Efficient strategies for boosting the performance of 2D graphitic carbon nitride nanomaterials during photoreduction of carbon dioxide to energy-rich chemicals

Angelo, 2017, Research handbook on climate change and agricultural law, Res. Handb. Clim. Chang. Agric. Law., 1 Adegoke, 2018, Photocatalytic conversion of co2 using zno semiconductor by hydrothermal method, Pak. J. Anal. Environ. Chem., 19, 1, 10.21743/pjaec/2018.06.01 Adegoke, 2020, Electrocatalytic conversion of CO2 to hydrocarbon and alcohol products: realities and prospects of Cu-based materials, Sustain. Mater. Technol., 25 Adegoke, 2020, Highly efficient formic acid and carbon dioxide electro-reduction to alcohols on indium oxide electrodes, Sustain. Energy Fuels, 4, 4030, 10.1039/D0SE00623H Shih, 2018, Powering the future with liquid sunshine, Joule, 2, 1925, 10.1016/j.joule.2018.08.016 Charles, 2021, Progress and challenges pertaining to the earthly-abundant electrocatalytic materials for oxygen evolution reaction, Sustain. Mater. Technol., 28 Adegoke, 2021, Porous metal−organic framework (MOF)-based and MOF-derived electrocatalytic materials for energy conversion, Mater. Today Energy, 100816, 10.1016/j.mtener.2021.100816 Song, 2006, Global challenges and strategies for control, conversion and utilization of CO2 for sustainable development involving energy, catalysis, adsorption and chemical processing, Catal. Today, 115, 2, 10.1016/j.cattod.2006.02.029 Li, 2014, A critical review of CO2 photoconversion: catalysts and reactors, Catal. Today, 224, 3, 10.1016/j.cattod.2013.12.006 Stocker, 2013 Goss, 1983 Xu, 2018, Highly efficient photoelectrocatalytic reduction of CO2 on the Ti3C2/g-C3N4 heterojunction with rich Ti3+ and pyri-N species, J. Mater. Chem. A, 6, 15213, 10.1039/C8TA03315C Akhundi, 2020, Graphitic carbon nitride-based photocatalysts: toward efficient organic transformation for value-added chemicals production, Mol. Catal., 488 Han, 2019, Chainmail co-catalyst of NiO shell-encapsulated Ni for improving photocatalytic CO2 reduction over g-C3N4, J. Mater. Chem. A, 7, 9726, 10.1039/C9TA01061K Gao, 2016, Single atom (Pd/Pt) supported on graphitic carbon nitride as an efficient photocatalyst for visible-light reduction of carbon dioxide, J. Am. Chem. Soc., 138, 6292, 10.1021/jacs.6b02692 Xiang, 2012, Synergetic effect of MoS 2 and graphene as cocatalysts for enhanced photocatalytic H 2 production activity of TiO 2 nanoparticles, J. Am. Chem. Soc., 134, 6575, 10.1021/ja302846n Lops, 2019, Sonophotocatalytic degradation mechanisms of Rhodamine B dye via radicals generation by micro- and nano-particles of ZnO, Appl. Catal. B Environ., 243, 629, 10.1016/j.apcatb.2018.10.078 Qin, 2020, Nitrogen-doped hydrogenated TiO2 modified with CdS nanorods with enhanced optical absorption, charge separation and photocatalytic hydrogen evolution, Chem. Eng. J., 384, 10.1016/j.cej.2019.123275 Tang, 2020, All-solid-state Z-scheme WO3 nanorod/ZnIn2S4 composite photocatalysts for the effective degradation of nitenpyram under visible light irradiation, J. Hazard Mater., 387, 10.1016/j.jhazmat.2019.121713 Uddin, 2012, Nanostructured SnO 2-ZnO heterojunction photocatalysts showing enhanced photocatalytic activity for the degradation of organic dyes, Inorg. Chem., 51, 7764, 10.1021/ic300794j Ismael, 2019, Perovskite-type LaFeO 3 : photoelectrochemical properties and photocatalytic degradation of organic pollutants under visible light irradiation, Catalysts, 9, 10.3390/catal9040342 Ma, 2021, Rational design of α-Fe2O3 nanocubes supported BiVO4 Z-scheme photocatalyst for photocatalytic degradation of antibiotic under visible light, J. Colloid Interface Sci., 581, 514, 10.1016/j.jcis.2020.07.127 Wei, 2021, Improved photocatalytic CO2 conversion efficiency on Ag loaded porous Ta2O5, Appl. Surf. Sci., 563, 10.1016/j.apsusc.2021.150273 Huang, 2021, Strategies to enhance photocatalytic activity of graphite carbon nitride-based photocatalysts, Mater. Des., 210, 110040, 10.1016/j.matdes.2021.110040 Li, 2020, Recent advances in g-C3N4-based heterojunction photocatalysts, J. Mater. Sci. Technol., 56, 1, 10.1016/j.jmst.2020.04.028 Ismael, 2020, A review on graphitic carbon nitride (g-C3N4) based nanocomposites: synthesis, categories, and their application in photocatalysis, J. Alloys Compd., 846, 10.1016/j.jallcom.2020.156446 Li, 2020, Design and application of active sites in g-C3N4-based photocatalysts, J. Mater. Sci. Technol., 56, 69, 10.1016/j.jmst.2020.03.033 Darkwah, 2019, Photocatalytic applications of heterostructure graphitic carbon nitride: pollutant degradation, hydrogen gas production (water splitting), and CO2 reduction, Nanoscale Res. Lett., 14, 10.1186/s11671-019-3070-3 Kessler, 2017, Functional carbon nitride materials-design strategies for electrochemical devices, Nat. Rev. Mater., 2, 10.1038/natrevmats.2017.30 Zhou, 2018, Molecular engineering of polymeric carbon nitride: advancing applications from photocatalysis to biosensing and more, Chem. Soc. Rev., 47, 2298, 10.1039/C7CS00840F Wen, 2017, A review on g-C 3 N 4 -based photocatalysts, Appl. Surf. Sci., 391, 72, 10.1016/j.apsusc.2016.07.030 Talapaneni, 2020, Nanostructured carbon nitrides for CO2 capture and conversion, Adv. Mater., 32, 1 Fu, 2018, g-C3N4-Based heterostructured photocatalysts, Adv. Energy Mater., 8, 10.1002/aenm.201701503 Sun, 2018, g-C3N4 based composite photocatalysts for photocatalytic CO2 reduction, Catal. Today, 300, 160, 10.1016/j.cattod.2017.05.033 Lin, 2015, Efficient synthesis of monolayer carbon nitride 2D nanosheet with tunable concentration and enhanced visible-light photocatalytic activities, Appl. Catal. B Environ., 163, 135, 10.1016/j.apcatb.2014.07.053 Niu, 2014, Switching the selectivity of the photoreduction reaction of carbon dioxide by controlling the band structure of a g-C3N4 photocatalyst, Chem. Commun., 50, 10837, 10.1039/C4CC03060E Niu, 2012, Graphene-like carbon nitride nanosheets for improved photocatalytic activities, Adv. Funct. Mater., 22, 4763, 10.1002/adfm.201200922 Kang, 2015, An amorphous carbon nitride photocatalyst with greatly extended visible-light-responsive range for photocatalytic hydrogen generation, Adv. Mater., 27, 4572, 10.1002/adma.201501939 Thomas, 2008, Graphitic carbon nitride materials: variation of structure and morphology and their use as metal-free catalysts, J. Mater. Chem., 18, 4893, 10.1039/b800274f Zheng, 2012, Graphitic carbon nitride materials: controllable synthesis and applications in fuel cells and photocatalysis, Energy Environ. Sci., 5, 6717, 10.1039/c2ee03479d Lakhi, 2017, Mesoporous carbon nitrides: synthesis, functionalization, and applications, Chem. Soc. Rev., 46, 72, 10.1039/C6CS00532B Cao, 2015, Polymeric photocatalysts based on graphitic carbon nitride, Adv. Mater., 27, 2150, 10.1002/adma.201500033 Zhang, 2012, Polymeric carbon nitrides: semiconducting properties and emerging applications in photocatalysis and photoelectrochemical energy conversion, Sci. Adv. Mater., 4, 282, 10.1166/sam.2012.1283 Zhang, 2012, Co-monomer control of carbon nitride semiconductors to optimize hydrogen evolution with visible light, Angew. Chem. Int. Ed., 51, 3183, 10.1002/anie.201106656 Wang, 2010, Boron- and fluorine-containing mesoporous carbon nitride polymers: metal-free catalysts for cyclohexane oxidation, Angew. Chem. Int. Ed., 49, 3356, 10.1002/anie.201000120 Li, 2016, In situ surface alkalinized g-C3N4 toward enhancement of photocatalytic H2 evolution under visible-light irradiation, J. Mater. Chem. A, 4, 2943, 10.1039/C5TA05128B Guo, 2016, Deprotonation of g-C3N4 with Na ions for efficient nonsacrificial water splitting under visible light, J. Mater. Chem. A, 4, 10806, 10.1039/C6TA03424A Lau, 2015, Low-molecular-weight carbon nitrides for