Photocatalytic properties of graphitic carbon nitrides (g-C3N4) for sustainable green hydrogen production: Recent advancement

Fuel - Tập 316 - Trang 123381 - 2022
Amir Al-Ahmed1
1Interdisciplinary Research Center for Renewable Energy and Power Systems (IRC-REPS), Research Institute, King Fahd University of Petroleum & Minerals, Dhahran, 31261, Saudi Arabia

Tài liệu tham khảo

Boyle, 1673 Cavendish, 1766, Three papers, containing experiments on factitious air, Philos Trans, 56, 141, 10.1098/rstl.1766.0019 http://www.knowledgedoor.com/2/elements_handbook/origin_of_element_name.html. https://www.britannica.com/science/hydrogen [accessed 15 November, 2021]. Fajrina, 2019, A critical review in strategies to improve photocatalytic water splitting towards hydrogen production, Int J Hydrogen Energy, 44, 540, 10.1016/j.ijhydene.2018.10.200 Ramis, 2021, Design of efficient photocatalytic processes for the production of hydrogen from biomass derived substrates, Int J Hydrogen Energy, 46, 12105, 10.1016/j.ijhydene.2020.02.192 Rivero, MJ, Iglesias O, Ribao P, Ortiz I. Kinetic performance of TiO2/Pt/reduced graphene oxide composites in the photocatalytic hydrogen production. Int J Hydrogen Energy 2019; 44:101-109. doi: 10.1016/ j.ijhydene.2018.02.115. Lv, 2019, Self-assembly photocatalytic reduction synthesis of graphene-encapsulated LaNiO3 nanoreactor with high efficiency and stability for photocatalytic water splitting to hydrogen, Chem Eng J, 356, 580, 10.1016/j.cej.2018.09.031 Baamran, 2019, Thermodynamic investigation and experimental analysis on phenol steam reforming towards enhanced H2 production over structured Ni/ZnTiO3 nanocatalyst, Energy Convers Manage, 180, 796, 10.1016/j.enconman.2018.10.099 Prabhu S, Cindrella L, Kwon OJ, Mohanraju K. Photoelectrochemical, photocatalytic and photochromic performance of rGO-TiO2WO3 composites. Mater Chem Phys 2019; 224:217-28. doi: 10.1016/ j. matchemphys.2018.12.030. Mo, 2019, Constructing Pd/2D-C3N4 composites for efficient photocatalytic H2 evolution through nonplasmon-induced bound electrons, Appl Surf Sci, 467, 151, 10.1016/j.apsusc.2018.10.115 Baamran, 2020, Effect of support size for stimulating hydrogen production in phenol steam reforming using Ni-embedded TiO2 nanocatalyst, J Environ Chem Eng, 8, 10.1016/j.jece.2019.103604 Xin, 2018, Graphene-based heterojunction photocatalysts, Appl Surf Sci, 430, 53, 10.1016/j.apsusc.2017.08.194 Meng, 2007, A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production, Renew Sustain Energy Rev, 11, 401, 10.1016/j.rser.2005.01.009 He, 2020, Enhanced photocatalytic H2-production activity of WO3/TiO2 step-scheme heterojunction by graphene modification, Chin J Catal, 41, 9, 10.1016/S1872-2067(19)63382-6 Zhang, 2021, Progress and prospects of hydrogen production: opportunities and challenges, J Electron Sci Technol, 19, 10.1016/j.jnlest.2021.100080 Zhou P, Lv F, Li N, Zhang Y, Mu Z, Tang Y, et al. Strengthening reactive metal-support interaction to stabilize high-density Pt single atoms on electron-deficient g-C3N4 for boosting photocatalytic H2 production, Nano Energy, 56(2019) 127-37. doi: 10.1016/ j.nanoen.2018.11.033. Wang S, Zhu B, Liu M, Zhang L, Yu J, Zhou M. Direct Z-scheme ZnO/CdS hierarchical photocatalyst for enhanced photocatalytic