzen, 2011, CO2-based methanol and DME – efficient technologies for industrial scale production, Catal. Today, 171, 242, 10.1016/j.cattod.2011.04.049 Chen, 2012, One-step synthesis of dimethyl ether from the gas mixture containing CO2 with high space velocity, Appl. Energy, 98, 92, 10.1016/j.apenergy.2012.02.082 Bozga, 2013, Dimethyl ether synthesis catalysts, processes and reactors, Recent Pat. Catal., 2, 68, 10.2174/2211548X11302010004 Falabella, 2011, Catalysis involved in dimethylether production and as an intermediate in the generation of hydrocarbons via Fischer–Tropsch synthesis and MTG process, Catalysis, 23, 284, 10.1039/9781849732772-00284 Diban, 2013, Influence of the membrane properties on the catalytic production of dimethyl ether with in situ water removal for the successful capture of CO2, Chem. Eng. J., 234, 140, 10.1016/j.cej.2013.08.062 Iliuta, 2010, Dimethyl ether synthesis with in situ H2O removal in fixed-bed membrane reactor: model and simulations, Ind. Eng. Chem. Res., 49, 6870, 10.1021/ie901726u Dadgar, 2015, Direct dimethyl ether synthesis from synthesis gas: the influence of methanol dehydration on methanol synthesis reaction, Catal. Today Centi, 2013, Advances in catalysts and processes for methanol synthesis from CO2, 147 Erena, 2011, Kinetic modelling of dimethyl ether synthesis from (H2+CO2) by considering catalyst deactivation, Chem. Eng. J., 174, 660, 10.1016/j.cej.2011.09.067 Pyatnitskii, 2009, Kinetic modeling for the conversion of synthesis gas to dimethyl ether on a mixed Cu–ZnO–Al2O3 catalyst with γ-Al2O3, Theor. Exp. Chem., 45, 325, 10.1007/s11237-009-9101-x Shim, 2009, Simulation of DME synthesis from coal syngas by kinetics model, Korean J. Chem. Eng., 26, 641, 10.1007/s11814-009-0107-9 An, 2008, Dimethyl ether synthesis from CO2 hydrogenation on a CuO–ZnO–Al2O3–ZrO2/HZSM-5 bifunctional catalyst, Ind. Eng. Chem. Res., 47, 6547, 10.1021/ie800777t Aguayo, 2007, Kinetic modeling of dimethyl ether synthesis in a single step on a CuO−ZnO−Al2O3/γ-Al2O3 catalyst, Ind. Eng. Chem. Res., 46, 5522, 10.1021/ie070269s Abu-Dahrieh, 2012, Activity and deactivation studies for direct dimethyl ether synthesis using CuO–ZnO–Al2O3 with NH4ZSM-5, HZSM-5 or γ-Al2O3, Chem. Eng. J., 203, 201, 10.1016/j.cej.2012.07.011 Khoshbin, 2013, Direct syngas to DME as a clean fuel: the beneficial use of ultrasound for the preparation of CuO–ZnO–Al2O3/HZSM-5 nanocatalyst, Chem. Eng. Res. Des., 91, 1111, 10.1016/j.cherd.2012.11.017 Allahyari, 2015, Direct synthesis of DME over nanostructured CuO–ZnO–Al2O3/HZSM-5 catalyst washcoated on high pressure microreactor: effect of catalyst loading and process condition on reactor performance, Chem. Eng. J., 262, 1175, 10.1016/j.cej.2014.10.062 Papari, 2014, DME direct synthesis from syngas in a large-scale three phase slurry bubble column reactor: transient modeling, Chem. Eng. Commun., 201, 612, 10.1080/00986445.2013.782292 Papari, 2012, Mathematical modeling of a slurry reactor for DME direct synthesis from syngas, J. Nat. Gas Chem., 21, 148, 10.1016/S1003-9953(11)60347-2 Moradi, 2014, A CFD simulation and optimization of the direct DME synthesis in a three dimensional fixed bed reactor, Petrol. Sci., 11, 323, 10.1007/s12182-014-0347-0 Clausen, 2011, Thermodynamic analysis of small-scale dimethyl ether (DME) and methanol plants based on the efficient two-stage gasifier, Energy, 36, 5805, 10.1016/j.energy.2011.08.047 Clausen, 2010, Technoeconomic analysis of a low CO2 emission dimethyl ether (DME) plant based on gasification of torrefied biomass, Energy, 35, 4831, 10.1016/j.energy.2010.09.004 Hayer, 2011, Synthesis of dimethyl ether from syngas in a microchannel reactor—simulation and experimental study, Chem. Eng. J., 167, 610, 10.1016/j.cej.2010.09.080 Vakili, 2011, Utilizing differential evolution (DE) technique to optimize operating conditions of an integrated thermally coupled direct DME synthesis reactor, Chem. Eng. J., 168, 321, 10.1016/j.cej.2011.01.032 Centi, 2013, Strategy and drivers for CO2 (Re)use Centi, 2014 Vakili, 2012, Incorporating differential evolution (DE) optimization strategy to boost hydrogen and DME production rate through a membrane assisted single-step DME heat exchanger reactor, J. Nat. Gas Sci. Eng., 9, 28, 10.1016/j.jngse.2012.05.006 Vakili, 2011, Direct dimethyl ether (DME) synthesis through a thermally coupled heat exchanger reactor, Appl. Energy, 88, 1211, 10.1016/j.apenergy.2010.10.023 Farsi, 2011, Modeling, simulation and control of dimethyl ether synthesis in an industrial fixed-bed reactor, Chem. Eng. Proc., 50, 85, 10.1016/j.cep.2010.11.013 Cho, 2011, Production of DME from CBM by KOGAS DME process, Trans. Korean Hydrogen New Energy Soc., 22, 925 Hu, 2008, Simulation and model design of pipe-shell reactor for the direct synthesis of dimethyl ether from syngas, J. Nat. Gas Chem., 17, 195, 10.1016/S1003-9953(08)60051-1 Wang, 2006, Influence of reaction conditions on methanol synthesis and WGS reaction in the syngas-to-DME process, J. Nat. Gas Chem., 15, 38, 10.1016/S1003-9953(06)60005-4 Green, 1999 De Santis, 1980 Bussche, 1996, A steady-state kinetic model for methanol synthesis and the water gas shift reaction on a commercial Cu/ZnO/Al2O3 catalyst, J. Catal., 161, 1, 10.1006/jcat.1996.0156 Herman, 1979, Catalytic synthesis of methanol from CO/H2: I. Phase composition, electronic properties, and activities of the Cu/ZnO/M2O3 catalysts, J. Catal., 56, 407, 10.1016/0021-9517(79)90132-5 Smith, 1980 Holman, 1989 Fogler, 1992 Reid, 1997 Moradi, 2011, Equilibrium calculations for direct synthesis of dimethyl ether from syngas, Can. J. Chem. Eng., 89, 108, 10.1002/cjce.20373 Wijngaarden, 1998