solar hydrogen evolution, J. Am. Chem. Soc., 137, 1064, 10.1021/ja511802c Zhang, 2015, Enhanced catalytic activity of potassium-doped graphitic carbon nitride induced by lower valence position, Appl. Catal. B Environ., 164, 77, 10.1016/j.apcatb.2014.09.020 Xiong, 2016, Bridging the g-C3N4 interlayers for enhanced photocatalysis, ACS Catal., 6, 2462, 10.1021/acscatal.5b02922 Zhu, 2017, Metal-free photocatalyst for H2 evolution in visible to near-infrared region: black phosphorus/graphitic carbon nitride, J. Am. Chem. Soc., 139, 13234, 10.1021/jacs.7b08416 Liu, 2015, Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway, Science (80-. ), 347, 970, 10.1126/science.aaa3145 Fu, 2019, Ultrathin 2D/2D WO3/g-C3N4 step-scheme H2-production photocatalyst, Appl. Catal. B Environ., 243, 556, 10.1016/j.apcatb.2018.11.011 Chen, 2017, Facile synthesis and enhanced photocatalytic H2-evolution performance of NiS2-modified g-C3N4 photocatalysts, Chin. J. Catal., 38, 296, 10.1016/S1872-2067(16)62554-8 He, 2018, In situ one-pot fabrication of g-C3N4 nanosheets/NiS cocatalyst heterojunction with intimate interfaces for efficient visible light photocatalytic H2 generation, Appl. Surf. Sci., 430, 208, 10.1016/j.apsusc.2017.08.191 Qiu, 2017, One step synthesis of oxygen doped porous graphitic carbon nitride with remarkable improvement of photo-oxidation activity: role of oxygen on visible light photocatalytic activity, Appl. Catal. B Environ., 206, 319, 10.1016/j.apcatb.2017.01.058 Miao, 2018, Nitrogen-doped carbon dots decorated on g-C3N4/Ag3PO4 photocatalyst with improved visible light photocatalytic activity and mechanism insight, Appl. Catal. B Environ., 227, 459, 10.1016/j.apcatb.2018.01.057 Chen, 2017, Cobalt-doped graphitic carbon nitride photocatalysts with high activity for hydrogen evolution, Appl. Surf. Sci., 392, 608, 10.1016/j.apsusc.2016.09.086 Zhang, 2018, One-pot annealing preparation of Na-doped graphitic carbon nitride from melamine and organometallic sodium salt for enhanced photocatalytic H2 evolution, Int. J. Hydrogen Energy, 43, 13953, 10.1016/j.ijhydene.2018.04.042 Yang, 2019, Plasma-modified Ti3C2Tx/CdS hybrids with oxygen-containing groups for high-efficiency photocatalytic hydrogen production, Nanoscale, 11, 18797, 10.1039/C9NR07242J Li, 2020, Porous graphitic carbon nitride for solar photocatalytic applications, Nanoscale Horiz., 5, 765, 10.1039/D0NH00046A Ba, 2019, Simultaneous formation of mesopores and homojunctions in graphite carbon nitride with enhanced optical absorption, charge separation and photocatalytic hydrogen evolution, Appl. Catal. B Environ., 253, 359, 10.1016/j.apcatb.2019.04.084 Liu, 2019, Quenching induced hierarchical 3D porous g-C3N4 with enhanced photocatalytic CO2 reduction activity, Chem. Commun., 55, 14023, 10.1039/C9CC07647F Bellardita, 2018, Selective photocatalytic oxidation of aromatic alcohols in water by using P-doped g-C3N4, Appl. Catal. B Environ., 220, 222, 10.1016/j.apcatb.2017.08.033 Liu, 2018, Synthesis of synergetic phosphorus and cyano groups (CN) modified g-C3N4 for enhanced photocatalytic H2 production and CO2 reduction under visible light irradiation, Appl. Catal. B Environ., 232, 521, 10.1016/j.apcatb.2018.03.094 Zhang, 2014, In situ ion exchange synthesis of strongly coupled Ag@AgCl/g-C3N4 porous nanosheets as plasmonic photocatalyst for highly efficient visible-light photocatalysis, ACS Appl. Mater. Interfaces, 6, 22116, 10.1021/am505528c Zhu, 2018, Visible light-driven photocatalytically active g-C3N4 material for enhanced generation of H2O2, Appl. Catal. B Environ., 232, 19, 10.1016/j.apcatb.2018.03.035 Zhang, 2019, Facile synthesis of nitrogen-deficient mesoporous graphitic carbon nitride for highly efficient photocatalytic performance, Appl. Surf. Sci., 478, 304, 10.1016/j.apsusc.2019.01.270 Dong, 2017, Morphology and defects regulation of carbon nitride by hydrochloric acid to boost visible light absorption and photocatalytic activity, Appl. Catal. B Environ., 217, 629, 10.1016/j.apcatb.2017.06.028 Kumar, 2021, An overview on polymeric carbon nitride assisted photocatalytic CO2 reduction: strategically manoeuvring solar to fuel conversion efficiency, Chem. Eng. Sci., 230, 116219, 10.1016/j.ces.2020.116219 Shen, 2018, Converting CO2 into fuels by graphitic carbon nitride-based photocatalysts, Nanotechnology, 29, 10.1088/1361-6528/aad4c8 Ghosh, 2021, Photocatalytic CO2reduction over g-C3N4based heterostructures: recent progress and prospects, J. Environ. Chem. Eng., 9, 104631 Liu, 2020, Recent advancements in g-C3N4-based photocatalysts for photocatalytic CO2reduction: a mini review, RSC Adv., 10, 29408, 10.1039/D0RA05779G Lang, 2014, Heterogeneous visible light photocatalysis for selective organic transformations, Chem. Soc. Rev., 43, 473, 10.1039/C3CS60188A Liu, 2018, Unique physicochemical properties of two-dimensional light absorbers facilitating photocatalysis, Chem. Soc. Rev., 47, 6410, 10.1039/C8CS00396C Yang, 2018, Photocatalysis: from fundamental principles to materials and applications, ACS Appl. Energy Mater., 1, 6657, 10.1021/acsaem.8b01345 Liu, 2011, Achieving maximum photo-oxidation reactivity of Cs0.68Ti 1.83O4-xNx photocatalysts through valence band fine-tuning, Catal. Sci. Technol., 1, 222, 10.1039/c0cy00029a Hautier, 2013, Identification and design principles of low hole effective mass p-type transparent conducting oxides, Nat. Commun., 4, 10.1038/ncomms3292 Yang, 2016, Enhanced photocatalytic H2 production in core–shell engineered rutile TiO2, Adv. Mater., 28, 5850, 10.1002/adma.201600495 Li, 2013, Spatial separation of photogenerated electrons and holes among {010} and {110} crystal facets of BiVO 4, Nat. Commun., 4 Khan, 2019, Recent advancements in engineering approach towards design of photo-reactors for selective photocatalytic CO2 reduction to renewable fuels, J. CO2 Util., 29, 205, 10.1016/j.jcou.2018.12.008 Habisreutinger, 2013, Photocatalytic reduction of CO2 on TiO2 and other semiconductors, Angew. Chem. Int. Ed., 52, 7372, 10.1002/anie.201207199 Sun, 2018, Catalysis of carbon dioxide photoreduction on nanosheets: fundamentals and challenges, Angew. Chem. Int. Ed., 57, 7610, 10.1002/anie.201710509 Li, 2015, Engineering heterogeneous semiconductors for solar water splitting, J. Mater. Chem. A, 3, 2485, 10.1039/C4TA04461D Inoue, 1979, Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders [3], Nature, 277, 637, 10.1038/277637a0 Anpo, 1995, Photocatalytic reduction of CO2 with H2O on various titanium oxide catalysts, J. Electroanal. Chem., 396, 21, 10.1016/0022-0728(95)04141-A Anpo, 1992, Photocatalytic reduction of CO2 on anchored titanium oxide catalysts, J. Mol. Catal., 74, 207, 10.1016/0304-5102(92)80238-C Todorova, 2020, Photocatalytic h2evolution, co2reduction, and noxoxidation by highly exfoliated g-c3n4, Catalysts, 10, 1, 10.3390/catal10101147 Ikeue, 2001, Photocatalytic reduction of CO2 with H2O on Ti-β zeolite photocatalysts: effect of the hydrophobic and hydrophilic properties, J. Phys. Chem. B, 105, 8350, 10.1021/jp010885g Subrahmanyam, 1999, A screening for the photo reduction of carbon dioxide supported on metal oxide catalysts for C1-C3 selectivity, Appl. Catal. B Environ., 23, 169, 10.1016/S0926-3373(99)00079-X Yang, 2011, Mechanistic study of hydrocarbon formation in photocatalytic CO2 reduction over Ti-SBA-15, J. Catal., 284, 1, 10.1016/j.jcat.2011.08.005 Dimitrijevic, 2012, Dynamics of interfacial charge transfer to formic acid, formaldehyde, and methanol on the surface of TiO 2 nanoparticles and its role in methane production, J. Phys. Chem. C, 116, 878, 10.1021/jp2090473 Liu, 2012, Spontaneous dissociation of CO 2 to CO on defective surface of Cu(I)/TiO 2- x nanoparticles at room temperature, J. Phys. Chem. C, 