Solvent and pressure effects on the kinetics of reaction of manganese pentacarbonyl bromide with 2,2′-bipyridyl and on the charge-transfer spectrum of MnBr(bipy)(CO)3

Springer Science and Business Media LLC - Tập 13 - Trang 126-130 - 1988
Razak bin Ali1, John Burgess1, Pilar Guardado1
1Department of Chemistry, University of Leicester, Leicester, UK

Tóm tắt

Rate laws, rate constants, and activation volumes are reported for reaction of MnBr(CO)5 with 2,2′-bipyridyl and with 1, 10-phenanthroline in methanol. The activation volume of +22cm3 mol−1 is consistent with a predominantlyD mechanism (CO loss) in this medium, but in 50% aqueous methanol both the kinetic pattern and activation volumes in the region of −20 cm3 mol−1 for the MnBr(CO)5 + bipy reaction indicate a key role for bromide dissociation. The solvatochromic behaviour of the MnBr(bipy)(CO)3 product of these reactions is compared with that of other ternaryd 6-diimine complexes, and the piezochromic behaviour of its MLCT spectrum outlined.

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