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J Ind Microbiol Biotechnol. 2010, 37: 495-501.\nKhanna S, Goyal A, Moholkar VS: Production of n -butanol from biodiesel derived crude glycerol using Clostridium pasteurianum immobilized on Amberlite. Fuel. 2013, 112: 557-561.\nGottumukkala LD, Parameswaran B, Valappil SK, Mathiyazhakan K: Biobutanol production from rice straw by a non acetone producing Clostridium sporogenes BE01. Bioresour Technol. 2013, 145: 182-187.\nChen WH, Chen YC, Lin JG: Evaluation of biobutanol production from non-pretreated rice straw hydrolysate under non-sterile environmental conditions. Bioresour Technol. 2013, 135: 262-268.\nNapoli F, Olivieri G, Russo ME, Marzocchella A, Salatino P: Butanol production by Clostridium acetobutylicum in a continuous packed bed reactor. J Ind Microbiol Biotechnol. 2010, 37: 603-608.\nLépiz-Aguilar L, Rodríguez-Rodríguez CE, Arias ML, Lutz G, Ulate W: Butanol production by Clostridium beijerinckii BA101 using cassava flour as fermentation substrate: enzymatic versus chemical pretreatments. World J Microbiol Biotechnol. 2011, 27: 1933-1939.\nQureshi N, Saha BC, Dien B, Hector RE, Cotta MA: Production of butanol (a biofuel) from agricultural residues: Part I – Use of barley straw hydrolysate. Biomass Bioenerg. 2010, 34: 559-565.\nQureshi N, Saha BC, Hector RE, Dien B, Hughes S, Liu S, Iten L, Bowman MJ, Sarath G, Cotta MA: Production of butanol (a biofuel) from agricultural residues: Part II – Use of corn stover and switchgrass hydrolysates. Biomass Bioenerg. 2010, 34: 566-571.\nLu C, Zhao J, Yang ST, Wei D: Fed-batch fermentation for n-butanol production from cassava bagasse hydrolysate in a fibrous bed bioreactor with continuous gas stripping. Bioresour Technol. 2012, 104: 380-387.\nNoomtim P, Cheirsilp B: Production of Butanol from Palm Empty Fruit Bunches Hydrolyzate by Clostridium acetobutylicum. Energy Procedia. 2011, 9: 140-146.\nEzeji TC, Qureshi N, Blaschek HP: Production of acetone butanol (AB) from liquefied corn starch, a commercial substrate, using Clostridium beijerinckii coupled with product recovery by gas stripping. J Ind Microbiol Biotechnol. 2007, 34: 771-777.\nAbd-Alla MH, El-Enany AWE: Production of acetone-butanol-ethanol from spoilage date palm (Phoenix dactyliferaL.) fruits by mixed culture of Clostridium acetobutylicum and Bacillus subtilis. Biomass Bioenerg. 2012, 42: 172-178.\nWang Y, Blaschek HP: Optimization of butanol production from tropical maize stalk juice by fermentation with Clostridium beijerinckii NCIMB 8052. Bioresour Technol. 2011, 102: 9985-9990.\nSun Z, Liu S: Production of n-butanol from concentrated sugar maple hemicellulosic hydrolysate by Clostridia acetobutylicum ATCC824. Biomass Bioenerg. 2012, 39: 39-47.\nAl-Shorgani NKN, Kalil MS, Yusoff WMW: Biobutanol production from rice bran and de-oiled rice bran by Clostridium saccharoperbutylacetonicum N1-4. Bioprocess Biosyst Eng. 2012, 35: 817-826.\nGuo T, Sun B, Jiang M, Wu H, Du T, Tang Y, Wei P, Ouyang P: Enhancement of butanol production and reducing power using a two-stage controlled-pH strategy in batch culture of Clostridium acetobutylicum XY16. World J Microbiol Biotechnol. 2012, 28: 2551-2558.\nRanjan A, Khanna S, Moholkar VS: Feasibility of rice straw as alternate substrate for biobutanol production. Appl Energ. 2013, 103: 32-38.\nRanjan A, Moholkar VS: Comparative study of various pretreatment techniques for rice straw saccharification for the production of alcoholic biofuels. Fuel. 2011, 112: 567-571.\nZhang WL, Liu ZY, Liu Z, Li FL: Butanol production from corncob residue using Clostridium beijerinckii NCIMB 8052. 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Bioresour Technol. 2011, 102: 4304-4312.\nLee J, Seo E, Kweon DH, Park K, Jin YS: Fermentation of rice bran and defatted rice bran for butanol production using Clostridium beijerinckii NCIMB 8052. J Microbiol Biotechnol. 2009, 19: 482-490.\nKumar P, Barrett DM, Delwiche MJ, Stroeve P: Methods for pretreatment of lignocellulosic biomass for efficient hydrolysis and biofuel production. Ind Eng Chem Res. 2009, 48: 3713-3729.\nOoi BG, Rambo AL, Hurtado MA: Overcoming the Recalcitrance for the Conversion of Kenaf Pulp to Glucose via Microwave-Assisted Pre-Treatment Processes. Int J Mol Sci. 2011, 12: 1451-1463.\nThirmal C, Dahman Y: Comparisons of existing pretreatment, saccharification, and fermentation processes for butanol production from agricultural residues. Can J Chem Eng. 2012, 90: 745-761.\nQureshi N, Saha BC, Hector RE, Cotta MA: Removal of fermentation inhibitors from alkaline peroxide pretreated and enzymatically hydrolyzed wheat straw: production of butanol from hydrolysate using Clostridium beijerinckiiin batch reactors. Biomass Bioenerg. 2008, 32: 1353-1358.\nParekh M, Formanek J, Blaschek HP: Pilot-scale production of butanol by Clostridium beijerinckii BA101 using a low-cost fermentation medium based on corn steep water. Appl Microbiol Biotechnol. 1999, 51: 152-157.\nZheng YN, Li LZ, Xian M, Ma YJ, Yang JM, Xu X, He DZ: Problems with the microbial production of butanol. J Ind Microbiol Biotechnol. 2009, 36: 1127-1138.\nMariano AP, Costa CBB, Angelis DF, Maugeri Filho F, Atala DIP, Maciel MRW, Maciel FR: Dynamics of a continuous flash fermentation for butanol production. Chem Eng Trans. 2010, 20: 285-290.\nSecuianu C, Feroiu V, Geana D: High-Pressure Vapor -Liquid Equilibria in the System Carbon Dioxide + 1-Butanol at Temperatures from (293.15 to 324.15) K. J Chem Eng Data. 2004, 49: 1635-1638.\nDhamole PB, Wang Z, Liu Y, Wang B, Feng H: Extractive fermentation with non-ionic surfactants to enhance butanol production. Biomass Bioenerg. 2012, 40: 112-119.\nNakayama S, Morita T, Negishi H, Ikegami T, Sakaki K, Kitamoto D: Candida krusei produces ethanol without production of succinic acid; a potential advantage for ethanol recovery by pervaporation membrane separation. FEMS Yeast Res. 2008, 8: 706-714.\nYen HW, Chen ZH, Yang IK: Use of the composite membrane of poly (ether-block-amide) and carbon nanotubes (CNTs) in a pervaporation system incorporated with fermentation for butanol production by Clostridium acetobutylicum. Bioresour Technol. 2012, 109: 105-109.\nEzeji TC, Qureshi N, Blaschek HP: Bioproduction of butanol from biomass: from genes to bioreactors. Curr Opin Biotechnol. 2007, 18: 220-227.\nTanaka S, Tashiro Y, Kobayashi G, Ikegami T, Negishi H, Sakaki K: Membrane-assisted extractive butanol fermentation by Clostridium saccharoperbutylacetonicum N1-4 with 1-dodecanol as the extractant. Bioresour Technol. 2012, 116: 448-452.\nMariano AP, Costa CBB, Angelis DF, Maugeri Filho F, Atala DIP, Maciel MRW, Maciel FR: Optimisation of a continuous flash fermentation for butanol production using the response surface methodology. Chem Eng Res Des. 2009, 88: 562-571.\nMariano AP, Costa CBB, Angelis DF, Maugeri Filho F, Atala DIP, Maciel MRW, Maciel FR: Optimisation of a fermentation process for butanol production by particle swarm optimisation (PSO). J Chem Technol Biotechnol. 2010, 85: 934-949.",{"EN":49},"Recent studies have shown that butanol is a potential gasoline replacement that can also be blended in significant quantities with conventional diesel fuel. However, biotechnological production of butanol has some challenges such as low butanol titer, high cost feedstocks and product inhibition. The present work reviewed the technical and economic feasibility of the main technologies available to produce biobutanol. The latest studies integrating continuous fermentation processes with efficient product recovery and the use of mathematical models as tools for process scale-up, optimization and control are presented.",{"EN":51},"Recent advances on biobutanol production",{"VOID":53},"10.1186\u002F2043-7129-2-15","PUBLICATION","Author affiliation is blank","https:\u002F\u002Fsustainablechemicalprocesses.springeropen.com\u002Farticles\u002F10.1186\u002F2043-7129-2-15",[58,76,83,96,109],{"id":59,"sortIndex":60,"researcher":20,"roles":61,"affiliations":63,"properties":73},"cf91f274-240b-40b3-92ad-8e87d1808d2a",1,[62],"AUTHOR",[64],{"id":20,"sortIndex":21,"affiliation":65,"properties":20},{"id":66,"createTime":67,"updateTime":67,"relativeEntities":68,"slug":20,"properties":69,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"19e8aed6-e2e0-4686-8405-97ca89912c46","2024-01-16T20:56:49.805+00:00",[],{"title":70},{"VI":71},"Department of Chemical Engineering, Federal University of Santa Maria, Santa Maria, Brazil","AFFILIATION",{"title":74},{"VI":75},"Heveline Enzweiler",{"id":77,"sortIndex":21,"researcher":20,"roles":78,"affiliations":79,"properties":80},"30154b84-af62-44a9-b567-d28d592d91dc",[62],[],{"title":81},{"VI":82},"Luiz J Visioli",{"id":84,"sortIndex":85,"researcher":20,"roles":86,"affiliations":87,"properties":93},"ac249f2e-a958-4779-bcee-f79f57c5ea85",3,[62],[88],{"id":20,"sortIndex":21,"affiliation":89,"properties":20},{"id":66,"createTime":67,"updateTime":67,"relativeEntities":90,"slug":20,"properties":91,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":92},{"VI":71},{"title":94},{"VI":95},"Marcio Schwaab",{"id":97,"sortIndex":98,"researcher":20,"roles":99,"affiliations":100,"properties":106},"8bb64f2b-ca92-4043-aad9-7a0d197ace5a",4,[62],[101],{"id":20,"sortIndex":21,"affiliation":102,"properties":20},{"id":66,"createTime":67,"updateTime":67,"relativeEntities":103,"slug":20,"properties":104,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":105},{"VI":71},{"title":107},{"VI":108},"Marcio A