‘In water’ exploration of Alpinia zerumbet-fabricated CuO NPs in the presence of NaPTS at room temperature: green synthesis of 1,8-dioxooctahydroxanthene derivatives

Research on Chemical Intermediates - 2021
Bipin Shinde1, Santosh Kamble2, Harsharaj Jadhav3, Prasad Mane2, Kalpesh Khude2, Hern Kim3, Bhausaheb Karale4, Arvind Burungale5
1Department of Chemistry, Rayat Shikshan Sanstha’s, Karmaveer Bhaurao Patil College, Vashi, India
2Department of Chemistry, Rayat Shikshan Sanstha’s, Yashavantrao Chavan Institute of Science, Satara, India
3Department of Energy Science and Technology, Myongji University, Yongin-si, Republic of Korea
4Department of Chemistry, Rayat Shikshan Sanstha’s Radhabai Kale Mahila Mahavidyalaya, Ahmednagar, India
5Rayat Shikshan Sanstha’s Yashawantrao Chavan Mahavidyalaya, Pachwad Satara, India

Tóm tắt

The biogenic synthesis of copper oxide nanoparticles (CuO NPs) from the leaf extract of Alpinia zerumbet was investigated in this protocol. The basic nature of A. zerumbet leaf extract helps in CuO NPs synthesis. The catalytic activity of A. zerumbet-fabricated CuO NPs is explored in water at room temperature only in the presence of NaPTS hydrotrope. The green catalytic protocol is investigated via synthesis of 1,8-dioxooctahydroxanthene. The biogenic leaf extract fabricated CuO NPs are efficiently reactive, stable and recyclable in aqueous solution of sodium p-toluenesulfonate (NaPTS) hydrotrope. CuO/NaPTS proved to be the best catalytic system as synergistic nanotrope in terms of yield and time of reaction in water at room temperature. The green synthetic approach of CuO NPs, greener medium, easy workup and proficient recyclability are advantages in the said protocol. This is first time report of catalytic activity of biogenic CuO NPs in water at room temperature in the presence of NaPTS.

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