A review of lithium-O2/CO2 and lithium-CO2 batteries: Advanced electrodes/materials/electrolytes and functional mechanisms

Gür, 2018, Review of electrical energy storage technologies, materials and systems: challenges and prospects for large-scale grid storage, Energy Environ. Sci., 11, 2696, 10.1039/C8EE01419A Lu, 2016, The role of nanotechnology in the development of battery materials for electric vehicles, Nat. Nanotechnol., 11, 1031, 10.1038/nnano.2016.207 Dunn, 2011, Electrical energy storage for the grid: a battery of choices, Science, 334, 928, 10.1126/science.1212741 Zheng, 2021, Solid oxide electrolysis of H2O and CO2 to produce hydrogen and low-carbon fuels, Electrochem. Energy Rev., 4, 508, 10.1007/s41918-021-00097-4 Wu, 2020, Review of system integration and control of proton exchange membrane fuel cells, Electrochem. Energy Rev., 3, 466, 10.1007/s41918-020-00068-1 Duan, 2020, Building safe lithium-ion batteries for electric vehicles: a review, Electrochem. Energy Rev., 3, 1, 10.1007/s41918-019-00060-4 Kim, 2019, Lithium-ion batteries: outlook on present, future, and hybridized technologies, J. Mater. Chem. A., 7, 2942, 10.1039/C8TA10513H Winter, 2018, Before Li ion batteries, Chem. Rev., 118, 11433, 10.1021/acs.chemrev.8b00422 Ezeigwe, 2021, A review of self-healing electrode and electrolyte materials and their mitigating degradation of Lithium batteries, Nano Energy, 84, 10.1016/j.nanoen.2021.105907 Bruce, 2012, Li-O2 and Li-S batteries with high energy storage, Nat. Mater., 11, 19, 10.1038/nmat3191 Lee, 2011, Metal–air batteries with high energy density: Li–Air versus Zn–Air, Adv. Energy Mater., 1, 34, 10.1002/aenm.201000010 Cheng, 2012, Metal–air batteries: from oxygen reduction electrochemistry to cathode catalysts, Chem. Soc. Rev., 41, 2172, 10.1039/c1cs15228a Li, 2014, Recent advances in zinc–air batteries, Chem. Soc. Rev., 43, 5257, 10.1039/C4CS00015C Wang, 2014, Oxygen electrocatalysts in metal-air batteries: from aqueous to nonaqueous electrolytes, Chem. Soc. Rev., 43, 7746, 10.1039/C3CS60248F Li, 2013, Challenges of non-aqueous Li–O2 batteries: electrolytes, catalysts, and anodes, Energy Environ. Sci., 6, 1125, 10.1039/c3ee00053b Narayanan, 2012, Materials challenges and technical approaches for realizing inexpensive and robust iron–air batteries for large-scale energy storage, Solid State Ion., 216, 105, 10.1016/j.ssi.2011.12.002 Li, 2017, Metal-air batteries: will they be the future electrochemical energy storage device of choice?, ACS Energy Lett., 2, 1370, 10.1021/acsenergylett.7b00119 Park, 2020, Potassium-oxygen batteries: significance, challenges, and prospects, J. Phys. Chem. Lett., 11, 7849, 10.1021/acs.jpclett.0c01596 Egan, 2013, Developments in electrode materials and electrolytes for aluminium–air batteries, J. Power Sources, 236, 293, 10.1016/j.jpowsour.2013.01.141 Mu, 2020, Li–CO2 and Na–CO2 batteries: toward greener and sustainable electrical energy storage, Adv. Mater., 32, 1, 10.1002/adma.201903790 Tan, 2017, Advances and challenges in lithium-air batteries, Appl. Energy, 204, 780, 10.1016/j.apenergy.2017.07.054 Ling, 2014, Intrinsic barrier to electrochemically decompose Li2CO3 and LiOH, J. Phys. Chem. C., 118, 26591, 10.1021/jp5093306 Sahapatsombut, 2014, Modelling of operation of a lithium-air battery with ambient air and oxygen-selective membrane, J. Power Sources, 249, 418, 10.1016/j.jpowsour.2013.10.128 Zhang, 2010, Oxygen-selective immobilized liquid membranes for operation of lithium-air batteries in ambient air, J. Power Sources, 195, 7438, 10.1016/j.jpowsour.2010.05.028 Meini, 2012, The effect of water on the discharge capacity of a non-catalyzed carbon cathode for Li-O2 batteries, Electrochem. Solid-State Lett., 15, 44, 10.1149/2.005204esl