Mazutti",{"id":110,"sortIndex":111,"researcher":20,"roles":112,"affiliations":113,"properties":119},"c867b9ac-84be-47a1-96c8-5949a47a7af4",2,[62],[114],{"id":20,"sortIndex":21,"affiliation":115,"properties":20},{"id":66,"createTime":67,"updateTime":67,"relativeEntities":116,"slug":20,"properties":117,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":118},{"VI":71},{"title":120},{"VI":121},"Raquel C Kuhn","ARTICLE",{"url":56,"publisher":124,"properties":138},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":125,"slug":10,"properties":126,"entityType":18,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"subjectFields":130,"manageAffiliations":131,"indexDatabases":132,"url":20,"thumbnailPath":20,"statistic":133,"gsStatistic":20,"type":34,"analyzePriority":20},[],{"issn":127,"title":128,"url":129},{"VOID":13},{"EN":15},{"VOID":17},[],[],[],{"impactFactor":21,"impactFactorByYear":134,"i10Index":21,"i10IndexLast5Year":21,"totalPublication":27,"totalPublicationByYear":135,"totalCitation":21,"totalCitationByYear":136,"totalCitationPerPublication":21,"totalCitationPerPublicationByYear":137,"hindexLast5Year":21,"hindex":21},{},{"2013":29,"2014":29,"2015":30,"2016":31},{},{},{"volume":139,"pages":141},{"VOID":140},"2",{"VOID":142},"1-9","2014-06-19",2014,false,{"id":147,"createTime":148,"updateTime":148,"relativeEntities":149,"slug":20,"properties":150,"entityType":54,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"primaryUrl":159,"fullTextUrl":20,"authors":160,"publicationType":122,"publisherRelationship":246,"citationCount":20,"citationInfo":20,"publishDate":265,"publishYear":144,"citationAnalyzeStatus":19,"lastCitationAnalyze":20,"indexDatabases":20,"openAccess":20,"references":20,"isForceReanalyzing":145},"f6aa43c4-4416-41fc-bf67-c42178559171","2023-12-05T23:20:54.541+00:00",[],{"references":151,"abstract":153,"title":155,"doi":157},{"VOID":152},"Clark JH: Green chemistry: challenges and opportunities. 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Chem Rev. 1996, 96: 2035-2052. 10.1021\u002Fcr950083f.\nLi F, Cui JN, Qian XH, Zhang R, Xiao Y: Highly chemoselective reduction of aromatic nitro compounds to the corresponding hydroxylamines catalysed by plant cells from a grape. Chem Commun. 2005, 43: 1901-1903.\nHe DP, Shi H, Wu Y, Xu BX: Synthesis of chloroanilines: selective hydrogenation of the nitro in chloronitrobenzenes over zirconia-supported gold catalyst. Green Chem. 2007, 9: 849-951. 10.1039\u002Fb618367k.\nLiang M, Wang X, Liu H, Wang J: Excellent catalytic properties over nanocomposite catalysts for selective hydrogenation of halonitrobenzenes. J Catal. 2008, 255: 335-342. 10.1016\u002Fj.jcat.2008.02.025.\nChandrasekhar S, Prakash SJ, Rao CL: Poly(ethylene Glycol) (400) as Superior Solvent Medium against Ionic Liquids for Catalytic Hydrogenations with PtO2. J Org Chem. 2006, 71: 2196-2199. 10.1021\u002Fjo052604x.\nShi Q, Lu R, Lu L, Fu X, Zhao D: Efficient Reduction of Nitroarenes over Nickel-Iron Mixed Oxide Catalyst Prepared from a Nickel-Iron Hydrotalcite Precursor. Adv Synth Catal. 2007, 349: 1877-1881. 10.1002\u002Fadsc.200700070.\nMandal PK, McMurray JS: Pd − C-Induced Catalytic Transfer Hydrogenation with Triethylsilane. J Org Chem. 2007, 72: 6599-6601. 10.1021\u002Fjo0706123.\nRahaim RJ, Maleczka REJ: Pd-Catalyzed Silicon Hydride Reductions of Aromatic and Aliphatic Nitro Groups. Org Lett. 2005, 7: 5087-5090. 10.1021\u002Fol052120n.\nWienhöfer G, Sorribes I, Boddien A, Westerhaus F, Junge K, Junge H, Llusar R, Beller M: General and Selective Iron-Catalyzed Transfer Hydrogenation of Nitroarenes without Base. J Am Chem Soc. 2011, 133: 12875-12879. 10.1021\u002Fja2061038.\nSharma U, Kumar P, Kumar N, Kumar V, Singh B: Highly Chemo- and Regioselective Reduction of Aromatic Nitro Compounds Catalyzed by Recyclable Copper(II) as well as Cobalt(II) Phthalocyanines. Adv Synth Catal. 2010, 352: 1834-1840. 10.1002\u002Fadsc.201000191.\nSong XY, Sun SX, Zhang WM, Yin ZL: A method for the synthesis of spherical copper nanoparticles in the organic phase. J Colloid Interface Sci. 2004, 273: 463-469. 10.1016\u002Fj.jcis.2004.01.019.\nMitudome T, Arita S, Mori H, Mizugaki T, Jitsukawa K, Kaneda K: Supported Silver-Nanoparticle-Catalyzed Highly Efficient Aqueous Oxidation of Phenylsilanes to Silanols. Angew Chem Int Ed. 2008, 47: 7938-7940. 10.1002\u002Fanie.200802761.\nMin KI, Choi JS, Chung YM, Ahn WS, Ryoo R, Lim PK: p-Aminophenol synthesis in an organic\u002Faqueous system using Pt supported on mesoporous carbons. Appl Catal A Gen. 2008, 337: 97-140. 10.1016\u002Fj.apcata.2007.12.004.\nTakasaki M, Motoyama Y, Higashi K, Yoon SH, Mochida I, Nagashima H: Chemoselective Hydrogenation of Nitroarenes with Carbon Nanofiber-Supported Platinum and Palladium Nanoparticles. Org Lett. 2008, 10: 1601-1604. 10.1021\u002Fol800277a.\nWang F, Liu JH, Xu XL: Layered material γ-ZrP supported platinum catalyst for liquid-phase reaction: a highly active and selective catalyst for hydrogenation of the nitro group in para-chloronitrobenzene. Chem Commun. 2008, 46: 2040-2042.\nMotoyamal Y, Lee YJ, Tsuji K, Yoon SH, Mochida I, Nagashima H: Platinum Nanoparticles Supported on Nitrogen-doped Carbon Nanofibers as Efficient Poisoning Catalysts for the Hydrogenation of Nitroarenes. ChemCatChem. 2011, 3: 1578-1581. 10.1002\u002Fcctc.201100135.\nLiu MH, Yu WY, Liu HF: Selective hydrogenation of o-chloronitrobenzene over polymer-stabilized ruthenium colloidal catalysts. J Mol Catal A Chem. 1999, 138: 295-303. 10.1016\u002FS1381-1169(98)00159-9.\nBoronat P, Concepción A, Corma S, González F, Serna IP: A Molecular Mechanism for the Chemoselective Hydrogenation of Substituted Nitroaromatics with Nanoparticles of Gold on TiO2 Catalysts: A Cooperative Effect between Gold and the Support. J Am Chem Soc. 2007, 129: 16230-16237. 10.1021\u002Fja076721g.\nLou XB, He L, Qian Y, Liu YM, Cao Y, Fan KN: Highly Chemo- and Regioselective Transfer Reduction of Aromatic Nitro Compounds using Ammonium Formate Catalyzed by Supported Gold Nanoparticles. Adv Synth Catal. 2011, 353: 281-286. 10.1002\u002Fadsc.201000621.\nCorma A, Serna P: Chemoselective Hydrogenation of Nitro Compounds with Supported Gold Catalysts. Science. 2006, 313: 332-334. 10.1126\u002Fscience.1128383.\nLuo PF, Xu KL, Zhang R, Huang L, Wang J, Xing WH, Huang J: Highly efficient and selective reduction of nitroarenes with hydrazine over supported rhodium nanoparticles. Catal Sci Technol. 2012, 2: 301-304. 10.1039\u002Fc1cy00358e.\nPradhan N, Pal A, Pal T: Catalytic Reduction of Aromatic Nitro Compounds by Coinage Metal Nanoparticles. Langmuir. 2001, 17: 1800-1802. 10.1021\u002Fla000862d.\nWen HL, Yao KS, Zhang YD, Zhou ZM, Kirschning A: Catalytic transfer hydrogenation of aromatic nitro compounds in presence of polymer-supported nano-amorphous Ni–B catalyst. Catal Commun. 2009, 10: 1207-1211. 10.1016\u002Fj.catcom.2009.01.030.\nRanu BC, Saha A, Jana R: Microwave-Assisted Simple and Efficient Ligand Free Copper Nanoparticle Catalyzed Aryl-Sulfur Bond Formation. Adv Synth Catal. 2007, 349: 2690-2696. 10.1002\u002Fadsc.200700289.\nBhadra S, Saha A, Ranu BC: One-pot copper nanoparticle-catalyzed synthesis of S-aryl- and S-vinyl dithiocarbamates in water: high diastereoselectivity achieved for vinyl dithiocarbamates. Green Chem. 2008, 10: 1224-1230. 10.1039\u002Fb809200a.\nKidwai M, Bansal V, Saxena A, Aerry S, Mozumdar S: Cu-Nanoparticles: efficient catalysts for the oxidative cyclization of Schiffs’ bases. Tetrahedron Lett. 2006, 47: 8049-8053. 10.1016\u002Fj.tetlet.2006.09.066.\nSingh P, Katyal A, Kalra R, Chandra R: Copper nanoparticles in an ionic liquid: an efficient catalyst for the synthesis of bis-(4-hydroxy-2-oxothiazolyl)methanes. Tetrahedron Lett. 2008, 49: 727-730. 10.1016\u002Fj.tetlet.2007.11.106.\nAhammed S, Saha A, Ranu BC: Hydrogenation of Azides over Copper Nanoparticle Surface Using Ammonium Formate in Water. J Org Chem. 2011, 76: 7235-7239. 10.1021\u002Fjo200915h.\nSaha A, Ranu BC: Highly Chemoselective Reduction of Aromatic Nitro Compounds by Copper Nanoparticles\u002FAmmonium Formate. J Org Chem. 2008, 73: 6867-6870. 10.1021\u002Fjo800863m.\nPeng YQ, Song GH: Simultaneous microwave and ultrasound irradiation: A rapid synthesis of hydrazides. Green Chem. 2001, 3: 302-304. 10.1039\u002Fb108878p.\nPeng YQ, Dou RL, Song GH: Surface cleaning under combined microwave and ultrasound irradiation: flash synthesis of 4H-pyrano[2,3-c]pyrazoles in aqueous media. Green Chem. 2006, 8: 573-575. 10.1039\u002Fb601209d.\nFeng HD, Li Y, Van der Eycken EV, Peng YQ, Song GH: Synthesis of polysubstituted pyridines under combined microwave and ultrasound irradiation: K2CO3-promoted tandem addition\u002Fcyclization\u002Fhydrogen shift process. Tetrahedron Lett. 2012, 53: 1160-1162. 10.1016\u002Fj.tetlet.2011.12.103.\nFeng HD, Lin SJ, Wang JY, Song GH, Peng YQ: Aqueous heterogeneous synthesis of polysubstituted 2,6-dicyanoanilines via combined microwave and ultrasound-assisted multicomponent reaction. Green Process Synth. 2012, 1: 463-468.\nFeng HD, Ying XL, Peng YQ, Van der Eycken EV, Liu CD, Zhao SS, Song GH: FeCl3- promoted synthesis of 1, 3, 4-thiadiazoles under combined microwave and ultrasound irradiation in water. Monatsh Chem. 2013, 144: 681-686. 10.1007\u002Fs00706-012-0846-x.\nZhu HT, Zhang CY, Yin YS: Novel synthesis of copper nanoparticles: influence of the synthesis conditions on the particle size. Nanotechnology. 2005, 16: 3079-3083. 10.1088\u002F0957-4484\u002F16\u002F12\u002F059.\nZhu HT, Zhang CY, Yin YS: Rapid synthesis of copper nanoparticles by sodium hypophosphite reduction in ethylene glycol under microwave irradiation. J Crystal Growth. 2004, 270: 722-728. 10.1016\u002Fj.jcrysgro.2004.07.008.