Metal–organic framework derived porous nanostructured Co3O4 as high-performance anode materials for lithium-ion batteries

Journal of Materials Science - Tập 56 - Trang 2451-2463 - 2020
Yan-Hua Lu1, Jin-Hui Li1, Zhi-Feng Xu1, Jia-Ming Liu1, Sui-Jun Liu1, Rui-Xiang Wang1
1Faculty of Materials, Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou, People’s Republic of China

Tóm tắt

Metal–organic frameworks (MOFs) are ideal self-sacrificial precursors for building materials with porous structures and high electrochemical performance because materials prepared with metal MOFs as precursors have the advantages of high porosity, diverse structures, and large surface area. In this work, porous nanostructured Co3O4 particles were prepared by using cobalt-based MOFs as a precursor, which exhibited superior electrochemical properties as anode materials for lithium-ion batteries. The reversible capacity reaches 924.1 mAh g−1 at 200 mA g−1 after 100 cycles, and the reversible capacity after 300 cycles is still as high as 838.6 mAh g−1 at 1000 mA g−1. Such superior electrochemical properties are mainly owe to the porous structure of Co3O4 particles. The porous structure is beneficial for the electrolyte to penetrate into the electrode material and shortens the transmission path of electrons and lithium ions, further improving the diffusion rate and the cycling performance. In addition, the porous structure can alleviate large volume changes of the material during lithiation and delithiation to improve the cycling stability.