Guo, 2014, Humidity effect on electrochemical performance of Li-O2 batteries, J. Power Sources, 264, 1, 10.1016/j.jpowsour.2014.04.079 Wu, 2016, A synergistic system for lithium-oxygen batteries in humid atmosphere integrating a composite cathode and a hydrophobic ionic liquid-based electrolyte, Adv. Funct. Mater., 26, 3291, 10.1002/adfm.201505420 Xu, 2016, The sodium–oxygen/carbon dioxide electrochemical cell, ChemSusChem, 9, 1600, 10.1002/cssc.201600423 Gowda, 2013, Implications of CO2 contamination in rechargeable nonaqueous Li-O2 batteries, J. Phys. Chem. Lett., 4, 276, 10.1021/jz301902h Takechi, 2011, A Li–O2/CO2 battery, Chem. Commun., 47, 3463, 10.1039/c0cc05176d Lim, 2013, Toward a lithium-“Air” battery: the effect of CO2 on the chemistry of a lithium-oxygen cell, J. Am. Chem. Soc., 135, 9733, 10.1021/ja4016765 Xie, 2017, Metal–CO2 batteries on the road: CO2 from contamination gas to energy source, Adv. Mater., 29, 10.1002/adma.201605891 Al Sadat, 2016, The O2-assisted Al/CO2 electrochemical cell: A system for CO2 capture/ conversion and electric power generation, Appl. Sci. Eng., 1 Li, 2016, Progress in research on Li-CO2 batteries: mechanism, catalyst and performance, cuihua Xuebao/Chinese, J. Catal., 37, 1016 Sun, 2021, Recent advances in rechargeable Li–CO2 batteries, Energy Fuels, 35, 9165, 10.1021/acs.energyfuels.1c00635 Xu, 2013, The Li-CO2 battery: a novel method for CO2 capture and utilization, RSC Adv., 3, 6656, 10.1039/c3ra40394g Wang, 2013, Challenges and opportunities of nanostructured materials for aprotic rechargeable lithium-air batteries, Nano Energy, 2, 443, 10.1016/j.nanoen.2012.11.014 Zhao, 2014, Enhanced cyclability of Li–O2 batteries based on TiO2 supported cathodes with no carbon or binder, Chem. Mater., 26, 2551, 10.1021/cm5004966 Lu, 2010, Platinum−gold nanoparticles: a highly active bifunctional electrocatalyst for rechargeable lithium−air batteries, J. Am. Chem. Soc., 132, 12170, 10.1021/ja1036572 Ma, 2015, Reversibility of noble metal-catalyzed aprotic Li-O2 batteries, Nano Lett., 15, 8084, 10.1021/acs.nanolett.5b03510 Freunberger, 2011, Reactions in the rechargeable lithium-O2 battery with alkyl carbonate electrolytes, J. Am. Chem. Soc., 133, 8040, 10.1021/ja2021747 Cai, 2018, Progress and future perspectives on Li(Na)-CO2 batteries, Adv. Sustain. Syst., 2, 10.1002/adsu.201800060 Yao, 2018 Kwak, 2020, Lithium-oxygen batteries and related systems: potential, status, and future, ACS Appl. Mater. Interfaces Yin, 2017, Chemical vs electrochemical formation of Li2CO as a discharge product in Li−O2 /CO2 batteries by controlling the superoxide intermediate, J. Phys. Chem. Lett., 8, 214, 10.1021/acs.jpclett.6b02610 Qiao, 2018, Li2CO3-free Li–O2/CO2 battery with peroxide discharge product, Energy Environ. Sci., 11, 1211, 10.1039/C7EE03341A Zhao, 2019, Probing lithium carbonate formation in trace‑O2‑ assisted aprotic Li-CO2 batteries using in situ surface-enhanced raman spectroscopy, J. Phys. Chem. Lett., 10, 322, 10.1021/acs.jpclett.8b03272 Kafafi, 1983, Carbon dioxide activation by lithium metal. 1. infrared spectra of Li+CO2-, Li+C2O4- and Li22+ CO22- in inert-gas matrices, J. Am. Chem. Soc., 105, 3886, 10.1021/ja00350a025 Das, 2012, High energy lithium-oxygen batteries - Transport barriers and thermodynamics, Energy Environ. Sci., 5, 8927, 10.1039/c2ee22470d Liu, 2014, Rechargeable Li/CO2-O2 (2:1) battery and Li/CO2 battery, Energy Environ. Sci., 7, 677, 10.1039/c3ee43318h Zhang, 2015, Rechargeable Li-CO2 batteries with carbon nanotubes as air cathodes, Chem. Commun., 51, 14636, 10.1039/C5CC05767A Jin, 2018, High-performance Li-CO2 batteries based on metal-free carbon quantum dot/holey graphene composite catalysts, Adv. Funct. Mater., 28, 1, 