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The contributions reflect the latest findings in these research areas and serve the development of new materials, such as super-hard materials, electrical superconductors, or intermetallic compounds. Up-to-date physical methods for the characterization of new chemical compounds and materials are also described.","PUBLISHER","PENDING",null,0,[27],{"id":28,"createTime":24,"updateTime":24,"relativeEntities":29,"label":30,"description":32,"parentId":24,"standard":24,"scholarHubFieldId":24},"76b5022b-c9dd-41ef-8fbc-a58b1f5555b9",[],{"EN":31},"Inorganic Chemistry",{},[34,41],{"id":35,"createTime":24,"updateTime":24,"relativeEntities":36,"slug":24,"properties":37,"entityType":24,"verifyStatus":24,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":24,"url":24,"parentIds":40,"statistic":24},"68fc5f5d-8131-454a-8d74-eb1970b9942b",[],{"title":38},{"EN":39},"WILEY-V C H VERLAG GMBH",[],{"id":42,"createTime":24,"updateTime":24,"relativeEntities":43,"slug":24,"properties":44,"entityType":24,"verifyStatus":24,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":24,"url":24,"parentIds":47,"statistic":24},"349eca5a-ec3b-495d-9fe4-7db32f062b72",[],{"title":45},{"EN":46},"Wiley-VCH Verlag",[],[49,66],{"id":50,"indexDatabase":51,"url":61,"indexYears":62,"academicFieldIds":63,"indexDatabaseRanking":65},"3054f1c3-c329-4bfa-b5a8-0e3b7c31034e",{"id":52,"createTime":24,"updateTime":24,"relativeEntities":53,"label":54,"description":56,"key":58,"publicationTags":59,"standard":24},"3c7051d4-eb7d-4c57-a56b-36fc74c5d1e9",[],{"EN":55,"VI":55},"Scopus - Elsevier",{"EN":55,"VI":57},"Cơ sở dữ liệu Scopus thuộc Elsevier","scopus",[60],"SCOPUS","https:\u002F\u002Fwww.scopus.com\u002Fsourceid\u002F22010","1892-1945,1947-2025",[64],"1eb1358f-abbb-4e80-a71e-708d7a8171b8","SCOPUS__Q2",{"id":67,"indexDatabase":68,"url":80,"indexYears":24,"academicFieldIds":81,"indexDatabaseRanking":24},"664a8f0d-6461-4bf1-9169-931688408601",{"id":69,"createTime":24,"updateTime":24,"relativeEntities":70,"label":71,"description":73,"key":76,"publicationTags":77,"standard":24},"a4921856-b128-4d9f-8f1f-e80813d3bbd4",[],{"EN":72,"VI":72},"ISI\u002FSCIE - Science Citation Index Expanded",{"EN":74,"VI":75},"SCIE database","Cơ sở dữ liệu SCIE","scie",[78,79],"SCIE","ISI","https:\u002F\u002Fmjl.clarivate.com\u002Fsearch-results?issn=0044-2313",[82],"c8afe963-0af5-4db8-bfd5-bc7a416f3ea3","https:\u002F\u002Fonlinelibrary.wiley.com\u002Fjournal\u002F15213749",{"meta":85,"data":87},{"total":86},"137",[88,232,442,622,953,1205,1340,1580,1879,2086],{"id":89,"createTime":90,"updateTime":91,"relativeEntities":92,"slug":93,"properties":94,"entityType":107,"verifyStatus":108,"verifyTime":90,"verifyNote":109,"languages":110,"translateLanguages":24,"viewCount":25,"primaryUrl":112,"fullTextUrl":24,"authors":113,"publicationType":131,"publisherRelationship":132,"citationCount":178,"citationInfo":179,"publishDate":187,"publishYear":180,"citationAnalyzeStatus":188,"lastCitationAnalyze":189,"indexDatabases":190,"openAccess":24,"references":191,"isForceReanalyzing":231},"ed114a20-655a-440a-8034-69201e7eb068","2024-09-01T13:57:56.059+00:00","2026-07-16T04:43:12.313+00:00",[],"Kraftkonstanten-von-Methylverbindungen-der-5-Gruppe",{"openalex":95,"mag":97,"abstract":99,"title":101,"gsPaper":103,"doi":105},{"VOID":96},"W2076225210",{"VOID":98},"2076225210",{"EN":100},"\u003Cjats:title>Abstract\u003C\u002Fjats:title>\u003Cjats:p>Für die Schwingungen der pyramidal gebauten Trimethyle X(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>3\u003C\u002Fjats:sub> (Symmetrie C\u003Cjats:sub>3v\u003C\u002Fjats:sub>) werden Frequenzformeln abgeleitet, wobei zur Erleichterung der Rechnung gewisse Vereinfachungen vorgenommen werden. Die beobachteten Frequenzen der hierher gehörigen Molekeln N(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>3\u003C\u002Fjats:sub>, P(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>3\u003C\u002Fjats:sub>, As(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>3\u003C\u002Fjats:sub>, Sb(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>3\u003C\u002Fjats:sub>, Bi(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>3\u003C\u002Fjats:sub> und S(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:inline-graphic xmlns:xlink=\"http:\u002F\u002Fwww.w3.org\u002F1999\u002Fxlink\" xlink:href=\"graphic\u002Ftex2gif-stack-1.gif\" xlink:title=\"urn:x-wiley:00442313:media:ZAAC19532730306:tex2gif-stack-1\" \u002F> werden den Schwingungsformen zugeordnet und die Kraftkonstanten berechnet. Diese werden mit früher angegebenen Zahlen anderer Autoren verglichen.\u003C\u002Fjats:p>\u003Cjats:p>Die Wechselwirkungskonstante f′\u003Cjats:sub>CX\u003C\u002Fjats:sub> ist Null mit Ausnahme der des N(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>3\u003C\u002Fjats:sub>. Daraus wird geschlossen, daß in den Trimethylen annähernd reine p‐Bindungen vorliegen. Im N(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>3\u003C\u002Fjats:sub> dagegen deutet sich sp\u003Cjats:sup>3\u003C\u002Fjats:sup>‐Bastardisierung an.\u003C\u002Fjats:p>\u003Cjats:p>Die Raman‐Spektren von As(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>4\u003C\u002Fjats:sub>Cl und Sb(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>4\u003C\u002Fjats:sub>Cl werden an wäßrigen Lösungen der Salze beobachtet. Die Frequenzen dieser Verbindungen sowie die des N(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>4\u003C\u002Fjats:sub>Cl lassen sich zwanglos den tetraedrischen Ionen X(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:inline-graphic xmlns:xlink=\"http:\u002F\u002Fwww.w3.org\u002F1999\u002Fxlink\" xlink:href=\"graphic\u002Ftex2gif-stack-2.gif\" xlink:title=\"urn:x-wiley:00442313:media:ZAAC19532730306:tex2gif-stack-2\" \u002F> zuordnen. Ihre Kraftkonstanten werden berechnet. Im N(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:inline-graphic xmlns:xlink=\"http:\u002F\u002Fwww.w3.org\u002F1999\u002Fxlink\" xlink:href=\"graphic\u002Ftex2gif-stack-3.gif\" xlink:title=\"urn:x-wiley:00442313:media:ZAAC19532730306:tex2gif-stack-3\" \u002F> nimmt die Valenzkraftkonstante gegenüber dem N(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>3\u003C\u002Fjats:sub> um 9% ab. Beim As(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:inline-graphic xmlns:xlink=\"http:\u002F\u002Fwww.w3.org\u002F1999\u002Fxlink\" xlink:href=\"graphic\u002Ftex2gif-stack-4.gif\" xlink:title=\"urn:x-wiley:00442313:media:ZAAC19532730306:tex2gif-stack-4\" \u002F> und Sb(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:inline-graphic xmlns:xlink=\"http:\u002F\u002Fwww.w3.org\u002F1999\u002Fxlink\" xlink:href=\"graphic\u002Ftex2gif-stack-5.gif\" xlink:title=\"urn:x-wiley:00442313:media:ZAAC19532730306:tex2gif-stack-5\" \u002F> werden Zunahmen um etwa 20% berechnet, Die (zu f\u003Cjats:sub>CX\u003C\u002Fjats:sub> proportionale) Konstante d\u003Cjats:sub>HCX\u003C\u002Fjats:sub> verhält sich ähnlich, dagegen die Konstante d\u003Cjats:sub>CXC\u003C\u002Fjats:sub> umgekehrt. Eine Erklärung für diese Veränderungen kann nicht gegeben werden. Eine von Pauling entwickelte Hypothese gibt die Verhältnisse nicht richtig wieder.