2D Monoelemental Arsenene, Antimonene, and Bismuthene: Beyond Black Phosphorus

Advanced Materials - Tập 29 Số 21 - 2017
Martin Pumera1, Zdeněk Sofer2
1Division of Chemistry & Biological Chemistry School of Physical and Mathematical Sciences Nanyang Technological University Singapore 637371 Singapore
2Department of Inorganic Chemistry, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague 6, Czech Republic

Tóm tắt

Two‐dimensional materials are responsible for changing research in materials science. After graphene and its counterparts, graphane, fluorographene, and others were introduced, waves of renewed interest in 2D binary compounds occurred, such as in metal oxides, transition‐metal dichalcogenides (most often represented by MoS2), metal oxy/hydroxide borides, and MXenes, to name the most prominent. Recently, interest has turned to two‐dimensional monoelemental structures, such as monolayer black phosphorus and, very recently, to monolayer arsenic, antimony, and bismuth. Here, a short overview is provided of the area of exponentially increasing research in arsenene, antimonene, and bismuthene, which belong to the fifth main group of elements, the so‐called pnictogens. A short review of historical work is provided, the properties of bulk allotropes of As, Sb, and Bi discussed, and then theoretical and experimental research on mono‐ and few‐layered arsenene, antimonene, and bismuthene addressed, discussing their structures and properties.

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Tài liệu tham khảo

10.1038/natrevmats.2016.42

10.1016/0039-6028(68)90089-7

Brodie B., 1855, Ann. Chim. Phys., 45, 351

10.1016/0025-5408(86)90011-5

10.1021/ja02184a002

10.1021/acs.chemrev.5b00287

10.1016/j.apmt.2015.12.001

10.1038/nnano.2014.85

10.1088/0022-3719/18/25/016

10.1016/0368-2048(94)80011-1

10.1016/0039-6028(93)90841-7

10.1016/j.susc.2005.05.013

10.1103/PhysRevB.31.2213

Hansen M., 1958, Cosntitution of Binary Alloys

10.1134/S0036023606090154

Gross A. J., 1963, The Art and Science of Growing Crystals, 323

10.1016/0022-0248(68)90188-7

10.1063/1.1713776

10.1002/adma.201501758

10.1002/smll.201402041

10.1002/anie.201507568

10.1021/acsami.5b02441

Hollerman N., 2001, Inorganic Chemistry, 741

10.1002/anie.201411246

10.1103/PhysRevB.91.085423

10.1103/PhysRevB.91.161404

10.1103/PhysRevB.94.014115

10.1016/j.spmi.2015.08.006

10.1038/srep16108

10.1016/j.cplett.2015.10.072

10.1103/PhysRevLett.97.216803

10.1186/s11671-015-0955-7

10.1103/PhysRevB.91.235446

10.1063/1.4948537

10.1063/1.4958702

10.1038/srep24114

10.1073/pnas.1413389111

10.1039/C6RA13101H

10.1039/C5RA25572D

10.1039/C6RA03927H

10.1039/C5CP04815J

10.1039/C6TC01141A

10.1038/ncomms12585

10.1039/C6TC01913G

10.1021/nl502997v

Grant M. W., 1992, Surf. Sci. Lett., 279, L180

10.1039/C6CC02778D

10.1002/anie.201605298

10.1002/adma.201602128

10.1080/14786437508229285

10.1002/adma.201501758

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Advanced Materials

Tập 29 Số 21

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