\nPark BK, Jeong S, Kim D, Moon J, Lim S, Kim JS: Synthesis and size control of monodisperse copper nanoparticles by polyol method. J Colloid Interface Sci. 2007, 311: 417-424. 10.1016\u002Fj.jcis.2007.03.039.\nJin ZH, Wang XY, Wang ST, Li D, Lu GZ: The effect of triethylamine on the hydrodechlorination of chlorophenols on Pd\u002FC at low temperature. Catal Commun. 2009, 10: 2027-2030. 10.1016\u002Fj.catcom.2009.07.024.\nCorma A, Concepcin P, Serna P: A different reaction pathway for the reduction of aromatic nitro compounds on gold catalysts. Angew Chem Int Ed. 2007, 46: 7266-7269. 10.1002\u002Fanie.200700823.",{"EN":154},"In situ preparation of copper nanoparticles from a copper acetate precursor and its application as an efficient catalyst for the selective reduction of aromatic nitro compounds with hydrazine hydrate under combined microwave and ultrasound irradiation were described in detail. The results reveal the synergetic effect of microwave and ultrasound on the synthesis of copper nanoparticles, and formation of various amino derivatives.",{"EN":156},"Nano Cu-catalyzed efficient and selective reduction of nitroarenes under combined microwave and ultrasound irradiation",{"VOID":158},"10.1186\u002F2043-7129-2-14","https:\u002F\u002Fsustainablechemicalprocesses.springeropen.com\u002Farticles\u002F10.1186\u002F2043-7129-2-14",[161,176,188,200,215],{"id":162,"sortIndex":98,"researcher":20,"roles":163,"affiliations":164,"properties":173},"d68d61ab-0ea0-40ed-98f3-2af8a4321ad9",[62],[165],{"id":20,"sortIndex":21,"affiliation":166,"properties":20},{"id":167,"createTime":168,"updateTime":168,"relativeEntities":169,"slug":20,"properties":170,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"74d95b3f-465c-43be-b90f-7804b46a7f6c","2023-12-05T23:20:54.593+00:00",[],{"title":171},{"VI":172},"Shanghai Key Laboratory of Chemical Biology, East China University of Science and Technology, Shanghai, P. 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PCT Int Appl. 2012, 157: 294728-WO 2012098044 A1 20120726 CAN\nKobayashi K, Nishikata T, Yamamoto Y, Miyaura N: Stepwise palladium-catalyzed 1,4-addition of arylboronic acids to enones and regioselective Baeyer-Villiger oxidation for enantioselective synthesis of β -diaryl esters and (+)-(R)-tolterodine. Bull Chem Soc Jpn. 2008, 81 (8): 1019-1025. 10.1246\u002Fbcsj.81.1019. CAN 149:471296\nWang G, Zhang J, He X, Wang Y: Process for preparation of Tolterodine and tartrate. Faming Zhuanli Shenqing. 2009, CN 101445462 A 20090603 CAN 151: 77765-\nKompella A, Thungathuthy Srinivasa R, Adibhtla Kali S, Bhujanga R, Venkaiah C, Nannapaneni: Process for the preparation of an intermediate useful in the synthesis of tolterodine. Indian Pat Appl. 2005, IN 2003CH01028 A 20051230 CAN 147: 486225-\nRazzetti G, Mantegazza S, Rossi R, Allegrini P: A process for the preparation of tolterodine. Eur Pat Appl. 2006, EP 1693361 A1 20060823 CAN 145: 271484-\nKelin L, Tunge JA: J Org Chem. 2008, 73: 8651-8653. 10.1021\u002Fjo801627z.\nLi K, Tunge JAJ: J Comb Chem. 2008, 10: 170-174. 10.1021\u002Fcc700150q.\nBussolari JC, Rehborn DC, Combs DW: Tetrahedron Lett. 1999, 40: 1241-1244. 10.1016\u002FS0040-4039(98)02598-2.\nJonsson N, Spart BA, Mikiver L, Moses P, Nilverbrant L, Glas G: U.S. Patent 5,382,600. 1995",{"EN":276},"An improved, cost effective process for the synthesis of N,N-diisopropyl-3-(2-hydroxy-5-methylphenyl)-3-phenylpropanamide; a key intermediate for the preparation of Tolterodine and its related substances were described. The process features one pot synthesis employing inexpensive reagents.",{"EN":278},"Improved one-pot synthesis of N, N-diisopropyl-3-(2-Hydroxy-5-methylphenyl)-3-phenyl propanamide; a key intermediate for the preparation of racemic Tolterodine",{"VOID":280},"10.1186\u002F2043-7129-2-2","VERIFIED","Auto Verify","https:\u002F\u002Fsustainablechemicalprocesses.springeropen.com\u002Farticles\u002F10.1186\u002F2043-7129-2-2",[285,300,316,328,340,352],{"id":286,"sortIndex":85,"researcher":20,"roles":287,"affiliations":288,"properties":297},"e7cd21ca-d2bb-426b-913a-3cb1b0aec2e9",[62],[289],{"id":20,"sortIndex":21,"affiliation":290,"properties":20},{"id":291,"createTime":292,"updateTime":292,"relativeEntities":293,"slug":20,"properties":294,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"dbe58d86-befa-4721-a8e4-8ce5261af6ce","2023-12-17T15:44:05.323+00:00",[],{"title":295},{"VI":296},"Chemical Research 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Reddy",{"id":353,"sortIndex":21,"researcher":20,"roles":354,"affiliations":355,"properties":368},"f987e6f6-660f-4d12-8cd4-3a90eff4ec05",[62],[356,363],{"id":357,"sortIndex":60,"affiliation":358,"properties":362},"a9e29b0e-5c7f-4751-807b-f6fb0329ccad",{"id":307,"createTime":308,"updateTime":308,"relativeEntities":359,"slug":20,"properties":360,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":361},{"VI":312},{},{"id":20,"sortIndex":21,"affiliation":364,"properties":20},{"id":291,"createTime":292,"updateTime":292,"relativeEntities":365,"slug":20,"properties":366,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":367},{"VI":296},{"title":369},{"VI":370},"Garaga Srinivas",{"url":283,"publisher":372,"properties":386},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":373,"slug":10,"properties":374,"entityType":18,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"subjectFields":378,"manageAffiliations":379,"indexDatabases":380,"url":20,"thumbnailPath":20,"statistic":381,"gsStatistic":20,"type":34,"analyzePriority":20},[],{"issn":375,"title":376,"url":377},{"VOID":13},{"EN":15},{"VOID":17},[],[],[],{"impactFactor":21,"impactFactorByYear":382,"i10Index":21,"i10IndexLast5Year":21,"totalPublication":27,"totalPublicationByYear":383,"totalCitation":21,"totalCitationByYear":384,"totalCitationPerPublication":21,"totalCitationPerPublicationByYear":385,"hindexLast5Year":21,"hindex":21},{},{"2013":29,"2014":29,"2015":30,"2016":31},{},{},{"volume":387,"pages":388},{"VOID":140},{"VOID":264},"2014-01-20",{"id":391,"createTime":392,"updateTime":393,"relativeEntities":394,"slug":395,"properties":396,"entityType":54,"verifyStatus":281,"verifyTime":393,"verifyNote":282,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"primaryUrl":405,"fullTextUrl":20,"authors":406,"publicationType":122,"publisherRelationship":461,"citationCount":20,"citationInfo":20,"publishDate":481,"publishYear":482,"citationAnalyzeStatus":19,"lastCitationAnalyze":20,"indexDatabases":20,"openAccess":20,"references":20,"isForceReanalyzing":145},"4a2bffff-4b94-4e9f-b121-21d2616cb380","2024-01-13T08:57:19.485+00:00","2025-02-19T22:08:07.094+00:00",[],"Environmental-assessment-of-residues-generated-after-consecutive-acid-base-pretreatment-of-sugarcane-bagasse-by-advanced-oxidative-process",{"references":397,"abstract":399,"title":401,"doi":403},{"VOID":398},"Goldemberg J, Coelho S, Guardabassi P: The sustainability of ethanol production from sugarcane. Ener Pol. 2008, 36: 2086-2097. 10.1016\u002Fj.enpol.2008.02.028.\nOjeda K, Ávila O, Suárez J, Kafarov V: Evaluation of technological alternatives for process integration of sugarcane bagasse for sustainable biofuels. Chem Eng Res Design. 2011, 89: 270-279. 10.1016\u002Fj.cherd.2010.07.007.\nChandel AK, Chan EC, Rudravaram R, Narasu ML, Rao LV, Ravindra P: Economics and environmental impact of bioethanol production technologies: an appraisal. Biotechnol Mol Biol Rev. 2007, 2: 014-032.\nCardona CA, Sánchez ÓJ: Fuel ethanol production: process design trends and integration opportunities. Bioresour Technol. 2010, 98: 2415-2457.\nChandel AK, Silva SS, Carvalho W, Singh OV: Sugarcane bagasse and leaves: foreseeable biomass of biofuel and bio-products. J Chem Technol Biotechnol. 2012, 87: 11-20. 10.1002\u002Fjctb.2742.\nRezende CA, Lima MA, Maziero P, Azevedo ER, Garcia W, Polikarpov I: Chemical and morphological characterization of sugarcane bagasse submitted to a delignification process for enhanced enzymatic digestibility. Biotechnol Biofuels. 2011, 4: 54-10.1186\u002F1754-6834-4-54.\nGiese EC, Pierozzi M, Dussan KJ, Chandel AK, Silva SS: Enzymatic saccharification of acid-alkali pretreated sugarcane bagasse using commercial enzyme preparations. J Chem Technol Biotechnol. 2012, 88: 1266-1272.\nCanilha L, Chandel AK, Milessi TSS, Antunes FAF, Freitas WLC, Felipe MGA, Silvio SS: Bioconversion of sugarcane biomass into ethanol: an overview about composition, pretreatment methods, detoxification of hydrolysates, enzymatic saccharification, and ethanol fermentation. J Biomed Biotechnol. 2012, 1: 15-\nMussatto SI, Dragone G, Guimarães PMR, Silva JPA, Carneiro LM, Roberto IC, Vicente A, Domingues L, Teixeira JA: Technological trends, global market, and challenges of bio-ethanol production. Biotechnol Adv. 2010, 28: 817-830.\nZhu JY, Pan XJ: Woody biomass pretreatment for cellulosic ethanol production: Technology and energy consumption evaluation. Bioresour Technol. 2010, 101: 4992-5002. 10.1016\u002Fj.biortech.2009.11.007.\nWang L, Chen H: Increased fermentability of enzymatically hydrolyzed steam-exploded corn stover for butanol production by removal of fermentation inhibitors. Proc Biochem. 2011, 46: 604-607. 10.1016\u002Fj.procbio.2010.09.027.\nCanilha L, Santos VTO, Rocha GJM, Silva JBA, Giulietti M, Silva SS, Felipe MGA, Ferraz A, Milagres AMF, Carvalho W: A study on the pretreatment of a sugarcane bagasse sample with dilute sulfuric acid. J Ind Microbiol Biotechnol. 2011, 38: 1467-1475. 10.1007\u002Fs10295-010-0931-2.\nChandel AK, Silva SS, Singh OV: Detoxification of lignocellulose hydrolysates: Biochemical and metabolic engineering towards white biotechnology. Bio Ener Res. 2013, 6: 388-401.