3D Se-doped NiCoP nanoarrays on carbon cloth for efficient alkaline hydrogen evolution

LIU Bao-cang, LI Huan, CAO Bo, JIANG Jia-ning, GAO Rui, ZHANG Jun. Few layered N, P dual-doped carbon-encapsulated ultrafine MoP nanocrystal/MoP cluster hybrids on carbon cloth: An ultrahigh active and durable 3D self-supported integrated electrode for hydrogen evolution reaction in a wide pH range [J]. Advanced Functional Materials, 2018, 28(30): 1801527–1801540. DOI: https://doi.org/10.1002/adfm.201801527. ZHU Yun-pei, LIU Yu-ping, REN Tie-zhen, YUAN Zhong-yong. Self-supported cobalt phosphide mesoporous nanorod arrays: A flexible and bifunctional electrode for highly active electrocatalytic water reduction and oxidation [J]. Advanced Functional Materials, 2015, 25(47): 7337–7347. DOI: https://doi.org/10.1002/adfm.201503666. QAZI U, JAVAID R, TAHIR N, JAMIL A, AFZAL A. Design of advanced self-supported electrode by surface modification of copper foam with transition metals for efficient hydrogen evolution reaction [J]. Int J Hydrogen Energy, 2020, 45(58): 33396–33406. DOI: https://doi.org/10.1016/j.ijhydene.2020.09.026. WANG Yang, LI Xiao-peng, ZHANG Meng-meng, ZHOU Yuan-guang, RAO De-wei, ZHONG Cheng, ZHANG Jinfeng, HAN Xiao-peng, HU Wen-bin, ZHANG Yu-cang, ZAGHIB K, WANG Yue-sheng, DENG Yi-da. Lattice-strain engineering of homogeneous NiS0.5Se0.5 core-shell nanostructure as a highly efficient and robust electrocatalyst for overall water splitting [J]. Adv Mater, 2020, 32(40): 2000231–2000240. DOI: https://doi.org/10.1002/adma.202000231. ZHANG Xing, YU Xiao-lu, ZHANG Lin-jie, ZHOU Feng, LIANG Yong-ye, WANG Rui-hu. Molybdenum phosphide/carbon nanotube hybrids as pH-universal electrocatalysts for hydrogen evolution reaction [J]. Advanced Functional Materials, 2018, 28(16): 1706523–1706530. DOI: https://doi.org/10.1002/adfm.201706523. YUAN Xu, YUE Wen-bo, ZHANG Jin. Electrochemically exfoliated graphene as high-performance catalyst support to promote electrocatalytic oxidation of methanol on Pt catalysts [J]. Journal of Central South University, 2020, 27(9): 2515–2529. DOI: https://doi.org/10.1007/s11771-020-4477-9. WANG Li-ping, TIAN Jing, LI Jing-sha, ZENG Xian-guang, PENG Zhi-guang, HUANG Xiao-bing, TANG You-gen, WANG Hai-yan. Red-blood-cell-like nitrogen-doped porous carbon as an efficient metal-free catalyst for oxygen reduction reaction [J]. Journal of Central South University, 2019, 26(6): 1458–1468. DOI: https://doi.org/10.1007/s11771-019-4102-y. XIE Tian, ZHAO Hai-xia, LV Zun-hang, XIE Guang-wen, HE Yan. A highly active composite electrocatalyst Ni-Fe-P-Nb2O5/NF for overall water splitting [J]. Int J Hydrogen Energy, 2021, 46(1): 581–588. DOI: https://doi.org/10.1016/j.ijhydene.2020.09.244. XIAO Chang-long, GADDAM R, WU Yi-lan, SUN Xiaoming, LIANG Yan, LI Yi-bing, ZHAO Xiu-song. Improvement of the electrocatalytic performance of FeP in neutral electrolytes with Fe nanoparticles [J]. Chemical Engineering