10.1002/adfm.201804630 Zhang, 2015, The first introduction of graphene to rechargeable Li-CO2 batteries, Angew. Chem. - Int. Ed., 54, 6550, 10.1002/anie.201501214 Hu, 2017, Flexible Li-CO2 batteries with liquid-free electrolyte, Angew. Chem. - Int. Ed., 56, 5785, 10.1002/anie.201701928 Qiao, 2017, Li-CO2 electrochemistry: a new strategy for CO2 fixation and energy storage, Joule, 1, 359, 10.1016/j.joule.2017.07.001 Hou, 2017, Mo2C/CNT: an efficient catalyst for rechargeable Li–CO2 Batteries, Adv. Funct. Mater., 27, 1, 10.1002/adfm.201700564 Meini, 2013, Rechargeability of Li-air cathodes pre-filled with discharge products using an ether-based electrolyte solution: Implications for cycle-life of Li-air cells, Phys. Chem. Chem. Phys., 15, 11478, 10.1039/c3cp51112j Mahne, 2018, Electrochemical oxidation of lithium carbonate generates singlet oxygen, Angew. Chem. - Int. Ed., 57, 5529, 10.1002/anie.201802277 Yang, 2016, Exploring the electrochemical reaction mechanism of carbonate oxidation in Li-air/CO2 battery through tracing missing oxygen, Energy Environ. Sci., 9, 1650, 10.1039/C6EE00004E Zhao, 2018, Achilles’ heel of lithium–air batteries: lithium carbonate, Angew. Chem. - Int. Ed., 57, 3874, 10.1002/anie.201710156 Yabuuchi, 2011, Detailed studies of a high-capacity electrode material for rechargeable batteries, Li2MnO3-LiCo1/3Ni 1/3Mn1/3O2, J. Am. Chem. Soc., 133, 4404, 10.1021/ja108588y Zhang, 2018, Verifying the rechargeability of Li-CO2 batteries on working cathodes of Ni nanoparticles highly dispersed on n-doped graphene, Adv. Sci., 5 Wang, 2012, Electrochemical decomposition of Li2CO3 in NiO-Li2CO3 nanocomposite thin film and powder electrodes, J. Power Sources, 218, 113, 10.1016/j.jpowsour.2012.06.082 Li, 2019, Monodispersed MnO nanoparticles in graphene-an interconnected N-doped 3D carbon framework as a highly efficient gas cathode in Li-CO2 batteries, Energy Environ. Sci., 12, 1046, 10.1039/C8EE03283A Yang, 2017, A reversible lithium-CO2 battery with Ru nanoparticles as a cathode catalyst, Energy Environ. Sci., 10, 972, 10.1039/C6EE03770D Liu, 2019, Recent advances in understanding Li – CO2 electrochemistry, Energy Environ. Sci., 12, 13, 10.1039/C8EE03417F Li, 2016, Progress in research on Li – CO2 batteries: mechanism, catalyst and performance, Chin. J. Catal., 37, 1016, 10.1016/S1872-2067(15)61125-1 Yu, 2020, Recent advances in lithium – carbon dioxide batteries, Small Struct., 2000027, 1 Jiao, 2021, Recent progress and prospects of Li-CO2 batteries: mechanisms, catalysts and electrolytes, Energy Storage Mater., 34, 148, 10.1016/j.ensm.2020.09.014 Xiao, 2020, Investigation on the discharge and charge behaviors of Li-CO2 batteries with carbon nanotube electrodes, ACS Sustain. Chem. Eng., 8, 9742, 10.1021/acssuschemeng.0c01863 Xing, 2019, Revealing the impacting factors of cathodic carbon catalysts for Li-CO2 batteries in the pore-structure point of view, Electrochim. Acta, 311, 41, 10.1016/j.electacta.2019.04.135 Qiao, 2020, Synergistic effect of bifunctional catalytic sites and defect engineering for high-performance Li – CO2 batteries, Energy Storage Mater., 27, 133, 10.1016/j.ensm.2020.01.021 Zhu, 2018, Defective N / S-codoped 3D cheese-like porous carbon nanomaterial toward efficient oxygen reduction and Zn – Air, Batteries, 1800563, 1 Czerw, 2001, Identification of electron donor states in n-doped carbon nanotubes, Nano Lett., 1, 457, 10.1021/nl015549q Li, 2019, Highly surface-wrinkled and n-doped CNTs anchored on metal wire: a novel fiber-shaped cathode toward high-performance flexible Li–CO2 batteries, Adv. Funct. Mater., 29, 1 Li, 2019, Bamboo-like nitrogen-doped carbon nanotube forests as durable metal-free catalysts for self-powered flexible Li – CO2 batteries, Adv. Mater., 