\nRodrigues GD, Silva LHM, Silva MCH: Alternativas verdes para o preparo de amostras e determinação de poluentes fenólicos em água. Química Nova. 2010, 33: 1370-1378.\nUğurlu M, Gürses A, Doğar Ç, Yalçın M: The removal of lignin and phenol from paper Mill effluents by electrocoagulation. J Environ Manag. 2008, 87: 420-428. 10.1016\u002Fj.jenvman.2007.01.007.\nUğurlu M, Karaoğlu MH: TiO2 supported on sepiolite: preparation, structural and thermal characterization and catalytic behaviour in photocatalytic treatment of phenol and lignin from olive mill wastewater. Chem Eng J. 2011, 166: 859-867. 10.1016\u002Fj.cej.2010.11.056.\nCansado IPP, Mourão PAM, Falcão AI, Ribeiro Carrott MML, Carrott PJM: The influence of the activated carbon post-treatment on the phenolic compounds removal. Fuel Proc Technol. 2012, 103: 64-70.\nGonçalves MR, Costa JC, Marques IP, Alves MM: Strategies for lipids and phenolics degradation in the anaerobic treatment of olive mill wastewater. Water Res. 2012, 46: 1684-1692. 10.1016\u002Fj.watres.2011.12.046.\nAmendola D, De Faveri DM, Egües I, Serrano L, Labidi J, Spigno G: Autohydrolysis and organosolv process for recovery of hemicelluloses, phenolic compounds and lignin from grape stalks. Bioresour Technol. 2012, 107: 267-274.\nBabuponnusamia A, Muthukumar K: Advanced oxidation of phenol: A comparison between Fenton, electro-Fenton, sono-electro-Fenton and photo-electro-Fenton processes. Chem Eng J. 2012, 183: 1-9.\nOller I, Malato S, Sánchez-Pére JA: Combination of advanced oxidation processes and biological treatments for wastewater decontamination - a review. Sci Total Environ. 2011, 409: 4141-4166. 10.1016\u002Fj.scitotenv.2010.08.061.\nFatta-Kassinos D, Vasquez MI, Kümmerer K: Transformation products of pharmaceuticals in surface waters and wastewater formed during photolysis and advanced oxidation process - Degradation, elucidation of by products and assessment of their biological potency. Chemosphere. 2011, 85: 693-709. 10.1016\u002Fj.chemosphere.2011.06.082.\nLamsal R, Walsh ME, Gagnon GA: Comparison of advanced oxidation processes for the removal of natural organic matter. Water Res. 2011, 45: 3263-3269. 10.1016\u002Fj.watres.2011.03.038.\nWols BA, Hofman-Caris CHM: Review of photochemical reaction constants of organic micropollutants required for UV advanced oxidation processes in water. Water Res. 2012, 46: 2815-2827. 10.1016\u002Fj.watres.2012.03.036.\nSharma VK, Triantis TM, Antoniou MG, He X, Pelaez M, Han C, Song W, O’Shea KE, de La Cruz AA, Kaloudis T, Hiskia A, Dionysiou DD: Destruction of microcystins by conventional and advanced oxidation processes: A review. Sep Purif Technol. 2012, 91: 3-17.\nTobaldi DM, Tucci A, Camera-Roda G, Baldi DG, Esposito L: Photocatalytic activity for exposed building materials. J European Ceramic Soc. 2008, 28: 2645-2652. 10.1016\u002Fj.jeurceramsoc.2008.03.032.\nMichalska K, Miazek K, Krzystek L, Ledakowicz S: Influence of pretreatment with Fenton’s reagent on biogas production and methane yield from lignocellulosic biomass. Bioresour Technol. 2012, 119: 72-78.\nCortez S, Teixeira P, Oliveira R, Mota M: Evaluation of Fenton and ozone-based advanced oxidation process as mature landfill leachate pre-treatments. J Environ Manag. 2011, 92: 749-755. 10.1016\u002Fj.jenvman.2010.10.035.\nChu L, Wang J, Dong J, Liu H, Sun X: Treatment of coking wastewater by an advanced Fenton oxidation process using iron powder and hydrogen peroxide. Chemosphere. 2012, 86: 409-414. 10.1016\u002Fj.chemosphere.2011.09.007.\nAPHA, American Public Health Association: Standard Methods for Examination of Water and Wastewater. 2005, Washington, DC: (APHA, AWWA), 2001-3710. 21\nLucas MS, Peres JA, Amor C, Prieto-Rodríguez L, Maldonado MI, Malato S: Tertiary treatment of pulp mill wastewater by solar photo-Fenton. J Hazard Mat. 2012, 225–226: 173-181.\nMa Y, Chang C, Chiang Y, Sung H, Chao AC: Photocatalytic degradation of lignin using Pt\u002FTiO2 as the catalyst. Chemosphere. 2008, 71: 998-1004. 10.1016\u002Fj.chemosphere.2007.10.061.\nNinomiya K, Takamatsu H, Onishi A, Takahashi K, Shimizu N: Sonocatalytic-Fenton reaction for enhanced OH radical generation and its application to lignin degradation. Ultrasonics Sonochem. 2013, 20: 1092-1097. 10.1016\u002Fj.ultsonch.2013.01.007.\nMakhotkina OA, Preis SV, Parkhomchuk EV: Water delignification by advanced oxidation processes: Homogeneous and heterogeneous Fenton and H2O2 photo-assisted reactions. Appl Catal B: Environmental. 2008, 84: 821-826. 10.1016\u002Fj.apcatb.2008.06.015.\nPupo Nogueira RF, Trovó AG, Silva MRA, Villa RD: Fundamentos e aplicações ambientais dos processos Fenton e foto-Fenton. Química Nova. 2007, 30: 400-408.\nManenti DR, Gomes LFS, Borba FH, Módenes NA, Espinoza-Quiñones FR, Palácio SM: Otimização do processo foto-Fenton utilizando irradiação artificial na degradação do efluente têxtil sintético. Engevista. 2010, 12: 22-32.\nHermosilla D, Merayo N, Ordóñez R, Blanco A: Optimization of conventional Fenton and ultraviolet-assisted oxidation processes for the treatment of reverse osmosis retentate from a paper Mill. Waste Manag. 2012, 32: 1236-1243. 10.1016\u002Fj.wasman.2011.12.011.\nSamet Y, Hmani E, Abdelhédi R: Fenton and solar photo-Fenton processes for the removal of chlorpyrifos insecticide in wastewater. Water. 2012, 38: 537-542.\nBentivenga G, Bonini C, D’Auria M, De Bona A: Degradation of steam-exploded lignin from beech by using Fenton’s reagent. Biomass Bioener. 2003, 24: 233-238. 10.1016\u002FS0961-9534(02)00135-6.\nSalazar RFS, Peixoto ALC, Izário Filho HJ: Avaliação da metodologia 5220 D. Closed reflux, colorimetric method para determinação da demanda química de oxigênio (DQO) em efluentes lácteo. Analytica. 2010, 44: 55-61.\nCompanhia de Tecnologia de Saneamento Ambiental: Variáveis de Qualidade das Águas. 2013, Disponível em: [http:\u002F\u002Fwww.cetesb.sp.gov.br\u002FAgua\u002Frios\u002Fvariaveis.asp#dbo] Accessed on April, 2013\nCONAMA - Conselho Nacional do Meio Ambiente: CONAMA - Conselho Nacional do Meio Ambiente. [http:\u002F\u002Fwww.mma.gov.br\u002Fconama] Accessed on April, 2013\nAutin O, Romelot C, Rust L, Hart J, Jarvis P, MacAdam J, Parsons SA, Jefferson B: Evaluation of a UV-light emitting diodes unit for the removal of micropollutants in water for low energy advanced oxidation processes. Chemosphere. 2013, 92: 745-751. 10.1016\u002Fj.chemosphere.2013.04.028.\nAzbar N, Yonar T, Kestioglu K: Comparison of various advanced oxidation processes and chemical treatment methods for COD and color removal from a polyester and acetate fiber dyeing effluent. Chemosphere. 2004, 55: 35-43. 10.1016\u002Fj.chemosphere.2003.10.046.\nCanizares P, Paz R, Sáez C, Rodrigo MA: Costs of the electrochemical oxidation of wastewaters: A comparison with ozonation and Fenton oxidation processes. J Environ Manag. 2009, 90: 410-420. 10.1016\u002Fj.jenvman.2007.10.010.\nChen YC, Smirniotis P: Enhancement of photocatalytic degradation of phenol and chloro-phenols by ultrasound. Ind Eng Chem Res. 2002, 41: 5958-5965. 10.1021\u002Fie020415o.\nChong MN, Sharma AK, Burn S, Saint CP: Feasibility study on the application of advanced oxidation technologies for decentralized wastewater treatment. J Cleaner Prod. 2012, 35: 230-238.\nMahamuni NN, Adewuyi YG: Advanced oxidation processes (AOPs) involving ultrasound for waste water treatment: A review with emphasis on cost estimation. Ultrason Sonochem. 2010, 17: 990-1003. 10.1016\u002Fj.ultsonch.2009.09.005.\nMódenes AN, Espinoza-Quiñones FR, Borba FH, Manenti DR: Performance evaluation of an integrated photo-Fenton – Electrocoagulation process applied to pollutant removal from tannery effluent in batch system. Chem Eng J. 2021, 197: 1-9.\nPérez JAS, Sánchez IMR, Carra I, Reina AC, López JLC, Malato S: Economic evaluation of a combined photo-Fenton\u002FMBR process using pesticides as model pollutant. Factors affecting costs. J Haz Mat. 2013, 244–245: 195-203.",{"EN":400},"Biofuels produced from sugarcane bagasse (SB) have shown promising results as a suitable alternative of gasoline. Biofuels provide unique, strategic, environmental and socio-economic benefits. However, production of biofuels from SB has negative impact on environment due to the use of harsh chemicals during pretreatment. Consecutive sulfuric acid-sodium hydroxide pretreatment of SB is an effective process which eventually ameliorates the accessibility of cellulase towards cellulose for the sugars production. Alkaline hydrolysate of SB is black liquor containing high amount of dissolved lignin. This work evaluates the environmental impact of residues generated during the consecutive acid-base pretreatment of SB. Advanced oxidative process (AOP) was used based on photo-Fenton reaction mechanism (Fenton Reagent\u002FUV). Experiments were performed in batch mode following factorial design L9 (Taguchi orthogonal array design of experiments), considering the three operation variables: temperature (°C), pH, Fenton Reagent (Fe2+\u002FH2O2) + ultraviolet. Reduction of total phenolics (TP) and total organic carbon (TOC) were responsive variables. Among the tested conditions, experiment 7 (temperature, 35°C; pH, 2.5; Fenton reagent, 144 ml H2O2+153 ml Fe2+; UV, 16W) revealed the maximum reduction in TP (98.65%) and TOC (95.73%). Parameters such as chemical oxygen demand (COD), biochemical oxygen demand (BOD), BOD\u002FCOD ratio, color intensity and turbidity also showed a significant change in AOP mediated lignin solution than the native alkaline hydrolysate. AOP based on Fenton Reagent\u002FUV reaction