Tài liệu tham khảo

Liu H, Yen S (2007) Characterization of electrolytic Co3O4 thin films as anodes for lithium-ion batteries. J Power Sour 166:478–484 Li L, Seng K, Chen Z, Guo Z, Liu H (2013) Self-assembly of hierarchical star-like Co3O4 micro/nanostructures and their application in lithium ion batteries. Nanoscale 5:1922–1928 Dai J, Song M, Wang M, Li P, Zhang C, Shen Y, Xie A (2015) Freeze-drying growth of Co3O4/N-doped reduced graphene oxide nanocomposite as excellent anode material for lithium-ion batteries. Ceram Int 42:2410–2415 Liang K, He H, Ren Y, Wang H, Liao Y, Huang X (2019) Porous lithium titanate nanosheets as an advanced anode material for sodium ion batteries. J Mater Sci 55:4372–4381. https://doi.org/10.1007/s10853-019-04290-1 Liu J, Lu Y, Wang R, Xu Z, Li X (2020) Simple and efficient combustion method for preparation of high-performance Co3O4 anode materials for lithium-ion batteries. JOM. https://doi.org/10.1007/s11837-020-04212-6 Hou C, Hou Y, Fan Y, Zhai Y, Wang Y, Sun Z, Fan R, Dang F, Wang J (2018) Oxygen vacancy derived local build-in electric field in mesoporous hollow Co3O4 microspheres promotes high-performance Li-ion batteries. J Mater Chem A 6:6967–6976 Baji DS, Nair SV, Rai AK (2017) Highly porous disk-like shape of Co3O4 as an anode material for lithium ion batteries. J Solid State Electr 21:2869–2875 Huang G, Xu S, Lu S, Li L, Sun H (2014) Micro-/nano-structured Co3O4 anode with enhanced rate capability for lithium-ion batteries. ACS Appl Mater Int 6:7236–7243 Cao W, Wang W, Shi H, Wang J, Cao M, Liang Y, Zhu M (2018) Hierarchical three-dimensional flower-like Co3O4 architectures with a mesocrystal structure as high capacity anode materials for long-lived lithium-ion batteries. Nano Res 11:1437–1446 Tranchemontagne DJ, Mendoza-Cortes JL, O’Keeffe M, Yaghi OM (2009) ChemInform abstract: secondary building units, nets and bonding in the chemistry of metal-organic frameworks. ChemInform. https://doi.org/10.1002/chin.200929228 O’Keeffe M, Yaghi OM (2012) Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets. Chem Rev 112:675–702 Tian D, Zhou X, Zhang Y, Zhou Z, Bu X (2015) MOF-derived porous Co3O4 hollow tetrahedra with excellent performance as anode materials for lithium-ion batteries. Inorg Chem 54:8159–8161 Kong L, Xie C, Gu H, Wang C, Zhou X, Liu J, Zhou Z, Li Z, Zhu J, Bu X (2018) Thermal instability induced oriented 2D pores for enhanced sodium storage. Small 14:1800639 Shuang W, Huang H, Kong L, Zhong M, Li A, Wang D, Xu Y, Bu X (2019) Nitrogen-doped carbon shell-confined Ni3S2 composite nanosheets derived from Ni-MOF for high performance sodium-ion battery anodes. Nano Energy 62:154–163 Kong L, Zhong M, Shuan W, Xu Y, Bu X (2020) Electrochemically active sites inside crystalline porous materials for energy storage and conversion. Chem Soc Rev 49:2378–2407 Zhu J, Qu T, Su F, Wu Y, Kang Y, Chen K, Yao Y, Ma W, Yang B, Dai Y, Liang F, Xue D (2020) Highly dispersed Co nanoparticles decorated on a N-doped defective carbon nano-framework for a hybrid Na-air battery. Dalton T 49:1811–1821 Jian S, Yang W, Lin W, Hu J, Zhang L (2017) Formation of hollow Co3O4 nanocages with hierarchical shell structure as anode materials for lithium-ion batteries. J Porous Mat 24:1079–1088 Feng Y, Yu X, Paik U (2016) Formation of Co3O4 microframes from MOFs with enhanced electrochemical performance for lithium storage and water oxidation. Chem Commun 52:6269–6272 Liu S, Cao C, Yang F, Yu M, Yao S, Zheng T, He W, Zhao H, Hu T, Bu X (2016) High proton conduction in two CoII and MnII anionic MOFs derived from 1,3,5-benzenetricarboxylic acid. Cryst Growth Des 16:6776–6780 Yang T, Liu Y, Huang Z, Liu J, Bian P, Ling CD, Liu H, Wang G, Zheng R (2018) In situ growth of ZnO nanodots on carbon hierarchical hollow spheres as high-performance electrodes for lithium-ion batteries. J Alloy Compd 735:1079–1087 Banerjee A, Singh U, Aravindan V, Srinivasan M, Ogale S (2013) Synthesis of CuO nanostructures from Cu-based metal organic framework (MOF-199) for application as anode for Li-ion batteries. Nano Energy 2:1158–1163 Zafeiratos S, Dintzer T, Teschner D, Blume R, Havecker M, Knopgericke A, Schlogl R (2010) Methanol oxidation over model cobalt catalysts: influence of the cobalt oxidation state on the reactivity. J Catal 269:309–317 Yang H, Su Y, Shen C, Yang T, Gao H (2004) Synthesis and magnetic properties of ε-cobalt nanoparticles. Surf Interface Anal 36:155–160 Guo H, Mao R, Tian D, Wang W, Zhao D, Yang X, Wang S (2013) Morphology-controlled synthesis of SnO2/C hollow core-shell nanoparticle aggregates with improved lithium storage. J Mater Chem A 1:3652–3658 Chen J, Xia X, Tu J, Xiong Q, Yu Y, Wang X, Gu CD (2012) Co3O4-C core-shell nanowire array as an advanced anode material for lithium ion batteries. J Mater Chem 22:15056–15061 