1903852, 1 Qie, 2017, Highly rechargeable lithium-CO2 batteries with a boron- and nitrogen-codoped holey-graphene cathode, Angew. Chem. - Int. Ed., 56, 6970, 10.1002/anie.201701826 Song, 2019, A long-life Li-CO2 battery employing a cathode catalyst of cobalt-embedded nitrogen-doped carbon nanotubes derived from a Prussian blue analogue, Chem. Commun., 55, 12781, 10.1039/C9CC05392A Qiao, 2018, 3D-printed graphene oxide framework with thermal shock synthesized nanoparticles for Li-CO2 batteries, Adv. Funct. Mater., 28, 10.1002/adfm.201805899 Li, 2020, Graphdiyne for crucial gas involved catalytic reactions in energy conversion applications, Energy Environ. Sci., 13, 1326, 10.1039/C9EE03558C Wang, 2019, Graphdiyne-based materials: preparation and application for electrochemical energy storage, Adv. Mater., 31, 10.1002/adma.201970300 Huang, 2018, Progress in research into 2D graphdiyne-based materials, Chem. Rev., 118, 7744, 10.1021/acs.chemrev.8b00288 Xu, 2019, Graphdiyne: a new photocatalytic CO2 reduction cocatalyst, Adv. Funct. Mater., 29, 10.1002/adfm.201904256 Cao, 2020, Enhanced photochemical CO2 reduction in the gas phase by graphdiyne, J. Mater. Chem. A., 7671, 10.1039/D0TA02256J Zhang, 2021, Rechargeable Li − CO2 batteries with graphdiyne as efficient metal-free cathode catalysts, Adv. Funct. Mater., 2101423, 1 Patel, 2016, Noble metal-free bifunctional oxygen evolution and oxygen reduction acidic media electro- catalysts, Nat. Publ. Gr., 1 Takimoto, 2017, Ru-core @ Pt-shell nanosheet for fuel cell electrocatalysts with high activity and durability, J. Catal., 345, 207, 10.1016/j.jcat.2016.11.026 Zhao, 2017, Decoupling atomic-layer-deposition ultrafine RuO2 for high-efficiency and ultralong-life Li-O2 batteries, Nano Energy, 34, 399, 10.1016/j.nanoen.2017.02.030 Sun, 2014, Porous graphene nanoarchitectures: an efficient catalyst for low charge-overpotential, long life, and high capacity lithium–oxygen batteries, Nano Lett., 14, 3145, 10.1021/nl500397y Sun, 2015, Mesoporous carbon nanocube architecture for high- performance lithium – oxygen batteries, Adv. Funct. Mater., 25, 4436, 10.1002/adfm.201500863 Su, 2016, Ruthenium nanocrystal decorated vertical graphene nanosheets @ Ni foam as highly efficient cathode catalysts for lithium-oxygen batteries, Nature, 8 Li, 2019, Ru-Coated metal–organic framework-derived Co-based particles embedded in porous N-doped carbon nanocubes as a catalytic cathode for a Li–O2 battery, Chem. Commun., 55, 10092, 10.1039/C9CC04720D Wang, 2017, Monodispersed Ru nanoparticles functionalized graphene nanosheets as efficient cathode catalysts for O2-assisted Li–CO2 battery, ACS Omega, 2, 9280, 10.1021/acsomega.7b01495 Zhao, 2019, Ru nanosheet catalyst supported by three-dimensional nickel foam as a binder-free cathode for Li-CO2 batteries, Electrochim. Acta, 299, 592, 10.1016/j.electacta.2019.01.027 Shi, 2019, Robust noble metal-based electrocatalysts for oxygen evolution reaction, Chem. Soc. Rev., 48, 3181, 10.1039/C8CS00671G Zhang, 2020, Synergetic effect of Ru and NiO in the electrocatalytic decomposition of Li2CO3 to enhance the performance of a Li-CO2/O2 battery, ACS Catal., 10, 1640, 10.1021/acscatal.9b04138 Zhang, 2018, Exploiting synergistic effect by integrating ruthenium – copper nanoparticles highly co-dispersed on graphene as efficient air cathodes for Li – CO2 batteries, Adv. Energy Mater., 1802805 Zhao, 2019, Ru nanosheet catalyst supported by three-dimensional nickel foam as a binder-free cathode for Li–CO2 batteries, Electrochim. Acta, 299, 592, 10.1016/j.electacta.2019.01.027 Jin, 2020, Achieving low charge overpotential in a Li-CO2 battery with bimetallic RuCo nanoalloy decorated carbon nanofiber cathodes, ACS Sustain. Chem. Eng., 8, 