mechanism showed efficient removal of TP and TOC from sugarcane bagasse alkaline hydrolysate (lignin solution). To the best of our knowledge, this is the first report on statistical optimization of the removal of TP and TOC from sugarcane bagasse alkaline hydrolysate employing Fenton reagent mediated AOP process.",{"EN":402},"Environmental assessment of residues generated after consecutive acid-base pretreatment of sugarcane bagasse by advanced oxidative process",{"VOID":404},"10.1186\u002F2043-7129-1-20","https:\u002F\u002Fsustainablechemicalprocesses.springeropen.com\u002Farticles\u002F10.1186\u002F2043-7129-1-20",[407,422,434,446],{"id":408,"sortIndex":60,"researcher":20,"roles":409,"affiliations":410,"properties":419},"38ca55ec-a15e-4ecd-8940-4f34f44897d9",[62],[411],{"id":20,"sortIndex":21,"affiliation":412,"properties":20},{"id":413,"createTime":414,"updateTime":414,"relativeEntities":415,"slug":20,"properties":416,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"695c9ad3-b6a6-49d2-add5-df9b86c52124","2024-01-13T08:57:19.509+00:00",[],{"title":417},{"VI":418},"Department of Biotechnology, Engineering School of Lorena, University of São Paulo, Estrada Municipal do Campinho, Brazil",{"title":420},{"VI":421},"Anuj K Chandel",{"id":423,"sortIndex":85,"researcher":20,"roles":424,"affiliations":425,"properties":431},"9f7f641a-65c5-43ed-bd03-ac01c9deab94",[62],[426],{"id":20,"sortIndex":21,"affiliation":427,"properties":20},{"id":413,"createTime":414,"updateTime":414,"relativeEntities":428,"slug":20,"properties":429,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":430},{"VI":418},{"title":432},{"VI":433},"Silvio Silvério da Silva",{"id":435,"sortIndex":21,"researcher":20,"roles":436,"affiliations":437,"properties":443},"d03a2504-fb6f-40bb-b461-28523e683e4f",[62],[438],{"id":20,"sortIndex":21,"affiliation":439,"properties":20},{"id":413,"createTime":414,"updateTime":414,"relativeEntities":440,"slug":20,"properties":441,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":442},{"VI":418},{"title":444},{"VI":445},"Ivy dos Santos Oliveira",{"id":447,"sortIndex":111,"researcher":20,"roles":448,"affiliations":449,"properties":458},"4e86f600-dc2a-4b9c-abfb-8c6b78e33d0f",[62],[450],{"id":20,"sortIndex":21,"affiliation":451,"properties":20},{"id":452,"createTime":453,"updateTime":453,"relativeEntities":454,"slug":20,"properties":455,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"c33307cc-1d90-44fd-9594-24d2890a7ab4","2023-12-06T15:56:12.263+00:00",[],{"title":456},{"VI":457},"Department of Chemical Engineering, Engineering School of Lorena, University of São Paulo, Lorena, Brazil",{"title":459},{"VI":460},"Messias Borges Silva",{"url":405,"publisher":462,"properties":476},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":463,"slug":10,"properties":464,"entityType":18,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"subjectFields":468,"manageAffiliations":469,"indexDatabases":470,"url":20,"thumbnailPath":20,"statistic":471,"gsStatistic":20,"type":34,"analyzePriority":20},[],{"issn":465,"title":466,"url":467},{"VOID":13},{"EN":15},{"VOID":17},[],[],[],{"impactFactor":21,"impactFactorByYear":472,"i10Index":21,"i10IndexLast5Year":21,"totalPublication":27,"totalPublicationByYear":473,"totalCitation":21,"totalCitationByYear":474,"totalCitationPerPublication":21,"totalCitationPerPublicationByYear":475,"hindexLast5Year":21,"hindex":21},{},{"2013":29,"2014":29,"2015":30,"2016":31},{},{},{"volume":477,"pages":479},{"VOID":478},"1",{"VOID":480},"1-10","2013-10-08",2013,{"id":484,"createTime":485,"updateTime":485,"relativeEntities":486,"slug":20,"properties":487,"entityType":54,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"primaryUrl":496,"fullTextUrl":20,"authors":497,"publicationType":122,"publisherRelationship":547,"citationCount":20,"citationInfo":20,"publishDate":566,"publishYear":144,"citationAnalyzeStatus":19,"lastCitationAnalyze":20,"indexDatabases":20,"openAccess":20,"references":20,"isForceReanalyzing":145},"ef941cb9-7051-4fda-bf50-231a3bbda239","2023-12-24T21:52:17.477+00:00",[],{"references":488,"abstract":490,"title":492,"doi":494},{"VOID":489},"Fontes CM, Gilbert HJ: Cellulosomes: highly efficient nanomachines designed to deconstruct plant cell wall complex carbohydrates. Annu Rev Biochem. 2010, 79: 655-681. 10.1146\u002Fannurev-biochem-091208-085603.\nBayer EA, Morag E, Lamed R: The cellulosome - a treasuretrove for biotechnology. TIBTECH. 1994, 12: 379-386. 10.1016\u002F0167-7799(94)90039-6.\nFierobe HP, Mechaly A, Tardif C, Belaich A, Lamed R, Shoham Y, Belaich JP, Bayer EA: Design and production of active cellulosome chimeras. Selective incorporation of dockerin-containing enzymes into defined functional complexes. J Biol Chem. 2001, 276: 21257-21261. 10.1074\u002Fjbc.M102082200.\nEklund M, Sandstrom K, Teeri TT, Nygren PA: Site-specific and reversible anchoring of active proteins onto cellulose using a cellulosome-like complex. J Biotechnol. 2004, 109: 277-286. 10.1016\u002Fj.jbiotec.2004.01.008.\nMingardon F, Chanal A, Tardif C, Bayer EA, Fierobe HP: Exploration of new geometries in cellulosome-like chimeras. Appl Environ Microbiol. 2007, 73: 7138-7149. 10.1128\u002FAEM.01306-07.\nHyeon JE, Jeon SD, Han SO: Cellulosome-based, Clostridium-derived multi-functional enzyme complexes for advanced biotechnology tool development: advances and applications. Biotechnol Adv. 2013, 31: 936-944. 10.1016\u002Fj.biotechadv.2013.03.009.\nXu Q, Ding SY, Brunecky R, Bomble YJ, Himmel ME, Baker JO: Improving activity of minicellulosomes by integration of intra- and intermolecular synergies. Biotechnol Biofuels. 2013, 6 (126): 1-10.\nKrauss J, Zverlov VV, Schwarz WH: In vitro reconstitution of the completeClostridium thermocellumcellulosome and synergistic activity on crystalline cellulose.Appl Environ Microbiol. 2012, 78: 4301-4307. 10.1128\u002FAEM.07959-11.\nSmith SP, Bayer EA: Insights into cellulosome assembly and dynamics: from dissection to reconstruction of the supramolecular enzyme complex. Curr Opin Struct Biol. 2013, 23: 686-694. 10.1016\u002Fj.sbi.2013.09.002.\nChen R, Chen Q, Kim H, Siu K, Sun Q, Tsai SL, Chen W: Biomolecular scaffolds for enhanced signaling and catalytic efficiency. Curr Opin Biotechnol. 2014, 28: 59-68. 10.1016\u002Fj.copbio.2013.11.007.\nMitsuzawa S, Kagawa H, Li Y, Chan SL, Paavola CD, Trent JD: The rosettazyme: a synthetic cellulosome. J Biotechnol. 2009, 143: 139-144. 10.1016\u002Fj.jbiotec.2009.06.019.\nKim DM, Umetsu M, Takai K, Matsuyama T, Ishida N, Takahashi H, Asano R, Kumagai I: Enhancement of cellulolytic enzyme activity by clustering cellulose binding domains on nanoscaffolds. Small. 2011, 7: 656-664. 10.1002\u002Fsmll.201002114.\nBlanchette C, Lacayo CI, Fischer NO, Hwang M, Thelen MP: Enhanced cellulose degradation using cellulase-nanosphere complexes. PLoS One. 2012, 7 (8): e42116-10.1371\u002Fjournal.pone.0042116.\nTsai SL, Park M, Chen W: Size-modulated synergy of cellulase clustering for enhanced cellulose hydrolysis. 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Appl Environ Microbiol. 2012, 78: 1437-1444. 10.1128\u002FAEM.07138-11.\nMorais S, Barak Y, Hadar Y, Wilson DB, Shoham Y, Lamed R, Bayer EA: Assembly of xylanases into designer cellulosomes promotes efficient hydrolysis of the xylan component of a natural recalcitrant cellulosic substrate. MBio. 2011, 2 (6): e00233-e00311. 10.1128\u002FmBio.00233-11.\nMcClendon SD, Mao Z, Shin HD, Wagschal K, Chen RR: Designer xylanosomes: protein nanostructures for enhanced xylan hydrolysis. Appl Biochem Biotechnol. 2012, 167: 395-411. 10.1007\u002Fs12010-012-9680-1.\nSun J, Wen F, Si T, Xu JH, Zhao H: Direct conversion of xylan to ethanol by recombinantSaccharomycescerevisiae strains displaying an engineered minihemicellulosome.Appl Environ Microbiol. 2012, 78: 3837-3845. 10.1128\u002FAEM.07679-11.",{"EN":491},"Cellulosic biomass is a sustainable source for fuels and value-added chemicals, and is available in large quantities. One of the key challenges in biomass processing is associated with the establishment of an efficient enzymatic degradation of plant cell wall. A multi-enzymatic complex, cellulosome, was identified as a highly efficient biocatalyst for the hydrolysis of cellulosic biomass in nature. Significant progress has been achieved on cellulosome production and application since its discovery, but there is still a gap for industrial use. Artificial systems are being developed by employing various pairs of proteins and scaffolds with the objective of reconstructing this natural multi-enzymatic complex for sustainable biotechnology application.",{"EN":493},"Biomolecular assembly strategies to develop potential artificial cellulosomes",{"VOID":495},"10.1186\u002Fs40508-014-0019-9","https:\u002F\u002Fsustainablechemicalprocesses.springeropen.com\u002Farticles\u002F10.1186\u002Fs40508-014-0019-9",[498,513,535],{"id":499,"sortIndex":60,"researcher":20,"roles":500,"affiliations":501,"properties":510},"d5b34507-dfee-470d-b99f-554037308d49",[62],[502],{"id":20,"sortIndex":21,"affiliation":503,"properties":20},{"id":504,"createTime":505,"updateTime":505,"relativeEntities":506,"slug":20,"properties":507,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"e267b897-a837-4bd3-88e9-73758c8e48a6","2023-12-24T21:52:17.533+00:00",[],{"title":508},{"VI":509},"Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, Fukuoka, Japan",{"title":511},{"VI":512},"Yutaro