H2-production activity. Appl Catal B: Environ 2019; 243:19-26. doi: 10.1016/ j. apcatb.2018.10.019. Wang P, Li H, Sheng Y, Chen F, Inhibited photocorrosion and improved photocatalytic H2-evolution activity of CdS photocatalyst by molybdate ions. Appl Surf Sci 2019; 463:27-33. doi: 10.1016/ j.apsusc.2018.08.125. Di T, Cheng B, Ho W, Yu J, Tang H. Hierarchically CdSeAg2S nanocomposites for efficient photocatalytic H2 production. Appl Surf Sci 2019; 470:196-204. doi: 10.1016/ j. apsusc.2018.11.010. Chang CJ, Lin YG, Chao PY, Chen JK. AgI-BiOI-graphene composite photocatalysts with enhanced interfacial charge transfer and photocatalytic H2 production activity. Appl Surf Sci 2019; 469:703-12. doi: 10.1016/ j. apsusc.2018.11.081. Karthik, 2020, Redox couple mediated charge carrier separation in g-C3N4/Cu Ophotocatalyst for enhanced photocatalytic H2 production, Int J Hydrogen Energy, 45, 7541, 10.1016/j.ijhydene.2019.06.045 Reddy RN, Bhargav U, Kumari MM, Cheralathan KK, Sakar M. Review on the interface engineering in the carbonaceous titania for the improved photocatalytic hydrogen production. Int J Hydrogen Energy 2020; 45:7584-615. doi: 10.1016/ j. ijhydene.2019.09.041. Fajrina, 2019, Engineering approach in stimulating photocatalytic H2 production in a slurry and monolithic photoreactor systems using Ag-bridged Z-scheme pCN/TiO2 nanocomposite, Chem Eng J, 374, 1076, 10.1016/j.cej.2019.06.011 Wang P, Xu S, Chen F, Yu H. Ni nanoparticles as electrontransfer mediators and NiS as interfacial active sites for coordinative enhancement of H2-evolution performance of TiO2. Chin J Catal 2019; 40:343-51. doi: 10.1016/ s1872-2067(18)63157-2. Wang, 2019, Nontopological transformation of hierarchical TiO2 by self-regulated etching and capping roles of F for photocatalytic H2 evolution, Appl Surf Sci, 473, 738, 10.1016/j.apsusc.2018.12.077 Qi, 2019, Electroless plating Ni-P cocatalyst decorated g-C3N4 with enhanced photocatalytic water splitting for H2 generation, Appl Surf Sci, 466, 847, 10.1016/j.apsusc.2018.10.037 Thomas, 2008, Graphitic carbon nitride materials: variation of structure and morphology and their use as metal-free catalysts, J Mater Chem, 18, 4893, 10.1039/b800274f Maeda, 2009, Photocatalytic activities of graphitic carbon nitride powder for water reduction and oxidation under visible light, J Phys Chem C, 113, 4940, 10.1021/jp809119m Maeda, 2010, Photocatalytic overall water splitting promoted by two different cocatalysts for hydrogen and oxygen evolution under visible light, Angew Chem, 122, 4190, 10.1002/ange.201001259 Wang, 2009, A metal-free polymeric photocatalyst for hydrogen production from water under visible light, Nat Mater, 8, 76, 10.1038/nmat2317 Yan, 2010, Organic–inorganic composite photocatalyst of g-C3N4 and TaON with improved visible light photocatalytic activities, Dalton Trans, 39, 1488, 10.1039/B914110C Ge, 2012, Synthesis of MWNTs/g-C3N4 composite photocatalysts with efficient visible light photocatalytic hydrogen evolution activity, Appl Catal B, 117, 268, 10.1016/j.apcatb.2012.01.021 Kang, 2012, Organic-inorganic composite of g-C3N4/SrTiO3: Rhphotocatalyst for improved H2 evolution under visible light irradiation, Int J Hydrogen Energy, 37, 11602, 10.1016/j.ijhydene.2012.05.020 Zheng, 