116, 7904, 10.1021/jp300932b Kočí, 2009, Effect of TiO2 particle size on the photocatalytic reduction of CO2, Appl. Catal. B Environ., 89, 494, 10.1016/j.apcatb.2009.01.010 Wang, 2019, Modeling the effect of Cu doped TiO2 with carbon dots on CO2 methanation by H2O in a photo-thermal system, Appl. Catal. B Environ., 256, 10.1016/j.apcatb.2019.117780 Kohno, 2000, Reaction mechanism in the photoreduction of CO2 with CH4 over ZrO2, Phys. Chem. Chem. Phys., 2, 5302, 10.1039/b005315p Fung, 2020, Recent progress in two-dimensional nanomaterials for photocatalytic carbon dioxide transformation into solar fuels, Mater. Today Sustain., 9, 100037, 10.1016/j.mtsust.2020.100037 Tan, 2006, Photocatalytic reduction of carbon dioxide into gaseous hydrocarbon using TiO2 pellets, Catal. Today, 115, 269, 10.1016/j.cattod.2006.02.057 Nie, 2013, Selectivity of CO2 reduction on copper electrodes: the role of the kinetics of elementary steps, Angew. Chem. Int. Ed., 52, 2459, 10.1002/anie.201208320 Shkrob, 2012, Photoredox reactions and the catalytic cycle for carbon dioxide fixation and methanogenesis on metal oxides, J. Phys. Chem. C, 116, 9450, 10.1021/jp300122v Shkrob, 2012, Heteroatom-transfer coupled photoreduction and carbon dioxide fixation on metal oxides, J. Phys. Chem. C, 116, 9461, 10.1021/jp300123z Kuhl, 2012, New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces, Energy Environ. Sci., 5, 7050, 10.1039/c2ee21234j Schouten, 2011, A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes, Chem. Sci., 2, 1902, 10.1039/c1sc00277e Li, 2019, Cocatalysts for selective photoreduction of CO 2 into solar fuels, Chem. Rev., 119, 3962, 10.1021/acs.chemrev.8b00400 Tachibana, 2012, Artificial photosynthesis for solar water-splitting, Nat. Photonics, 6, 511, 10.1038/nphoton.2012.175 Zhou, 2012, Towards highly efficient photocatalysts using semiconductor nanoarchitectures, Energy Environ. Sci., 5, 6732, 10.1039/c2ee03447f Zhao, 2016, Layered double hydroxide nanostructured photocatalysts for renewable energy production, Adv. Energy Mater., 6, 10.1002/aenm.201501974 Li, 2016, Nanostructured catalysts for electrochemical water splitting: current state and prospects, J. Mater. Chem. A, 4, 11973, 10.1039/C6TA02334G Chen, 2015, Synthetic strategies to nanostructured photocatalysts for CO2 reduction to solar fuels and chemicals, J. Mater. Chem. A, 3, 14487, 10.1039/C5TA01592H Xie, 2016, Photocatalytic and photoelectrocatalytic reduction of CO2 using heterogeneous catalysts with controlled nanostructures, Chem. Commun., 52, 35, 10.1039/C5CC07613G Shiraishi, 2005, Adsorption-driven photocatalytic activity of mesoporous titanium dioxide, J. Am. Chem. Soc., 127, 12820, 10.1021/ja053265s Ikeda, 2007, Size-selective photocatalytic reactions by titanium(IV) oxide coated with a hollow silica shell in aqueous solutions, Phys. Chem. Chem. Phys., 9, 6319, 10.1039/b709891j Shen, 2009, Selective photocatalysis on molecular imprinted TiO2 thin films prepared via an improved liquid phase deposition method, New J. Chem., 33, 1673, 10.1039/b901087d Kou, 2017, Selectivity enhancement in heterogeneous photocatalytic transformations, Chem. Rev., 117, 1445, 10.1021/acs.chemrev.6b00396 Ikeda, 2007, Encapsulation of titanium(IV) oxide particles in hollow silica for size-selective photocatalytic reactions, Chem. Commun., 3753, 10.1039/b704468b Inumaru, 2011, Nanocomposites of crystalline TiO2 particles and mesoporous silica: molecular selective photocatalysis tuned by controlling pore size and structure, J. Mater. Chem., 21, 12117, 10.1039/c1jm11839k Zhang, 2013, Aggregation- and leaching-resistant, reusable, and multifunctional Pd@CeO2 as a robust nanocatalyst achieved by a hollow core-shell strategy, Chem. Mater., 25, 1979, 10.1021/cm400750c Ghosh-Mukerji, 2003, Controlled mass transport as a means for obtaining selective photocatalysis, J. Photochem. Photobiol. A Chem., 160, 77, 10.1016/S1010-6030(03)00224-7 Ghosh-Mukerji, 2001, Selective photocatalysis by means of molecular recognition [20], J. Am. Chem. Soc., 123, 10776, 10.1021/ja0117635 Higashimoto, 2009, Selective photocatalytic oxidation of benzyl alcohol and its derivatives into corresponding aldehydes by molecular oxygen on titanium dioxide under visible light irradiation, J. Catal., 266, 279, 10.1016/j.jcat.2009.06.018 Shen, 2012, Molecular imprinting for removing highly toxic organic pollutants, Chem. Commun., 48, 788, 10.1039/C2CC14654A Tang, 2012, Selective photocatalysis mediated by magnetic molecularly imprinted polymers, Separ. Purif. Technol., 95, 165, 10.1016/j.seppur.2012.05.004 Zhang, 2012, Transforming CdS into an efficient visible light photocatalyst for selective oxidation of saturated primary C-H bonds under ambient conditions, Chem. Sci., 3, 2812, 10.1039/c2sc20603j Liu, 2010, Tunable photocatalytic selectivity of hollow TiO2 microspheres composed of anatase polyhedra with exposed {001} facets, J. Am. Chem. Soc., 132, 11914, 10.1021/ja105283s Xiang, 2011, Tunable photocatalytic selectivity of TiO2 films consisted of flower-like microspheres with exposed (001) facets, Chem. Commun., 47, 4532, 10.1039/c1cc10501a Palmisano, 2010, Advances in selective conversions by heterogeneous photocatalysis, Chem. Commun., 46, 7074, 10.1039/c0cc02087g Palmisano, 2011, Titania photocatalysts for selective oxidations in water, ChemSusChem, 4, 1431, 10.1002/cssc.201100196 Brusa, 2007, Photocatalytic air oxidation of cyclohexane in CH2Cl2-C6H12 mixtures over TiO2 particles. An attempt to rationalize the positive effect of dichloromethane on the yields of valuable oxygenates, J. Mol. Catal. Chem., 268, 29, 10.1016/j.molcata.2006.12.008 Augugliaro, 2008, Photocatalytic oxidation of aromatic alcohols to aldehydes in aqueous suspension of home-prepared titanium dioxide. 1. Selectivity enhancement by aliphatic alcohols, Appl. Catal. Gen., 349, 182, 10.1016/j.apcata.2008.07.032 Lang, 2011, Selective formation of imines by aerobic photocatalytic oxidation of amines on TiO2, Angew. Chem. Int. Ed., 50, 3934, 10.1002/anie.201007056 Mao, 2018, Visible light driven selective oxidation of amines to imines with BiOCl: does oxygen vacancy concentration matter?, Appl. Catal. B Environ., 228, 87, 10.1016/j.apcatb.2018.01.018 Parrino, 2008, Semiconductor-photocatalyzed sulfoxidation of alkanes, Angew. Chem. Int. Ed., 47, 7107, 10.1002/anie.200800326 Li, 2003, Synthesis and photocatalytic oxidation properties of iron doped titanium dioxide nanosemiconductor particles, New J. Chem., 27, 1264, 10.1039/b301998e Zhang, 2013, Band-gap tuning of N-doped TiO2 photocatalysts for visible-light-driven selective oxidation of alcohols to aldehydes in water, RSC Adv., 3, 7215, 10.1039/c3ra40518d Meng, 2018, Simultaneous dehydrogenation and hydrogenolysis of aromatic alcohols in one reaction system via visible-light-driven heterogeneous photocatalysis, J. Catal., 357, 247, 10.1016/j.jcat.2017.11.015 Kubacka, 2009, W, N-codoped tio2-anatase: a sunlight-operated catalyst for efficient and selective aromatic hydrocarbons photo-oxidation, J. Phys. Chem. C, 113, 8553, 10.1021/jp902618g Qamar, 2015, Highly efficient and selective oxidation of aromatic alcohols photocatalyzed by nanoporous hierarchical Pt/Bi2WO6 in organic solvent-free environment, ACS Appl. Mater. Interfaces, 7, 1257, 10.1021/am507428r Fujishima, 2000, Titanium dioxide photocatalysis, J. Photochem. Photobiol. C Photochem. Rev., 1, 1, 10.1016/S1389-5567(00)00002-2 Tahir, 2013, Advances in visible light responsive titanium oxide-based photocatalysts for CO2 conversion to hydrocarbon fuels, Energy Convers. Manag., 76, 194, 10.1016/j.enconman.2013.07.046 Wang, 2012, Polymeric graphitic carbon nitride as a heterogeneous organocatalyst: from photochemistry to multipurpose catalysis to