Mori",{"id":514,"sortIndex":111,"researcher":20,"roles":515,"affiliations":516,"properties":532},"84698bfb-4d5d-4719-b8dc-585b256b1540",[62],[517,522],{"id":20,"sortIndex":21,"affiliation":518,"properties":20},{"id":504,"createTime":505,"updateTime":505,"relativeEntities":519,"slug":20,"properties":520,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":521},{"VI":509},{"id":523,"sortIndex":60,"affiliation":524,"properties":531},"3bb07785-a917-4932-a3fb-5cbbadd57140",{"id":525,"createTime":526,"updateTime":526,"relativeEntities":527,"slug":20,"properties":528,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"69d8cb24-bcdf-43a9-818c-f5dda28a1ff9","2023-12-06T22:39:09.188+00:00",[],{"title":529},{"VI":530},"Center for Future Chemistry, Kyushu University, Fukuoka, Japan",{},{"title":533},{"VI":534},"Noriho Kamiya",{"id":536,"sortIndex":21,"researcher":20,"roles":537,"affiliations":538,"properties":544},"f6b92ec1-1dca-40c0-b07b-8e398584cfb0",[62],[539],{"id":20,"sortIndex":21,"affiliation":540,"properties":20},{"id":504,"createTime":505,"updateTime":505,"relativeEntities":541,"slug":20,"properties":542,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":543},{"VI":509},{"title":545},{"VI":546},"Geisa AL Gonçalves",{"url":496,"publisher":548,"properties":562},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":549,"slug":10,"properties":550,"entityType":18,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"subjectFields":554,"manageAffiliations":555,"indexDatabases":556,"url":20,"thumbnailPath":20,"statistic":557,"gsStatistic":20,"type":34,"analyzePriority":20},[],{"issn":551,"title":552,"url":553},{"VOID":13},{"EN":15},{"VOID":17},[],[],[],{"impactFactor":21,"impactFactorByYear":558,"i10Index":21,"i10IndexLast5Year":21,"totalPublication":27,"totalPublicationByYear":559,"totalCitation":21,"totalCitationByYear":560,"totalCitationPerPublication":21,"totalCitationPerPublicationByYear":561,"hindexLast5Year":21,"hindex":21},{},{"2013":29,"2014":29,"2015":30,"2016":31},{},{},{"volume":563,"pages":564},{"VOID":140},{"VOID":565},"1-5","2014-10-07",{"id":568,"createTime":569,"updateTime":570,"relativeEntities":571,"slug":572,"properties":573,"entityType":54,"verifyStatus":281,"verifyTime":570,"verifyNote":282,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"primaryUrl":582,"fullTextUrl":20,"authors":583,"publicationType":122,"publisherRelationship":626,"citationCount":20,"citationInfo":20,"publishDate":644,"publishYear":144,"citationAnalyzeStatus":19,"lastCitationAnalyze":20,"indexDatabases":20,"openAccess":20,"references":20,"isForceReanalyzing":145},"80673b71-506a-400d-afcc-c7c621a1789b","2024-01-23T09:41:38.967+00:00","2025-02-17T21:48:32.911+00:00",[],"Enzyme-promiscuity-using-the-dark-side-of-enzyme-specificity-in-white-biotechnology",{"references":574,"abstract":576,"title":578,"doi":580},{"VOID":575},"Gupta MN, Raghava S: Relevance of chemistry to white biotechnology. 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J Biotechnol. 2011, 153: 111-115. 10.1016\u002Fj.jbiotec.2011.03.009.\nYang F, Wang Z, Wang H, Zhang H, Yue H, Wang L: Enzyme catalytic promiscuity: lipase catalyzed synthesis of substituted 2H-chromenes by a three-component reaction. RSC Adv. 2014, 4: 25633-25636. 10.1039\u002Fc4ra03367a.\nJiang L, Yu HW: An example of enzymatic promiscuity: the Baylis-Hillman reaction catalyzed by a biotin esterase (BioH) from Escherichia coli . Biotechnol Lett. 2014, 36: 99-103. 10.1007\u002Fs10529-013-1329-9.\nXie ZB, Wang N, Wu WX, Le ZG, Yu XQ: Trypsin-catalyzed tandem reaction: one-pot synthesis of 3,4-dihydropyrimidin-2(1H)-ones by in situ formed acetaldehyde. J Biotechnol. 2014, 170: 1-5. 10.1016\u002Fj.jbiotec.2013.10.031.\nJia B, Cheong GW, Zhang S: Multifunctional enzymes in archaea: promiscuity and moonlight. Extremophiles. 2013, 17: 193-203. 10.1007\u002Fs00792-012-0509-1.\nMittag T, Kay LE, Forman-Kay JD: Protein dynamics and conformational disorder in molecular recognition. J Mol Recognit. 2010, 23: 105-116.\nSkolnick J, Gao M: Interplay of physics and evolution in the likely origin of protein biochemical function. Proc Natl Acad Sci. 2013, 110: 9344-9349. 10.1073\u002Fpnas.1300011110.\nHou L, Honaker MT, Shireman LM, Balogh LM, Roberts AG, Ng K, Nath A, Atkins WM: Functional promiscuity correlates with conformational heterogeneity in A-class glutathione S-transferases. J Biol Chem. 2007, 282: 23263-23274.\nHonaker MT, Acchione M, Sumida JP, Atkins WM: Ensemble perspective for catalytic promiscuity: calorimetric analysis of the active site conformational landscape of a detoxification enzyme. J Biol Chem. 2011, 286: 42769-42776. 10.1074\u002Fjbc.M111.304386.\nHonaker MT, Acchione M, Zhang W, Mannervik B, Atkins WM: Enzymatic detoxification, conformational selection, and the role of molten globule active sites. J Biol Chem. 2013, 288: 18599-18611. 10.1074\u002Fjbc.M112.445767.\nSkopelitou K, Dhavala P, Papageorgiou AC, Labrou NE: A glutathione transferase from Agrobacterium tumefaciens reveals a novel class of bacterial GST superfamily. PLoS ONE. 2012, 7: e34263-10.1371\u002Fjournal.pone.0034263.\nLabrou NE: Affinity chromatography. Methods for Affinity-Based Separations of Enzymes and Proteins. Edited by: Gupta MN. 2002, Birkhauser Verlag, Basel, 16-28. 10.1007\u002F978-3-0348-8127-2_2.\nWatson JD, Hopkins NH, Roberts JW, Steitz JA, Weiner AM: Molecular Biology of the Gene. 1987, The Benjamin\u002FCummings Publishing Company Inc, California, fourth",{"EN":577},"Enzyme promiscuity can be classified into substrate promiscuity, condition promiscuity and catalytic promiscuity. Enzyme promiscuity results in far larger ranges of organic compounds which can be obtained by biocatalysis. While early examples mostly involved use of lipases, more recent literature shows that catalytic promiscuity occurs more widely and many other classes of enzymes can be used to obtain diverse kinds of molecules. This is of immense relevance in the context of white biotechnology as enzyme catalysed reactions use greener conditions.\n                \n                  \n                  \n                \n                \n                  \n                \n              ",{"EN":579},"Enzyme promiscuity: using the dark side of enzyme specificity in white biotechnology",{"VOID":581},"10.1186\u002Fs40508-014-0025-y","https:\u002F\u002Fsustainablechemicalprocesses.springeropen.com\u002Farticles\u002F10.1186\u002Fs40508-014-0025-y",[584,599,614],{"id":585,"sortIndex":21,"researcher":20,"roles":586,"affiliations":587,"properties":596},"05924981-ada4-45f1-adcf-ae4d4d608266",[62],[588],{"id":20,"sortIndex":21,"affiliation":589,"properties":20},{"id":590,"createTime":591,"updateTime":591,"relativeEntities":592,"slug":20,"properties":593,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"4f9d164f-9b9b-47e8-8eec-c44705f177cd","2024-01-21T15:11:12.617+00:00",[],{"title":594},{"VI":595},"Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, India",{"title":597},{"VI":598},"Benu Arora",{"id":600,"sortIndex":111,"researcher":20,"roles":601,"affiliations":602,"properties":611},"9d382360-c56b-4b78-a058-8c0ffdcb4db1",[62],[603],{"id":20,"sortIndex":21,"affiliation":604,"properties":20},{"id":605,"createTime":606,"updateTime":606,"relativeEntities":607,"slug":20,"properties":608,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"60f0f54f-42ec-4971-8761-70e8b8c045fa","2023-12-13T10:43:20.841+00:00",[],{"title":609},{"VI":610},"Department of Biochemical Engineering and Biotechnology, Indian Institute of Technology, Delhi Hauz Khas, India",{"title":612},{"VI":613},"Munishwar Nath Gupta",{"id":615,"sortIndex":60,"researcher":20,"roles":616,"affiliations":617,"properties":623},"4e8e3bc4-ee93-4db9-8b3e-fa4f59dd8633",[62],[618],{"id":20,"sortIndex":21,"affiliation":619,"properties":20},{"id":590,"createTime":591,"updateTime":591,"relativeEntities":620,"slug":20,"properties":621,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":622},{"VI":595},{"title":624},{"VI":625},"Joyeeta Mukherjee",{"url":582,"publisher":627,"properties":641},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":628,"slug":10,"properties":629,"entityType":18,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"subjectFields":633,"manageAffiliations":634,"indexDatabases":635,"url":20,"thumbnailPath":20,"statistic":636,"gsStatistic":20,"type":34,"analyzePriority":20},[],{"issn":630,"title":631,"url":632},{"VOID":13},{"EN":15},{"VOID":17},[],[],[],{"impactFactor":21,"impactFactorByYear":637,"i10Index":21,"i10IndexLast5Year":21,"totalPublication":27,"totalPublicationByYear":638,"totalCitation":21,"totalCitationByYear":639,"totalCitationPerPublication":21,"totalCitationPerPublicationByYear":640,"hindexLast5Year":21,"hindex":21},{},{"2013":29,"2014":29,"2015":30,"2016":31},{},{},{"volume":642,"pages":643},{"VOID":140},{"VOID":142},"2014-12-31",{"id":646,"createTime":647,"updateTime":648,"relativeEntities":649,"slug":650,"properties":651,"entityType":54,"verifyStatus":281,"verifyTime":648,"verifyNote":282,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"primaryUrl":660,"fullTextUrl":20,"authors":661,"publicationType":122,"publisherRelationship":731,"citationCount":20,"citationInfo":20,"publishDate":749,"publishYear":144,"citationAnalyzeStatus":19,"lastCitationAnalyze":20,"indexDatabases":20,"openAccess":20,"references":20,"isForceReanalyzing":145},"73a83d87-b550-4f16-91ff-66eb5e7eb5c7","2024-01-09T05:35:30.956+00:00","2024-12-29T21:32:05.595+00:00",[],"GreenCaps-towards-solid-curing-agents-for-sustainable-polyurethane-foams",{"references":652,"abstract":654,"title":656,"doi":658},{"VOID":653},"Sonnenschein MF, Koonce W: Polyurethanes. Encyclopedia of Polymer Science and Technology. 2011, Wiley, New York\nConsultants IAL: Global Overview of the Spray Polyurethane Foam (SPF) & One Component Foam (OCF). 