Journal, 2020: 127330. DOI: https://doi.org/10.1016/j.cej.2020.127330. CHEN Jia-dong, CHEN Chun-hong, CHEN Yu-zhuo, WANG Hai-yan, MAO Shan-jun, WANG Yong. Improving alkaline hydrogen evolution reaction kinetics on molybdenum carbide: Introducing Ru dopant [J]. Journal of Catalysis, 2020, 392: 313–321. DOI: https://doi.org/10.1016/j.jcat.2020.10.020. TANG Chun, GAN Lin-feng, ZHANG Rong, LU Wen-bo, JIANG Xiue, ASIRI A, SUN Xu-ping, WANG Jin, CHEN Liang. Ternary FexCo1−xP nanowire array as a robust hydrogen evolution reaction electrocatalyst with Pt-like activity: Experimental and theoretical insight [J]. Nano Lett, 2016, 16(10): 6617–6621. DOI: https://doi.org/10.1021/acs.nanolett.6b03332. WANG Xu-dong, XU Yang-fan, RAO Hua-shang, XU Weijian, CHEN Hong-yan, ZHANG Wei-xiong, KUANG Dai-bin, SU Cheng-yong. Novel porous molybdenum tungsten phosphide hybrid nanosheets on carbon cloth for efficient hydrogen evolution [J]. Energy & Environmental Science, 2016, 9(4): 1468–1475. DOI: https://doi.org/10.1039/c5ee03801d. YU Luo, MISHRA I, XIE Yun-long, ZHOU Hai-qing, SUN Jing-ying, ZHOU Jian-qing, NI Yi-zhou, LUO Dan, YU Fang, YU Ying, CHEN Shuo, REN Zhi-feng. Ternary Ni2(1−x)Mo2xP nanowire arrays toward efficient and stable hydrogen evolution electrocatalysis under large-current-density [J]. Nano Energy, 2018, 53: 492–500. DOI: https://doi.org/10.1016/j.nanoen.2018.08.025. ZHENG Xiao-zhong, CHEN Yu-zhuo, BAO Xiao-bing, MAO Shan-jun, FAN Ru-xue, WANG Yong. In situ formed bimetallic carbide Ni6Mo6C nanodots and NiMoOx nanosheet array hybrids anchored on carbon cloth: Efficient and Flexible self-supported catalysts for hydrogen evolution [J]. ACS Catalysis, 2020, 10(19): 11634–11642. https://doi.org/10.1021/acscatal.0c03355. KIBSGAARD J, TSAI C, CHAN K, BENCK J, NØRSKOV J, ABILD-PEDERSEN F, JARAMILLO T. Designing an improved transition metal phosphide catalyst for hydrogen evolution using experimental and theoretical trends [J]. Energy & Environmental Science, 2015, 8(10): 3022–3029. DOI: https://doi.org/10.1039/c5ee02179k. LIN Jing-huang, YAN Yao-tian, LIU Tao, CAO Jian, ZHOU Xin, FENG Ji-cai, QI Jun-lei. Optimize the electrocatalytic performances of NiCoP for water splitting by the synergic effect of S dopant and P vacancy [J]. Inter J Hydrogen Energy, 2020, 45(32): 16161–16168. https://doi.org/10.1016/j.ijhydene.2020.04.069. LIU Chun-lei, ZHANG Gong, YU Li, QU Jiu-hui, LIU Huijuan. Oxygen doping to optimize atomic hydrogen binding energy on NiCoP for highly efficient hydrogen evolution [J]. Small, 2018, 14(22): 1800421–1800429. DOI: https://doi.org/10.1002/smll.201800421. MA Yuan-yuan, WU Cai-xia, FENG Xiao-jia, TAN Hua-qiao, YAN Li-kai, LIU Yang, KANG Zhen-hui, WANG En-bo, LI Yang-guang. Highly efficient hydrogen evolution from seawater by a low-cost and stable CoMoP@C electrocatalyst superior to Pt/C [J]. Energy & Environmental Science, 2017, 10(3): 788–798. DOI: https://doi.org/10.1039/c6ee03768b. QI Yu-yang, ZHANG