Reddy MV, Beichen Z, Nicholette LJ, Zhang K, Chowdaril BVR (2011) Molten salt synthesis and its electrochemical characterization of Co3O4 for lithium batteries. Electrochem Solid State Lett 14:A79–A82 Larcher D, Sudant G, Leriche J, Chabre Y, Tarascon J (2002) The electrochemical reduction of Co3O4 in a lithium cell. J Electrochem Soc 149:A234–A241 Kim G, Nam I, Kim ND, Park J, Park S, Yi J (2012) A synthesis of graphene/Co3O4 thin films for lithium ion battery anodes by coelectrodeposition. Electrochem Commun 22:93–96 Xiao M, Meng Y, Duan C, Zhu F, Zhang Y (2019) Ionic liquid derived Co3O4/Nitrogen doped carbon composite as anode of lithium ion batteries with enhanced rate performance and cycle stability. J Mater Sci-Mater El 30:6148–6156 Huang G, Zhang F, Du X, Qin Y, Yin D, Wang L (2015) Metal organic frameworks route to in situ insertion of multiwalled carbon nanotubes in Co3O4 polyhedra as anode materials for lithium-ion batteries. ACS Nano 9:1592–1599 Yin D, Huang G, Sun Q, Li Q, Wang X, Yuan D, Wang C, Wang L (2016) RGO/Co3O4 composites prepared using GO-MOFs as precursor for advanced lithium-ion batteries and supercapacitors electrodes. Electrochim Acta 215:410–419 Wu Q, Shao Q, Li Q, Duan Q, Li Y, Wang H (2018) Dual carbon-confined SnO2 hollow nanospheres enabling high performance for the reversible storage of alkali metal ions. ACS Appl Mater Int 10:15642–15651 Wang H, Wu Q, Wang Y, Wang X, Wu L, Song S, Zhang H (2019) Molecular engineering of monodisperse SnO2 nanocrystals anchored on doped graphene with high-performance lithium/sodium-storage properties in half/full cells. Adv Energy Mater 9:1802993 Wu Q, Liu Y, Wang H, Hou J, Li Y, Duan Q (2020) Graphene encapsulated metallic state Ce2Sn2O7 as a novel anode material for superior lithium-ion batteries and capacitors. J Mater Chem A 8:5517–5524 Wang J, Zhang Q, Li X, Zhang B, Mai L, Zhang K (2015) Smart construction of three-dimensional hierarchical tubular transition metal oxide core/shell heterostructures with high-capacity and long-cycle-life lithium storage. Nano Energy 12:437–446 Liu J, Lu Y, Wang R, Xu Z, Li X (2020) The effect of calcination temperature on combustion preparation of ZnFe2O4 as anode for lithium batteries. Int J Electrochem Sc 15:1571–1580 Yan C, Wu C, Zhuang Q, Tian L, Cui Y, Zhao X, Ju Z, Sun X (2016) Investigation of the lithiation mechanism of Fe3O4-based composite anode: the effect of the carbon matrix. ChemistrySelect 1:3979–3991 Li F, Zhuang Q, Qiu X, Sun Z (2013) Investigation of lithiation mechanism of LiCr3O8 as potential anode materials for lithium-ion batteries. Int J Electrochem Sci 8:3551–3563 Bao W, Zhuang Q, Xu S, Cui Y, Shi Y, Qiang Y (2013) Investigation of electronic and ionic transport properties in α-MoO3 cathode material by electrochemical impedance spectroscopy. Ionics 19:1005–1013 Wu C, Zhang H, Wu Y, Zhuang Q, Tian L, Zhang X (2014) Synthesis and characterization of Fe@Fe2O3 core-shell nanoparticles/graphene anode material for lithium-ion batteries. Electrochim Acta 134:18–27 Zhao X, Zhuang Q, Qiu X, Xu S, Shi Y, Cui Y (2011) Electrochemical performance of Cr2O3/TiO2 composite material for lithium ion batteries. Acta Phys-Chim Sin 27:1666–1672 Zhao X, Zhuang Q, Xu S, Xu Y, Shi Y, Zhang X (2015) Investigation of Cr2O3 as anode materials for lithium-ion batteries by electrochemical impedance spectroscopy. J Electrochem Soc 162:A1156–A1162 Qu X, Liu Y, Li B, Xing B, Cao Y (2020) Nanostructured T-Nb2O5-based composite with reduced graphene oxide for improved performance lithium-ion battery anode. J Mater Sci 55:13062–13074. https://doi.org/10.1007/s10853-020-04910-1 Yang X, Zhang R, Zhao J, Wei Z, Wang D, Bie X, Gao Y, Wang J, Du F, Chen G (2017) Amorphous tin-based composite oxide: a high-rate and ultralong-life sodium-ion-storage material. Adv Energy Mater 8:1701827 Yuan T, Jiang Y, Sun W, Xiang B, Li Y, Yan M, Xu B, Dou S (2016) Ever-increasing pseudocapacitance in RGO-MnO-RGO sandwich nanostructures for ultrahigh-rate lithium storage. Adv Funct Mater 26:2198–2206 Chen C, Wen Y, Hu X, Ji X, Yan M, Mai L, Hu P, Shan B, Huang Y (2015) Na+ intercalation pseudocapacitance in graphene-coupled titanium oxide enabling ultra-fast sodium storage and long-term cycling. Nat Commun 6:6929 Li G, Yang Z, Jiang Y, Jin C, Huang W, Ding X, Huang Y (2016) Towards polyvalent ion batteries: a zinc-ion battery based on Nasicon structured Na3V2(PO4)3. Nano Energy 25:211–217 Chao D, Zhu C, Yang P, Xia X, Liu J, Wang J, Fan X, Savilov S, Lin J, Fan H, Shen Z (2016) Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance. Nat Commun 7:12122 Xia S, Yu S, Yao L, Li F, Li X, Cheng F, Shen X, Sun C, Guo H, Liu J (2019) Robust hexagonal nut-shaped titanium(IV) MOF with porous structure for ultra-high performance lithium storage. Electrochim Acta 296:746–754