sustainable chemistry, Angew. Chem. Int. Ed., 51, 68, 10.1002/anie.201101182 Kudo, 2009, Heterogeneous photocatalyst materials for water splitting, Chem. Soc. Rev., 38, 253, 10.1039/B800489G Vinu, 2009, Photocatalytic activity of Ag-substituted and impregnated nano-TiO2, Appl. Catal. A Gen., 366, 130, 10.1016/j.apcata.2009.06.048 Shen, 2007, Synthesis of molecular imprinted polymer coated photocatalysts with high selectivity, Chem. Commun., 1163, 10.1039/b615303h Wackerlig, 2015, Molecularly imprinted polymer nanoparticles in chemical sensing - synthesis, characterisation and application, Sensor. Actuator. B Chem., 207, 144, 10.1016/j.snb.2014.09.094 Shen, 2014, Selective photocatalytic degradation of nitrobenzene facilitated by molecular imprinting with a transition state analog, Catal. Today, 225, 164, 10.1016/j.cattod.2013.07.011 Bhatia, 2017, An overview of microdiesel — a sustainable future source of renewable energy, Renew. Sustain. Energy Rev., 79, 1078, 10.1016/j.rser.2017.05.138 Samanta, 2020, Catalytic conversion of CO 2 to chemicals and fuels: the collective thermocatalytic/photocatalytic/electrocatalytic approach with graphitic carbon nitride, Mater. Adv., 1, 1506, 10.1039/D0MA00293C Hasselman, 2006, Theoretical solar-to-electrical energy-conversion efficiencies of perylene-porphyrin light-harvesting arrays, J. Phys. Chem. B, 110, 25430, 10.1021/jp064547x Lang, 2016, Mobility anisotropy of two-dimensional semiconductors, Phys. Rev. B, 10.1103/PhysRevB.94.235306 Li, 2016, Charge transport and mobility engineering in two-dimensional transition metal chalcogenide semiconductors, Chem. Soc. Rev., 45, 118, 10.1039/C5CS00517E Liu, 2012, Photocatalytic CO2 reduction with H2O on TiO2 nanocrystals: comparison of anatase, rutile, and brookite polymorphs and exploration of surface chemistry, ACS Catal., 2, 1817, 10.1021/cs300273q Ola, 2015, Review of material design and reactor engineering on TiO2 photocatalysis for CO2 reduction, J. Photochem. Photobiol. C Photochem. Rev., 24, 16, 10.1016/j.jphotochemrev.2015.06.001 Ola, 2012, Performance comparison of CO 2 conversion in slurry and monolith photoreactors using Pd and Rh-TiO 2 catalyst under ultraviolet irradiation, Appl. Catal. B Environ., 126, 172, 10.1016/j.apcatb.2012.07.024 Sastre, 2012, 185 nm photoreduction of CO 2 to methane by water. Influence of the presence of a basic catalyst, J. Am. Chem. Soc., 134, 14137, 10.1021/ja304930t Song, 2015, Photocatalytic reduction of carbon dioxide over ZnFe2O4/TiO2 nanobelts heterostructure in cyclohexanol, J. Colloid Interface Sci., 442, 60, 10.1016/j.jcis.2014.11.039 Kočí, 2008, Effect of temperature, pressure and volume of reacting phase on photocatalytic CO2 reduction on suspended nanocrystalline TiO 2, Collect. Czech Chem. Commun., 73, 1192, 10.1135/cccc20081192 Tseng, 2002, Photoreduction of CO2 using sol-gel derived titania and titania-supported copper catalysts, Appl. Catal. B Environ., 37, 37, 10.1016/S0926-3373(01)00322-8 Tahir, 2013, Photocatalytic CO2 reduction with H2O vapors using montmorillonite/TiO2 supported microchannel monolith photoreactor, Chem. Eng. J., 230, 314, 10.1016/j.cej.2013.06.055 Sharma, 2017, Photocatalytic reduction of carbon dioxide to methanol using nickel-loaded TiO2 supported on activated carbon fiber, Catal. Today, 298, 158, 10.1016/j.cattod.2017.05.003 Chen, 2016, Production of renewable fuels by the photohydrogenation of CO2: effect of the Cu species loaded onto TiO2 photocatalysts, Phys. Chem. Chem. Phys., 18, 4942, 10.1039/C5CP06999H Tahir, 2016, Photocatalytic CO2 methanation over NiO/In2O3 promoted TiO2 nanocatalysts using H2O and/or H2 reductants, Energy Convers. Manag., 119, 368, 10.1016/j.enconman.2016.04.057 Song, 2018, Alternative pathways for efficient CO2 capture by hybrid processes—a review, Renew. Sustain. Energy Rev., 82, 215, 10.1016/j.rser.2017.09.040 Zhang, 2009, Photocatalytic reduction of CO2 with H2O on Pt-loaded TiO2 catalyst, Catal. Today, 148, 335, 10.1016/j.cattod.2009.07.081 Park, 2015, Effective CH4 production from CO2 photoreduction using TiO2/x mol% Cu-TiO2 double-layered films, Energy Convers. Manag., 103, 431, 10.1016/j.enconman.2015.06.029 Mehrotra, 2005, Macro kinetic studies for photocatalytic degradation of benzoic acid in immobilized systems, Chemosphere, 60, 1427, 10.1016/j.chemosphere.2005.01.074 Merajin, 2013, Photocatalytic conversion of greenhouse gases (CO2 and CH4) to high value products using TiO2 nanoparticles supported on stainless steel webnet, J. Taiwan Inst. Chem. Eng., 44, 239, 10.1016/j.jtice.2012.11.007 Lo, 2007, Photoreduction of carbon dioxide with H2 and H2O over TiO2 and ZrO2 in a circulated photocatalytic reactor, Sol. Energy Mater. Sol. Cells, 91, 1765, 10.1016/j.solmat.2007.06.003 Nguyen, 2008, Photoreduction of CO2 in an optical-fiber photoreactor: effects of metals addition and catalyst carrier, Appl. Catal. A Gen., 335, 112, 10.1016/j.apcata.2007.11.022 Liou, 2011, Photocatalytic CO2 reduction using an internally illuminated monolith photoreactor, Energy Environ. Sci., 4, 1487, 10.1039/c0ee00609b Xiong, 2017, Photocatalytic CO2 reduction over V and W codoped TiO2 catalyst in an internal-illuminated honeycomb photoreactor under simulated sunlight irradiation, Appl. Catal. B Environ., 219, 412, 10.1016/j.apcatb.2017.07.078 Lee, 2013, A novel twin reactor for CO2 photoreduction to mimic artificial photosynthesis, Appl. Catal. B Environ., 132–133, 445, 10.1016/j.apcatb.2012.12.024 Chu, 2017, Modeling photocatalytic conversion of carbon dioxide in bubbling twin reactor, Energy Convers. Manag., 149, 514, 10.1016/j.enconman.2017.07.049 Qin, 2013, Photocatalytic reduction of carbon dioxide to formic acid, formaldehyde, and methanol using dye-sensitized TiO2film, Appl. Catal. B Environ., 129, 599, 10.1016/j.apcatb.2012.10.012 Ampelli, 2010, Synthesis of solar fuels by a novel photoelectrocatalytic approach, Energy Environ. Sci., 3, 292, 10.1039/b925470f Li, 2016, Photocatalytic CO2 conversion to methanol by Cu2O/graphene/TNA heterostructure catalyst in a visible-light-driven dual-chamber reactor, Nano Energy, 27, 320, 10.1016/j.nanoen.2016.06.056 Morikawa, 2014, Photocatalytic conversion of carbon dioxide into methanol in reverse fuel cells with tungsten oxide and layered double hydroxide photocatalysts for solar fuel generation, Catal. Sci. Technol., 4, 1644, 10.1039/C3CY00959A Guan, 2003, Reduction of carbon dioxide with water under concentrated sunlight using photocatalyst combined with Fe-based catalyst, Appl. Catal. B Environ., 41, 387, 10.1016/S0926-3373(02)00174-1 Nguyen, 2008, Photoreduction of CO2 over Ruthenium dye-sensitized TiO2-based catalysts under concentrated natural sunlight, Catal. Commun., 9, 2073, 10.1016/j.catcom.2008.04.004 Wang, 2019, Insights into photocatalytic CO2 reduction on C3N4: strategy of simultaneous B, K co-doping and enhancement by N vacancies, Appl. Catal. B Environ., 254, 270, 10.1016/j.apcatb.2019.05.002 Fu, 2020, Product selectivity of photocatalytic CO2 reduction reactions, Mater. Today, 32, 222, 10.1016/j.mattod.2019.06.009 Tong, 2015, An efficient top-down approach for the fabrication of large-aspect-ratio g-C3N4 nanosheets with enhanced photocatalytic activities, Phys. Chem. Chem. Phys., 17, 23532, 10.1039/C5CP04057D Ding, 2017, Graphitic carbon nitride-based nanocomposites as visible-light driven photocatalysts for environmental purification, Environ. Sci. Nano, 4, 1455, 10.1039/C7EN00255F Schwinghammer, 2014, Crystalline carbon nitride nanosheets for improved visible-light hydrogen evolution, J. Am. Chem. Soc., 136, 1730, 10.1021/ja411321s Zhang, 2013, Enhanced photoresponsive ultrathin graphitic-phase C3N4 nanosheets for bioimaging, J. Am. Chem. Soc., 135, 18, 10.1021/ja308249k Bai, 