2783, 10.1021/acssuschemeng.9b06668 Jin, 2019, Tuning electronic and composition effects in ruthenium-copper alloy nanoparticles anchored on carbon nanofibers for rechargeable Li-CO2 batteries, Chem. Eng. J., 375, 10.1016/j.cej.2019.121978 Wang, 2020, Photoinduced homogeneous RuO2 nanoparticles on TiO2 nanowire arrays: a high-performance cathode toward flexible Li–CO2 batteries, J. Power Sources, 475, 10.1016/j.jpowsour.2020.228703 Song, 2017, Complete decomposition of Li2CO3 in Li–O2 batteries using Ir/B4C as noncarbon-based oxygen electrode, Nano Lett., 17, 1417, 10.1021/acs.nanolett.6b04371 Tang, 2017, Two-dimensional IrO2/MnO2 enabling conformal growth of amorphous Li2O2 for high-performance Li–O2 batteries, Energy Storage Mater., 9, 206, 10.1016/j.ensm.2017.07.016 Lu, 2016, A lithium–oxygen battery based on lithium superoxide, Nature, 529, 377, 10.1038/nature16484 Zhou, 2015, Iridium incorporated into deoxygenated hierarchical graphene as a high-performance cathode for rechargeable Li – O2 batteries, J. Mater. Chem. A., 3, 14556, 10.1039/C5TA03482E Wang, 2018, Fabricating Ir/C nanofiber networks as free-standing air cathodes for rechargeable Li-CO2 batteries, Small, 14 Xing, 2018, Crumpled Ir nanosheets fully covered on porous carbon nanofibers for long-life rechargeable lithium – CO2 batteries, Adv. Mater., 30, 10.1002/adma.201803124 Mao, 2019, Long-life Li–CO2 cells with ultrafine IrO2-decorated few-layered δ-MnO2 enabling amorphous Li2CO3 growth, Energy Storage Mater., 18, 405, 10.1016/j.ensm.2018.08.011 Wu, 2020, Design of ultralong-life Li–CO2 batteries with IrO2 nanoparticles highly dispersed on nitrogen-doped carbon nanotubes, J. Mater. Chem. A., 8, 3763, 10.1039/C9TA11028C Liang, 2019, Defect regulation of heterogeneous nickel-based oxides via interfacial engineering for long-life lithium-oxygen batteries, Electrochim. Acta, 321, 10.1016/j.electacta.2019.134716 Cheng, 2013, Enhancing electrocatalytic oxygen reduction on MnO2 with vacancies, Angew. Chem. Int. Ed., 52, 2474, 10.1002/anie.201208582 Koketsu, 2021, Challenge in metal-air batteries: From the design to the performance of metal oxide-based electrocatalysts, 187 Liu, 2018, Advances in manganese-based oxides cathodic electrocatalysts for Li–Air batteries, Adv. Funct. Mater., 28 Zhang, 2021, A “two-pronged” strategy: Boosting electrocatalytic oxygen reduction reaction property based on the Ni–MnO synergistic effect and high conductivity of rod-like Ni–MnO/N–C composites prepared via simple solution-free route, J. Power Sources, 485, 10.1016/j.jpowsour.2020.229330 Ma, 2018, Porous Mn2O3 cathode for highly durable Li–CO2 batteries, J. Mater. Chem. A., 6, 20829, 10.1039/C8TA06143B Zhang, 2017, Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities, Nat. Commun., 8, 405, 10.1038/s41467-017-00467-x Hao, 2019, The role of alkali metal in α-MnO2 catalyzed ammonia-selective catalysis, Angew. Chem. Int. Ed., 58, 6351, 10.1002/anie.201901771 Tang, 2021, Promoting the performance of Li–CO2 batteries via constructing three-dimensional interconnected K+ doped MnO2 nanowires networks, Front. Chem., 9, 1, 10.3389/fchem.2021.670612 Liu, 2021, Facile synthesis of birnessite δ-MnO2 and carbon nanotube composites as effective catalysts for Li-CO2 batteries, ACS Appl. Mater. Interfaces, 13, 16585, 10.1021/acsami.1c03229 Ge, 2019, A Co-doped MnO2 catalyst for Li-CO2 batteries with low overpotential and ultrahigh cyclability, Small, 15, 10.1002/smll.201902220 Zhang, 2018, High performance Li–CO2 batteries with NiO–CNT cathodes, J. Mater. Chem. A., 6, 2792, 10.1039/C7TA11015D Zheng, 2021, Oxygen vacancy engineering of vertically aligned NiO nanosheets for effective CO2 reduction and capture in Li-CO2 battery, Electrochim. Acta, 383, 