Extractive distillation of binary azeotropic mixtures
Tóm tắt
The conditions have been determined under which an azeotropic binary mixture can be separated by extractive distillation and under which separation into almost pure components is impossible at any amount of the extracting agent. A general algorithm is suggested for analysis of special manifolds in order to see whether extractive distillation is efficient.
Tài liệu tham khảo
Kazaz, M.S., Mozzhukhin, A.S., and Serafimov, L.A., Selecting a Separating Agent for Distillation: Azeotropic Drying of Ethanol with Amines, Tr. Mosk. Inst. Tonkoi Khim. Tekhnol., 1972, vol. 2,issue 2, p. 102.
Serafimov, L.A., Classification of the Phase Diagrams of Real Batch Distillation, Teor. Osn. Khim. Tekhnol., 2001, vol. 35, no. 3, p. [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 35, no. 3, p. 237].
Serafimov, L.A. and Frolkova, A.K., Fundamental Principle of Concentration-Field Redistribution between Separation Regions as a Basis for the Design of Technological Systems, Teor. Osn. Khim. Tekhnol., 1997, vol. 31, no. 2, p. 184 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 31, no. 2, p. 159].
Zharov, V.T. and Serafimov, L.A., Fiziko-khimicheskie osnovy distillyatsii i rektifikatsii (Physical and Chemical Foundations of Distillation and Rectification), Leningrad: Khimiya, 1975.
Pisarenko, Yu.A. and Serafimov, L.A., Some Properties of the Tie-Line Vector Fields in the Diagrams of Multicomponent Mixtures, Uch. Zap. MITKhT, 2003, no. 8, p. 13.
Serafimov, L.A. and Pisarenko, Yu.A., α = 1 Manifolds in Two-Phase Multicomponent Systems, Teor. Osn. Khim. Tekhnol., 2004, vol. 38, no. 3, p. 261 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 38, no. 3, p. 243].
Kushner, T.M., Tatsievskaya, G.A., and Serafimov, L.A., Arrangement of K = 1 and α = 1 Lines in Ternary Systems Containing One Nonvolatile Component, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1988, vol. 18, no. 4, p. 583.
Münster, A., Chemische Thermodynamik, Berlin: Akademie, 1969.
Serafimov, L.A., Zharov, V.T., and Vitman, T.A., Arrangement of Some Isomanifolds in the Equilibrium Diagrams of Two-Phase Multicomponent Systems, Zh. Fiz. Khim., 1972, vol. 46, no. 11, p. 2724.
Vitman, T.A., Kushner, T.M., and Serafimov, L.A., Arrangement of Some Isomanifolds in Three-Phase Systems Containing One Nonvolatile Component, Zh. Fiz. Khim., 1978, vol. 52, no. 9, p. 2278.
Serafimov, L.A., Tatsievskaya, G.I., and Frolkova, A.K., Extractive Distillation Systems with Separating Agents Undistributed between Phases, Teor. Osn. Khim. Tekhnol., 2004, vol. 38, no. 1, p. 24 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 38, no. 1, p. 22].
Serafimov, L.A., Gol’berg, Yu.E., Kiva, V.N., et al., Basic Properties of α = 1 Manifolds and Their Arrangement in Concentration Spaces, in Khimiya (Chemistry), Ivanovo: Ivanov. Energeticheskii Inst., 1972, issue 14, p. 166.
Reshetov, S.A. and Kravchenko, S.V., Statistics of Liquid-Vapor Phase Equilibrium Diagrams for Various Ternary Zeotropic Mixtures, Teor. Osn. Khim. Tekhnol., 2007, vol. 41, no. 4, p. 439 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 41, no. 4, p. 451].
Susarev, M.P., Kudryavtseva, L.S., and Eizen, O.G., Troinye azeotropnye sistemy (Ternary Azeotropic Systems), Tallinn: Valgus, 1973.
Storonkin, A.V., Termodinamika geterogennykh sistem (Thermodynamics of Heterogeneous Systems), Leningrad: Leningr. Gos. Univ., 1967.
Serafimov, L.A., in Azeotropiya i poliazeotropiya (Azeotropy and Polyazeotropy), Moscow: Khimiya, 1968, p. 186.
