A study of the spectra and reactivity of oxysulphur-radical anions involved in the chain oxidation of S(IV): A pulse and γ-radiolysis study

Bielski, 1985, Reactivity of HO2·/O2− radicals in aqueous solution, J. phys. chem. Ref. Data, 14, 1041, 10.1063/1.555739 Bühler, 1984, Ozone decomposition in water studied by pulse radiolysis. 1. HO2/O2− and H03/03 as intermediates, J. phys. Chem., 88, 2560, 10.1021/j150656a026 Buxton, 1987, Radiation chemistry of the liquid state: (1) water and homogeneous aqueous solutions, 321 Buxton, 1989, Effect of temperature and scavenging power on the sum of G(eeq−) + G(H) + G(· OH) in the range 20–200°C. A pulse radiolysis study, Radiat. Phys. Chem., 34, 699 Buxton, 1988, Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (· OH/· O−) in aqueous solution, J. phys. chem. Ref. Data, 17, 513, 10.1063/1.555805 Buxton, 1988, Ionisation constants of · OH and H02 in aqueous solution up to 200° A pulse radiolysis study, J. Chem. Soc. Faraday Trans., 84, 1113, 10.1039/f19888401113 Buxton, 1991, Spectra and reactivity of S03, SO4− and SOS, 303 Buxton, 1995, Re-evaluation of the thiocyanate dosimeter for pulse radiolysis, J. Chem. Soc. Faraday Trans., 91, 279, 10.1039/ft9959100279 Chameides, 1982, The free radical chemistry of cloud droplets and its impact upon the composition of rain, J. geophys. Res., 87, 4863, 10.1029/JC087iC07p04863 Curtis, 1987 Dainton, 1972, Pulse radiolysis of solutions of stilbene. 1. Evidence for triplet and singlet excited state formation, J. phys. Chem., 77, 2156 Deister, 1990, Photoxoidation of SO32−in aqueous solution, J. phys. Chem., 94, 2191, 10.1021/j100368a084 Eigen, 1955, Untersuchungen fiber die Kinetic der Neutralisation, Z. Electrochem., 59, 986 Elliot, 1992, Temperature dependence of the reactions OH + O2− and OH + H02 in water up to 200°C, J. Chem. Soc. Faraday Trans., 88, 2465, 10.1039/FT9928802465 Gracdel, 1985, Influence of transition metal complexes on atmospheric droplet acidity, Nature, 317, 240, 10.1038/317240a0 Grimshaw, 1994, Dissociative electron transfer between arene radical anions and halogenoalkanes: a pulse radiolysis study, J. Chem. Soc. Faraday Trans., 90, 75, 10.1039/ft9949000075 Hayon, 1972, Electronic spectra, photochemistry and autooxidation mechanism of the sulfite-bisulfite-pyrosulfite systems, J. Am. chem. Soc., 94, 47, 10.1021/ja00756a009 Herrmann, 1993, Investigations of the sulfur species SOx− (x = 3, 4, 5) with a new laser photolysis/time-resolved multi-channel absorption experiment, 253 Huie, 1987, Rate constants for some oxidations of S(IV) by radicals in aqueous solution, Atmospheric Environment, 21, 1743, 10.1016/0004-6981(87)90113-2 Huie, 1989, A pulse radiolysis and flash photolysis study of the radicals S02−, S03, S04 and SO5−, Radiat. Phys. Chem., 33, 293 Lati, 1978, Oxidation of first-row bivalent transition-metal complexes containing ethylenediaminetetra-acetate and nitrolotriacetate ligands by free radicals: a pulse radiolysis study, J. Chem. Soc. Dalton Trans., 1105, 10.1039/dt9780001105 Marsh, 1989, The free-radical decomposition of peroxymonosulfate, Prog. React. Kinet., 15, 35 McElroy, 1986, The aqueous oxidation of S02 by OH radicals, Atmospheric Environment, 20, 324 McElroy, 1990, Kinetics of the reaction of the SO4− radical with SO42− S2O82−, H2O and Fe2+, J. Chem. Soc. Faraday Trans., 86, 2557, 10.1039/ft9908602557 McGowan, 1994, The oxidation of SO2 in cloudwater Reddy, 1992, Kinetics and mechanism of the sulfite-induced autoxidation of Fe(II) in acidic aqueous solution, Atmospheric Environment, 26, 661, 10.1016/0960-1686(92)90177-M Reese, 1995, Spectroscopic and kinetic investigations of SO x− (x = 3, 4, 5) radical anions and their role in the conversion of S(IV) in aqueous solutions, 61 Schuler, 1981, Track effects in radiation chemistry. Concentration dependence for the scavenging of OH by ferrocyanide in N2Osaturated aqueous solutions, J. phys. Chem., 85, 192, 10.1021/j150602a017 Spinks, 1976, An Introduction to Radiation Chemistry, 93 Warneck, 1995, Reaction mechanism of the iron(III)-catalyzed autoxidation of bisulfite in aqueous solution: steady-state description for benzene as radical scavenger, Ber. Bunsenges, Phys. Chem., 99, 59, 10.1002/bbpc.19950990109 Waygood, 1992, A laser flash photolysis study of the S03, SO4−, SOS radicals in aqueous solution, 23 Wood, 1989, Radiation chemistry of aqueous solutions up to 200°C Yermakov, 1993, The branching ratio of SOS radicals self-reaction in aqueous solution, J. phys. Chem., 97, 10712, 10.1021/j100143a031 Zagorski, 1971, Pulse radiolysis of aqueous alkaline sulfite solutions, J. phys. Chem., 75, 3510, 10.1021/j100692a004