The effect of synthetic dermal secretion on transfer and dissipation of the insecticide aldicarb from granular formulation to fabric
Tóm tắt
This research investigated the potential for contamination of fabric by aldicarb (Temik® 15G) pesticide. Fabric soiled with synthetic perspiration or synthetic sebum was contaminated with Temir® granules for various time periods and extracted with methanol. Extracts were analyzed with high performance liquid chromatography. The aldicarb transferred to both soiled and unsoiled fabric; however, the sebum soil and longer contact time increased the transfer of aldicarb to fabric. The dissipation of aldicarb from fabric was affected by the soil type and the formulation of the Temik® granule. It is apparent a potential for dermal exposure to granular pesticide exists when the pesticide is trapped in pockets or folds of clothing.
Tài liệu tham khảo
AATCC Technical Manual (1985) American Association of Textile Chemists and Colorists, Research Triangle Park, NC
Altman PE (1961) Blood and other body fluids. Federation of American Societies for Experimental Biology, New York
Baker DE, Bradshaw W (1979) Science and Technology Guide. (Bulletin No. 1918). University of Missouri Extension Division, Columbia
Branson DH, Ayers GS, Henry MS (1986) Effectiveness of selected work fabrics as barriers to pesticide penetration. In: Barker RL, Coletta GC (eds) Performance of protective clothing (ASTM STP 900). American Society for Testing and Materials, Philadelphia, pp 114–120
Cutler WG, Davis RC (eds) (1972) Detergency theory and test methods part 1. Marcel Dekker, NY
Davies JE (1980) Minimizing occupational exposure to pesticides: Personal monitoring. Residue Rev 75:35–50
Downing DT (1976) Mammalian waxes. In: Loattukudy PE (ed) Chemistry and biochemistry of natural waxes. Elsevier Publishing Co, Amsterdam, pp 17–48
Federal Register (1974) 39:16888–16891
Freed VR, Davies JE, Peters LJ, Parveen F (1980) Minimizing occupational exposure to pesticides: Repellency and penetrability of treated textiles to pesticide sprays. Residue Rev 75:159–167
Hadley NF (1985) The adaptive role of lipids in biological systems. John Wiley and Sons, NY, pp 137–138
Hollies NRS (1980) The skin barrier: How does it handle materials lost from clothing? Text Chem Color 12(6):29–30, 40
Hollies NRS, Krejci V, Smith IT (1982) The transfer of chemicals from clothing to skin. Tex Res J 52:370–376
Huisman MA, Morris MA (1971) A study of the removal of synthetic sebum from durable-press fabrics using a liquid scintillation technique. Tex Res J 41:657–666
Jacobs RR (1990) Overview of skin structure, function, and toxicology. In: Johnson JS, Anderson KJ (eds) Chemical protective clothing. Volume 1. American Industrial Hygiene Association, Akron, OH, pp 7–23
Johnson JS, Henry NW, Anderson KJ (1990) Introduction. In: Johnson JS, Anderson KJ (eds) Chemical protective clothing. Volume 1. American Industrial Hygiene Association, Akron, OH, pp 1–5
Johnson JS, Varos J (1990) Chemical protective clothing types, methods of construction, and typical applications. In: Johnson JS, Anderson KJ (eds) Chemical protective clothing. Volume 1. American Industrial Hygiene Association, Akron, OH, pp 69–114
Kurh RJ, Dorough HW (1976) Carbamate insecticides, chemistry and toxicology. CRC Press, Cleveland, OH
Lange NA (1979) Lange's handbook of chemistry. McGraw-Hill, NY
Laughlin JM, Easley CB, Gold RE, Hill RM (1986) Fabric parameters and pesticide characteristics that impact on dermal exposure of applicators. In: Barker RL, Coletta, GC (eds) Performance of protective clothing (ASTM STP 900). American Society for Testing and Materials, Philadelphia, pp 136–150
Laughlin JM, Gold RE (1987) The vaporization of methyl parathion from contaminated cotton fabrics. Tex Chem Color 19(5):39–42
Laughlin J, Gold RE (1990) Methyl parathion residue removal from protective apparel fabric soiled with synthetic sebum or vegetable oil. Arch Environ Contain Toxicol 19:205–213
Lavy TL, Mattice JD, Flynn RR (1983) Field studies monitoring worker exposure to pesticides. In: Seymour KG (ed) Pesticide formation and application (ASTM STP 745). American Society for Testing and Materials, Philadelphia, pp 60–74
Leonas KK, Easter EP, DeJonge JO (1989) Effect of fabric characteristics on pesticide penetration through selected apparel fabrics. Bull Environ Contain Toxicol 43:231–238
Matthews GA (1979) Pesticide Application Methods. Longman Group, Inc., NY
Nigg HN, Stamper JH, Easter E, DeJonge JO (1992) Field evaluation of coverall fabrics; Heat stress and pesticide penetration. Arch Environ Contain Toxicol 23:281–288
Olson W, Nelson CN (1984) Washing clothes worn while applying pesticides (HE-FS-2312). University of Minnesota Agricultural Extension Service, St. Paul
Payne LK, Stansbury HA, Weiden MHJ (1966) The synthesis and insecticidal properties of some cholinergic trisubstituted acetaldehyde o-(methalcarbamoyl)oximes. J Agric Food Chem 14:356–365
Raheel M (1988) Dermal exposure to pesticides. The barrier effectiveness of protective clothing. J Environ Health 51(2):82–84
Raheel M, Gitz EC (1985) Effect of fabric geometry on resistance to pesticide penetration and degradation. Arch Environ Contain Toxicol 14:273–279
Rucker M, Branson D, Nelson C, Olson W, Slocum A, Stone J (1988) Farm households attitudes and practices regarding pesticide application and protective clothing: A five state comparison. Part 1: Pesticide applicators. Clothing Textile Res J 6(4):37–46
Scheuplein RJ, Blank IH (1971) Permeability of the skin. Physiol Rev 51:702–747
Shern LC (1986) Protective clothing actions of Michigan corn and apple growers in regard to pesticides. Unpublished Master's Thesis, Michigan State University, East Lansing
Sparacino CM, Hines JW (1976) High performance liquid chromatography of carbamate pesticides. J Environ Health 48:259–264
Studen LR, Hodgon JD (1981) Evaluation of the private applicator pesticide training and certification program: A five state study. Prepared for US Environmental Protection Agency, Washington, DC by ABT Associates, Inc, Cambridge, MA
Union Carbide (1983) Temik®, aldicarb: A perspective. Union Carbide Agricultural Products Company, Inc, Research Triangle Park, NC
Waldron AC (1985) Minimizing pesticide exposure risk for the mixerloader, applicator, and field worker. In: Honeycutt RC, Zweig G, Ragsdale N (eds) Dermal exposure related to pesticide use (ACS Symposium Series 273). American Chemical Society, Washington, DC, pp 413–425
Wicker GW, Williams WA, Bradley JR, Gerthie FE (1979) Exposure of field workers to organophosphorus pesticides: Cotton. Arch Environ Contain Toxicol 8:433–440
Worthing CR, Walker SB (1983) The Pesticide Manual, 7th ed. Lavenham Press, Laveham, Suffolk, England