Long, SUN Lan, CHEN Guan-jun, LUO Qiao-mei, XIN Hong-qiang, PENG Jia-hui, LI Yan, MA Fei. Sulfur doping enhanced desorption of intermediates on NiCoP for efficient alkaline hydrogen evolution [J]. Nanoscale, 2020, 12(3): 1985–1993. DOI: https://doi.org/10.1039/c9nr08583a. QU Mei-jiao, JIANG Yi-min, YANG Miao, LIU Shu, GUO Qi-fei, SHEN Wei, LI Ming, HE Rong-xing. Regulating electron density of NiFe-P nanosheets electrocatalysts by a trifle of Ru for high-efficient overall water splitting [J]. Appl Catalysis B: Environ, 2020, 263: 118324–118332. DOI: https://doi.org/10.1016/j.apcatb.2019.118324. CAO Bo, CHENG Yan, HU Ming-hao, JING Peng, MA Zhixue, LIU Bao-cang, GAO Rui, ZHANG Jun. Efficient and durable 3D self-supported nitrogen-doped carbon-coupled nickel/cobalt phosphide electrodes: Stoichiometric ratio regulated phase-and morphology-dependent overall water splitting performance [J]. Advanced Functional Materials, 2019, 29(44): 1906316–1906333. DOI: https://doi.org/10.1002/adfm.201906316. YAN Yao-tian, LIN Jing-huang, CAO Jian, GUO Shu, ZHENG Xiao-hang, FENG Ji-cai, QI Jun-lei. Activating and optimizing the activity of NiCoP nanosheets for electrocatalytic alkaline water splitting through the V doping effect enhanced by P vacancies [J]. Journal of Materials Chemistry A, 2019, 7(42): 24486–24492. DOI: https://doi.org/10.1039/c9ta09283h. FU Qiang, WU Tao, FU Gang, GAO Tang-ling, HAN Jie-cai, YAO Tai, ZHANG Yu-min, ZHONG Wen-wu, WANG Xianjie, SONG Bo. Skutterudite-type ternary Co1−xNixP3 nanoneedle array electrocatalysts for enhanced hydrogen and oxygen evolution [J]. ACS Energy Letters, 2018, 3(7): 1744–1752. DOI: https://doi.org/10.1021/acsenergylett.8b00908. JIN Huan-yu, LIU Xin, CHEN Shuang-ming, VASILEFF A, LI Lai-quan, JIAO Yan, SONG Li, ZHENG Yao, QIAO Shizhang. Heteroatom-doped transition metal electrocatalysts for hydrogen evolution reaction [J]. ACS Energy Letters, 2019, 4(4): 805–810. DOI: https://doi.org/10.1021/acsenergylett.9b00348. WANG Ling, WU Hai-jun, XI Shi-bo, CHUA Sing-teng, WANG Feng-he, PENNYCOOK S, YU Zhi-gen, DU Yong-hua, XUE Jun-min. Nitrogen-doped cobalt phosphide for enhanced hydrogen evolution activity [J]. ACS Appl Mater Interfaces, 2019, 11(19): 17359–17367. DOI: https://doi.org/10.1021/acsami.9b01235. ZHOU Qing-wen, SHEN Zi-han, ZHU Chao, LI Jia-chen, DING Zhi-yuan, WANG Peng, PAN Feng, ZHANG Zhi-yong, MA Hai-xia, WANG Shuang-yin, ZHANG Hui-gang. Nitrogen-doped CoP electrocatalysts for coupled hydrogen evolution and sulfur generation with low energy consumption [J]. Adv Mater, 2018, 30(27): 1800140–1800147. DOI: https://doi.org/10.1002/adma.201800140. YAN Liang, ZHANG Bing, ZHU Jun-lu, LIU Zhong-gang, ZHANG Hai-yan, LI Yun-yong. Callistemon-like Zn and S codoped CoP nanorod clusters as highly efficient electrocatalysts for neutral-pH overall water splitting [J]. Journal of Materials Chemistry A, 2019, 7(39): 22453–22462. DOI: https://doi.org/10.1039/c9ta08812a. REN Xian-pei, MA