Design and optimization of Kemira-Leonard process for formic acid production

Aguilo, 1985, Formic Acid Andrushkevich, 2014, A new gas-phase method for formic acid production: tests on a pilot plant, Catal. Ind., 6, 17, 10.1134/S2070050414010024 Aslam, 2012, Overview on Direct Formic Acid Fuel Cells (DFAFCs) as an energy sources, APCBEE Procedia, 3, 33, 10.1016/j.apcbee.2012.06.042 Aspen Technology, 2008. Aspen Plus User Models. Burlington. Bai, 1996, Kinetics of the carbonylation of methanol in a mechanically agitated reactor, J. Nat. Gas Chem., 5, 229 Boyce, 2008, Transport and Storage of Fluids Branan, 2005 Brennan, 2007, Life-Cycle Evaluation of Chemical Processing Plants Chen, 2004, Kinetics of methanol carbonylation to methyl formate catalyzed by sodium methoxide, J. Nat. Gas Chem., 13, 225 da Cunha, 2017, Retrofitting via Intensification: application to formic acid process, 1093 da Cunha, 2018, Design, optimization and retrofit of the formic acid process I: base case design and dividing-wall column retrofit, Ind. Eng. Chem. Res., 57, 9554, 10.1021/acs.iecr.8b00883 Hietala, 2016, Formic acid Hoch, 1983 Huang, H.P., Lee, M.J., Lee, H.Y., Chen, J.H., 2012. Formic Acid Manufacturing System and Method of Manufacturing Formic Acid. U.S. Patent 0123157 A1. Jogunola, 2010, Reversible autocatalytic hydrolysis of alkyl formate: Kinetic and reactor modeling, Ind. Eng. Chem. Res., 49, 4099, 10.1021/ie902031d Jogunola, 2012, Kinetic studies of alkyl formate hydrolysis using formic acid as a catalyst, J. Chem. Technol. Biotechnol., 87, 286, 10.1002/jctb.2714 Kashani, 2014, Simulation of Leonard-Kemira’s formic acid production process from CO Koretsky, 2013 Leonard, J.D., 1981. Preparation of Formic Acid by Hydrolysis of Methyl Formate. 4,299,981. Liu, 1988 Luyben, 2012, Pressure-swing distillation for minimum- and maximum-boiling homogeneous azeotropes, Ind. Eng. Chem. Res., 51, 10881, 10.1021/ie3002414 Market Research Future, 2017. Formic Acid Market Research Report- Forecast to 2027. Novita, 2018, Plantwide design for high-purity formic acid reactive distillation process with dividing wall column and external heat integration arrangements, Korean J. Chem. Eng., 35, 1, 10.1007/s11814-017-0342-4 Novita, 2015, Self-heat recuperative dividing wall column for enhancing the energy efficiency of the reactive distillation process in the formic acid production process, Chem. Eng. Process. Process Intensif., 97, 144, 10.1016/j.cep.2015.09.007 2017 Rangaiah, 2015, Multi-objective optimization for the design and operation of energy efficient chemical processes and power generation, Curr. Opin. Chem. Eng., 10, 49, 10.1016/j.coche.2015.08.006 Sauer, 2013 Sengupta, 2013, Chemicals from biomass : integrating bioprocesses into chemical production complexes for sustainable development, Green Chem. Chem. Eng., 471 Sharma, 2018, Intensification and performance assessment of the formic acid production process through a dividing wall reactive distillation column with vapor recompression, Chem. Eng. Process. Process Intensif., 123, 204, 10.1016/j.cep.2017.11.016 Sharma, 2017, Integrated Multi-Objective Differential Evolution and its Application to Amine Absorption Process for Natural Gas Sweetening Skoog, 2000 Turton, 2013 Wankat, 2007 Wolf, D., Schmidt, R., Block, U., Schoenmakers, H., Bott, K., Kaibel, G., 1982. Production of Anhydrous or Substantially Anhydrous Formic Acid. U.S. Patent 4,326,073.