\u003C\u002Fjats:p>",{"EN":102},"Kraftkonstanten von Methylverbindungen der 5. 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W. F.Kohlrausch Raman‐Spektren Akad. Verlagsges. Leipzig1943.",{},{"id":24,"text":211,"url":24,"identifiers":212},"10.1002\u002Fzaac.19522710109",{"doi":211},{"id":24,"text":214,"url":24,"identifiers":215},"Den Herren Prof.Dr.R.Meckeu.Dr.W.Lüttke(Freiburg) danke ich herzlich für ihr Entgegenkommen.",{},{"id":24,"text":217,"url":24,"identifiers":218},"10.1063\u002F1.1723859",{"doi":217},{"id":24,"text":220,"url":24,"identifiers":221},"10.1063\u002F1.1749739",{"doi":220},{"id":24,"text":223,"url":24,"identifiers":224},"10.1063\u002F1.1750013",{"doi":223},{"id":24,"text":226,"url":24,"identifiers":227},"10.1002\u002Fcber.19060390130",{"doi":226},{"id":24,"text":229,"url":24,"identifiers":230},"Pauling L., 1939, The nature of the chemical bond",{},false,{"id":233,"createTime":234,"updateTime":235,"relativeEntities":236,"slug":237,"properties":238,"entityType":107,"verifyStatus":108,"verifyTime":234,"verifyNote":109,"languages":249,"translateLanguages":24,"viewCount":25,"primaryUrl":250,"fullTextUrl":24,"authors":251,"publicationType":131,"publisherRelationship":271,"citationCount":317,"citationInfo":318,"publishDate":321,"publishYear":319,"citationAnalyzeStatus":322,"lastCitationAnalyze":323,"indexDatabases":324,"openAccess":24,"references":325,"isForceReanalyzing":231},"7deb6dfe-90e5-4245-80f6-28a10eb26460","2024-07-18T11:22:03.678+00:00","2026-04-08T13:36:24.585+00:00",[],"Doppelverbindungen-vom-Typ-Me-Me-sup-II-sup-X-sup-VI-sup-O-sub-4-sub-sub-2-sub-mit-der-Struktur-von-Sr-sub-3-sub-PO-sub-4-sub-sub-2-sub-III-Chromate",{"openalex":239,"abstract":241,"title":243,"gsPaper":245,"doi":247},{"VOID":240},"W4245280590",{"EN":242},"\u003Cjats:title>Abstract\u003C\u002Fjats:title>\u003Cjats:p>Es wird die Darstellung von Doppelchromaten(VI) des Typs Me\u003Cjats:inline-graphic xmlns:xlink=\"http:\u002F\u002Fwww.w3.org\u002F1999\u002Fxlink\" xlink:href=\"graphic\u002Ftex2gif-stack-2.gif\" xlink:title=\"urn:x-wiley:00442313:media:ZAAC19663450503:tex2gif-stack-2\" \u002F>Me\u003Cjats:sup>II\u003C\u002Fjats:sup>(CrO\u003Cjats:sub>4\u003C\u002Fjats:sub>)\u003Cjats:sub>2\u003C\u002Fjats:sub> für Me\u003Cjats:sup>I\u003C\u002Fjats:sup> = K, NH\u003Cjats:sub>4\u003C\u002Fjats:sub>, Rb, Tl und Me\u003Cjats:sup>II\u003C\u002Fjats:sup> = Sr, Pb, Ba beschrieben; sie ist sowohl auf thermischem Wege als auch aus Lösung möglich. Sämtliche Verbindungen kristallisieren nach Ausweis der Röntgenpulverdiagramme mit der hexagonal‐rhomboedrischen Struktur von Sr\u003Cjats:sub>3\u003C\u002Fjats:sub>(Cr\u003Cjats:sup>V\u003C\u002Fjats:sup>O\u003Cjats:sub>4\u003C\u002Fjats:sub>)\u003Cjats:sub>2\u003C\u002Fjats:sub>. Damit ergibt sich eine weitere kristallchemische Beziehung zwischen Chromaten(V) und (VI).\u003C\u002Fjats:p>\u003Cjats:p>In allen Fällen stehen die aus den Gitterdimensionen errechneten Dichten im Einklang mit den pyknometrisch bestimmten Dichten.\u003C\u002Fjats:p>\u003Cjats:p>Die nähere Untersuchung einzelner Systeme Me\u003Cjats:inline-graphic xmlns:xlink=\"http:\u002F\u002Fwww.w3.org\u002F1999\u002Fxlink\" xlink:href=\"graphic\u002Ftex2gif-stack-3.gif\" xlink:title=\"urn:x-wiley:00442313:media:ZAAC19663450503:tex2gif-stack-3\" \u002F>CrO\u003Cjats:sub>4\u003C\u002Fjats:sub>\u002FMe\u003Cjats:sup>II\u003C\u002Fjats:sup>CrO\u003Cjats:sub>4\u003C\u002Fjats:sub> zeigt, daß die 1:1‐Doppelverbindungen, zumindest im untersuchten Temperaturbereich die einzigen in den Systemen existenzfähigen Verbindungen sind.\u003C\u002Fjats:p>\u003Cjats:p>Am Ende folgen einige Bemerkungen zur zweckmäßigen analytischen Untersuchung der Doppelchromate.\u003C\u002Fjats:p>",{"EN":244},"Doppelverbindungen vom Typ Me(Me\u003Csup>II\u003C\u002Fsup>(X\u003Csup>VI\u003C\u002Fsup>O\u003Csub>4\u003C\u002Fsub>)\u003Csub>2\u003C\u002Fsub> mit der Struktur von Sr\u003Csub>3\u003C\u002Fsub>(PO\u003Csub>4\u003C\u002Fsub>)\u003Csub>2\u003C\u002Fsub>. III. Chromate",{"VOID":246},"[]",{"VOID":248},"10.1002\u002Fzaac.19663450503",[111],"https:\u002F\u002Fonlinelibrary.wiley.com\u002Fdoi\u002F10.1002\u002Fzaac.19663450503",[252],{"id":253,"sortIndex":25,"researcher":24,"roles":254,"affiliations":255,"properties":264,"displayName":268,"givenName":24,"familyName":24},"11a9e661-53b3-4b4a-bc8f-cd297a422a82",[],[256],{"id":257,"sortIndex":25,"affiliation":258,"properties":24},"902f1c05-c867-43f3-84c5-199640584171",{"id":257,"createTime":24,"updateTime":24,"relativeEntities":259,"slug":24,"properties":260,"entityType":24,"verifyStatus":24,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":24,"url":24,"parentIds":263,"statistic":24},[],{"title":261},{"EN":262},"Karlsruhe, Institut für Anorganische Chemie der Technischen Hochschule",[],{"orcid":265,"title":267,"openalex":269},{"VOID":266},"https:\u002F\u002Forcid.org\u002F0000-0002-1708-8948",{"EN":268},"H. 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Suchy Techn. Hochschule Karlsruhe1953.",{},{"id":24,"text":339,"url":24,"identifiers":340},"10.1002\u002Fange.19540661603",{"doi":339},{"id":24,"text":342,"url":24,"identifiers":343},"10.1002\u002Fzaac.19633260103",{"doi":342},{"id":24,"text":345,"url":24,"identifiers":346},"10.1107\u002FS0365110X5900127X",{"doi":345},{"id":24,"text":348,"url":24,"identifiers":349},"10.1107\u002FS0365110X48000697",{"doi":348},{"id":24,"text":351,"url":24,"identifiers":352},"10.1002\u002Fzaac.19663440106",{"doi":351},{"id":24,"text":354,"url":24,"identifiers":355},"10.1002\u002Fzaac.19633230509",{"doi":354},{"id":24,"text":357,"url":24,"identifiers":358},"10.1002\u002Fzaac.19070540116",{"doi":357},{"id":24,"text":360,"url":24,"identifiers":361},"10.1002\u002Fzaac.19080580138",{"doi":360},{"id":24,"text":363,"url":24,"identifiers":364},"Gröger M., 1906, Z. anorg. 