Rationalization on high-loading iron and cobalt dual metal single atoms and mechanistic insight into the oxygen reduction reaction

Nano Energy - Tập 93 - Trang 106793 - 2022
Min Jiang1, Fei Wang1, Fan Yang2, Hao He3, Jian Yang1, Wei Zhang4, Jiayan Luo1, Jiao Zhang1, Chaopeng Fu1
1School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, PR China
2Institute of Fuel Cells, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, PR China
3College of Materials Science and Engineering, Changsha University of Science & Technology, Changsha, 410114, PR China
4Advanced Technology Institute, University of Surrey, Guildford GU2 7XH, UK

Tài liệu tham khảo

Du, 2019, Recent advances in the interface engineering of solid-state Li-ion batteries with artificial buffer layers: challenges, materials, construction, and characterization, Energy Environ. Sci., 12, 1780, 10.1039/C9EE00515C Jiang, 2019, Defect-engineered MnO2 enhancing oxygen reduction reaction for high performance Al-air batteries, Energy Storage Mater., 18, 34, 10.1016/j.ensm.2018.09.026 Chung, 2017, Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst, Science, 357, 479, 10.1126/science.aan2255 Luo, 2020, Secondary-atom-doping enables robust Fe–N–C single-atom catalysts with enhanced oxygen reduction reaction, Nano-Micro Lett., 12, 163, 10.1007/s40820-020-00502-5 Wan, 2020, In situ phosphatizing of triphenylphosphine encapsulated within metal–organic frameworks to design atomic Co1–P1N3 interfacial structure for promoting catalytic performance, J. Am. Chem. Soc., 142, 8431, 10.1021/jacs.0c02229 Han, 2019, Generation of nanoparticle, atomic-cluster, and single-atom cobalt catalysts from zeolitic imidazole frameworks by spatial isolation and their use in zinc-air, Batter. Angew. Chem. Int. Ed., 58, 5359, 10.1002/anie.201901109 Hou, 2020, Single-atom iron catalysts on overhang-eave, Carbon Cages High. Perform. Oxyg. Reduct. React., Angew. Chem. Int. Ed., 132, 7454 Jiao, 2020, Nanocasting SiO2 into metal–organic frameworks imparts dual protection to high-loading Fe single-atom electrocatalysts, Nat. Commun., 11, 2831, 10.1038/s41467-020-16715-6 Xiao, 2018, Microporous framework induced synthesis of single-atom dispersed Fe-N-C acidic ORR catalyst and its in situ reduced Fe-N4 active site identification revealed by X-ray absorption spectroscopy, ACS Catal., 8, 2824, 10.1021/acscatal.8b00138 Yang, 2019, A universal ligand mediated method for large scale synthesis of transition metal single atom catalysts, Nat. Commun., 10, 4585, 10.1038/s41467-019-12510-0 Wang, 2018, Heterogeneous single-atom catalysis, Nat. Rev. Chem., 2, 65, 10.1038/s41570-018-0010-1 Han, 2017, Hollow N-doped carbon spheres with isolated cobalt single atomic sites: superior electrocatalysts for oxygen reduction, J. Am. Chem. Soc., 139, 17269, 10.1021/jacs.7b10194 Zhu, 2020, Engineering local coordination environments of atomically dispersed and heteroatom-coordinated single metal site electrocatalysts for clean energy-conversion, Adv. Energy Mater., 10 Zhang, 2018, Cation vacancy stabilization of single-atomic-site Pt1/Ni(OH)x catalyst for diboration of alkynes and alkenes, Nat. Commun., 9, 1002, 10.1038/s41467-018-03380-z Chen, 2018, Single-Atom, Catal. Synth. Strateg. Electrochem. Appl. Joule, 2, 1242 Qu, 2018, Direct transformation of bulk copper into copper single sites via emitting and trapping of atoms, Nat. Catal., 1, 781, 10.1038/s41929-018-0146-x Fei, 2018, General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities, Nat. Catal., 1, 63, 10.1038/s41929-017-0008-y Chen, 2021, Atomic-level modulation of electronic density at cobalt single-atom sites derived from metal–organic frameworks: enhanced oxygen reduction performance, Angew. Chem. Int. Ed., 60, 3212, 10.1002/anie.202012798 Han, 2021, An adjacent atomic platinum site enables single-atom iron with high oxygen reduction reaction performance, Angew. Chem. Int. Ed., 60, 19262, 10.1002/anie.202105186 Gong, 2021, Self-templated hierarchically porous carbon nanorods embedded with atomic Fe-N4 active sites as efficient oxygen reduction electrocatalysts in Zn-air batteries, Adv. Funct. Mater., 31, 10.1002/adfm.202008085 Yang, 2020, O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution, Sci. Adv., 6, eaba6586, 10.1126/sciadv.aba6586 Han, 2019, Atomically dispersed binary co-ni sites in nitrogen-doped hollow carbon nanocubes for reversible