<scp><scp>BiFeO</scp></scp><sub>3</sub> Ceramics: Processing, Electrical, and Electromechanical Properties

Journal of the American Ceramic Society - Tập 97 Số 7 - Trang 1993-2011 - 2014
Tadej Rojac1, Andreja Benčan1, Barbara Malič1, Goknur Tutuncu2, Jacob L. Jones3, J. Daniels4, Dragan Damjanović5
1Electronic Ceramics Department, Jozef Stefan Institute, Ljubljana, 1000 Slovenia
2Department of Materials Science and Engineering, University of Florida, Gainesville, 32611 Florida
3Department of Materials Science and Engineering, North Carolina State University, Raleigh, 27695 North Carolina
4School of Materials Science and Engineering, University of New South Wales, NSW 2052, Australia
5Ceramics Laboratory, Swiss Federal Institute of Technology (EPFL), Lausanne 1015, Switzerland

Tóm tắt

Bismuth ferrite (BiFeO3), a perovskite material, rich in properties and with wide functionality, has had a marked impact on the field of multiferroics, as evidenced by the hundreds of articles published annually over the past 10 years. Studies from the very early stages and particularly those on polycrystalline BiFeO3 ceramics have been faced with difficulties in the preparation of the perovskite free of secondary phases. In this review, we begin by summarizing the major processing issues and clarifying the thermodynamic and kinetic origins of the formation and stabilization of the frequently observed secondary, nonperovskite phases, such as Bi25FeO39 and Bi2Fe4O9. The second part then focuses on the electrical and electromechanical properties of BiFeO3, including the electrical conductivity, dielectric permittivity, high‐field polarization, and strain response, as well as the weak‐field piezoelectric properties. We attempt to establish a link between these properties and address, in particular, the macroscopic response of the ceramics under an external field in terms of the dynamic interaction between the pinning centers (e.g., charged defects) and the ferroelectric/ferroelastic domain walls.

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Journal of the American Ceramic Society

Tập 97 Số 7

1993-2011

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