Qiang, FAN Hai-bo, PANG Liu-qing, ZHANG Yun-xia, YAO Yao, REN Xiao-dong, LIU Sheng-zhong (Frank). A Se-doped MoS2 nanosheet for improved hydrogen evolution reaction [J]. Chem Commun (Camb), 2015, 51(88): 15997–16000. DOI: https://doi.org/10.1039/c5cc06847a. HU Cong-ling, ZHANG Lei, ZHAO Zhi-Jian, LI Ang, CHANG Xiao-xia, GONG Jin-long. Synergism of geometric construction and electronic regulation: 3D Se-(NiCo)Sx/(OH)x nanosheets for highly efficient overall water splitting [J]. Adv Mater, 2018, 30(12): 1705538–1705545. DOI: https://doi.org/10.1002/adma.201705538. YAO Na, LI Peng, ZHOU Zi-rui, ZHAO Yuan-meng, CHENG Gong-zhen, CHEN Sheng-li, LUO Wei. Synergistically tuning water and hydrogen binding abilities over Co4N by Cr doping for exceptional alkaline hydrogen evolution electrocatalysis [J]. Advanced Energy Materials, 2019, 9(41): 1902449–1902456. DOI: https://doi.org/10.1002/aenm.201902449. HUANG Ling, WU Hao, ZHANG Yun. One-step synthesis of CoPSe-CoSe2/CNTs as efficient electrocatalyst for oxygen evolution reaction [J]. Electrochim Acta, 2020, 331: 135362–135368. DOI: https://doi.org/10.1016/j.electacta.2019.135362. ZHOU Guang-yao, LI Meng, LI Yan-le, DONG Hang, SUN Dong-mei, LIU Xi-en, XU Lin, TIAN Zi-qi, TANG Ya-wen. Regulating the electronic structure of CoP nanosheets by O incorporation for high-efficiency electrochemical overall water splitting [J]. Advanced Functional Materials, 2019, 30(7): 1905252–1905259. DOI: https://doi.org/10.1002/adfm.201905252. LUO Qiao-mei, ZHAO Yi-wei, QI Yu-yang, XIN Hong-qiang, WANG Chen, CHEN Guan-jun, SUN Jun, LIU Ming-xia, XU Ke-wei, MA Fei. Plasma-assisted nitrogen doping in Ni-Co-P hollow nanocubes for efficient hydrogen evolution electrocatalysis [J]. Nanoscale, 2020, 12(25): 13708–13718. DOI: https://doi.org/10.1039/d0nr01783c. HUANG Chu-qiang, YU Luo, ZHANG Wei, XIAO Qin, ZHOU Jian-qing, ZHANG Yuan-lu, AN Peng-fei, ZHANG Jing, YU Ying. N-doped Ni-Mo based sulfides for high-efficiency and stable hydrogen evolution reaction [J]. Applied Catalysis B: Environmental, 2020, 276:119137–119144. DOI: https://doi.org/10.1016/j.apcatb.2020.119137. PAN Yuan, SUN Kai-an, LIN Yan, CAO Xing, CHENG Yuan-sheng, LIU Shou-jie, ZENG Ling-you, CHEONG Weng-chon, ZHAO Di, WU Kong-lin, LIU Zhi, LIU Yun-qi, WANG Ding-sheng, PENG Qing, CHEN Chen, LI Ya-dong. Electronic structure and d-band center control engineering over M-doped CoP (M=Ni, Mn, Fe) hollow polyhedron frames for boosting hydrogen production [J]. Nano Energy, 2019, 56: 411–419. DOI: https://doi.org/10.1016/j.nanoen.2018.11.034. ZHANG Ming-yuan, HU Ai-ping, LIU Zheng, XU Ya-li, FAN Bin-bin, TANG Qun-li, ZHANG Shi-ying, DENG Wei-na, CHEN Xiao-hua. Synergistic effect of three-dimensional cobalt diselenide/carbon nanotube arrays composites for enhanced hydrogen evolution reaction [J]. Electrochimica Acta, 2018, 285: 254–261. DOI: https://doi.org/10.1016/j.electacta.2018.07.226. WANG Jing, XU Fan, JIN Hai-yan, CHEN