Development of the plasma technology for the production of uranium oxides with a given oxygen coefficient for the fabrication of pelletized nuclear fuel

Inorganic Materials: Applied Research - Tập 6 - Trang 205-211 - 2015
Yu. N. Tumanov1, N. V. Dedov2
1National Research Centre “Kurchatov Institute”, Moscow, Russia
2Seversk Institute of Technology, Seversk, Russia

Tóm tắt

The process of uranium reduction via plasma denitration of uranyl nitrate solutions in a plasma reactor of a nuclear-safe geometry with the use of soluble reducing agents (carbamide (NH2)2CO, sucrose C12H22O11, and acetic acid CH3COOH) is studied. Dispersed uranium oxide with the required oxygen coefficient (2.1–2.3) is obtained. It is found that acetic acid is the optimum reducing agent, and the optimum mass ratio HAc/U is 0.5–0.6. It is demonstrated that the synthesis of uranium oxides by the plasma denitration method is economically more viable than the mainstream technology.

Tài liệu tham khảo

Tumanov, Yu.N., Plazmennye, vysokochastotnye, mikrovolnovye i lazernye tekhnologii v khimikometallurgicheskikh protsessakh (Plasma, Radio-Frequency, Microwave, and Laser Technologies in Chemical and Metallurgical Processes), Moscow: Fizmatlit, 2010. Alekseyev, A.I., Zakharov, V.I., and Zyrichev, N.A., Application of plasma chemistry in the process of packaged and nitric acid processing of nepheline raw-stock, in Research in the Field of Chemistry and Technology of Rare-Earth Rawstock, Apatity: Kola Science Centre of the Russian Academy of Sciences, 1993, pp. 8–13. Dedov, N.V., Kozyrev, A.S., and Tumanov, Yu.N., Development and investigation of nuclear-secure plasma reactor, Fiz. Khim. Obrab. Mater., 2012, no. 1, pp. 40–45. Patton, F., Googin, J., and Griffith, W., Enriched Uranium Processing, int. Ser. of Monographs on Nuclear Energy. Vol. 2, Oxford: Pergamon, 1963. Dorda, F.A., Dedov, N.V., Ivanov, Yu.F., Kozlov, E.V., Mikhaylova, N.A., Sigaylo, V.D., Skuratov, V.A., and Khokhlov, V.A., USSR Inventor’s Certificate, no. 1805641, Byull. Izobret., 1995, no. 4, p. 240. Dorda, F.A., Dedov, N.V., Goloshchapov, R.G., Korobtsev, V.P., and Solovyev, A.I., RF Patent 2071678, Byull. Izobret., 1997, no. 1, p. 241. Mayorov, A.A. and Braverman, I., Tekhnologiya polucheniya poroshkov keramicheskoy dvuokisi urana (Technology of Production of Powders of Ceramic Uranium Dioxide), Moscow: Energoatmizdat, 1985. Hagemark, K., Broli, M., and Haas, P.A., Equilibrium oxygen pressures over the nonstoichiometric uranium oxides UO2 + x and U3O8 − z at higher temperatures, J. Inorg. Nucl. Chem., 1966, vol. 28, pp. 2837–2850. Bykhovsky, D.N., Dedov, N.V., Karelin, A.I., Kutyavin, E.M., and Novikov, G.S., RF Patent 2066299, Byull. Izobret. 1996, no. 25, p. 166. Dedov, N.V., Korobtsev, V.P., Kutyavin, E.M., Maly, Ye.N., Solovyev, A.I., and Khandorin, G.P., RF Patent 2093468, Byull. Izobret., 1997, no. 29, p. 10. Haas, P.A., A comparison of processes for the conversion of uranylnitrate into ceramic-grade UO2, Nucl. Technol., 1988, vol. 81, pp. 393–406. Stakebake, J.L., A thermal desorption study of the surface interactions between water and plutonium dioxide, J. Phys. Chem., 1973, vol. 77, pp. 581–586.