2012, Graphitic carbon nitride materials: controllable synthesis and applications in fuel cells and photocatalysis, Energy Environ Sci, 5, 6717, 10.1039/c2ee03479d Chang, 2016, Nitrogen-doped graphene for photocatalytic hydrogen generation, Chem Asian J, 11, 1125, 10.1002/asia.201501328 Lin, 2016, Construction of novel three dimensionally ordered macroporous carbon nitride for highly efficient photocatalytic activity, Appl Catal B, 198, 276, 10.1016/j.apcatb.2016.05.069 Wen, 2017, A review on g-C3N4-based photocatalysts, Appl Surf Sci, 391, 72, 10.1016/j.apsusc.2016.07.030 Fajrina, 2019, 2D-montmorillonite-dispersed g-C3N4/TiO2 2D/0D nanocomposite for enhanced photo-induced H2 evolution from glycerol-water mixture, Appl Surf Sci, 471, 1053, 10.1016/j.apsusc.2018.12.076 Li, 2019, Recent advances in 3D g-C3N4 composite photocatalysts for photocatalytic water splitting, degradation of pollutants and CO2 reduction, J Alloy Compd, 802, 196, 10.1016/j.jallcom.2019.06.185 Lin, 2020, One-step preparation of halogenated aminobenzonitrile modified g-C3N4 via copolymerization and in situ halogen doping for highly enhanced visible light hydrogen evolution, Int J Hydrogen Energy, 11, 6341, 10.1016/j.ijhydene.2019.12.123 Mishra, 2019, Graphitic carbon nitride (g-C3N4) based metal-free photocatalysts for water splitting: a review, Carbon, 149, 693, 10.1016/j.carbon.2019.04.104 Tahir, 2020, Recent development in band engineering of binary semiconductor materials for solar driven photocatalytic hydrogen production, Int J Hydrogen Energy, 32, 15985, 10.1016/j.ijhydene.2020.04.071 Yue, 2011, Hydrogen production using zinc-doped carbon nitride catalyst irradiated with visible light, Sci Technol Adv Mater, 12, 10.1088/1468-6996/12/3/034401 Pan, 2011, Ab initio study on a novel photocatalyst: functionalized graphitic carbon nitride nanotube, ACS Catal, 1, 99, 10.1021/cs100045u Ding G, Wang W, Jiang T, Han B, Fan H, Yang G. Highly selective synthesis of phenol from benzene over a vanadium-doped graphitic carbon nitride catalyst. Chem Cat Chem 2013; 5:192-200. 10.1002/cctc.201200502. Jiang J, Cao S, Hu C, Chen C. A comparison study of alkali metal‐doped g‐C3N4 for visible‐light photocatalytic hydrogen evolution. Chinese J Catal 2017; 38:1981–1989. doi: 10.1016/S1872‐2067(17)62936‐X. Samanta, 2014, Facile synthesis of Au/g-C3N4 nanocomposites: an inorganic/organic hybrid plasmonicphotocatalyst with enhanced hydrogen gas evolution under visible-light irradiation, Chem Cat Chem, 6, 1453 Ye X, Cui Y, Qiu X, Wang X. Selective oxidation of benzene to phenol by Fe-CN/TS-1 catalysts under visible light irradiation. Applied Catalysis B: Environmental 2014; 152:383-389. 10.1016/j.apcatb.2014.01.050. Han X, Si T, Liu Q, Zhu F, Li R, Chen X, Liu J, Sun H, Zhao J, Ling H, Zhang Q, Wang H. 2D bimetallic RuNi alloy Co-catalysts remarkably enhanced the photocatalytic H2 evolution performance of g-C3N4 nanosheets. Chem. Eng J 2021; 426:130824. 