2014, Two-dimensional g-C3N4: an ideal platform for examining facet selectivity of metal co-catalysts in photocatalysis, Chem. Commun., 50, 6094, 10.1039/C4CC00745J Zhao, 2014, Fabrication of atomic single layer graphitic-C3N4 and its high performance of photocatalytic disinfection under visible light irradiation, Appl. Catal. B Environ., 152–153, 46, 10.1016/j.apcatb.2014.01.023 Yang, 2013, Exfoliated graphitic carbon nitride nanosheets as efficient catalysts for hydrogen evolution under visible light, Adv. Mater., 25, 2452, 10.1002/adma.201204453 She, 2014, Exfoliated graphene-like carbon nitride in organic solvents: enhanced photocatalytic activity and highly selective and sensitive sensor for the detection of trace amounts of Cu2+, J. Mater. Chem. A, 2, 2563, 10.1039/c3ta13768f Zhang, 2015, Two-dimensional covalent carbon nitride nanosheets: synthesis, functionalization, and applications, Energy Environ. Sci., 8, 3092, 10.1039/C5EE01895A Yang, 2011, Graphene-based carbon nitride nanosheets as efficient metal-free electrocatalysts for oxygen reduction reactions, Angew. Chem. Int. Ed. Zhang, 2011, Sulfur-mediated synthesis of carbon nitride: band-gap engineering and improved functions for photocatalysis, Energy Environ. Sci., 4, 675, 10.1039/C0EE00418A Zhang, 2015, Sol processing of conjugated carbon nitride powders for thin-film fabrication, Angew. Chem. Int. Ed., 54, 6297, 10.1002/anie.201501001 Sun, 2015, Facile synthesis of high photocatalytic active porous g-C3N4 with ZnCl2 template, J. Colloid Interface Sci., 451, 108, 10.1016/j.jcis.2015.03.059 Zheng, 2015, Graphitic carbon nitride polymers toward sustainable photoredox catalysis, Angew. Chem. Int. Ed., 54, 12868, 10.1002/anie.201501788 Wang, 2017, Recent advances of graphitic carbon nitride-based structures and applications in catalyst, sensing, imaging, and leds, Nano-Micro Lett., 9, 1, 10.1007/s40820-017-0148-2 Liang, 2021, Recent progress on carbon nitride and its hybrid photocatalysts for CO2 reduction, Sol. RRL, 5, 2000478, 10.1002/solr.202000478 Zhang, 2021, Advancing graphitic carbon nitride-based photocatalysts toward broadband solar energy harvesting, ACS Mater. Lett., 3, 663, 10.1021/acsmaterialslett.1c00160 Wang, 2020, Graphitic carbon nitride-based photocatalytic materials: preparation strategy and application, ACS Sustain. Chem. Eng., 8, 16048, 10.1021/acssuschemeng.0c05246 Li, 2021, Preparation, characterization of graphitic carbon nitride photo-catalytic nanocomposites and their application in wastewater remediation: a review, Crystals, 11 Wang, 2009, A metal-free polymeric photocatalyst for hydrogen production from water under visible light, Nat. Mater., 8, 76, 10.1038/nmat2317 Huo, 2021, Amine-modified S-scheme porous g-C3N4/CdSe-diethylenetriamine composite with enhanced photocatalytic CO2 Reduction activity, ACS Appl. Energy Mater., 4, 956, 10.1021/acsaem.0c02896 Yan, 2009, Photodegradation performance of g-C3N4 fabricated by directly heating melamine, Langmuir, 25, 10397, 10.1021/la900923z Dong, 2012, Porous structure dependent photoreactivity of graphitic carbon nitride under visible light, J. Mater. Chem., 22, 1160, 10.1039/C1JM14312C Zhang, 2012, Porous graphitic carbon nitride synthesized via direct polymerization of urea for efficient sunlight-driven photocatalytic hydrogen production, Nanoscale, 4, 5300, 10.1039/c2nr30948c Mo, 2015, Synthesis of g-C3N4 at different temperatures for superior visible/UV photocatalytic performance and photoelectrochemical sensing of MB solution, RSC Adv., 5, 101552, 10.1039/C5RA19586A Luo, 2021, Controllable synthesis of nitrogen-doped carbon containing Co and Co3Fe7 nanoparticles as effective catalysts for electrochemical oxygen conversion, J. Colloid Interface Sci., 590, 622, 10.1016/j.jcis.2021.01.097 Shen, 2019, Facile large-scale synthesis of macroscopic 3D porous graphene-like carbon nanosheets architecture for efficient CO2 adsorption, Carbon N. Y., 145, 751, 10.1016/j.carbon.2019.01.093 Wang, 2018, Dramatic enhancement of CO2 photoreduction by biodegradable light-management paper, Adv. Energy Mater., 8, 2 Shen, 2020, Facile synthesis of silica nanosheets with hierarchical pore structure and their amine-functionalized composite for enhanced CO2 capture, Chem. Eng. Sci., 217, 10.1016/j.ces.2020.115528 Hollmann, 2014, Structure-activity relationships in bulk polymeric and sol-gel-derived carbon nitrides during photocatalytic hydrogen production, Chem. Mater., 26, 1727, 10.1021/cm500034p Dong, 2013, Engineering the nanoarchitecture and texture of polymeric carbon nitride semiconductor for enhanced visible light photocatalytic activity, J. Colloid Interface Sci., 401, 70, 10.1016/j.jcis.2013.03.034 He, 2015, The facile synthesis of mesoporous g-C3N4 with highly enhanced photocatalytic H2 evolution performance, Chem. Commun., 51, 16244, 10.1039/C5CC06713H Long, 2014, Thermally-induced desulfurization and conversion of guanidine thiocyanate into graphitic carbon nitride catalysts for hydrogen photosynthesis, J. Mater. Chem. A., 2, 2942, 10.1039/c3ta14339b Niu, 2014, Increasing the visible light absorption of graphitic carbon nitride (Melon) photocatalysts by homogeneous self-modifi cation with nitrogen vacancies, Adv. Mater., 26, 8046, 10.1002/adma.201404057 Goettmann, 2006, Chemical synthesis of mesoporous carbon nitrides using hard templates and their use as a metal-free catalyst for Friedel-Crafts reaction of benzene, Angew. Chem. Int. Ed., 45, 4467, 10.1002/anie.200600412 Jun, 2009, Mesoporous, 2D hexagonal carbon nitride and titanium nitride/carbon composites, Adv. Mater., 21, 4270, 10.1002/adma.200803500 Zhang, 2013, An optimized and general synthetic strategy for fabrication of polymeric carbon nitride nanoarchitectures, Adv. Funct. Mater., 23, 3008, 10.1002/adfm.201203287 Wang, 2015, Environment-friendly preparation of porous graphite-phase polymeric carbon nitride using calcium carbonate as templates, and enhanced photoelectrochemical activity, J. Mater. Chem. A, 3, 5126, 10.1039/C4TA06778A Shen, 2011, Facile one-pot synthesis of bimodal mesoporous carbon nitride and its function as a lipase immobilization support, J. Mater. Chem., 21, 3890, 10.1039/c0jm03666h Wang, 2010, Facile one-pot synthesis of nanoporous carbon nitride solids by using soft templates, ChemSusChem, 3, 435, 10.1002/cssc.200900284 Jun, 2013, From melamine-cyanuric acid supramolecular aggregates to carbon nitride hollow spheres, Adv. Funct. Mater., 23, 3661, 10.1002/adfm.201203732 Liao, 2014, Tailoring the morphology of g-C3N4 by self-assembly towards high photocatalytic performance, ChemCatChem, 6, 3419, 10.1002/cctc.201402654 Shalom, 2014, In situ formation of heterojunctions in modified graphitic carbon nitride: synthesis and noble metal free photocatalysis, Chem. Mater., 26, 5812, 10.1021/cm503258z Jordan, 2015, “Caffeine doping” of carbon/nitrogen-based organic catalysts: caffeine as a supramolecular edge modifier for the synthesis of photoactive carbon nitride tubes, Chem Cat Chem, 7, 2826 Pawar, 2019, In situ reduction and exfoliation of g-C 3 N 4 nanosheets with copious active sites via a thermal approach for effective water splitting, Catal. Sci. Technol., 9, 1004, 10.1039/C8CY02318B Mo, 2019, Porous nitrogen-rich g-C3N4 nanotubes for efficient photocatalytic CO2 reduction, Appl. Catal. B Environ., 256, 117854, 10.1016/j.apcatb.2019.117854 Xu, 2019, Nanostructured materials for photocatalysis to cite this version : HAL Id : hal-02185643 Nanostructured materials for photocatalysis, Chem. Soc. Rev., 48, 3868, 10.1039/C9CS00102F Yang, 2018, Efficient nanomaterials for harvesting clean fuels from electrochemical and photoelectrochemical CO 2 reduction, Sustain. Energy Fuels, 2, 510, 10.1039/C7SE00371D Wang, 2014, The