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No. 78 418 (1961).",{},{"id":24,"text":396,"url":24,"identifiers":397},"K.Sagel Tabellen zur Röntgenstrukturanalyse Berlin‐Göttingen‐Heidelberg1958 S.63.",{"doi":398},"10.1007\u002F978-3-642-51126-4",{"id":24,"text":400,"url":24,"identifiers":401},"10.1063\u002F1.1702202",{"doi":400},{"id":24,"text":403,"url":24,"identifiers":404},"Druckschrift der Fa. Siemens u. Halske AG SH 8407 Eg 4a.",{},{"id":24,"text":406,"url":24,"identifiers":407},"Belyaev I. N., 1964, Russian J. inorg. Chem., 9, 1483",{},{"id":24,"text":409,"url":24,"identifiers":410},"Eigene Messung mit NaCl (a0= 5 6392 Å24)) als Standard.",{},{"id":24,"text":412,"url":24,"identifiers":413},"Jevins A., 1936, Z. physik. Chem., Abt. B, 34, 402",{},{"id":24,"text":415,"url":24,"identifiers":416},"Wolf H., 1954, Z. analyt. 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Chem., 5, 310",{},{"id":24,"text":551,"url":24,"identifiers":552},"Lacroix I., 1962, C. R. hebd. Séances Acad. Sci., 255, 961",{},{"id":24,"text":554,"url":24,"identifiers":555},"Ghiron D., 1935, Gazz. chim. ital., 65, 1244",{},{"id":24,"text":557,"url":24,"identifiers":558},"Boullé A., 1953, C. R. hebd. Séances Acad. Sci., 237, 161",{},{"id":24,"text":560,"url":24,"identifiers":561},"Jary R., 1957, Ann. Chimie [13], 2, 58",{},{"id":24,"text":563,"url":24,"identifiers":564},"B.Lelong Thèses présentées à la Faculté des Sciences de l'Université de Paris (1963).",{},{"id":24,"text":566,"url":24,"identifiers":567},"10.1002\u002Fzaac.19633250106",{"doi":566},{"id":24,"text":569,"url":24,"identifiers":570},"Awdujewskaja K. A., 1963, J. anorg. Chem., 8, 1020",{},{"id":24,"text":572,"url":24,"identifiers":573},"1965, J. anorg. Chem., 10, 366",{},{"id":24,"text":575,"url":24,"identifiers":576},"Lin‐Na Tschan, 1964, J. anorg. Chem., 9, 1472",{},{"id":24,"text":578,"url":24,"identifiers":579},"Awdujewskaja K. A., 1965, J. anorg. Chem., 10, 372",{},{"id":24,"text":581,"url":24,"identifiers":582},"10.1016\u002F0022-1902(64)80238-4",{"doi":581},{"id":24,"text":584,"url":24,"identifiers":585},"10.1246\u002Fbcsj.36.1316",{"doi":584},{"id":24,"text":587,"url":24,"identifiers":588},"10.1016\u002F0022-1902(64)80173-1",{"doi":587},{"id":24,"text":590,"url":24,"identifiers":591},"I. J.Galu.O. S.Gal Proc. 2nd int. Conf. peaceful Uses of atomic Energy",{},{"id":24,"text":593,"url":24,"identifiers":594},"1958, Geneva, 28, 24",{},{"id":24,"text":596,"url":24,"identifiers":597},"10.1246\u002Fbcsj.34.1736",{"doi":596},{"id":24,"text":599,"url":24,"identifiers":600},"10.1002\u002Fprac.18510540150",{"doi":599},{"id":24,"text":602,"url":24,"identifiers":603},"10.1002\u002Fange.19640761608",{"doi":602},{"id":24,"text":605,"url":24,"identifiers":606},"H.Worzala Diss. Humboldt‐Univ. Berlin1965.",{},{"id":24,"text":608,"url":24,"identifiers":609},"K.‐H.Jost H.WorzalaundE.Thilo Acta crystallogr. [Copenhagen]im Druck.",{},{"id":24,"text":611,"url":24,"identifiers":612},"Levi G. R., 1935, Z. Kristallogr., Mineralog. Petrogr., Abt. A, 92, 190",{},{"id":24,"text":614,"url":24,"identifiers":615},"Völlenkle H., 1963, Mh. Chem., 94, 956",{},{"id":24,"text":617,"url":24,"identifiers":618},"10.1007\u002FBF01185114",{"doi":617},{"id":24,"text":620,"url":24,"identifiers":621},"Handb. analyt. Chem. Teil III Bd. IVb S.273 Berlin‐Göttingen‐Heidelberg1950.",{},{"id":623,"createTime":624,"updateTime":625,"relativeEntities":626,"slug":627,"properties":628,"entityType":107,"verifyStatus":108,"verifyTime":624,"verifyNote":109,"languages":640,"translateLanguages":24,"viewCount":25,"primaryUrl":641,"fullTextUrl":24,"authors":642,"publicationType":131,"publisherRelationship":730,"citationCount":182,"citationInfo":776,"publishDate":779,"publishYear":777,"citationAnalyzeStatus":322,"lastCitationAnalyze":625,"indexDatabases":780,"openAccess":24,"references":781,"isForceReanalyzing":231},"a59b615d-0840-43e7-8031-2b3be6452f08","2025-02-05T06:12:55.600+00:00","2025-02-09T03:28:50.389+00:00",[],"About-Lanthanoid-Fluoride-Selenide-Oxoselenotantalates-with-the-Composition-i-Ln-i-sub-3-sub-F-sub-2-sub-Se-sub-2-sub-TaO-sub-4-sub-i-Ln-i-La-Nd-",{"openalex":629,"mag":631,"abstract":633,"title":635,"gsPaper":637,"doi":638},{"VOID":630},"W3091720261",{"VOID":632},"3091720261",{"EN":634},"\u003Cjats:p>After solid‐state reactions of the light lanthanoid metals, their oxides and fluorides as well as selenium in sealed tantalum ampoules with sodium chloride as a fluxing agent at 850 °C for 8 days needle‐shaped single crystals of \u003Cjats:italic>Ln\u003C\u002Fjats:italic>\u003Cjats:sub>3\u003C\u002Fjats:sub>F\u003Cjats:sub>2\u003C\u002Fjats:sub>Se\u003Cjats:sub>2\u003C\u002Fjats:sub>TaO\u003Cjats:sub>4\u003C\u002Fjats:sub> (\u003Cjats:italic>Ln\u003C\u002Fjats:italic> = La – Nd) were obtained. They crystallize in the orthorhombic space group \u003Cjats:italic>Pnma\u003C\u002Fjats:italic> analogous to La\u003Cjats:sub>3\u003C\u002Fjats:sub>F\u003Cjats:sub>2\u003C\u002Fjats:sub>Se\u003Cjats:sub>2\u003C\u002Fjats:sub>NbO\u003Cjats:sub>4\u003C\u002Fjats:sub> with \u003Cjats:italic>a\u003C\u002Fjats:italic> = 1133–1120 pm, \u003Cjats:italic>b\u003C\u002Fjats:italic> = 400–393 pm and \u003Cjats:italic>c\u003C\u002Fjats:italic> = 1812–1778 pm (\u003Cjats:italic>Ln\u003C\u002Fjats:italic> = La – Nd) for \u003Cjats:italic>Z\u003C\u002Fjats:italic> = 4 as the first known quinary lanthanoid(III) oxoselenotantalates(V) with fluoride and selenide anions. The three crystallographically different \u003Cjats:italic>Ln\u003C\u002Fjats:italic>\u003Cjats:sup>3+\u003C\u002Fjats:sup> cations are all surrounded by nine anions (O\u003Cjats:sup>2–\u003C\u002Fjats:sup>, F\u003Cjats:sup>–\u003C\u002Fjats:sup> and Se\u003Cjats:sup>2–\u003C\u002Fjats:sup>) each. Tantalum resides in an octahedral chalcogen coordination by forming \u003Cjats:italic>trans\u003C\u002Fjats:italic>‐vertex oxygen‐connected [TaO\u003Cjats:sub>5\u003C\u002Fjats:sub>Se]\u003Cjats:sup>7–\u003C\u002Fjats:sup> polyhedra, which build up chains \u003Cjats:sup>1\u003C\u002Fjats:sup>\u003Cjats:sub>∞\u003C\u002Fjats:sub>{[TaO\u003Cjats:sup>V\u003C\u002Fjats:sup>\u003Cjats:sub>2\u002F2\u003C\u002Fjats:sub>O\u003Cjats:sup>t\u003C\u002Fjats:sup>\u003Cjats:sub>3\u002F1\u003C\u002Fjats:sub>Se\u003Cjats:sup>t\u003C\u002Fjats:sup>\u003Cjats:sub>1\u002F1\u003C\u002Fjats:sub>]\u003Cjats:sup>5–\u003C\u002Fjats:sup>} along [010]. The sites of the four crystallographically different oxygen atoms and the two distinct fluoride anions were established by bond‐valence calculations. One fluorine and three oxygen atoms are surrounded tetrahedrally by cations, while another fluoride and oxide anion exhibit just triangular non‐planar coordination spheres. The two independent Se\u003Cjats:sup>2–\u003C\u002Fjats:sup> anions have five or six cationic neighbors.