10.1016/j.cej.2021.130824. Wu, 2014, Synthesis of potassium-modified graphitic carbon nitride with high photocatalytic activity for hydrogen evolution, ChemSusChem, 7, 2654, 10.1002/cssc.201402180 Habibi-Yangjeh, 2019, Boosting visible-light photocatalytic performance of g-C3N4/Fe3O4 anchored with CoMoO4 nanoparticles: Novel magnetically recoverable photocatalysts, J Photochem Photobiol, A, 368, 120, 10.1016/j.jphotochem.2018.09.026 Zhou, 2016, Brand new P-doped g-C3N4: enhanced photocatalytic activity for H2 evolution and Rhodamine B degradation under visible light, J Mater Chem A, 3, 3862, 10.1039/C4TA05292G Wen, 2015, Enhanced visible-light H2 evolution of g-C3N4 photocatalysts via the synergetic effect of amorphous NiS and cheap metal-free carbon black nanoparticles as cocatalysts, Appl Surf Sci, 358, 204, 10.1016/j.apsusc.2015.08.244 Fang, 2015, Nitrogen self-doped graphitic carbon nitride as efficient visible light photocatalyst for hydrogen evolution, J Mater Chem A, 3, 13819, 10.1039/C5TA02257F Qin J, Huo J, Zhang P, Zeng J, Wang T, Zeng H. Improving the photocatalytic hydrogen production of Ag/g-C3N4 nanocomposites by dye-sensitization under visible light irradiation. Nanoscale 2016; 8:2249-59. 10.1039/ c5nr06346a. Kong, 2016, Light-assisted rapid preparation of a Ni/g-C3N4 magnetic composite for robust photocatalytic H2 evolution from water, J Mater Chem A, 4, 9998, 10.1039/C6TA03178A Wang, 2017, Facile gel-based morphological control of Ag/g-C3N4 porous nanofibers for photocatalytic hydrogen generation, ACS Sustainable Chem Eng, 5, 10633, 10.1021/acssuschemeng.7b02608 Xu, 2017, Making co-condensed amorphous carbon/g-C3N4 composites with improved visible-light photocatalytic H2-production performance using Pt as cocatalyst, Carbon, 118, 241, 10.1016/j.carbon.2017.03.052 Ma, 2018, Hierarchical Cu2O foam/g-C3N4 photocathode for photoelectrochemical hydrogen production, Appl Surf Sci, 427, 907, 10.1016/j.apsusc.2017.09.075 Lv, 2017, Facile constructing novel 2D porous g-C3N4/BiOBr hybrid with enhanced visible-light-driven photocatalytic activity, Sep Purif Technol, 178, 6, 10.1016/j.seppur.2017.01.019 Liu, 2019, Ultrafine 1D graphene interlayer in g-C3N4/graphene/ recycled carbon fiber heterostructure for enhanced photocatalytic hydrogen generation, Chem Eng J, 359, 1352, 10.1016/j.cej.2018.11.043 Gao, 2019, Construction of heterostructured g-C3N4@TiATA/Pt composites for efficacious photocatalytic hydrogen evolution, Int J Hydrogen Energy, 44, 24407, 10.1016/j.ijhydene.2019.07.211 Li J, Tang Y, Jin R, Meng Q, Chen Y, Long X, Wang L, Guo H, Zhang S. Ultrasonic-microwave assisted synthesis of GO/g-C3N4 composites for efficient photocatalytic H2 evolution. Solid State Sci 2019; 97:105990. 10.1016/ j.solidstatesciences.2019.105990. Zhang, 2013, Synthesis and luminescence mechanism of multicolor-emitting g-C3N4 nanopowders by low temperature thermal condensation of melamine, Sci Rep, 3, 1 Huang, 2013, Well-dispersed g-C3N4 nanophases in mesoporous silica channels and their catalytic activity for carbon dioxide activation and conversion, Appl Catal B: Environ, 136, 269, 10.1016/j.apcatb.2013.01.057 Bai, 2013, Photocatalytic activity enhanced via g-C3N4 nanoplates to nanorods, J Phys Chem C, 117, 9952, 10.1021/jp402062d Chen, 2014, Activation of n-p* transitions in two-dimensional conjugated polymers for visible light photocatalysis, J Phys Chem C, 118, 29981, 10.1021/jp510187c Wang, 2015, Water assisted production of honeycomb-like g-C3N4 with ultralong carrier lifetime and outstanding photocatalytic activity, Nanoscale, 7, 2471, 10.1039/C4NR05732E