Yi-qing, WANG Yong. Non-noble metal-based carbon composites in hydrogen evolution reaction: Fundamentals to applications [J]. Adv Mater, 2017, 29(14): 1605838–1605872. DOI: https://doi.org/10.1002/adma.201605838. CAO Er-ping, CHEN Zhi-min, WU Hao, YU Peng, WANG Ying, XIAO Fei, CHEN Shuo, DU Shi-chao, XIE Ying, WU Yi-qun, REN Zhi-yu. Boron-induced electronic-structure reformation of CoP nanoparticles drives enhanced pH-universal hydrogen evolution [J]. Angew Chem Int Ed Engl, 2020, 59(10): 4154–4160. DOI: https://doi.org/10.1002/ange.201915254. BAO Xiao-bing, GONG Yu-tong, ZHENG Xiao-zhong, CHEN Jia-yi, MAO Shan-jun, WANG Yong. Highly performed platinum nanosheets synthesized under in situ reaction conditions for hydrogen generation [J]. Journal of Energy Chemistry, 2020, 51: 272–279. DOI: https://doi.org/10.1016/j.jechem.2020.03.064. ZHAO Wen-xi, MA Xiao-qing, WANG Guang-zhao, LONG Xiao-jiang, LI Ya-dong, ZHANG Wan-li, ZHANG Peng. Carbon-coated CoP3 nanocomposites as anode materials for high-performance sodium-ion batteries [J]. Applied Surface Science, 2018, 445: 167–174. ZHU Chang-rong, WANG An-liang, XIAO Wen, CHAO Dong-liang, ZHANG Xiao, TIEP N H, CHEN Shi, KANG Jia-ni, WANG Xin, DING Jun, WANG John, ZHANG Hua, FAN Hong-jin. In situ grown epitaxial heterojunction exhibits high-performance electrocatalytic water splitting [J]. Adv Mater, 2018, 30(13): 1705516–1705523. LI Jia-yuan, YAN Ming, ZHOU Xue-mei, HUANG Zheng-Qing, XIA Zhao-ming, CHANG Chun-Ran, MA Yuan-yuan, QU Yong-quan. Mechanistic insights on ternary Ni2−xCoxP for hydrogen evolution and their hybrids with graphene as highly efficient and robust catalysts for overall water splitting [J]. Advanced Functional Materials, 2016, 26(37): 6785–6796. ZHANG Ying, SHAO Qi, LONG Shui, HUANG Xiao-qing. Cobalt-molybdenum nanosheet arrays as highly efficient and stable earth-abundant electrocatalysts for overall water splitting [J]. Nano Energy, 2018, 45: 448–455. HAN A-li, CHEN Huan-lin, ZHANG Han-yu, SUN Zi-jun, DU Ping-wu. Ternary metal phosphide nanosheets as a highly efficient electrocatalyst for water reduction to hydrogen over a wide pH range from 0 to 14 [J]. Journal of Materials Chemistry A, 2016, 4(26): 10195–10202. ZHANG Hao-jie, LI Xiao-peng, HäHNEL A, NAUMANN V, LIN Chao, AZIMI S, SCHWEIZER S, MAIJENBURG A W, WEHRSPOHN R B. Bifunctional heterostructure assembly of NiFe LDH nanosheets on NiCoP nanowires for highly efficient and stable overall water splitting [J]. Advanced Functional Materials, 2018, 28(14): 1706847. CHEN Peng-zuo, ZHOU Tian-pei, ZHANG Meng-xing, TONG Yun, ZHONG Cheng-an, ZHANG Nan, ZHANG Li-dong, WU Chang-zheng, XIE Yi. 3D Nitrogen-anion-decorated nickel sulfides for highly efficient overall water splitting [J]. Adv Mater, 2017, 29(30): 1701584–1701589. DENG Sheng-jue, ZHONG Yu, ZENG Yin-xiang, WANG Ya-dong, WANG Xiu-li, LU Xi-hong, XIA Xin-hui, TU Jiang-ping. Hollow TiO2@Co9S8 core-branch arrays as bifunctional electrocatalysts