oxygen reduction and evolution, Adv. Mater., 31, 10.1002/adma.201905622 Wang, 2018, Synergistic effect of well-defined dual sites boosting the oxygen reduction reaction, Energy Environ. Sci., 11, 3375, 10.1039/C8EE02656D Yang, 2018, Atomically dispersed Ni as the active site for electrochemical CO2 reduction, Nat. Energy, 3, 140, 10.1038/s41560-017-0078-8 Tao, 2019, Bridging the surface charge and catalytic activity of a defective, Carbon Electro, Angew. Chem. Int. Ed., 58, 1019, 10.1002/anie.201810207 Pan, 2018, A bimetallic Zn/Fe polyphthalocyanine-derived single-atom Fe-N4 catalytic site:a superior trifunctional catalyst for overall water splitting and Zn-air, 57, 8614 Chen, 2019, Interfacial engineering of cobalt sulfide/graphene hybrids for highly efficient ammonia electrosynthesis, P. Natl. Acad. Sci., 116, 6635, 10.1073/pnas.1817881116 Yang, 2019, Boosting oxygen reduction catalysis with Fe-N4 sites decorated porous carbons toward fuel cells, ACS Catal., 9, 2158, 10.1021/acscatal.8b04381 Ye, 2017, Surface functionalization of ZIF-8 with ammonium ferric citrate toward high exposure of Fe-N active sites for efficient oxygen and carbon dioxide electroreduction, Nano Energy, 38, 281, 10.1016/j.nanoen.2017.05.042 Li, 2019, Bottom-up construction of active sites in a Cu-N4-C catalyst for highly efficient oxygen reduction reaction, ACS Nano, 13, 3177, 10.1021/acsnano.8b08692 Jiang, 2018, Edge-site engineering of atomically dispersed Fe-N4 by selective C-N bond cleavage for enhanced oxygen reduction reaction activities, J. Am. Chem. Soc., 140, 11594, 10.1021/jacs.8b07294 Cao, 2019, Identification of single-atom active sites in carbon-based cobalt catalysts during electrocatalytic hydrogen evolution, Nat. Catal., 2, 134, 10.1038/s41929-018-0203-5 Yin, 2016, Single cobalt atoms with precise N-coordination as superior oxygen reduction reaction catalysts, Angew. Chem. Int. Ed., 128, 10958, 10.1002/ange.201604802 Liang, 2015, Molecular metal–Nx centres in porous carbon for electrocatalytic hydrogen evolution, Nat. Commun., 6, 7992, 10.1038/ncomms8992 Wang, 2020, N-coordinated dual-metal single-site catalyst for low-temperature CO oxidation, ACS Catal., 10, 2754, 10.1021/acscatal.0c00097 Liu, 2021, Strengthening absorption ability of Co–N–C as efficient bifunctional oxygen catalyst by modulating the d band center using MoC, Green, Energy Environ. Guo, 2020, Metal-tuned acetylene linkages in hydrogen substituted graphdiyne boosting the electrochemical oxygen reduction, Small, 16, 10.1002/smll.201907341 Zhang, 2020, Atomically dispersed hierarchically ordered porous Fe–N–C electrocatalyst for high performance electrocatalytic oxygen reduction in Zn-Air battery, Nano Energy, 71, 10.1016/j.nanoen.2020.104547 Chen, 2020, Dual single-atomic Ni-N4 and Fe-N4 sites constructing janus hollow graphene for selective oxygen electrocatalysis, Adv. Mater., 32 Cao, 2021, Operando X-ray spectroscopy visualizing the chameleon-like structural reconstruction on an oxygen evolution electrocatalyst, Energy Environ. Sci., 14, 906, 10.1039/D0EE02276D Zhang, 2019, Structural evolution of CoMoO4 to CoOOH by ion electrochemical etching for boosting oxygen evolution reaction, J. Power Sources, 442, 10.1016/j.jpowsour.2019.227252 Zhong, 2019, Layered two-dimensional conjugated metal-organic framework as a highly efficient electrocatalyst for the oxygen reduction reaction, Angew. Chem. Int. Ed., 131, 10787, 10.1002/ange.201907002 Dong, 2020, Direct in situ Raman spectroscopic evidence of oxygen reduction reaction intermediates at high-index Pt(hkl) surfaces, J. Am. Chem. Soc., 142, 715, 10.1021/jacs.9b12803 Dong, 2019, In situ Raman spectroscopic evidence for oxygen reduction reaction intermediates at platinum single-crystal surfaces, Nat. Energy, 4, 60, 10.1038/s41560-018-0292-z Lien, 2020, Probing the active site in single-atom oxygen reduction catalysts via operando X-ray and electrochemical spectroscopy, Nat. Commun., 11, 4233, 10.1038/s41467-020-17975-y Hammer, 2000, Theoretical surface science and catalysis—calculations and concepts, Adv. Catal., 45, 71 Cui, 2019, A copper single-atom catalyst towards efficient and durable oxygen reduction for fuel cells, J. Mater. Chem. A, 7, 16690, 10.1039/C9TA03518D Wang, 2019, Iron-free cathode catalysts for proton-exchange-membrane fuel cells: cobalt catalysts and the peroxide mitigation approach, Adv. Mater., 31