Zheng, 2015, Shell-engineering of hollow g-C3N4 nanospheres via copolymerization for photocatalytic hydrogen evolution, Chem Commun, 51, 9706, 10.1039/C5CC03143E Liu, 2018, An amorphous/crystalline g-C3N4 homojunction for visible light photocatalysis reactions with superior activity, Chem Commun, 54, 4720, 10.1039/C8CC01824C Li X, Xiong J, Gao X, Huang J, Feng Z, Chen Z, Zhu Y, Recent advances in 3D g-C3N4 composite photocatalysts for photocatalytic water splitting, degradation of pollutants and CO2 reduction. J Alloys Compd 2019; 802:196-209. doi: 10.1016/j.jallcom.2019.06.185. Zhang, 2020, Enhanced visible-light photocatalytic H2 production of a hierarchical g-C3N4 hexagon by one-step self-assembly strategy, Appl Surf Sci, 499, 10.1016/j.apsusc.2019.143942 Hong, 2014, Porous carbon nitride nanosheets for enhanced photocatalytic activities, Nanoscale, 6, 14984, 10.1039/C4NR05341A He, 2015, The facile synthesis of mesoporous g- g-C3N4 with highly enhanced photocatalytic H2 evolution performance, Chem Commun, 51, 16244, 10.1039/C5CC06713H Li, 2016, Porous graphitic carbon nitride derived from melamine–ammonium oxalate stacking sheets with excellent photocatalytic hydrogen evolution activity, Chem Cat Chem, 8, 2128 Tian, 2017, Precursor-reforming protocol to 3D mesoporous g-C3N4 established by ultrathin self-doped nanosheets for superior hydrogen evolution, Nanomater Energy, 38, 72, 10.1016/j.nanoen.2017.05.038 Huang, 2017, Template-free precursor-surface-etching route to porous, thin g-C3N4 nanosheets for enhancing photocatalytic reduction and oxidation activity, J Mater Chem A, 5, 17452, 10.1039/C7TA04639A Zhao, 2018, Facile one-step synthesis of hollow mesoporous g-C3N4 spheres with ultrathin nanosheets for photoredox water splitting, Carbon, 126, 247, 10.1016/j.carbon.2017.10.033 Liu Q, Wang X, Yang Q, Zhang Z, Fang X. Mesoporous g-C3N4 nanosheets prepared by calcining a novel supramolecular precursor for high-efficiency photocatalytic hydrogen evolution. Appl Surf Sci 2018; 450:46-56. doi: 10.1016/j.apsusc.2018.04.175. Ruan, 2018, Defects rich g-C3N4 with mesoporous structure for efficient photocatalytic H2 production under visible light irradiation, Appl Catal B Environ, 238, 638, 10.1016/j.apcatb.2018.07.028 Xu J, Zhang L, Shi R, Zhu Y. Chemical exfoliation of graphitic carbon nitride for efficient heterogeneous photocatalysis. J Mater Chem A; 1:14766-72. doi: 10.1039/c3ta13188b. Wang, 2013, Carbon nitride nanosheets for photocatalytic hydrogen evolution: remarkably enhanced activity by dye sensitization, Catal Sci Technol, 3, 1703, 10.1039/c3cy20836b Yang, 2013, Exfoliated graphitic carbon nitride nanosheets as efficient catalysts for hydrogen evolution under visible light, Adv Mater, 25, 2452, 10.1002/adma.201204453 Cao, 2013, In-situ growth of CdS quantum dots on g-C3N4 nanosheets for highly efficient photocatalytic hydrogen generation under visible light irradiation, Int J Hydrogen Energy, 38, 1258, 10.1016/j.ijhydene.2012.10.116 Han, 2015, Facile production of ultrathin graphitic carbon nitride nanoplatelets for efficient visible-light water splitting, Nano Res, 8, 1718, 10.1007/s12274-014-0675-9 Han Q, Wang B, Gao J, Cheng Z, Zhao Y, Zhang Z, Qu L. Atomically thin mesoporous nanomesh of graphitic C3N4 for high-efficiency photocatalytic hydrogen evolution. ACS Nano 2016; 10:2745-51. doi: 10.1021/ acsnano.5b07831. Gao, 2017, A facile one-step synthesis of Fe-doped g-C3N4 nanosheets and their improved visible-light photocatalytic performance, Chem Cat Chem, 9, 1708 Fang LJ, Li YH, Liu PF, Wang DP, Zeng HD, Wang XL, Yang HG. Facile fabrication of large-aspect-ratio g-C3N4 nanosheets for enhanced photocatalytic hydrogen evolution. ACS Sustain Chem Eng 2017; 5:2039-43. 