potential of carbon-based materials for photocatalytic application, Curr. Org. Chem., 18, 1346, 10.2174/1385272819666140424214022 Kandy, 2020, Carbon-based photocatalysts for enhanced photocatalytic reduction of CO2 to solar fuels, Sustain. Energy Fuels, 4, 469, 10.1039/C9SE00827F Xia, 2018, 2D/2D g-C3N4/MnO2 nanocomposite as a direct Z-scheme photocatalyst for enhanced photocatalytic activity, ACS Sustain. Chem. Eng., 6, 965, 10.1021/acssuschemeng.7b03289 Sun, 2019, Mesocrystals for photocatalysis: a comprehensive review on synthesis engineering and functional modifications, Nanoscale Adv, 1, 34, 10.1039/C8NA00196K Liu, 2016, 3 Jiang, 2018, A hierarchical Z-scheme α-Fe2O3/g-C3N4 hybrid for enhanced photocatalytic CO2 reduction, Adv. Mater., 30, 1, 10.1002/adma.201706108 Shi, 2019, Defects promote ultrafast charge separation in graphitic carbon nitride for enhanced visible-light-driven CO 2 reduction activity, Chem. Eur J., 25, 5028, 10.1002/chem.201805923 Serpone, 1995, Subnanosecond relaxation dynamics in TiO2 colloidal sols (particle sizes Rp = 1.0-13.4 nm). Relevance to heterogeneous photocatalysis, J. Phys. Chem., 99, 16655, 10.1021/j100045a027 ming Su, 2016, Recent advances in the photocatalytic reduction of carbon dioxide, Environ. Chem. Lett., 14, 99, 10.1007/s10311-015-0528-0 L. Zhang, M. Li, M. Wang, J. Shi, Converting CO2 into fuels by graphitic carbon nitride based photocatalysts, (n.d.) 3–4. Wen, 2017, Fabricating the robust g-C3N4 nanosheets/carbons/NiS multiple heterojunctions for enhanced photocatalytic H2 generation: an insight into the trifunctional roles of nanocarbons, ACS Sustain. Chem. Eng., 5, 2224, 10.1021/acssuschemeng.6b02490 Wang, 2016, Indirect Z-scheme BiOI/g-C3N4 photocatalysts with enhanced photoreduction CO2 activity under visible light irradiation, ACS Appl. Mater. Interfaces, 8, 3765, 10.1021/acsami.5b09901 He, 2015, New application of Z-scheme Ag3PO4/g-C3N4 composite in converting CO2 to fuel, Environ. Sci. Technol., 49, 649, 10.1021/es5046309 Di, 2017 Huo, 2019, All-solid-state artificial Z-scheme porous g-C3N4/Sn2S3-DETA heterostructure photocatalyst with enhanced performance in photocatalytic CO2 reduction, Appl. Catal. B Environ., 241, 528, 10.1016/j.apcatb.2018.09.073 Huo, 2021, Efficient interfacial charge transfer of 2D/2D porous carbon nitride/bismuth oxychloride step-scheme heterojunction for boosted solar-driven CO2 reduction, J. Colloid Interface Sci., 585, 684, 10.1016/j.jcis.2020.10.048 Di, 2017, A direct Z-scheme g-C3N4/SnS2 photocatalyst with superior visible-light CO2 reduction performance, J. Catal., 352, 532, 10.1016/j.jcat.2017.06.006 Adekoya, 2017, g-C3N4/(Cu/TiO2) nanocomposite for enhanced photoreduction of CO2 to CH3OH and HCOOH under UV/visible light, J. CO2 Util., 18, 261, 10.1016/j.jcou.2017.02.004 Shen, 2020, Adsorption-enhanced nitrogen-doped mesoporous CeO2as an efficient visible-light-driven catalyst for CO2 photoreduction, J. CO2 Util., 39, 2 Wang, 2020, Application of ion beam technology in (photo)electrocatalytic materials for renewable energy, Appl. Phys. Rev., 7, 10.1063/5.0021322 Zhang, 2017, Visible-light-driven photooxidation of alcohols using surface-doped graphitic carbon nitride, Green Chem., 19, 2096, 10.1039/C7GC00539C Djurišić, 2020, Visible-light photocatalysts: prospects and challenges, Apl. Mater., 8, 10.1063/1.5140497 Jiang, 2016, Enhancement of catalytic activity and oxidative ability for graphitic carbon nitride, J. Photochem. Photobiol. C Photochem. Rev., 28, 87, 10.1016/j.jphotochemrev.2016.06.001 Wang, 2016, Facile one-step synthesis of hybrid graphitic carbon nitride and carbon composites as high-performance catalysts for CO2 photocatalytic conversion, ACS Appl. Mater. Interfaces, 8, 17212, 10.1021/acsami.6b03472 Liu, 2017, Enhanced photocatalytic conversion of greenhouse gas CO2 into solar fuels over g-C3N4 nanotubes with decorated transparent ZIF-8 nanoclusters, Appl. Catal. B Environ., 211, 1, 10.1016/j.apcatb.2017.04.009 Huang, 2013, Well-dispersed g-C3N4 nanophases in mesoporous silica channels and their catalytic activity for carbon dioxide activation and conversion, Appl. Catal. B Environ., 136–137, 269, 10.1016/j.apcatb.2013.01.057 Liu, 2018, Phosphorus-doped graphitic carbon nitride nanotubes with amino-rich surface for efficient CO2 capture, enhanced photocatalytic activity, and product selectivity, ACS Appl. Mater. Interfaces, 10, 4001, 10.1021/acsami.7b17503 Fagan, 2016, Photocatalytic properties of g-C3N4-TiO2 heterojunctions under UV and visible light conditions, Materials (Basel), 9, 10.3390/ma9040286 Zhou, 2014, Facile in situ synthesis of graphitic carbon nitride (g-C3N4)-N-TiO2 heterojunction as an efficient photocatalyst for the selective photoreduction of CO2 to CO, Appl. Catal. B Environ., 158–159, 20, 10.1016/j.apcatb.2014.03.037 Li, 2016, Graphene in photocatalysis: a review, Small, 12, 6640, 10.1002/smll.201600382 Chen, 2012, Thermodynamic oxidation and reduction potentials of photocatalytic semiconductors in aqueous solution, Chem. Mater., 24, 3659, 10.1021/cm302533s Di, 2016, Enhanced photocatalytic H 2 production on CdS nanorod using cobalt-phosphate as oxidation cocatalyst, Appl. Surf. Sci., 389, 775, 10.1016/j.apsusc.2016.08.002 Wang, 2014, Semiconductor-redox catalysis promoted by metal-organic frameworks for CO2 reduction, Phys. Chem. Chem. Phys., 16, 14656, 10.1039/c4cp02173h Pan, 2012, Plasmon-enhanced photocatalytic properties of Cu 2O nanowire-Au nanoparticle assemblies, Langmuir, 28, 12304, 10.1021/la301813v Wang, 2020, Porous two-dimensional materials for photocatalytic and electrocatalytic applications, Matter, 2, 1377, 10.1016/j.matt.2020.04.002 Wang, 2014, Cu(II) as a general cocatalyst for improved visible-light photocatalytic performance of photosensitive Ag-based compounds, J. Phys. Chem. C, 118, 8891, 10.1021/jp410413s Peng, 2015, Ultrasound assisted synthesis of ZnO/reduced graphene oxide composites with enhanced photocatalytic activity and anti-photocorrosion, Appl. Surf. Sci., 356, 762, 10.1016/j.apsusc.2015.08.070 Chen, 2017, Two-dimensional nanomaterials for photocatalytic CO2 reduction to solar fuels, Sustain. Energy Fuels, 1, 1875, 10.1039/C7SE00344G Low, 2016, Carbon-based two-dimensional layered materials for photocatalytic CO2 reduction to solar fuels, Energy Storage Mater., 3, 24, 10.1016/j.ensm.2015.12.003 Li, 2015, Preparation and characterization of graphene oxide/Ag 2 CO 3 photocatalyst and its visible light photocatalytic activity, Appl. Surf. Sci., 358, 168, 10.1016/j.apsusc.2015.07.007 Raziq, 2015, Synthesis of TiO2/g-C3N4 nanocomposites as efficient photocatalysts dependent on the enhanced photogenerated charge separation, Mater. Res. Bull., 70, 494, 10.1016/j.materresbull.2015.05.018 Zhang, 2016, Ultrasound exfoliation of g-C3N4 with assistance of cadmium ions and synthesis of CdS/g-C3N4 ultrathin nanosheets with efficient photocatalytic activity, J. Taiwan Inst. Chem. Eng., 60, 643, 10.1016/j.jtice.2015.11.013 Yu, 2015, In situ self-transformation synthesis of g-C 3 N 4 -modified CdS heterostructure with enhanced photocatalytic activity, Appl. Surf. Sci., 358, 385, 10.1016/j.apsusc.2015.06.074 Tian, 2015, Mixed-calcination synthesis of CdWO 4/g-C 3 N 4 heterojunction with enhanced visible-light-driven photocatalytic activity, Appl. Surf. Sci., 358, 343, 10.1016/j.apsusc.2015.07.154 Zhu, 2015, Synthesis of g-C3N4/Ag3VO4 composites with enhanced photocatalytic activity under visible light irradiation, Chem. Eng. J., 271, 96, 10.1016/j.cej.2015.02.018 Maeda, 2013, Z-scheme water splitting using two different semiconductor photocatalysts, ACS Catal., 3, 1486, 10.1021/cs4002089 Li, 2020, Crystalline carbon nitride supported copper single atoms for photocatalytic CO2 reduction