\u003C\u002Fjats:p>",{"EN":636},"About Lanthanoid Fluoride Selenide Oxoselenotantalates with the Composition \u003Ci>Ln\u003C\u002Fi>\u003Csub>3\u003C\u002Fsub>F\u003Csub>2\u003C\u002Fsub>Se\u003Csub>2\u003C\u002Fsub>TaO\u003Csub>4\u003C\u002Fsub> (\u003Ci>Ln\u003C\u002Fi> = La – Nd)",{"VOID":246},{"VOID":639},"10.1002\u002Fzaac.202000087",[111],"https:\u002F\u002Fonlinelibrary.wiley.com\u002Fdoi\u002F10.1002\u002Fzaac.202000087",[643,660,675,690,705],{"id":644,"sortIndex":25,"researcher":24,"roles":645,"affiliations":646,"properties":655,"displayName":657,"givenName":24,"familyName":24},"1a68c040-ceb5-4ae1-9823-0e4ce2748ca4",[],[647],{"id":648,"sortIndex":25,"affiliation":649,"properties":24},"24b2bebb-aced-47af-ab4c-e230d7a659f8",{"id":648,"createTime":24,"updateTime":24,"relativeEntities":650,"slug":24,"properties":651,"entityType":24,"verifyStatus":24,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":24,"url":24,"parentIds":654,"statistic":24},[],{"title":652},{"VI":653},"Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany",[],{"title":656,"openalex":658},{"EN":657},"Hagen Grossholz",{"VOID":659},"A5081342385",{"id":661,"sortIndex":183,"researcher":24,"roles":662,"affiliations":663,"properties":670,"displayName":672,"givenName":24,"familyName":24},"450a0f81-a38a-466d-9708-cdb3a8b58a27",[],[664],{"id":648,"sortIndex":25,"affiliation":665,"properties":24},{"id":648,"createTime":24,"updateTime":24,"relativeEntities":666,"slug":24,"properties":667,"entityType":24,"verifyStatus":24,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":24,"url":24,"parentIds":669,"statistic":24},[],{"title":668},{"VI":653},[],{"title":671,"openalex":673},{"EN":672},"Constantin Buyer",{"VOID":674},"A5016044655",{"id":676,"sortIndex":182,"researcher":24,"roles":677,"affiliations":678,"properties":685,"displayName":687,"givenName":24,"familyName":24},"a3a24568-365c-4511-a47f-1920021757f8",[],[679],{"id":648,"sortIndex":25,"affiliation":680,"properties":24},{"id":648,"createTime":24,"updateTime":24,"relativeEntities":681,"slug":24,"properties":682,"entityType":24,"verifyStatus":24,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":24,"url":24,"parentIds":684,"statistic":24},[],{"title":683},{"VI":653},[],{"title":686,"openalex":688},{"EN":687},"Sebastian M. 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P., 1988, Kristallografiya, 33, 105",{},{"id":954,"createTime":955,"updateTime":955,"relativeEntities":956,"slug":957,"properties":958,"entityType":107,"verifyStatus":108,"verifyTime":955,"verifyNote":109,"languages":969,"translateLanguages":24,"viewCount":25,"primaryUrl":970,"fullTextUrl":24,"authors":971,"publicationType":131,"publisherRelationship":1034,"citationCount":1079,"citationInfo":1080,"publishDate":1083,"publishYear":1081,"citationAnalyzeStatus":23,"lastCitationAnalyze":24,"indexDatabases":1084,"openAccess":24,"references":1085,"isForceReanalyzing":231},"8cd6e961-ef60-4f79-8618-ec40a6ef1ed9","2025-02-06T11:52:22.176+00:00",[],"Untersuchungen-an-Selen-Sauerstoff-Verbindungen-XLII-Dimethyl-und-Di%C3%A4thylselenoxid-sowie-ihre-Oxoniumsalze-Darstellung-Eigenschaften-und-Schwingungsspektren",{"openalex":959,"mag":961,"abstract":963,"title":965,"doi":967},{"VOID":960},"W1988621189",{"VOID":962},"1988621189",{"EN":964},"\u003Cjats:title>Abstract\u003C\u002Fjats:title>\u003Cjats:p>(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>2\u003C\u002Fjats:sub>SeO und (C\u003Cjats:sub>2\u003C\u002Fjats:sub>H\u003Cjats:sub>5\u003C\u002Fjats:sub>)\u003Cjats:sub>2\u003C\u002Fjats:sub>SeO werden aus R\u003Cjats:sub>2\u003C\u002Fjats:sub>SeBr\u003Cjats:sub>2\u003C\u002Fjats:sub>mit Ag\u003Cjats:sub>2\u003C\u002Fjats:sub>O in CH\u003Cjats:sub>3\u003C\u002Fjats:sub>OH dargestellt. Bei der Oxydation von R\u003Cjats:sub>2\u003C\u002Fjats:sub>Se mit NO\u003Cjats:sub>2\u003C\u002Fjats:sub>erhält man die Addukte R\u003Cjats:sub>2\u003C\u002Fjats:sub>SeO · N\u003Cjats:sub>2\u003C\u002Fjats:sub>O\u003Cjats:sub>4\u003C\u002Fjats:sub>. Das Studium der thermischen Zersetzung der Methylverbindung ergibt (CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>2\u003C\u002Fjats:sub>SeO · N\u003Cjats:sub>2\u003C\u002Fjats:sub>O\u003Cjats:sub>4\u003C\u002Fjats:sub>→ CH\u003Cjats:sub>3\u003C\u002Fjats:sub>SeO · OH + CH\u003Cjats:sub>2\u003C\u002Fjats:sub>O + 2 NO. Nach Molmassebestimmungen, R\u003Cjats:sc>AMAN\u003C\u002Fjats:sc>‐ und IR‐Spektren liegen in wäßriger Lösung keine Dihydroxide R\u003Cjats:sub>2\u003C\u002Fjats:sub>Se(OH)\u003Cjats:sub>2\u003C\u002Fjats:sub>, sondern monomere R\u003Cjats:sub>2\u003C\u002Fjats:sub>SeO‐Molekeln mit H‐brückengebundenen H\u003Cjats:sub>2\u003C\u002Fjats:sub>O‐Molekeln in dem pH‐abhängigen Gleichgewicht R\u003Cjats:sub>2\u003C\u002Fjats:sub>SeO …︁ HOH ⇄ [R\u003Cjats:sub>2\u003C\u002Fjats:sub>SeOH]\u003Cjats:sup>+\u003C\u002Fjats:sup>+ OH\u003Cjats:sup>−\u003C\u002Fjats:sup>vor. Aus äquimolaren Lösungen von (CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>2\u003C\u002Fjats:sub>SeO mit HClO\u003Cjats:sub>4\u003C\u002Fjats:sub>, HNO\u003Cjats:sub>3\u003C\u002Fjats:sub>und HCl Kristallisieren die Verbindungen [(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>2\u003C\u002Fjats:sub>SeOH]ClO\u003Cjats:sub>4\u003C\u002Fjats:sub>, [(CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>2\u003C\u002Fjats:sub>SeOH]NO\u003Cjats:sub>3\u003C\u002Fjats:sub>und\u003Cjats:inline-graphic xmlns:xlink=\"http:\u002F\u002Fwww.w3.org\u002F1999\u002Fxlink\" xlink:href=\"graphic\u002Fnust001.gif\" xlink:title=\"chemical structure image\" \u002F>, deren Strukturen aus R\u003Cjats:sc>AMAN\u003C\u002Fjats:sc>‐ und IR‐Spektren abgeleitet werden. Nach R\u003Cjats:sc>AMAN\u003C\u002Fjats:sc>‐Spektren liegen in den wäßrigen Lösungen der Verbindungen (CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>2\u003C\u002Fjats:sub>SeCl\u003Cjats:sub>2\u003C\u002Fjats:sub>und\u003Cjats:inline-graphic xmlns:xlink=\"http:\u002F\u002Fwww.w3.org\u002F1999\u002Fxlink\" xlink:href=\"graphic\u002Fnust002.gif\" xlink:title=\"chemical structure image\" \u002F>Beim Kristallisieren erfolgt vollständige Verschiebung nach links. Gegenüber Pyridin verhält sich (CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>2\u003C\u002Fjats:sub>SeO als Lewis‐Säure und bildet den Komplex (CH\u003Cjats:sub>3\u003C\u002Fjats:sub>)\u003Cjats:sub>2\u003C\u002Fjats:sub>SeO · 2 Py. 