10.1021/ acssuschemeng.6b02721. Kumar S, Reddy NL, Kumar A, Shankar MV, Krishnan V. Two dimensional N-doped ZnO-graphitic carbon nitride nanosheets heterojunctions with enhanced photocatalytic hydrogen evolution. Int. J. Hydrogen Energy 2018; 43:3988-4002. doi: 10.1016/ j.ijhydene.2017.09.113. Vu MH, Sakar M, Nguyen CC, Do TO. Chemically bonded Ni cocatalyst onto the S doped g-C3N4 nanosheets and their synergistic enhancement in H2 production under sunlight irradiation, ACS Sustain Chem Eng 2018; 6:4194-203 doi: 10.1021/acssuschemeng.7b04598. Liu, 2018, A novel route combined precursor-hydrothermal pretreatment with microwave heating for preparing holey g-C3N4 nanosheets with high crystalline quality and extended visible light absorption, Appl Catal B Environ, 225, 22, 10.1016/j.apcatb.2017.11.044 Fang, 2018, One-step Nickel foam assisted synthesis of holey G-carbon nitride nanosheets for efficient visible-light photocatalytic H2 evolution, ACS Appl Mater Interfaces, 10, 20521, 10.1021/acsami.8b04783 Sun, 2020, Synergistic effect of Co(II)-hole and Pt-electron cocatalysts for enhanced photocatalytic hydrogen evolution performance of P-doped g-C3N4, Chin J Catal, 41, 72, 10.1016/S1872-2067(19)63430-3 Lin, 2013, Nanostructure engineering and doping of conjugated carbon nitride semiconductors for hydrogen photosynthesis, Angew Chem Int Ed, 52, 1735, 10.1002/anie.201209017 Zhu, 2014, Cobalt sulfide modified graphitic carbon nitride semiconductor for solar hydrogen production, Int J Hydrogen Energy, 39, 11873, 10.1016/j.ijhydene.2014.06.025 Katsumata, 2014, Z-scheme photocatalytic hydrogen production over WO3/g-C3N4 composite photocatalysts, RSC Adv, 4, 21405, 10.1039/C4RA02511C Martin, 2014, Visible light-driven pure water splitting by a nature-inspired organic semiconductor-based system, J Am Chem Soc, 136, 12568, 10.1021/ja506386e Wang, 2015, Structural distortion in graphitic- C3N4 realizing an efficient photoreactivity, Nanoscale, 7, 5152, 10.1039/C4NR07645A He, 2018, In situ one-pot fabrication of g-C3N4 nanosheets/NiScocatalyst heterojunction with intimate interfaces for efficient visible light photocatalytic H2 generation, Appl Surf Sci, 430, 208, 10.1016/j.apsusc.2017.08.191 Mao, 2017, Novel g-C3N4/CoO nanocomposites with significantly enhanced visible-light photocatalytic activity for H2 evolution, ACS Appl Mater Interfaces, 9, 12427, 10.1021/acsami.7b00370 Zhu, 2019, Tunable Type I and II heterojunction of CoOx nanoparticles confined in g-C3N4 nanotubes for photocatalytic hydrogen production, ApplCatal B: Environ, 244, 814, 10.1016/j.apcatb.2018.12.015 Guo, 2018, Novel mesoporous TiO2@g-C3N4 hollow core@shell heterojunction with enhanced photocatalytic activity for water treatment and H2 production under simulated sunlight, J Hazard Mater, 353, 80, 