with nearly 100% CO selectivity, ACS Nano, 14, 10552, 10.1021/acsnano.0c04544 Cometto, 2021, Copper single-atoms embedded in 2D graphitic carbon nitride for the CO2 reduction, Npj 2D Mater. Appl., 5, 63, 10.1038/s41699-021-00243-y Cao, 2018, Single Pt atom with highly vacant d-orbital for accelerating photocatalytic H2 evolution, ACS Appl. Energy Mater., 1, 6082, 10.1021/acsaem.8b01143 Deng, 2015, Triggering the electrocatalytic hydrogen evolution activity of the inert two-dimensional MoS2 surface via single-atom metal doping, Energy Environ. Sci., 8, 1594, 10.1039/C5EE00751H Ta, 2018, Single Cr atom catalytic growth of graphene, Nano Res, 11, 2405, 10.1007/s12274-017-1861-3 Wang, 2017, Two-dimensional materials confining single atoms for catalysis, Chin. J. Catal., 38, 1443, 10.1016/S1872-2067(17)62839-0 Xiao, 2021, Single metal atom decorated carbon nitride for efficient photocatalysis: synthesis, structure, and applications, Sol. RRL, 5, 2000609, 10.1002/solr.202000609 He, 2019, Single Pt atom decorated graphitic carbon nitride as an efficient photocatalyst for the hydrogenation of nitrobenzene into aniline, Nano Res, 12, 1817, 10.1007/s12274-019-2439-z Huang, 2021, Effect of carbon doping on CO2-reduction activity of single cobalt sites in graphitic carbon nitride, ChemNanoMat, 10.1002/cnma.202100164 Cheng, 2020, Single Ni atoms anchored on porous few-layer g-C3N4 for photocatalytic CO2 reduction: the role of edge confinement, Small, 16, 2002411, 10.1002/smll.202002411 Liu, 2021, Junction engineering for photocatalytic and photoelectrocatalytic CO2 reduction, Sol. RRL, 5, 2000430, 10.1002/solr.202000430 Tu, 2017, Investigating the role of tunable nitrogen vacancies in graphitic carbon nitride nanosheets for efficient visible-light-driven H2 evolution and CO2 reduction, ACS Sustain. Chem. Eng., 5, 7260, 10.1021/acssuschemeng.7b01477 Zou, 2021, Nitrogen vacancy engineering in graphitic carbon nitride for strong, stable, and wavelength tunable electrochemiluminescence emissions, Anal. Chem., 93, 2678, 10.1021/acs.analchem.0c05027 Xie, 2011, Self-doped SrTiO 3-δ photocatalyst with enhanced activity for artificial photosynthesis under visible light, Energy Environ. Sci., 4, 4211, 10.1039/c1ee01594j Zhao, 2015, Defect-rich ultrathin ZnAl-layered double hydroxide nanosheets for efficient photoreduction of CO2 to CO with water, Adv. Mater., 27, 7824, 10.1002/adma.201503730 Lin, 2014, Photochemical reduction of CO2 by graphitic carbon nitride polymers, ACS Sustain. Chem. Eng., 2, 353, 10.1021/sc4004295 Kuriki, 2017, Robust binding between carbon nitride nanosheets and a binuclear ruthenium(II) complex enabling durable, selective CO2 reduction under visible light in aqueous solution, Angew. Chem. Int. Ed., 56, 4867, 10.1002/anie.201701627 ten Elshof, 2016, Two-dimensional metal oxide and metal hydroxide nanosheets: synthesis, controlled assembly and applications in energy conversion and storage, Adv. Energy Mater., 6, 10.1002/aenm.201600355 Chen, 2010, Semiconductor-based photocatalytic hydrogen generation, Chem. Rev., 110, 6503, 10.1021/cr1001645 Kang, 2018, Improving the photocatalytic activity of graphitic carbon nitride by thermal treatment in a high-pressure hydrogen atmosphere, Prog. Nat. Sci. Mater. Int., 28, 183, 10.1016/j.pnsc.2018.02.006 Wen, 2013, Hybrid artificial photosynthetic systems comprising semiconductors as light harvesters and biomimetic complexes as molecular cocatalysts, Acc. Chem. Res., 46, 2355, 10.1021/ar300224u Liu, 2010, Titania-based photocatalysts - crystal growth, doping and heterostructuring, J. Mater. Chem., 20, 831, 10.1039/B909930A Tang, 2019, Midgap-state-mediated two-step photoexcitation in nitrogen defect-modified g-C3N4 atomic layers for superior photocatalytic CO2 reduction, Catal. Sci. Technol., 9, 2335, 10.1039/C9CY00449A Shen, 2019, Carbon-vacancy modified graphitic carbon nitride: enhanced CO 2 photocatalytic reduction performance and mechanism probing, J. Mater. Chem. A., 7, 1556, 10.1039/C8TA09302D Yang, 2019, Carbon vacancies in a melon polymeric matrix promote photocatalytic carbon dioxide conversion, Angew. Chem. Int. Ed., 58, 1134, 10.1002/anie.201810648 Novoselov, 2004, Electric field in atomically thin carbon films, Science (80-. ), 306, 666, 10.1126/science.1102896 Lee, 2018, Copper-doped flower-like molybdenum disulfide/bismuth sulfide photocatalysts for enhanced solar water splitting, Int. J. Hydrogen Energy, 43, 748, 10.1016/j.ijhydene.2017.10.169 Shi, 2018, Photocatalytic reduction of CO 2 to CO over copper decorated g-C 3 N 4 nanosheets with enhanced yield and selectivity, Appl. Surf. Sci., 427, 1165, 10.1016/j.apsusc.2017.08.148 Ying Tang, 2018, Enhancement of photocatalytic performance in CO2 reduction over Mg/g-C3N4 catalysts under visible light irradiation, Catal. Commun., 107, 92, 10.1016/j.catcom.2018.01.006 Wang, 2016, Synthesis of Mo-doped graphitic carbon nitride catalysts and their photocatalytic activity in the reduction of CO2 with H2O, Catal. Commun., 74, 75, 10.1016/j.catcom.2015.10.029 Sun, 2017, Enriching CO2 activation sites on graphitic carbon nitride with simultaneous introduction of electron-transfer promoters for superior photocatalytic CO2-to-Fuel conversion, Adv. Sustain. Syst., 1, 1700003, 10.1002/adsu.201700003 Wang, 2020, Potassium-doped g-C3N4 achieving efficient visible-light-driven CO2 reduction, ACS Sustain. Chem. Eng., 8, 8214, 10.1021/acssuschemeng.0c01151 Mamba, 2016, Graphitic carbon nitride (g-C3N4) nanocomposites: a new and exciting generation of visible light driven photocatalysts for environmental pollution remediation, Appl. Catal. B Environ., 198, 347, 10.1016/j.apcatb.2016.05.052 Luo, 2016, Shape and composition effects on photocatalytic hydrogen production for Pt-Pd alloy cocatalysts, ACS Appl. Mater. Interfaces, 8, 20667, 10.1021/acsami.6b04388 Ng, 2018, Sub-2 nm Pt-decorated Zn0.5Cd0.5S nanocrystals with twin-induced homojunctions for efficient visible-light-driven photocatalytic H2 evolution, Appl. Catal. B Environ., 224, 360, 10.1016/j.apcatb.2017.10.005 Yang, 2013, Ar300227E.Pdf, Accounts Chem. Res., 46, 1900, 10.1021/ar300227e Clavero, 2014, Plasmon-induced hot-electron generation at nanoparticle/metal-oxide interfaces for photovoltaic and photocatalytic devices, Nat. Photonics, 8, 95, 10.1038/nphoton.2013.238 Seh, 2012, Janus Au-TiO 2 photocatalysts with strong localization of plasmonic near-fields for efficient visible-light hydrogen generation, Adv. Mater., 24, 2310, 10.1002/adma.201104241 Yu, 2014, Photocatalytic reduction of CO2 into hydrocarbon solar fuels over g-C3N4-Pt nanocomposite photocatalysts, Phys. Chem. Chem. Phys., 16, 11492, 10.1039/c4cp00133h Cao, 2017, Facet effect of Pd cocatalyst on photocatalytic CO2 reduction over g-C3N4, J. Catal., 349, 208, 10.1016/j.jcat.2017.02.005 Lang, 2017, Twin defects engineered Pd cocatalyst on C3N4 nanosheets for enhanced photocatalytic performance in CO2 reduction reaction, Nanotechnology, 28, 484003, 10.1088/1361-6528/aa9137 Wang, 2018, DFT study on sulfur-doped g-C3N4 nanosheets as a photocatalyst for CO2 reduction reaction, J. Phys. Chem. C, 122, 7712, 10.1021/acs.jpcc.8b00098 Wang, 2015, Sulfur-doped g-C3N4 with enhanced photocatalytic CO2-reduction performance, Appl. Catal. B Environ., 176–177, 44 Kumar, 2018, Facile one-pot two-step synthesis of novel in situ selenium-doped carbon nitride nanosheet photocatalysts for highly enhanced solar fuel production from CO2, ACS Appl. Nano Mater., 1, 47, 10.1021/acsanm.7b00024 Shcherban, 2016, Simple method for preparing of sulfur–doped graphitic carbon nitride with superior activity in CO2 photoreduction, ChemistrySelect, 1, 4987, 10.1002/slct.201601283 Ye, 2016, Phosphorylation of g-C3N4 for enhanced photocatalytic