for efficient oxygen/hydrogen production [J]. Advanced Science, 2018, 5(3): 1700772–1700779. WANG Peng-yan, PU Zong-hua, LI Yan-hui, WU Lin, TU Zheng-kai, JIANG Min, KOU Zong-kui, AMIINU I S, MU Shi-chun. Iron-doped nickel phosphide nanosheet arrays: An efficient bifunctional electrocatalyst for water splitting [J]. ACS Appl Mater Interfaces, 2017, 9(31): 26001–26007. DU Hui-tong, XIA Lian, ZHU Shu-yun, QU Fei, QU Feng-li. Al-Doped Ni2P nanosheet array: A superior and durable electrocatalyst for alkaline hydrogen evolution [J]. Chem Commun (Camb), 2018, 54(23): 2894–2897. CHEN Peng-zuo, XU Kun, TAO Shi, ZHOU Tian-pei, TONG Yun, DING Hui, ZHANG Li-dong, CHU Wang-sheng, WU Chang-zheng, XIE Yi. Phase-transformation engineering in cobalt diselenide realizing enhanced catalytic activity for hydrogen evolution in an alkaline medium [J]. Adv Mater, 2016, 28(34): 7527–7532. XIA Chuan, LIANG Han-feng, ZHU Jia-jie, SCHWINGENSCHLÖGL U, ALSHAREEF H. Active edge sites engineering in nickel cobalt selenide solid solutions for highly efficient hydrogen evolution [J]. Advanced Energy Materials, 2017, 7(9): 1602089. SIVANANTHAM A, GANESAN P, SHANMUGAM S. Hierarchical NiCo2S4 Nanowire arrays supported on Ni foam: An efficient and durable bifunctional electrocatalyst for oxygen and hydrogen evolution reactions [J]. Advanced Functional Materials, 2016, 26(26): 4661–4672. WANG Peng-cheng, LIU Xue-feng, YAN Yao-tian, CAO Jian, FENG Ji-cai, QI Jun-lei. Exploring CoP core-shell nanosheets by Fe and Zn dual cation doping as efficient electrocatalysts for overall water splitting [J]. Catalysis Science & Technology, 2020, 10(5): 1395–1400. XU Xiu-juan, DU Pu-yu, CHEN Zong-kun, HUANG Ming-hua. An electrodeposited cobalt-selenide-based film as an efficient bifunctional electrocatalyst for full water splitting [J]. Journal of Materials Chemistry A, 2016, 4(28): 10933–10939. JIA Heng-lei, JIANG Rui-bin, LU Wen-zheng, RUAN Qi-feng, WANG Jian-fang, YU J. Aerosol-spray metal phosphide microspheres with bifunctional electrocatalytic properties for water splitting [J]. Journal of Materials Chemistry A, 2018, 6(11): 4783–4792. PAN Yuan, SUN Kai-an, LIU Shou-jie, CAO Xing, WU Kong-jie, CHEONG Weng-Chon, CHEN Zheng, WANG Yu, LI Yang, LIU Yun-qi, WANG Ding-sheng, PENG Qing, CHEN Chen, LI Ya-dong. Core-shell ZIF-8@ZIF-67-derived CoP nanoparticle-embedded n-doped carbon nanotube hollow polyhedron for efficient overall water splitting [J]. J Am Chem Soc, 2018, 140(7): 2610–2618. TANG Chun, ZHANG Rong, LU Wen-bo, HE Liang-bo, JIANG Xiue, ASIRI A, SUN Xu-ping. Fe-doped CoP nanoarray: A monolithic multifunctional catalyst for highly efficient hydrogen generation [J]. Adv Mater, 2017, 29(2): 1602441–1602446. CHEN Gao-feng, MA Tian-yi, LIU Zhao-qing, LI Nan, SU Yu-zhi, DAVEY K, QIAO Shi-zhang. Efficient and stable bifunctional electrocatalysts Ni/NixMy (M = P, S) for overall water splitting [J]. Advanced Functional Materials, 2016, 26(19): 3314–3323.