2014, IAL Consultants, London, 4\nAshida K: Polyurethane and Related Foams: Chemistry and Technology. 2007, CRC Press, Boca Raton, FL\nMeckel-Jonas C: (Henkel), Polyurethane Laminating Adhesives and Food Safety: A Smart Alliance. 2009, TAPPI Flexible Packaging Symposium India, New Delhi\nUS Environmental Protection Agency: Methylene Diphenyl Diisocyanate (MDI) and Related Compounds Action Plan Summary; 2013. Available at the URL: , [http:\u002F\u002Fwww.epa.gov\u002Foppt\u002Fexistingchemicals\u002Fpubs\u002Factionplans\u002Fmdi.html]\nCiriminna R, Loddo V, Alterman A, de Schrijver A, Pagliaro M: Enhanced one component spray polyurethane foams via sol-gel microspheres doped with aqueous glycerol. ACS Sustainable Chem Engineer. 2014, 2: 506-511. 10.1021\u002Fsc400431x.\nCiriminna R, Della Pina C, Rossi M, Pagliaro M: Understanding the Glycerol Market. Eur J Lipid Sci Technol. 2014, 116: 1432-1439. 10.1002\u002Fejlt.201400229.\nTadros TF: Applied Surfactants: Principles and Applications. 2005, Wiley-VCH, Weinheim\nPagliaro M, Sciortino M, Ciriminna R, Alonzo G, De Schrijver A: From molecules to systems: sol-gel microencapsulation in silica-based materials. Chem Rev. 2011, 111: 765-789. 10.1021\u002Fcr100161x.\nPagliaro M, Sciortino M, Ciriminna R, Alonzo G, De Schrijver A: Chem Rev. 2011, 111: 765-789. 10.1021\u002Fcr100161x.",{"EN":655},"Testing and further investigation of organosilica microspheres functionalized with aqueous glycerol as solid curing agents for polyurethane (PU) foams confirms the potential of these materials to cure better and greener PU foams. The developed microspheres were found to be stable in the foam precursor mixture, allowing handling and mixing of the foam cans, and were shown to provide a slight improvement of the curing speed. The foams obtained from the froth containing the microspheres were found to maintain the level of quality of reference foam samples. Termed “GreenCaps”, these microspheres will subsequently be tested in pre-commercial applications.",{"EN":657},"GreenCaps: towards solid curing agents for sustainable polyurethane foams",{"VOID":659},"10.1186\u002Fs40508-014-0024-z","https:\u002F\u002Fsustainablechemicalprocesses.springeropen.com\u002Farticles\u002F10.1186\u002Fs40508-014-0024-z",[662,677,692,704,719],{"id":663,"sortIndex":98,"researcher":20,"roles":664,"affiliations":665,"properties":674},"054d23ec-834d-4843-9c07-239c7d85c825",[62],[666],{"id":20,"sortIndex":21,"affiliation":667,"properties":20},{"id":668,"createTime":669,"updateTime":669,"relativeEntities":670,"slug":20,"properties":671,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"d4a51124-ad72-4586-af72-5e37c77c676a","2024-01-09T05:35:31.018+00:00",[],{"title":672},{"VI":673},"Istituto per lo Studio dei Materiali Nanostrutturati, CNR, Palermo, Italy",{"title":675},{"VI":676},"Mario Pagliaro",{"id":678,"sortIndex":111,"researcher":20,"roles":679,"affiliations":680,"properties":689},"87f0e40f-1308-4155-ba52-3a943f469e76",[62],[681],{"id":20,"sortIndex":21,"affiliation":682,"properties":20},{"id":683,"createTime":684,"updateTime":684,"relativeEntities":685,"slug":20,"properties":686,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"251721ba-d635-4b7b-9eed-e7b66a5fb001","2024-01-10T14:22:31.465+00:00",[],{"title":687},{"VI":688},"Centro de Recursos Naturais e Ambiente (CERENA), Instituto Superior Técnico, Universidade de Lisboa, Lisbon, Portugal",{"title":690},{"VI":691},"João C Bordado",{"id":693,"sortIndex":21,"researcher":20,"roles":694,"affiliations":695,"properties":701},"7c7be701-cb8b-4894-b7b7-7c907f9c2dc0",[62],[696],{"id":20,"sortIndex":21,"affiliation":697,"properties":20},{"id":668,"createTime":669,"updateTime":669,"relativeEntities":698,"slug":20,"properties":699,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":700},{"VI":673},{"title":702},{"VI":703},"Rosaria Ciriminna",{"id":705,"sortIndex":85,"researcher":20,"roles":706,"affiliations":707,"properties":716},"c324a989-88c9-49f0-a16b-4762253f1533",[62],[708],{"id":20,"sortIndex":21,"affiliation":709,"properties":20},{"id":710,"createTime":711,"updateTime":711,"relativeEntities":712,"slug":20,"properties":713,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"691815e6-4f52-4f20-8d1c-517d084380b0","2024-01-09T05:35:31.007+00:00",[],{"title":714},{"VI":715},"Greenseal Chemicals NV, Port of Ghent, Ghent, Belgium",{"title":717},{"VI":718},"Aster de Schrijver",{"id":720,"sortIndex":60,"researcher":20,"roles":721,"affiliations":722,"properties":728},"27309300-c920-44cb-8ea9-616ce9503e65",[62],[723],{"id":20,"sortIndex":21,"affiliation":724,"properties":20},{"id":683,"createTime":684,"updateTime":684,"relativeEntities":725,"slug":20,"properties":726,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":727},{"VI":688},{"title":729},{"VI":730},"Ana C Marques",{"url":660,"publisher":732,"properties":746},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":733,"slug":10,"properties":734,"entityType":18,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"subjectFields":738,"manageAffiliations":739,"indexDatabases":740,"url":20,"thumbnailPath":20,"statistic":741,"gsStatistic":20,"type":34,"analyzePriority":20},[],{"issn":735,"title":736,"url":737},{"VOID":13},{"EN":15},{"VOID":17},[],[],[],{"impactFactor":21,"impactFactorByYear":742,"i10Index":21,"i10IndexLast5Year":21,"totalPublication":27,"totalPublicationByYear":743,"totalCitation":21,"totalCitationByYear":744,"totalCitationPerPublication":21,"totalCitationPerPublicationByYear":745,"hindexLast5Year":21,"hindex":21},{},{"2013":29,"2014":29,"2015":30,"2016":31},{},{},{"volume":747,"pages":748},{"VOID":140},{"VOID":264},"2014-11-22",{"id":751,"createTime":752,"updateTime":752,"relativeEntities":753,"slug":20,"properties":754,"entityType":54,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"primaryUrl":763,"fullTextUrl":20,"authors":764,"publicationType":122,"publisherRelationship":831,"citationCount":20,"citationInfo":20,"publishDate":849,"publishYear":482,"citationAnalyzeStatus":19,"lastCitationAnalyze":20,"indexDatabases":20,"openAccess":20,"references":20,"isForceReanalyzing":145},"45caae9e-1664-4ea5-bee1-daaf37efeb25","2023-12-11T21:30:52.769+00:00",[],{"references":755,"abstract":757,"title":759,"doi":761},{"VOID":756},"Pulz O: Photobioreactors: production systems for phototrophic microorganisms. Appl Microbiol Biotechnol. 2001, 57: 287-293. 10.1007\u002Fs002530100702.\nPutz O, Gross W: Valuable products from biotechnology of microalgae. Appl Microbiol Biotechnol. 2004, 65: 635-648. 10.1007\u002Fs00253-004-1647-x.\nBelnap J, Lange OL: Biological Soil Crusts: Structure, Function and Management. 2001, Berlin Heidelberg: Springer\nRascher U, Lakatos M, Büdel B, Lüttge U: Photosynthetic field capacity of cyanobacteria of a tropical inselberg of the guiana highlands. Eur J Phycol. 2003, 38: 247-256. 10.1080\u002F0967026031000121679.\nBoyd MR, Gustafson KR, McMahon JB, Shoemaker RH, O´Keefe BR, Mori T, Gulakowski RJ, Wu L, Rivera MI, Laurencot CM, Currens MJ, Cardellina JH, Buckheit RW, Nara PL, Pannel LK, Sowder RC, Hender LE: Discovery of cyanovirin-N, a novel human immunodeficiency virus-inactivating protein that binds viral surface envelope glycoprotein gp120: potential applications to microbicide development. Antimicrob Agents Chemother. 1997, 41: 1521-1530.\nBewley CA, Gustafson KR, Boyd MR, Covell DG, Bax A, Clore GM, Gronenborn AM: Solution structure of cyanovirin-N, a potent HIV-inactivating protein. Nat Struct Biol. 1998, 5: 571-578. 10.1038\u002F828.\nMuller-Feuga A, Moal J, Kaas R: The microalgae for aquaculture. Life feeds in marine aquaculture. Edited by: Stottrup JG, McEvoy LA. 2003, Oxford: Blackwell\nKrinsky NI: Carotenoid protection against oxidation. Pure Appl Chem. 1979, 51: 649-660. 10.1351\u002Fpac197951030649.\nPalozza P, Krinsky NI: Antioxidant effects of carotenoids in vivo and in vitro: an overview. Methods Enzymol. 1992, 213: 403-419.\nHeinrich U, Tronnier H: Systemische Fotoprotektion durch Carotinoide. Zeitschrift für Phytotherapie. 2010, 31: 185-187. 10.1055\u002Fs-0030-1262393.\nLakatos M, Bilger W, Büdel B: Carotenoid composition of terrestrial cyanobacteria: response to natural light conditions in habitats in Venezuela. Eur J Phycol. 2001, 36: 367-375.\nLüttge U, Kluge M, Bauer G: Botanik. 2005, Darmstadt: Wiley-VCH\nBrougham RW: The Relationship between the Critical Leaf Area, Total Chlorophyll Content, and Maximum Growth-rate of some Pasture and Crop Plants. Ann Bot. 1960, 96: 463-474.\nEppley RW, Sloan PR: Growth Rates of Marine Phytoplankton - Correlation with Light Absorption by Cell Chlorophyll Alpha. Physiol Plant. 1966, 19 (1): 47-10.1111\u002Fj.1399-3054.1966.tb09073.x.\nBilger W, Bohuschke M, Ehling-Schulz M: Annual time courses of the contents of carotenoids and uv-protective pigments in the cyanobacterium nostoc commune. J. Cramer in Der Gebrueder Borntraeger Verlagsbuchhandlung. 1997, Berlin, Germany: E. Schweizerbart'sche Verlagsbuchhandlung: Stuttgart, Germany\nBrock TD: Life at high temperatures. Science. 1967, 158: 1012-1018. 10.1126\u002Fscience.158.3804.1012.\nPotts M: Desiccation Tolerance of Prokaryotes. Microbiol Rev. 1994, 58: 755-805.\nVincent WF, Downes MT, Castenholz RW, Howard-Williams C: Community structure and pigment organisation of cyanobacteria dominated microbial mats in Antarctica. Eur J Phycol. 1993, 28: 213-221. 10.1080\u002F09670269300650321.\nLeisner JMR, Bilger W, Czygan FC, Lange OL: Lipophilous carotenoids of cyanobacterial lichens from different habitats, including an extreme desert site. Cryptogamic Botany. 