CO2 reduction, Chem. Eng. J., 304, 376, 10.1016/j.cej.2016.06.059 Ansari, 2013, Carbon dioxide augmented oxidation of aromatic alcohols over mesoporous carbon nitride as a metal free catalyst, Catal. Sci. Technol., 3, 1261, 10.1039/c3cy20869a Xu, 2015, Metal halides supported on mesoporous carbon nitride as efficient heterogeneous catalysts for the cycloaddition of CO2, J. Mol. Catal. A Chem., 403, 77, 10.1016/j.molcata.2015.03.024 Lan, 2016, Phosphorous-modified bulk graphitic carbon nitride: facile preparation and application as an acid-base bifunctional and efficient catalyst for CO2 cycloaddition with epoxides, Carbon N. Y., 100, 81, 10.1016/j.carbon.2015.12.098 Marschall, 2014, Semiconductor composites: strategies for enhancing charge carrier separation to improve photocatalytic activity, Adv. Funct. Mater., 24, 2421, 10.1002/adfm.201303214 Zhang, 2015, Waltzing with the versatile platform of graphene to synthesize composite photocatalysts, Chem. Rev., 115, 10307, 10.1021/acs.chemrev.5b00267 Kumar, 2016, Nickel decorated on phosphorous-doped carbon nitride as an efficient photocatalyst for reduction of nitrobenzenes, Nanomaterials, 6, 10.3390/nano6040059 Xie, 2015, Advances in graphene-based semiconductor photocatalysts for solar energy conversion: fundamentals and materials engineering, Nanoscale, 7, 13278, 10.1039/C5NR03338A Tu, 2013, An in situ simultaneous reduction-hydrolysis technique for fabrication of TiO2-graphene 2D sandwich-like hybrid nanosheets: graphene-promoted selectivity of photocatalytic-driven hydrogenation and coupling of CO 2 into methane and ethane, Adv. Funct. Mater., 23, 1743, 10.1002/adfm.201202349 Luo, 2016, Recent advances in 2D materials for photocatalysis, Nanoscale, 8, 6904, 10.1039/C6NR00546B Ran, 2014, Earth-abundant cocatalysts for semiconductor-based photocatalytic water splitting, Chem. Soc. Rev., 43, 7787, 10.1039/C3CS60425J Ong, 2020, Rational design of carbon-based 2D nanostructures for enhanced photocatalytic CO2 reduction: a dimensionality perspective, Chem. Eur J., 26, 9710, 10.1002/chem.202000708 Rahman, 2016, Surface activated carbon nitride nanosheets with optimized electro-optical properties for highly efficient photocatalytic hydrogen production, J. Mater. Chem. A, 4, 2445, 10.1039/C5TA10194H Xu, 2017, Making co-condensed amorphous carbon/g-C3N4 composites with improved visible-light photocatalytic H2-production performance using Pt as cocatalyst, Carbon N. Y., 118, 241, 10.1016/j.carbon.2017.03.052 Xiang, 2015, Graphene-based photocatalysts for solar-fuel generation, Angew. Chem. Int. Ed., 54, 11350, 10.1002/anie.201411096 Shi, 2014, Polymeric g-C3N4 coupled with NaNbO3 nanowires toward enhanced photocatalytic reduction of CO2 into renewable fuel, ACS Catal., 4, 3637, 10.1021/cs500848f Li, 2015, Highly selective CO2 photoreduction to CO over g-C3N4/Bi2WO6 composites under visible light, J. Mater. Chem. A., 3, 5189, 10.1039/C4TA06295G Li, 2021, Mesoporous g-C3N4/MXene (Ti3C2Tx) heterojunction as a 2D electronic charge transfer for efficient photocatalytic CO2 reduction, Appl. Surf. Sci., 546, 149111, 10.1016/j.apsusc.2021.149111 Gong, 2021, Facile synthesis of C3N4-supported metal catalysts for efficient CO2 photoreduction, Nano Res Lin, 2021, Graphitic carbon nitride-based Z-scheme structure for photocatalytic CO2 reduction, Energy Fuels, 35, 7, 10.1021/acs.energyfuels.0c03048 Hou, 2021, Variable dimensional structure and interface design of g-C3N4/BiOI composites with oxygen vacancy for improving visible-light photocatalytic properties, J. Clean. Prod., 287, 125072, 10.1016/j.jclepro.2020.125072 Huang, 2015, Efficient photocatalytic reduction of CO 2 by amine-functionalized g-C 3 N 4, Appl. Surf. Sci., 358, 350, 10.1016/j.apsusc.2015.07.082 Qin, 2015, Photocatalytic reduction of CO2 by graphitic carbon nitride polymers derived from urea and barbituric acid, Appl. Catal. B Environ., 179, 1, 10.1016/j.apcatb.2015.05.005 Ovcharov, 2015, Hard template synthesis of porous carbon nitride materials with improved efficiency for photocatalytic CO2 utilization, Mater. Sci. Eng. B Solid-State Mater. Adv. Technol., 202, 1, 10.1016/j.mseb.2015.08.003 Zheng, 2014, Helical graphitic carbon nitrides with photocatalytic and optical activities, Angew. Chem. Int. Ed., 53, 11926, 10.1002/anie.201407319 Sun, 2017, Enhanced CO2 photocatalytic reduction on alkali-decorated graphitic carbon nitride, Appl. Catal. B Environ., 216, 146, 10.1016/j.apcatb.2017.05.064 Fu, 2017, Hierarchical porous O-doped g-C3N4 with enhanced photocatalytic CO2 reduction activity, Small, 13, 1, 10.1002/smll.201603938 Mao, 2013, Effect of graphitic carbon nitride microstructures on the activity and selectivity of photocatalytic CO2 reduction under visible light, Catal. Sci. Technol., 3, 1253, 10.1039/c3cy20822b Xia, 2017, Ultra-thin nanosheet assemblies of graphitic carbon nitride for enhanced photocatalytic CO2 reduction, J. Mater. Chem. A, 5, 3230, 10.1039/C6TA08310B Dao, 2020, Boosting photocatalytic CO2Reduction efficiency by heterostructures of NH2-MIL-101(Fe)/g-C3N4, ACS Appl. Energy Mater., 3, 3946, 10.1021/acsaem.0c00352 Xu, 2021, Realizing efficient CO2 photoreduction in Bi3O4Cl: constructing van der Waals heterostructure with g-C3N4, Chem. Eng. J., 409, 128178, 10.1016/j.cej.2020.128178 Osterloh, 2017, Photocatalysis versus photosynthesis: a sensitivity analysis of devices for solar energy conversion and chemical transformations, ACS Energy Lett, 2, 445, 10.1021/acsenergylett.6b00665 Rajeshwar, 2015, Photocatalytic activity of inorganic semiconductor surfaces: myths, hype, and reality, J. Phys. Chem. Lett., 6, 139, 10.1021/jz502586p He, 2020, Recent advances in solar-driven carbon dioxide conversion: expectations versus reality, ACS Energy Lett, 5, 1996, 10.1021/acsenergylett.0c00645 Chang, 2016, CO2 photo-reduction: insights into CO2 activation and reaction on surfaces of photocatalysts, Energy Environ. Sci., 9, 2177, 10.1039/C6EE00383D Xiao, 2019, Enhancing photocatalytic activity of tantalum nitride by rational suppression of bulk, interface and surface charge recombination, Appl. Catal. B Environ., 246, 195, 10.1016/j.apcatb.2019.01.053 Kamat, 2018, Semiconductor photocatalysis: “tell us the complete story!”, ACS Energy Lett., 3, 622, 10.1021/acsenergylett.8b00196 Kramm, 2019, Pitfalls in heterogeneous thermal, electro- and photocatalysis, ChemCatChem, 11, 2563, 10.1002/cctc.201900137 Raziq, 2018, Synthesis of S-Doped porous g-C3N4 by using ionic liquids and subsequently coupled with Au-TiO2 for exceptional cocatalyst-free visible-light catalytic activities, Appl. Catal. B Environ., 237, 1082, 10.1016/j.apcatb.2018.06.009 Hu, 2019, Insight into the kinetics and mechanism of visible-light photocatalytic degradation of dyes onto the P doped mesoporous graphitic carbon nitride, J. Alloys Compd., 794, 594, 10.1016/j.jallcom.2019.04.235 Liu, 2021, Fine tuning of phosphorus active sites on g-C3N4 nanosheets for enhanced photocatalytic decontamination, J. Mater. Chem. A, 9, 10933, 10.1039/D1TA01537K Sun, 2016, Applications of hierarchically structured porous materials from energy storage and conversion, catalysis, photocatalysis, adsorption, separation, and sensing to biomedicine, Chem. Soc. Rev., 45, 3479, 10.1039/C6CS00135A Morris, 2009, Molecular approaches to the photocatalytic reduction of carbon dioxide for solar fuels, Acc. Chem. Res., 42, 1983, 10.1021/ar9001679 Fujita, 1999, Photochemical carbon dioxide reduction with metal complexes, Coord. Chem. Rev., 185–186, 373, 10.1016/S0010-8545(99)00023-5 Takeda, 2008, Development of an efficient photocatalytic system for CO2 reduction using rhenium(I) complexes based on mechanistic studies, J. Am. Chem. Soc., 130, 2023, 10.1021/ja077752e Regalbuto, 2006