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Chem.(In the Press).",{},{"id":1341,"createTime":1342,"updateTime":1342,"relativeEntities":1343,"slug":1344,"properties":1345,"entityType":107,"verifyStatus":108,"verifyTime":1342,"verifyNote":109,"languages":1355,"translateLanguages":24,"viewCount":25,"primaryUrl":1356,"fullTextUrl":24,"authors":1357,"publicationType":131,"publisherRelationship":1406,"citationCount":1452,"citationInfo":1453,"publishDate":1456,"publishYear":1454,"citationAnalyzeStatus":23,"lastCitationAnalyze":24,"indexDatabases":1457,"openAccess":24,"references":1458,"isForceReanalyzing":231},"0d630857-0e1a-46ce-a52d-af675e5d5352","2025-02-05T06:12:50.982+00:00",[],"The-Crystal-Structures-of-Er-sub-3-sub-OFS-sub-3-sub-and-Er-sub-3-sub-OF-sub-3-sub-S-sub-2-sub-Two-Erbium-Oxide-Fluoride-Sulfides-with-Condensed-Tetrahedral-ZEr-sub-4-sub-Units-Z-O-and-F-",{"openalex":1346,"mag":1348,"abstract":1350,"title":1352,"doi":1354},{"VOID":1347},"W2012215833",{"VOID":1349},"2012215833",{"EN":1351},"\u003Cjats:title>Abstract\u003C\u002Fjats:title>\u003Cjats:p>The two new compounds Er\u003Cjats:sub>3\u003C\u002Fjats:sub>OFS\u003Cjats:sub>3\u003C\u002Fjats:sub> and Er\u003Cjats:sub>3\u003C\u002Fjats:sub>OF\u003Cjats:sub>3\u003C\u002Fjats:sub>S\u003Cjats:sub>2\u003C\u002Fjats:sub> vary mostly in their fluoride and sulfide content. The fluoride‐poor erbium(III) oxide fluoride sulfide Er\u003Cjats:sub>3\u003C\u002Fjats:sub>OFS\u003Cjats:sub>3\u003C\u002Fjats:sub> crystallizes in the tetragonal space group \u003Cjats:italic>I\u003C\u002Fjats:italic>4\u002F\u003Cjats:italic>mmm\u003C\u002Fjats:italic> (\u003Cjats:italic>a\u003C\u002Fjats:italic> = 374.86(2), \u003Cjats:italic>c\u003C\u002Fjats:italic> = 2068.41(9) pm, \u003Cjats:italic>Z\u003C\u002Fjats:italic> = 2) with two crystallographically different Er\u003Cjats:sup>3+\u003C\u002Fjats:sup> cations. (Er1)\u003Cjats:sup>3+\u003C\u002Fjats:sup> is surrounded by six S\u003Cjats:sup>2–\u003C\u002Fjats:sup> anions in the shape of a slightly distorted octahedron, whereas (Er2)\u003Cjats:sup>3+\u003C\u002Fjats:sup> exhibits a coordination number of eight (4 × O\u003Cjats:sup>2–\u003C\u002Fjats:sup>\u002FF\u003Cjats:sup>–\u003C\u002Fjats:sup> and 4 × S\u003Cjats:sup>2–\u003C\u002Fjats:sup> arranged as a square antiprism). In the crystal structure of Er\u003Cjats:sub>3\u003C\u002Fjats:sub>OFS\u003Cjats:sub>3\u003C\u002Fjats:sub> edge‐sharing tetrahedral [ZEr\u003Cjats:sub>4\u003C\u002Fjats:sub>]\u003Cjats:sup>10.5+\u003C\u002Fjats:sup> units (Z\u003Cjats:italic>\u003Cjats:sup>n\u003C\u002Fjats:sup>\u003C\u002Fjats:italic>\u003Cjats:sup>–\u003C\u002Fjats:sup> = 50 % O\u003Cjats:sup>2–\u003C\u002Fjats:sup> + 50 % F\u003Cjats:sup>–\u003C\u002Fjats:sup>) form condensed \u003Cjats:styled-content>{}^2_\\infty\u003C\u002Fjats:styled-content>[OFEr\u003Cjats:sub>2\u003C\u002Fjats:sub>]\u003Cjats:sup>3+\u003C\u002Fjats:sup> layers. These layers alternate with \u003Cjats:styled-content>{}^2_\\infty\u003C\u002Fjats:styled-content>[ErS\u003Cjats:sub>3\u003C\u002Fjats:sub>]\u003Cjats:sup>3–\u003C\u002Fjats:sup> sheets, built up of [ErS\u003Cjats:sub>6\u003C\u002Fjats:sub>]\u003Cjats:sup>9–\u003C\u002Fjats:sup> octahedra, which are connected through four common edges, to complete the three‐dimensional crystal structure of Er\u003Cjats:sub>3\u003C\u002Fjats:sub>OFS\u003Cjats:sub>3\u003C\u002Fjats:sub>. The fluoride‐rich erbium(III) oxide fluoride sulfide Er\u003Cjats:sub>3\u003C\u002Fjats:sub>OF\u003Cjats:sub>3\u003C\u002Fjats:sub>S\u003Cjats:sub>2\u003C\u002Fjats:sub> crystallizes in the orthorhombic space group \u003Cjats:italic>Ccce\u003C\u002Fjats:italic> (\u003Cjats:italic>a\u003C\u002Fjats:italic> = 538.31(2), \u003Cjats:italic>b\u003C\u002Fjats:italic> = 1892.03(9), \u003Cjats:italic>c\u003C\u002Fjats:italic> = 538.27(2) pm, \u003Cjats:italic>Z\u003C\u002Fjats:italic> = 4). Two crystallographically distinct Er\u003Cjats:sup>3+\u003C\u002Fjats:sup> cations are present in its crystal structure. (Er1)\u003Cjats:sup>3+\u003C\u002Fjats:sup> is surrounded by eight Z\u003Cjats:italic>\u003Cjats:sup>n\u003C\u002Fjats:sup>\u003C\u002Fjats:italic>\u003Cjats:sup>–\u003C\u002Fjats:sup> anions (Z = 25 % O\u003Cjats:sup>2–\u003C\u002Fjats:sup> + 75 % F\u003Cjats:sup>–\u003C\u002Fjats:sup>) in the shape of a twisted square antiprism, whereas (Er2)\u003Cjats:sup>3+\u003C\u002Fjats:sup> holds a coordination number of nine (4 × O\u003Cjats:sup>2–\u003C\u002Fjats:sup>\u002FF\u003Cjats:sup>–\u003C\u002Fjats:sup> and 5 × S\u003Cjats:sup>2–\u003C\u002Fjats:sup> arranged as a monocapped square antiprism), copying the arrangement around the Er\u003Cjats:sup>3+\u003C\u002Fjats:sup> cations in PbFCl‐type ErFS. The three‐dimensional structure of Er\u003Cjats:sub>3\u003C\u002Fjats:sub>OF\u003Cjats:sub>3\u003C\u002Fjats:sub>S\u003Cjats:sub>2\u003C\u002Fjats:sub> is built up of S\u003Cjats:sup>2–\u003C\u002Fjats:sup> sheets and \u003Cjats:styled-content>{}^2_\\infty\u003C\u002Fjats:styled-content>[OF\u003Cjats:sub>3\u003C\u002Fjats:sub>Er\u003Cjats:sub>3\u003C\u002Fjats:sub>]\u003Cjats:sup>4+\u003C\u002Fjats:sup> double layers, which are formed by strongly contorted tetrahedral [ZEr\u003Cjats:sub>4\u003C\u002Fjats:sub>]\u003Cjats:sup>10.75+\u003C\u002Fjats:sup> units (Z\u003Cjats:italic>\u003Cjats:sup>n\u003C\u002Fjats:sup>\u003C\u002Fjats:italic>\u003Cjats:sup>–\u003C\u002Fjats:sup> = 25 % O\u003Cjats:sup>2–\u003C\u002Fjats:sup> + 75 % F\u003Cjats:sup>–\u003C\u002Fjats:sup>). The crystals of this compound show a prominent superstructure in the tetragonal space group \u003Cjats:italic>I\u003C\u002Fjats:italic>4\u002F\u003Cjats:italic>mmm\u003C\u002Fjats:italic> with \u003Cjats:italic>a\u003C\u002Fjats:italic> = 380.59(3), \u003Cjats:italic>c\u003C\u002Fjats:italic> = 1892.03(9) pm and \u003Cjats:italic>Z\u003C\u002Fjats:italic> = 2. In the crystal structures of both title compounds, the light anions O\u003Cjats:sup>2–\u003C\u002Fjats:sup> and F\u003Cjats:sup>–\u003C\u002Fjats:sup> occupy one crystallographically unique \u003Cjats:italic>Wyckoff\u003C\u002Fjats:italic> position in a statistic allocation. Subject to the O\u002FF content in the formulae, the ratio of O\u003Cjats:sup>2–\u003C\u002Fjats:sup>:F\u003Cjats:sup>–\u003C\u002Fjats:sup> is 1:1 in Er\u003Cjats:sub>3\u003C\u002Fjats:sub>OFS\u003Cjats:sub>3\u003C\u002Fjats:sub> and 1:3 in Er\u003Cjats:sub>3\u003C\u002Fjats:sub>OF\u003Cjats:sub>3\u003C\u002Fjats:sub>S\u003Cjats:sub>2\u003C\u002Fjats:sub>.