10.1016/j.jhazmat.2018.03.044 Fu, 2018, High-performance NiO/g-C3N4 composites for visible-light-driven photocatalytic overall water splitting, Inorg Chem Front, 5, 1646, 10.1039/C8QI00292D Yuan, 2014, Microwave-assisted heating synthesis: a general and rapid strategy for large-scale production of highly crystalline g-C3N4 with enhanced photocatalytic H2 production, Green Chem, 16, 4663, 10.1039/C4GC01517G Schwinghammer K, Mesch MB, Duppel V, Ziegler C, Senker J, Lotsch BV. Crystalline carbon nitride nanosheets for improved visible-light hydrogen evolution. J Am Chem Soc 2014; 136:1730-3. 10.1021/ ja411321s. Guo Y, Li J, Yuan Y, Li L, Zhang M, Zhou C, Lin Z. A rapid microwave-assisted thermolysis route to highly crystalline carbon nitrides for efficient hydrogen generation. Angew Chem Int Ed 2016; 55:14693-7. 10.1002/ anie.201608453. Ou, 2017, Tri-s-triazine-Based crystalline carbon nitride nanosheets for an improved hydrogen evolution, Adv Mater, 29, 1700008, 10.1002/adma.201700008 Iqbal, 2018, Self-modified breaking hydrogen bonds to highly crystalline graphitic carbon nitrides nanosheets for drastically enhanced hydrogen production, Appl Catal B Environ, 232, 306, 10.1016/j.apcatb.2018.03.072 Zou, 2017, Fabrication of g-C3N4/Au/C-TiO2 hollow structure as visible-light-driven Z-scheme photocatalyst with enhanced photocatalytic H2 evolution, ChemCatChem, 19, 3752, 10.1002/cctc.201700542 Li, 2017, Z scheme electronic transfer of quantum-sized a-Fe2O3 modified g-C3N4 hybrids for enhanced photocatalytic hydrogen production, Int. J. Hydrogen Energy, 42, 28327, 10.1016/j.ijhydene.2017.09.137 Wang, 2019, Direct Z scheme ZnO/CdS hierarchical photocatalyst for enhanced photocatalytic H2-production activity, Appl Catal B: Environ, 243, 19, 10.1016/j.apcatb.2018.10.019 Wang, 2018, Mimicking natural photosynthesis: solar to renewable H2 fuel synthesis by Z-scheme water splitting systems, Chem Rev, 118, 5201, 10.1021/acs.chemrev.7b00286 Luo, 2019, Strengthened spatial charge separation over Z-scheme heterojunction photocatalyst for efficient photocatalytic H2 evolution, Appl Surf Sci, 475, 453, 10.1016/j.apsusc.2018.12.285 Yang, 2020, Co3O4 imbedded g-C3N4 heterojunction photocatalysts for visible-light-driven hydrogen evolution, Renew Energy, 145, 691, 10.1016/j.renene.2019.06.072 Liu, 2019, A Z-scheme mechanism of N-ZnO/g-C3N4 for enhanced H2 evolution and photocatalytic degradation, Appl Surf Sci, 466, 133, 10.1016/j.apsusc.2018.10.027 Wen, 2020, A highly active three-dimensional Z scheme ZnO/Au/g-C3N4 photocathode for efficient photoelectrochemical water splitting, Appl Catal B: Environ, 263, 10.1016/j.apcatb.2019.118180 Wang J, Wang G, Wang X, Wu Y, Su Y, Tang H. 3D/2D direct Z-scheme heterojunctions of hierarchical TiO2microflowers/g-C3N4nanosheets with enhanced charge carrier separation for photocatalytic H2 evolution. Carbon 2019; 149:618-26. doi: 10.1016/ j.carbon.2019.04.088. Cao, 2019, Engineering of Z-scheme 2D/3D architectures with Ni(OH)2 on 3D porous g-C3N4 for efficiently photocatalytic H2 evolution, Appl Catal B: Environ, 258, 10.1016/j.apcatb.2019.117997 Zhang, 2020, Facile strategy to construction Z-scheme ZnCo2O4/g-C3N4 photocatalyst with efficient H2 evolution activity, Appl Surf Sci, 515, 10.1016/j.apsusc.2020.146039