10.1016/j.electacta.2021.138359 Pipes, 2018, Nanostructured anatase titania as a cathode catalyst for Li–CO2 batteries, ACS Appl. Mater. Interfaces, 10, 37119, 10.1021/acsami.8b13910 Xie, 2018, A porous Zn cathode for Li – CO2 batteries, J. Mater. Chem. A., 6, 13952, 10.1039/C8TA02771D Kim, 2021, Capillary-driven formation of iron nanoparticles embedded in nanotubes for catalyzed lithium–carbon dioxide reaction, ACS Mater. Lett., 3, 815, 10.1021/acsmaterialslett.1c00078 Zhang, 2018, Identification of cathode stability in Li- CO2 batteries with Cu nanoparticles highly dispersed, J. Mater. Chem. A., 6, 3218, 10.1039/C7TA10497A Zhou, 2019, A quasi-solid-state flexible fiber-shaped Li–CO2 battery with low overpotential and high energy efficiency, Adv. Mater., 31, 1 Zhu, 2017, Towards real Li-air batteries: a binder-free cathode with high electrochemical performance in CO2 and O2, Energy Storage Mater., 7, 209, 10.1016/j.ensm.2017.03.004 Yang, 2020, Unraveling reaction mechanisms of Mo2C as cathode catalyst in a Li-CO2 battery, J. Am. Chem. Soc., 142, 6983, 10.1021/jacs.9b12868 Pipes, 2020, Freestanding vanadium nitride nanowire membrane as an ef fi cient, carbon-free gas diffusion cathode for Li–CO2 batteries, Energy Storage Mater., 31, 95, 10.1016/j.ensm.2020.06.009 Pipes, 2019, Efficient Li − CO2 batteries with molybdenum disulfide nanosheets on carbon nanotubes as a catalyst, ACS Appl. Energy Mater., 2, 8685, 10.1021/acsaem.9b01653 Ahmadiparidari, 2019, A long-cycle-life lithium – CO2 battery with carbon neutrality, Adv. Mater., 31, 10.1002/adma.201902518 Chen, 2021, Catalytically active site identification of molybdenum disulfide as gas cathode in a nonaqueous Li−CO2 battery, ACS Appl. Mater. Interfaces, 13, 6156, 10.1021/acsami.0c17942 Li, 2020, Bulk COFs and COF nanosheets for electrochemical energy storage and conversion, Chem. Soc. Rev., 49, 3565, 10.1039/D0CS00017E Tilford, 2008, Tailoring microporosity in covalent organic frameworks, Adv. Mater., 20, 2741, 10.1002/adma.200800030 Feng, 2012, Covalent organic frameworks, Chem. Soc. Rev., 41, 6010, 10.1039/c2cs35157a Fang, 2014, Designed synthesis of large-pore crystalline polyimide covalent organic frameworks, Nat. Commun., 5, 4503, 10.1038/ncomms5503 Wang, 2021, Covalent organic framework-based materials for energy applications, Energy Environ. Sci., 14, 688, 10.1039/D0EE02309D Yusran, 2020, Electroact. Covalent Org. Framew.: Des., Synth., Appl., 2002038, 1 Li, 2019, Covalent-organic-framework-based Li – CO2 batteries, Adv. Mater., 31, 10.1002/adma.201905879 Jiang, 2021, Exfoliation of covalent organic frameworks into MnO2-loaded ultrathin nanosheets as efficient cathode catalysts for Li-CO2 batteries, Cell Rep. Phys. Sci., 2 Zhang, 2021, Single metal site and versatile transfer channel merged into covalent organic frameworks facilitate high-performance Li-CO2 batteries, ACS Cent. Sci., 7, 175, 10.1021/acscentsci.0c01390 Zhou, 2012, Introduction to metal–organic frameworks, Chem. Rev., 112, 673, 10.1021/cr300014x Li, 2009, Selective gas adsorption and separation in metal-organic frameworks, Chem. Soc. Rev., 38, 1477, 10.1039/b802426j Lei, 2018, MOFs-based heterogeneous catalysts: new opportunities for energy-related CO2 conversion, Adv. Energy Mater., 8, 10.1002/aenm.201801587 Deng, 2012, Large-pore apertures in a series of metal-organic frameworks, Science, 336, 1018, 10.1126/science.1220131 Li, 2018, Carbon dioxide in the cage: manganese metal-organic frameworks for high performance CO2 electrodes in Li-CO2 batteries, Energy Environ. Sci., 11, 1318, 10.1039/C8EE00415C Li, 2019, Drawing a pencil-trace cathode for a high-performance polymer-based Li–CO 2 battery with redox mediator, Adv. Funct. Mater., 29, 1 Pipes, 2019, Phenyl disulfide