\u003C\u002Fjats:p>",{"EN":1353},"The Crystal Structures of Er\u003Csub>3\u003C\u002Fsub>OFS\u003Csub>3\u003C\u002Fsub> and Er\u003Csub>3\u003C\u002Fsub>OF\u003Csub>3\u003C\u002Fsub>S\u003Csub>2\u003C\u002Fsub>: Two Erbium Oxide Fluoride Sulfides with Condensed Tetrahedral [ZEr\u003Csub>4\u003C\u002Fsub>] Units (Z = O and F) ",{"VOID":813},[111],"https:\u002F\u002Fonlinelibrary.wiley.com\u002Fdoi\u002F10.1002\u002Fzaac.200900188",[1358,1373,1390],{"id":1359,"sortIndex":25,"researcher":24,"roles":1360,"affiliations":1361,"properties":1368,"displayName":1370,"givenName":24,"familyName":24},"75878f92-fc37-45f9-825f-03f7d671ee59",[],[1362],{"id":648,"sortIndex":25,"affiliation":1363,"properties":24},{"id":648,"createTime":24,"updateTime":24,"relativeEntities":1364,"slug":24,"properties":1365,"entityType":24,"verifyStatus":24,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":24,"url":24,"parentIds":1367,"statistic":24},[],{"title":1366},{"VI":653},[],{"title":1369,"openalex":1371},{"EN":1370},"Sabine 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Sie sind Additions‐ [Na(Sm\u003Cjats:sub>2\u003C\u002Fjats:sub>)Cl\u003Cjats:sub>6\u003C\u002Fjats:sub>] bzw. Additions‐ \u002F Substitutionsvarianten [Na\u003Cjats:sub>2x\u003C\u002Fjats:sub>(Na\u003Cjats:sub>x\u003C\u002Fjats:sub>M\u003Cjats:sub>2–x\u003C\u002Fjats:sub>)Cl\u003Cjats:sub>6\u003C\u002Fjats:sub>] des UCl\u003Cjats:sub>3\u003C\u002Fjats:sub>‐Strukturtyps [□(U\u003Cjats:sub>2\u003C\u002Fjats:sub>)Cl\u003Cjats:sub>6\u003C\u002Fjats:sub>]. Röntgenabsorptionsspektren (XANES) an der L\u003Cjats:sub>m\u003C\u002Fjats:sub>‐Kante charakterisieren NaSm\u003Cjats:sub>2\u003C\u002Fjats:sub>Cl\u003Cjats:sub>6\u003C\u002Fjats:sub> und NaNd\u003Cjats:sub>2\u003C\u002Fjats:sub>Cl\u003Cjats:sub>6\u003C\u002Fjats:sub> als gemischtvalente Verbindungen mit Valenzen von +2 und +3 in statistischer Verteilung (etwa 1:1) für Sm bzw. Nd.\u003C\u002Fjats:p>",{"EN":1593},"Die Chloride Na\u003Csub>3x\u003C\u002Fsub>M\u003Csub>2–x\u003C\u002Fsub>Cl\u003Csub>6\u003C\u002Fsub> (M = LaSm) und NaM\u003Csub>2\u003C\u002Fsub>Cl\u003Csub>6\u003C\u002Fsub> (M = Nd, Sm): Derivate des UCl\u003Csub>3\u003C\u002Fsub>‐Typs. 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F., 1987, Handbook on the Physics and Chemistry of Rare Earths",{},{"id":24,"text":1877,"url":24,"identifiers":1878},"Z.Hu G.Kaindl K.Krämer H.Mattfeld G.Meyer in Vorbereitung",{},{"id":1880,"createTime":1881,"updateTime":1881,"relativeEntities":1882,"slug":1883,"properties":1884,"entityType":107,"verifyStatus":108,"verifyTime":1881,"verifyNote":109,"languages":1894,"translateLanguages":24,"viewCount":25,"primaryUrl":1895,"fullTextUrl":24,"authors":1896,"publicationType":131,"publisherRelationship":1913,"citationCount":1745,"citationInfo":1959,"publishDate":1962,"publishYear":1960,"citationAnalyzeStatus":23,"lastCitationAnalyze":24,"indexDatabases":1963,"openAccess":24,"references":1964,"isForceReanalyzing":231},"14eed770-ba60-4e94-a287-122b1ea42420","2025-02-05T06:12:43.689+00:00",[],"Zwei-Formen-von-Dy-sub-2-sub-OS-sub-2-sub-",{"openalex":1885,"mag":1887,"abstract":1889,"title":1891,"doi":1893},{"VOID":1886},"W1994182254",{"VOID":1888},"1994182254",{"EN":1890},"\u003Cjats:title>Abstract\u003C\u002Fjats:title>\u003Cjats:p>Die Oxidation von DyCl\u003Cjats:sub>2\u003C\u002Fjats:sub> mit Schwefel in Gegenwart von NaCl (Tantal‐Kapsel, 800°C, 7 d) liefert Einkristalle von Dy\u003Cjats:sub>2\u003C\u002Fjats:sub>S\u003Cjats:sub>3\u003C\u002Fjats:sub> im U\u003Cjats:sub>2\u003C\u002Fjats:sub>S\u003Cjats:sub>3\u003C\u002Fjats:sub>‐Typ als Hauptprodukt. Oxidische Verunreinigungen (z. B. DyOCl) werden dabei zu Dy\u003Cjats:sub>2\u003C\u002Fjats:sub>OS\u003Cjats:sub>2\u003C\u002Fjats:sub> umgesetzt, das in zwei verschiedenen einkristallinen Formen anfällt: fast farblose Nadeln (I: orthorhombisch, Pnma (Nr. 62), a = 1542,71(9); b = 380,07(2); c = 674,49(3) pm; V\u003Cjats:sub>m\u003C\u002Fjats:sub> = 59,540(6) cm\u003Cjats:sup>3\u003C\u002Fjats:sup>\u002Fmol, Z = 4; R = 0,023; R\u003Cjats:sub>w\u003C\u002Fjats:sub> = 0,021) und blaß;gelbe, flächenreiche Prismen (II: monoklin, P2\u003Cjats:sub>1\u003C\u002Fjats:sub>\u002Fc (Nr. 14), a = 825,09(6); b = 691,06(5); c = 686,25(5) pm; β = 99,612(7)°; V\u003Cjats:sub>m\u003C\u002Fjats:sub> = 58,082(7) cm\u003Cjats:sup>3\u003C\u002Fjats:sup>\u002Fmol, Z = 4; R = 0,026; R\u003Cjats:sub>w\u003C\u002Fjats:sub> = 0,025). Entsprechend der um 2,5% kleineren Dichte (D\u003Cjats:sub>x\u003C\u002Fjats:sub> = 6,80 für I gegenüber 6,97 g\u002Fcm\u003Cjats:sup>3\u003C\u002Fjats:sup> für II) soll hier die orthorhombische Form von Dy\u003Cjats:sub>2\u003C\u002Fjats:sub>OS\u003Cjats:sub>2\u003C\u002Fjats:sub> als „Normaldruck”︁‐Form (I) bezeichnet werden. Beide Strukturen von Dy\u003Cjats:sub>2\u003C\u002Fjats:sub>OS\u003Cjats:sub>2\u003C\u002Fjats:sub> werden von O\u003Cjats:sup>2−\u003C\u002Fjats:sup>‐zentrierten Tetraedern [O(Dy)\u003Cjats:sub>4\u003C\u002Fjats:sub>]\u003Cjats:sup>10+\u003C\u002Fjats:sup> aufgebaut, die in I über zwei cis‐ständige Kanten zu Zick‐Zack‐Ketten der Zusammensetzung \u003Cjats:inline-graphic xmlns:xlink=\"http:\u002F\u002Fwww.w3.org\u002F1999\u002Fxlink\" xlink:href=\"graphic\u002Ftex2gif-stack-1.gif\" xlink:title=\"urn:x-wiley:00442313:media:ZAAC19916020105:tex2gif-stack-1\" \u002F>[O(Dy1)\u003Cjats:sub>3\u002F3\u003C\u002Fjats:sub>(Dy2)\u003Cjats:sub>1\u002F1\u003C\u002Fjats:sub>]\u003Cjats:sup>4+\u003C\u002Fjats:sup>, in II über eine Kante und zwei Ecken zu gewellten Schichten der Zusammensetzung \u003Cjats:inline-graphic xmlns:xlink=\"http:\u002F\u002Fwww.w3.org\u002F1999\u002Fxlink\" xlink:href=\"graphic\u002Ftex2gif-stack-2.gif\" xlink:title=\"urn:x-wiley:00442313:media:ZAAC19916020105:tex2gif-stack-2\" \u002F>[O(Dy1)\u003Cjats:sub>3\u002F3\u003C\u002Fjats:sub>(Dy2)\u003Cjats:sub>1\u002F1\u003C\u002Fjats:sub>]\u003Cjats:sup>4+\u003C\u002Fjats:sup>, verknüpft sind. Ladungsausgleich und dreidimensionale Vernetzung erfolgt in beiden Fällen über je zwei kristallographisch unterschiedliche S\u003Cjats:sup>2−\u003C\u002Fjats:sup>, die tetragonal‐pyramidal (C.N. = 5) von Dy\u003Cjats:sup>3+\u003C\u002Fjats:sup> umgeben sind. Dy\u003Cjats:sub>2\u003C\u002Fjats:sub>OS\u003Cjats:sub>2\u003C\u002Fjats:sub>—I enthält Dy1 in achtfacher (3O und 5S, doppelt bekapptes trigonales Prisma) und Dy2 in sechsfacher anionischer Koordination (1O und 5S, „Oktaeder”︁). In Form II sind beide Dy\u003Cjats:sup>3+\u003C\u002Fjats:sup> von jeweils sieben Anionen (Dy1: 3O und 4S, Dy2: 1O und 6S) einfach‐bekappt trigonal‐prismatisch umgeben.