Normalization and calculation of lanthanide element concentrations in environmental samples

Biophysik - Tập 28 - Trang 213-221 - 1989
B. Markert1, H. Piehler1, H. Lieth1, A. Sugimae2
1Systems Research Group, University of Osnabrück, Osnabrück, Germany
2Industrial Technology Research Institute, Osaka Prefecture, Osaka, Japan

Tóm tắt

A mathematical model for the prediction of lanthanide element concentrations in soil and plant samples is presented. A comparison between pre dicted and measured lanthanide values in soil and plant samples show, that the model produces good results for the elements in the soil samples and for most elements in plant material. The accuracy of prediction worsens with decreasing concentration of the heavier lanthanide elements. The mathematical model presented is not valid on other environmental samples like aerosols, because no data for these matrices are available yet to calibrate our normalized curves.

Tài liệu tham khảo

Fryer BJ, Taylor RP (1987) Rare-earth element distribution in uraninites: implications for ore genesis. Chem Geol 63:101–108 Harkins WD (1928) cited after Hollemann AF, Wiberg E (1976) Lehrbuch der Anorganischen Chemie. De Gruyter, Berlin Kabata-Pendias A, Pendias H (1984) Trace elements in soils and plants. CRC Press, Boca Raton, Florida Laul JC, Weimer WC, Rancitelli LA (1979) Biogeochemical distribution of rare earths and other trace elements in plants and soils. In: Ahrens LH (ed) Origin and distribution of the elements. Pergamon Press, Oxford, pp 819–827 Markert B (1987) The pattern of distribution of lanthanide elements in soils and plants. Phytochemistry 26:3167–3170 Masuda A, Nakamura N, Tanaka T (1973) Fine structure of mutually normalized rare-earth patterns of chondrites. Geochim Cosmochim Acta 37:239–248 Nance WB, Taylor SR (1976) Rare earth element patterns and crustal evolution I. Australian post-Archean sedimentary rocks. Geochim Cosmochim Acta 40:1539–1551 Nance WB, Taylor SR (1977) Rare earth element patterns and crustal evolution II. Archean sedimentary rocks from Kalgoorlie, Australia. Geochim Cosmochim Acta 41:225–231 Sugimae A (1980) Atmospheric Concentrations and sources of rare earth elements in the Osaka area, Japan Atmospheric environment 14:1171–1175 Taylor SR, Gorton MP (1977) Geochemical application of spark source mass spectrography II. Element sensitivity, precision and accuracy. Geochim Cosmochim Acta 41:1375–1380