additive for solution-mediated carbon dioxide utilization in Li–CO2 batteries, Adv. Energy Mater., 9, 10.1002/aenm.201900453 Li, 2017, A rechargeable Li-CO2 battery with a gel polymer electrolyte, Angew. Chem. - Int. Ed., 56, 9126, 10.1002/anie.201705017 Xiao, 2020, Toward the rational design of cathode and electrolyte materials for aprotic Li‐CO2 batteries: a numerical investigation, Int. J. Energy Res., 44, 496, 10.1002/er.4952 Liu, 2019, Recent advances in understanding Li-CO2 electrochemistry, Energy Environ. Sci., 12, 887, 10.1039/C8EE03417F Bryantsev, 2011, Predicting solvent stability in aprotic electrolyte li–air batteries: nucleophilic substitution by the superoxide anion radical (O2•–), J. Phys. Chem. A., 115, 12399, 10.1021/jp2073914 Bryantsev, 2011, Computational study of the mechanisms of superoxide-induced decomposition of organic carbonate-based electrolytes, J. Phys. Chem. Lett., 2, 379, 10.1021/jz1016526 Qiao, 2016, Spectroscopic investigation for oxygen reduction and evolution reactions with tetrathiafulvalene as a redox mediator in Li–O2 battery, J. Phys. Chem. C., 120, 15830, 10.1021/acs.jpcc.5b11692 Peng, 2012, A reversible and higher-rate Li-O2 battery, Science, 337, 563, 10.1126/science.1223985 Sharon, 2013, Oxidation of dimethyl sulfoxide solutions by electrochemical reduction of oxygen, J. Phys. Chem. Lett., 4, 3115, 10.1021/jz4017188 Yin, 2017, Chemical vs electrochemical formation of Li2CO3 as a discharge product in Li-O2/CO2 batteries by controlling the superoxide intermediate, J. Phys. Chem. Lett., 8, 214, 10.1021/acs.jpclett.6b02610 Khurram, 2019, Governing role of solvent on discharge activity in lithium-CO2 batteries, J. Phys. Chem. Lett., 10, 6679, 10.1021/acs.jpclett.9b02615 Liu, 2017, Decomposing lithium carbonate with a mobile catalyst, Nano Energy, 36, 390, 10.1016/j.nanoen.2017.04.049 Kwak, 2016, Li-O2 cells with LiBr as an electrolyte and a redox mediator, Energy Environ. Sci., 9, 2334, 10.1039/C6EE00700G Zhao, 2020, Halide-based solid-state electrolyte as an interfacial modifier for high performance solid-state Li–O2 batteries, Nano Energy, 75, 10.1016/j.nanoen.2020.105036 Ma, 2019, Prevention of dendrite growth and volume expansion to give high-performance aprotic bimetallic Li-Na alloy–O2 batteries, Nat. Chem., 11, 64, 10.1038/s41557-018-0166-9 Wang, 2017, Improving electrochemical performances of rechargeable Li−CO2 batteries with an electrolyte redox mediator, ChemElectroChem, 4, 2145, 10.1002/celc.201700539 Gurkan, 2015, Quinone reduction in ionic liquids for electrochemical CO2 separation, ACS Sustain. Chem. Eng., 3, 1394, 10.1021/acssuschemeng.5b00116 Rheinhardt, 2017, Electrochemical capture and release of carbon dioxide, ACS Energy Lett., 2, 454, 10.1021/acsenergylett.6b00608 Mizen, 1989, Reductive addition of CO2 to 9,10–phenanthrenequinone, J. Electrochem. Soc., 136, 941, 10.1149/1.2096891 Yin, 2018, Electrochemical reduction of CO2 mediated by quinone derivatives: implication for Li-CO2 battery, J. Phys. Chem. C., 122, 6546, 10.1021/acs.jpcc.8b00109 Shiga, 2019, Bifunctional catalytic activity of iodine species for lithium-carbon dioxide battery, ACS Sustain. Chem. Eng., 7, 14280, 10.1021/acssuschemeng.9b03949 Khurram, 2018, Tailoring the discharge reaction in Li-CO2 batteries through incorporation of CO2 capture chemistry, Joule, 2, 2649, 10.1016/j.joule.2018.09.002 Singh, 2017, Electrochemical capture and release of carbon dioxide using a disulfide–thiocarbonate redox cycle, J. Am. Chem. Soc., 139, 1033, 10.1021/jacs.6b10806 Wadhawan, 2001, Microelectrode studies of the reaction of superoxide with carbon dioxide in dimethyl sulfoxide, J. Phys. Chem. B., 105, 10659, 10.1021/jp012160i Li, 2016, Progress in research on Li–CO2 batteries: mechanism, catalysat and performance, Chin. J. Catal., 37, 1016, 10.1016/S1872-2067(15)61125-1 Wang, 2021, Research status and perspectives of rechargeable Li-CO2 battery, Ionics, 27, 2785, 10.1007/s11581-021-04009-w Wang, 2019, Safety-reinforced rechargeable Li-CO2 battery based on a composite solid state electrolyte, Nano Res, 12, 2543, 10.1007/s12274-019-2482-9 Yi, 2015, Novel stable gel polymer electrolyte: toward a high safety and long life li–air battery, ACS Appl. Mater. Interfaces, 7, 23798, 10.1021/acsami.5b08462 Yi, 2017, Status and prospects of polymer electrolytes for solid-state Li-O2 (air) batteries, Energy Environ. Sci., 10, 860, 10.1039/C6EE03499C Mushtaq, 2018, Polymer electrolyte with composite cathode for solid-state Li–CO2 battery, Rare Met, 37, 520, 10.1007/s12598-018-1044-8 Zhao, 2019, Ultralong-life quasi-solid-state li-o2 batteries enabled by coupling advanced air electrode design with li metal anode protection, Small Methods, 3, 10.1002/smtd.201800437 Li, 2019, Highly surface-wrinkled and n-doped CNTs anchored on metal wire: a novel fiber-shaped cathode toward high-performance flexible Li–CO2 batteries, Adv. Funct. Mater., 29 Zhang, 2021, Protecting Li-metal anode with ethylenediamine-based layer and in-situ formed gel polymer electrolyte to construct the high-performance Li–CO2 battery, J. Power Sources, 506, 10.1016/j.jpowsour.2021.230226 Huang, 2019, CO2 nanoenrichment and nanoconfinement in cage of imine covalent organic frameworks for high-performance CO2 cathodes in Li-CO2 batteries, Small, 15, 10.1002/smll.201904830 Chen, 2019, Conjugated cobalt polyphthalocyanine as the elastic and reprocessable catalyst for flexible Li–CO2 batteries, Adv. Mater., 31 Bie, 2019, Carbon nanotube@RuO2 as a high performance catalyst for Li–CO2 batteries, ACS Appl. Mater. Interfaces, 11, 5146, 10.1021/acsami.8b20573 Song, 2020, An ultra-long life, high-performance, flexible Li–CO2 battery based on multifunctional carbon electrocatalysts, Nano Energy, 71, 10.1016/j.nanoen.2020.104595 Feng, 2021, Mechanism-of-action elucidation of reversible Li–CO2 batteries using the water-in-salt electrolyte, ACS Appl. Mater. Interfaces, 13, 7396, 10.1021/acsami.1c01306 Wang, 2021, Bio-inspired design of strong self-standing cathode toward highly stable reversible Li-CO2 batteries, Chem. Eng. J., 426 Xiao, 2021, Ultrafine Co-doped NiO nanoparticles decorated on carbon nanotubes improving the electrochemical performance and cycling stability of Li–CO2 batteries, ACS Appl. Energy Mater. Ma, 2022, Regulating the nucleation of Li2CO3 and C by anchoring Li-containing carbonaceous species towards high performance Li-CO2 batteries, J. Energy Chem., 65, 472, 10.1016/j.jechem.2021.06.016 Zhang, 2021, Breaking the stable triangle of carbonate via W–O bonds for li-co2 batteries with low polarization, ACS Energy Lett., 6, 3503, 10.1021/acsenergylett.1c01428 Liang, 2019, A novel NiFe@NC-functionalized N-doped carbon microtubule network derived from biomass as a highly efficient 3D free-standing cathode for Li-CO2 batteries, Appl. Catal. B Environ., 244, 559, 10.1016/j.apcatb.2018.11.075 Deng, 2021, Electron structure and reaction pathway regulation on porous cobalt-doped CeO2/graphene aerogel: A free-standing cathode for flexible and advanced Li-CO2 batteries, Energy Storage Mater., 42, 484, 10.1016/j.ensm.2021.08.006 Zou, 2021, Synergistic effect of Cu-La0.96Sr0.04Cu0.3Mn0.7O3-δ heterostructure and oxygen vacancy engineering for high-performance Li-CO2 batteries, Electrochim. Acta, 395, 10.1016/j.electacta.2021.139209 Zhai, 2021, Super-assembled atomic Ir catalysts on Te substrates with synergistic catalytic capability for Li-CO2 batteries, Energy Storage Mater., 43, 391, 10.1016/j.ensm.2021.09.017