\u003C\u002Fjats:p>",{"EN":1892},"Zwei Formen von Dy\u003Csub>2\u003C\u002Fsub>OS\u003Csub>2\u003C\u002Fsub>",{"VOID":1475},[111],"https:\u002F\u002Fonlinelibrary.wiley.com\u002Fdoi\u002F10.1002\u002Fzaac.19916020105",[1897],{"id":1898,"sortIndex":25,"researcher":24,"roles":1899,"affiliations":1900,"properties":1909,"displayName":727,"givenName":24,"familyName":24},"65412355-f6ed-4fad-beb2-0c1096910590",[],[1901],{"id":1902,"sortIndex":25,"affiliation":1903,"properties":24},"be41f33f-08c2-45a7-a524-0475cdfa5872",{"id":1902,"createTime":24,"updateTime":24,"relativeEntities":1904,"slug":24,"properties":1905,"entityType":24,"verifyStatus":24,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":24,"url":24,"parentIds":1908,"statistic":24},[],{"title":1906},{"EN":1907},"Inst. f. Anorg. Chemie d. Univ., Callinstr.9, W‐3000 Hannover 1, Bundesrepublik Deutschland",[],{"orcid":1910,"title":1911,"openalex":1912},{"VOID":725},{"EN":727},{"VOID":729},{"url":24,"publisher":1914,"properties":1952},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":1915,"slug":10,"properties":1916,"entityType":22,"verifyStatus":23,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":25,"subjectFields":1921,"manageAffiliations":1926,"indexDatabases":1937,"url":83,"thumbnailPath":24,"statistic":24,"gsStatistic":24,"type":24,"analyzePriority":24},[],{"country":1917,"eissn":1918,"issn":1919,"title":1920},{"VOID":13},{"VOID":15},{"VOID":17},{"EN":19},[1922],{"id":28,"createTime":24,"updateTime":24,"relativeEntities":1923,"label":1924,"description":1925,"parentId":24,"standard":24,"scholarHubFieldId":24},[],{"EN":31},{},[1927,1932],{"id":35,"createTime":24,"updateTime":24,"relativeEntities":1928,"slug":24,"properties":1929,"entityType":24,"verifyStatus":24,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":24,"url":24,"parentIds":1931,"statistic":24},[],{"title":1930},{"EN":39},[],{"id":42,"createTime":24,"updateTime":24,"relativeEntities":1933,"slug":24,"properties":1934,"entityType":24,"verifyStatus":24,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":24,"url":24,"parentIds":1936,"statistic":24},[],{"title":1935},{"EN":46},[],[1938,1945],{"id":50,"indexDatabase":1939,"url":61,"indexYears":62,"academicFieldIds":1944,"indexDatabaseRanking":65},{"id":52,"createTime":24,"updateTime":24,"relativeEntities":1940,"label":1941,"description":1942,"key":58,"publicationTags":1943,"standard":24},[],{"EN":55,"VI":55},{"EN":55,"VI":57},[60],[64],{"id":67,"indexDatabase":1946,"url":80,"indexYears":24,"academicFieldIds":1951,"indexDatabaseRanking":24},{"id":69,"createTime":24,"updateTime":24,"relativeEntities":1947,"label":1948,"description":1949,"key":76,"publicationTags":1950,"standard":24},[],{"EN":72,"VI":72},{"EN":74,"VI":75},[78,79],[82],{"issue":1953,"pages":1955,"volume":1957},{"VOID":1954},"1",{"VOID":1956},"39-47",{"VOID":1958},"602",{"total":1745,"publishYear":1960,"statisticByYear":1961},1991,{"2013":185,"2016":183,"2017":182,"2019":183,"2020":182,"2021":183,"2022":183,"2024":183},"1991-09-01",[65,78],[1965,1968,1971,1974,1977,1980,1983,1986,1989,1992,1995,1998,2001,2004,2007,2010,2013,2016,2018,2020,2022,2024,2027,2030,2033,2037,2040,2043,2045,2048,2051,2054,2056,2059,2062,2064,2066,2069,2072,2074,2077,2080,2083],{"id":24,"text":1966,"url":24,"identifiers":1967},"Besançon P., 1971, C. R. Acad. Sci,, 273, 1348",{},{"id":24,"text":1969,"url":24,"identifiers":1970},"10.1016\u002F0022-4596(73)90159-X",{"doi":1969},{"id":24,"text":1972,"url":24,"identifiers":1973},"Schleid Th.;Lissner F.:J. Less‐Common Met.(1991).",{},{"id":24,"text":1975,"url":24,"identifiers":1976},"10.1107\u002FS0567740873003869",{"doi":1975},{"id":24,"text":1978,"url":24,"identifiers":1979},"10.1063\u002F1.329083",{"doi":1978},{"id":24,"text":1981,"url":24,"identifiers":1982},"Khodadad P., 1965, C. R. Acad. Sci., 260, 2235",{},{"id":24,"text":1984,"url":24,"identifiers":1985},"Ostoréro J., 1990, Acta Crystallogr., 1376",{},{"id":24,"text":1987,"url":24,"identifiers":1988},"10.1016\u002F0025-5408(67)90068-2",{"doi":1987},{"id":24,"text":1990,"url":24,"identifiers":1991},"10.1007\u002FBF00364913",{"doi":1990},{"id":24,"text":1993,"url":24,"identifiers":1994},"10.1107\u002FS0365110X48000703",{"doi":1993},{"id":24,"text":1996,"url":24,"identifiers":1997},"10.1107\u002FS0365110X49000138",{"doi":1996},{"id":24,"text":1999,"url":24,"identifiers":2000},"Flahaut J., Bull. Soc. Chim. Fr., 1958, 990",{},{"id":24,"text":2002,"url":24,"identifiers":2003},"10.1107\u002FS0567740873007284",{"doi":2002},{"id":24,"text":2005,"url":24,"identifiers":2006},"10.1016\u002F0022-3697(68)90236-9",{"doi":2005},{"id":24,"text":2008,"url":24,"identifiers":2009},"10.1016\u002F0022-4596(76)90174-2",{"doi":2008},{"id":24,"text":2011,"url":24,"identifiers":2012},"10.1016\u002F0022-5088(90)90440-U",{"doi":2011},{"id":24,"text":2014,"url":24,"identifiers":2015},"Schleid Th., 1991, Eur. J. Solid State Inorg. 