Bancroft, W.D., The Phase Rule, New York: Ithaca, 1897.
Demusenko, E.V. and Mozzhukhin, A.S., Bancroft Rule and Its Applicability in Designing Rectification Flow Sheets, Teor. Osn. Khim. Tekhnol., 1997, vol. 31, no. 5, p. 491 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 31, no. 5, p. 444].
Boyarinov, A.I., Vetokhin, V.N., Gartman, T.N., et al., Distillation Region Boundary Calculations, Zh. Fiz. Khim., 1974, vol. 48, no. 2, p. 299.
Van Dongen, D. and Doherty, M., On the Dynamics of Distillation Processes: V. Topology of the Boiling Temperature Surface and Its Relation to Azeotropic Distillation, Chem. Eng. Sci., 1984, vol. 39, no. 5, p. 883.
Serafimov, L.A., Thermodynamic and Topological Analysis and Problems in Separation of Multicomponent Polyazeotropic Mixtures, Teor. Osn. Khim. Tekhnol., 1987, vol. 21, no. 1, p. 74.
Serafimov, L.A. and Frolkova, A.K., Investigation of the Modified Form of the Van der Waals-Storonkin Equation, Teor. Osn. Khim. Tekhnol., 1999, vol. 33, no. 4, p. 341 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 33, no. 4, p. 305].
Serafimov, L.A., Frolkova, A.K., and Chelyuskina, T.V., Equation Relating the Tie-Line Vector Field and the Temperature (Pressure) Scalar Field for Two-Phase Liquid-Vapor Systems, Vestn. MITKhT, 2007, vol. 2, no. 2, p. 73.
Serafimov, L.A., Bushina, D.I., and Chelyuskina, T.V., Heterogeneous Systems of Extractive Rectification with One High-Boiling Component, Teor. Osn. Khim. Tekhnol., 2007, vol. 41, no. 6, p. 646 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 41, no. 6, p. 839].
Serafimov, L.A. and Timoshenko, A.V., Analysis of Distillation Using the Mass-Transfer Equation in Multicomponent Mixtures, Teor. Osn. Khim. Tekhnol., 2005, vol. 39, no. 4, p. 407 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 39, no. 4, p. 385].
Kushner, T.M., Shutova, G.V., and Serafimov, L.A., Evolution of the Liquid-Vapor Equilibrium Diagrams of Biazeotropic Binary Mixtures under Pressure Variations, in Voprosy termodinamiki geterogennykh sistem i teorii poverkhnostnykh yavlenii (Topics in Surface Thermodynamics and Surface Phenomenon Theory), St. Petersburg: Sankt Peterburg Univ., 1992, p. 64.
Kushner, T.M., Shutova, G.V., and Serafimov, L.A., Pseudoideal Points of Vapor-Liquid Equilibrium Diagrams and the Role That They Play in the Evolution of Binary Azeotropes under Temperature (Pressure) Variations, Zh. Fiz. Khim., 2001, vol. 75, no. 7, p. 1196 [Russ. J. Phys. Chem. (Engl. Transl.), vol. 75, no. 7, p. 1079].
Serafimov, L.A. and Raeva, V.M., Location of Binary Azeotropes in the Concentration Simplex, Teor. Osn. Khim. Tekhnol., 2003, vol. 37, no. 3, p. 272 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 37, no. 3, p. 250].
Hala, E., Pick, J., Fried, V., et al., Vapor-Liquid Equilibrium, Oxford: Pergamon, 1958.
Serafimov, L.A., Timofeev, V.S., Pisarenko, Yu.A., and Solokhin, A.V., Tekhnologiya osnovnogo organicheskogo sinteza: Sovmeshchennye protsessy (Engineering in Basic Organic Synthesis: Combined Processes), Moscow: Khimiya, 1993.
Walas, S., Phase Equilibria in Chemical Engineering, London: Butterworth, 1985.
Nikitskii, A.V., Kushner, T.M., and Serafimov, L.A., Diagrams of Excess Gibbs Thermodynamic Potential in Ternary Systems, Zh. Fiz. Khim., 1998, vol. 72, no. 12, p. 2138 [Russ. J. Phys. Chem. (Engl. Transl.), vol. 72, no. 12, p. 1943].