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Naturforsch., 889, 10.1515\u002Fznb-1975-11-1212",{"doi":2036},"10.1515\u002Fznb-1975-11-1212",{"id":24,"text":2038,"url":24,"identifiers":2039},"10.1002\u002Fzaac.19905900112",{"doi":2038},{"id":24,"text":2041,"url":24,"identifiers":2042},"10.1002\u002Fzaac.19875541104",{"doi":2041},{"id":24,"text":1853,"url":24,"identifiers":2044},{"doi":1853},{"id":24,"text":2046,"url":24,"identifiers":2047},"Flahaut J., 1972, Intern. Rev. Sci. Inorg. Chem., Ser. One, 10, 189",{},{"id":24,"text":2049,"url":24,"identifiers":2050},"10.1016\u002F0022-4596(73)90141-2",{"doi":2049},{"id":24,"text":2052,"url":24,"identifiers":2053},"Soose J.;Meyer G.:SOS: Programm zur Auswertung von Guinier‐Aufnahmen Gießen (1980).",{},{"id":24,"text":1832,"url":24,"identifiers":2055},{"doi":1832},{"id":24,"text":2057,"url":24,"identifiers":2058},"Karcher B.: Ph. D. Thesis Iowa State University Ames (Iowa) U.S.A. (1982).",{},{"id":24,"text":2060,"url":24,"identifiers":2061},"Sheldrick G. M.:SHELX‐76: Programm zur Kristallstrukturbestimmung aus Diffraktometerdaten Cambridge U.K. (1976).",{},{"id":24,"text":1826,"url":24,"identifiers":2063},{"doi":1826},{"id":24,"text":1829,"url":24,"identifiers":2065},{"doi":1829},{"id":24,"text":2067,"url":24,"identifiers":2068},"Flahaut J., 1957, C. R. Acad. Sci., 245, 2291",{},{"id":24,"text":2070,"url":24,"identifiers":2071},"10.1016\u002F0038-1098(74)90285-3",{"doi":2070},{"id":24,"text":1572,"url":24,"identifiers":2073},{},{"id":24,"text":2075,"url":24,"identifiers":2076},"10.1002\u002Fange.19700820103",{"doi":2075},{"id":24,"text":2078,"url":24,"identifiers":2079},"Hoppe R., 1973, Izvj. Jugoslav. Centr. Krist. Zagreb, 8, 21",{},{"id":24,"text":2081,"url":24,"identifiers":2082},"10.6028\u002Fjres.064A.030",{"doi":2081},{"id":24,"text":2084,"url":24,"identifiers":2085},"10.1107\u002FS0567740869005255",{"doi":2084},{"id":2087,"createTime":2088,"updateTime":2088,"relativeEntities":2089,"slug":2090,"properties":2091,"entityType":107,"verifyStatus":108,"verifyTime":2101,"verifyNote":109,"languages":2102,"translateLanguages":24,"viewCount":25,"primaryUrl":2103,"fullTextUrl":24,"authors":2104,"publicationType":131,"publisherRelationship":2207,"citationCount":2253,"citationInfo":2254,"publishDate":2257,"publishYear":2255,"citationAnalyzeStatus":23,"lastCitationAnalyze":24,"indexDatabases":2258,"openAccess":24,"references":2259,"isForceReanalyzing":231},"4acb0eb1-20a2-47d8-9e54-c10de2136681","2025-02-05T06:12:43.404+00:00",[],"Two-Hexagonal-Series-of-Lanthanoid-III-Oxide-Fluoride-Selenides-i-M-i-sub-6-sub-O-sub-2-sub-F-sub-8-sub-Se-sub-3-sub-i-M-i-La-Nd-and-i-M-i-sub-2-sub-OF-sub-2-sub-Se-i-M-i-Nd-Sm-Gd-Ho-",{"openalex":2092,"mag":2094,"abstract":2096,"title":2098,"doi":2100},{"VOID":2093},"W1549329667",{"VOID":2095},"1549329667",{"EN":2097},"\u003Cjats:title>Abstract\u003C\u002Fjats:title>\u003Cjats:p> Two hexagonal series of lanthanoid(III) oxide fluoride selenides with similar structure types can be obtained by the reaction of the components \u003Cjats:italic>M\u003C\u002Fjats:italic>F\u003Cjats:sub>3\u003C\u002Fjats:sub>, \u003Cjats:italic>M\u003C\u002Fjats:italic>\u003Cjats:sub>2\u003C\u002Fjats:sub>O\u003Cjats:sub>3\u003C\u002Fjats:sub>, \u003Cjats:italic>M\u003C\u002Fjats:italic>, and Se in sealed niobium tubes at 850 °C using CsI as fluxing agent. The compounds with the lighter and larger representatives (\u003Cjats:italic>M\u003C\u002Fjats:italic> = La – Nd) occur with the formula \u003Cjats:italic>M\u003C\u002Fjats:italic>\u003Cjats:sub>6\u003C\u002Fjats:sub>O\u003Cjats:sub>2\u003C\u002Fjats:sub>F\u003Cjats:sub>8\u003C\u002Fjats:sub>Se\u003Cjats:sub>3\u003C\u002Fjats:sub>, whereas with the heavier and smaller ones (\u003Cjats:italic>M\u003C\u002Fjats:italic> = Nd, Sm, Gd – Ho) their composition is \u003Cjats:italic>M\u003C\u002Fjats:italic>\u003Cjats:sub>2\u003C\u002Fjats:sub>OF\u003Cjats:sub>2\u003C\u002Fjats:sub>Se. For both systems single‐crystal determinations were used in all cases. The compounds crystallize in the hexagonal crystal system (space group: \u003Cjats:italic>P\u003C\u002Fjats:italic>6\u003Cjats:sub>3\u003C\u002Fjats:sub>\u002F\u003Cjats:italic>m\u003C\u002Fjats:italic>) with lattice parameters of \u003Cjats:italic>a\u003C\u002Fjats:italic> = 1394–1331 pm and \u003Cjats:italic>c\u003C\u002Fjats:italic> = 403–372 pm (\u003Cjats:italic>Z\u003C\u002Fjats:italic> = 2 for \u003Cjats:italic>M\u003C\u002Fjats:italic>\u003Cjats:sub>6\u003C\u002Fjats:sub>O\u003Cjats:sub>2\u003C\u002Fjats:sub>F\u003Cjats:sub>8\u003C\u002Fjats:sub>Se\u003Cjats:sub>3\u003C\u002Fjats:sub> and \u003Cjats:italic>Z\u003C\u002Fjats:italic> = 6 for \u003Cjats:italic>M\u003C\u002Fjats:italic>\u003Cjats:sub>2\u003C\u002Fjats:sub>OF\u003Cjats:sub>2\u003C\u002Fjats:sub>Se). The (\u003Cjats:italic>M\u003C\u002Fjats:italic>1)\u003Cjats:sup>3+\u003C\u002Fjats:sup> cations show different square antiprismatic coordination spheres with or without an extra capping fluoride anion. All (\u003Cjats:italic>M\u003C\u002Fjats:italic>2)\u003Cjats:sup>3+\u003C\u002Fjats:sup> cations exhibit a ninefold coordination environment shaped as tricapped trigonal prism. In both structure types the Se\u003Cjats:sup>2–\u003C\u002Fjats:sup> anions are sixfold coordinated as trigonal prisms of \u003Cjats:italic>M\u003C\u002Fjats:italic>\u003Cjats:sup>3+\u003C\u002Fjats:sup> cations, being first condensed by edges to generate trimeric units and then via faces to form strands running along [001]. The light anions reside either in threefold triangular or in fourfold tetrahedral cationic coordination. For charge compensation, both structures have to contain a certain amount of oxide besides fluoride anions. Since F\u003Cjats:sup>–\u003C\u002Fjats:sup> and O\u003Cjats:sup>2–\u003C\u002Fjats:sup> can not be distinguished by X‐ray diffraction, bond‐valence calculations were used to address the problem of their adjunction to the available crystallographic sites.\u003C\u002Fjats:p>",{"EN":2099},"Two Hexagonal Series of Lanthanoid(III) Oxide Fluoride Selenides: \u003Ci>M\u003C\u002Fi>\u003Csub>6\u003C\u002Fsub>O\u003Csub>2\u003C\u002Fsub>F\u003Csub>8\u003C\u002Fsub>Se\u003Csub>3\u003C\u002Fsub> (\u003Ci>M\u003C\u002Fi> = La – Nd) and \u003Ci>M\u003C\u002Fi>\u003Csub>2\u003C\u002Fsub>OF\u003Csub>2\u003C\u002Fsub>Se (\u003Ci>M\u003C\u002Fi> = Nd, Sm, Gd – Ho)",{"VOID":828},"2025-02-05T06:12:43.403+00:00",[111],"https:\u002F\u002Fonlinelibrary.wiley.com\u002Fdoi\u002F10.1002\u002Fzaac.201500253",[2105,2120,2133,2146,2171,2193],{"id":2106,"sortIndex":25,"researcher":24,"roles":2107,"affiliations":2108,"properties":2115,"displayName":2117,"givenName":24,"familyName":24},"ef1051d8-b72b-4fab-bc2e-db7465136a62",[],[2109],{"id":648,"sortIndex":25,"affiliation":2110,"properties":24},{"id":648,"createTime":24,"updateTime":24,"relativeEntities":2111,"slug":24,"properties":2112,"entityType":24,"verifyStatus":24,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":24,"url":24,"parentIds":2114,"statistic":24},[],{"title":2113},{"VI":653},[],{"title":2116,"openalex":2118},{"EN":2117},"Dirk D. 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