1993, 4: 74-82.\nDavis R, Aden A, Pienkos PT: Techno-economic analysis of autotrophic microalgae for fuel production. Appl Energ. 2011, 88 (10): 3524-3531. 10.1016\u002Fj.apenergy.2011.04.018.\nNorsker NH, Barbosa MJ, Vermuë MH, Wijffels RH: Microalgal production — A close look at the economics. Biotechnol Adv. 2011, 29 (1): 24-27.\nKieseler S, Neubauer Y, Zobel N: Ultimate and Proximate Correlations for Estimating the Higher Heating Value of Hydrothermal Solids. Energy Fuel. 2013, 27 (2): 908-918. 10.1021\u002Fef301752d.\nKrause GH, Weis E: Chlorophyll fluorescence and photosynthesis: The basis. Ann Rev Plant Physiol Plant Mol Biol. 1991, 42: 313-349. 10.1146\u002Fannurev.pp.42.060191.001525.\nBilger W, Schreiber U, Bock M: Determination of the quantum efficiency of photosystem II and of non-photochemical quenching of chlorophyll a fluorescence in the field. Oecologia. 1995, 102: 425-432. 10.1007\u002FBF00341354.",{"EN":758},"Terrestrial cyanobacteria have seldom been used for biotechnological processes, even though they offer great potential for new pharmaceutical products or other value-added substances. Particularly cyanobacteria of xeric habitats are of biotechnological interest, because they tolerate high temperatures, are desiccation-tolerant and feature low water consumption. In addition, the cyanobacteria collected in deserts are able to produce more photoprotective agents than their counterparts from other habitats, because of their genetical preadaptation. In this study, carotenoid and chlorophyll content of two representative terrestrial cyanobacteria strains, i.e. Nostoc muscorum and Leptolyngbya spec. sampled in Columbia (USA) and Soebatsfontein (RSA), were studied after exposure of the strains to different light conditions and cultivation temperatures. A temperature raise from 17°C to 30°C led to an increase of 46% in chlorophyll a content as well as an increase of 39% in carotenoid content of Nostoc muscorum. An irradiation raise from 19 μmol m-2s-1 to 125 μmol m-2s-1 resulted in an increase of a 10 to 20 times higher chlorophyll content. Additional results from light-curves support the potential future use of terrestrial cyanobacteria within low energy biotechnological processes using a novel type of photobioreactor to reduce the downstream process costs and nutrients needed during the cultivation. Results indicate that especially light intensity optimization currently holds unused potential.",{"EN":760},"Characterization of terrestrial cyanobacteria to increase process efficiency in low energy consuming production processes",{"VOID":762},"10.1186\u002F2043-7129-1-6","http:\u002F\u002Fsustainablechemicalprocesses.springeropen.com\u002Farticles\u002F10.1186\u002F2043-7129-1-6",[765,780,795,807,819],{"id":766,"sortIndex":98,"researcher":20,"roles":767,"affiliations":768,"properties":777},"77d0b9eb-ed0d-4ec3-a0b4-10dc5e99dfbb",[62],[769],{"id":20,"sortIndex":21,"affiliation":770,"properties":20},{"id":771,"createTime":772,"updateTime":772,"relativeEntities":773,"slug":20,"properties":774,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"3c1832bb-c49a-4c23-a520-af30d7c654fb","2023-12-11T12:16:05.576+00:00",[],{"title":775},{"VI":776},"Institute of Bioprocess Engineering, University of Kaiserslautern, Kaiserslautern, Germany",{"title":778},{"VI":779},"Roland Ulber",{"id":781,"sortIndex":111,"researcher":20,"roles":782,"affiliations":783,"properties":792},"edc12f8d-fe2c-4bfb-9187-88ccee13562c",[62],[784],{"id":20,"sortIndex":21,"affiliation":785,"properties":20},{"id":786,"createTime":787,"updateTime":787,"relativeEntities":788,"slug":20,"properties":789,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"1907594c-3b16-4341-bf88-b1e81f0d1207","2023-12-11T21:30:52.805+00:00",[],{"title":790},{"VI":791},"Experimental Ecology, University of Kaiserslautern, Kaiserslautern, Germany",{"title":793},{"VI":794},"Sarah Foltz",{"id":796,"sortIndex":60,"researcher":20,"roles":797,"affiliations":798,"properties":804},"0ce2ca18-b3eb-4f0e-9275-be5fd0faa5fa",[62],[799],{"id":20,"sortIndex":21,"affiliation":800,"properties":20},{"id":786,"createTime":787,"updateTime":787,"relativeEntities":801,"slug":20,"properties":802,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":803},{"VI":791},{"title":805},{"VI":806},"Michael Lakatos",{"id":808,"sortIndex":85,"researcher":20,"roles":809,"affiliations":810,"properties":816},"7b098123-f6aa-44cd-bbda-0b5a7f8e6a58",[62],[811],{"id":20,"sortIndex":21,"affiliation":812,"properties":20},{"id":771,"createTime":772,"updateTime":772,"relativeEntities":813,"slug":20,"properties":814,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":815},{"VI":776},{"title":817},{"VI":818},"Kai Muffler",{"id":820,"sortIndex":21,"researcher":20,"roles":821,"affiliations":822,"properties":828},"fa68472d-4278-4e38-b502-0b18816a264c",[62],[823],{"id":20,"sortIndex":21,"affiliation":824,"properties":20},{"id":771,"createTime":772,"updateTime":772,"relativeEntities":825,"slug":20,"properties":826,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":827},{"VI":776},{"title":829},{"VI":830},"Stephan Kuhne",{"url":763,"publisher":832,"properties":846},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":833,"slug":10,"properties":834,"entityType":18,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"subjectFields":838,"manageAffiliations":839,"indexDatabases":840,"url":20,"thumbnailPath":20,"statistic":841,"gsStatistic":20,"type":34,"analyzePriority":20},[],{"issn":835,"title":836,"url":837},{"VOID":13},{"EN":15},{"VOID":17},[],[],[],{"impactFactor":21,"impactFactorByYear":842,"i10Index":21,"i10IndexLast5Year":21,"totalPublication":27,"totalPublicationByYear":843,"totalCitation":21,"totalCitationByYear":844,"totalCitationPerPublication":21,"totalCitationPerPublicationByYear":845,"hindexLast5Year":21,"hindex":21},{},{"2013":29,"2014":29,"2015":30,"2016":31},{},{},{"volume":847,"pages":848},{"VOID":478},{"VOID":264},"2013-06-12",{"id":851,"createTime":852,"updateTime":853,"relativeEntities":854,"slug":855,"properties":856,"entityType":54,"verifyStatus":281,"verifyTime":853,"verifyNote":282,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"primaryUrl":865,"fullTextUrl":20,"authors":866,"publicationType":122,"publisherRelationship":930,"citationCount":20,"citationInfo":20,"publishDate":949,"publishYear":482,"citationAnalyzeStatus":19,"lastCitationAnalyze":20,"indexDatabases":20,"openAccess":20,"references":20,"isForceReanalyzing":145},"025197ee-0bc6-4477-b078-b209b410e8a4","2024-01-25T04:59:19.332+00:00","2025-02-18T21:08:38.335+00:00",[],"Recent-advances-in-application-of-chitosan-in-fuel-cells",{"references":857,"abstract":859,"title":861,"doi":863},{"VOID":858},"Berenjian A, Chan N, Jafarizadeh Malmiri H: Volatile organic compounds removal methods: A review. 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Trends Biotechnol. 2004, 22: 99-100.\nMinteer SD, Liaw BY, Cooney MJ: Enzyme-based biofuel cells. Curr Opin Biotechnol. 2007, 18: 228-234.\nBarton SC, Gallaway J, Atanassov P: Enzymatic biofuel cells for implantable and microscale devices. Chem Rev. 2004, 104: 4867-4886.\nKim J, Jia H, Wang P: Challenges in biocatalysis for enzymebased biofuel cells. Biotechnol Adv. 2006, 24: 296-308.\nKatz E, Lioubashevski O, Willner I: Magnetic field effects on bioelectrocatalytic reactions of surface-confined enzyme systems: enhanced performance of biofuel cells. J Am Chem Soc. 2005, 127: 3979-3988.\nArning MD, Treu BL, Minteer SD: Citric acid cycle biomimic in an ammonium salt modified nafion membrane for fuel cell applications. Polym Mater Sci Eng. 2004, 90: 566-569.\nBeilke MC, Minteer SD: Immobilization of glycolysis enzymes in hydrophobically modified Nafion. Polym Mater Sci Eng. 2006, 94: 556-557.\nAranaz I, Harris R, Heras A: Chitosan amphiphilic derivatives, chemistry and applications. Curr Org Chem. 2010, 14: 308-330.\nScott K, Yu EH, Ghangrekar MM, Erable B, Duteanu NM: Biological and microbial fuel cells. Compr Renew Energy. 2012, 4: 277-300.\nVirdis B, Freguia S, Rozendal RA, Rabaey K, Yuan Z, Keller J: Microbial fuel cells. Treatise Water Sci. 2011, 4: 641-665.\nMoon H, Chang IS, Kim BH: Continuous electricity production from artificial wastewater using a mediator-less microbial fuel cell. Bioresource Tech. 2005, 97: 621-627.\nKim BH, Chang IS, Gil GC, Park HS, Kim HJ: Novel BOD sensor using mediator-less microbial fuel cell. Biotechnol Lett. 2003, 25: 541-545.\nBond DR, Lovely DR: Evidence for involvement of an electron shuttle in electricity generation by Geothrix fermentans. Appl Environ Microbiol. 2005, 71: 2186-2189.\nDavis F, Higso SPJ: Biofuel cells-Recent advances and applications. Biosens Bioelectron. 2007, 22: 1224-1235.\nGülzow E: Alkaline fuel cells: a critical view. J Power Sources. 1996, 61: 99-104.\nZaidi SMJ: PhD Thesis. Development of proton conducting composite membranes for fuel cell applications. 2000, Laval University\nSouzy R, Ameduri B: Functional fluoropolymers for fuel cell membranes. Prog Polym Sci. 2005, 30: 644-687.\nSouzy R, Ameduri B, Boutevin B: Functional fluoropolymers for fuel cell membranes. Prog Polym Sci. 2004, 29: 75-106.\nFeichtinger J, Galm R, Walker M, Baumgartner KM, Schulz A, Rauchle E, Schumacher U: Plasma polymerized barrier films on membranes for direct methanol fuel cells. Surf Coat Technol. 2001, 142–144: 181-186.\nLi L, Zhang J, Wang Y: Sulfonated poly (ether ether ketone) membranes for direct methanol fuel cell. J Membr Sci. 2003, 226: 159-167.\nJung DH, Cho SY, Peck DH, Shin DR, Kim JS: Performance evaluation of a Nafion\u002Fsilicon oxide hybrid membrane for direct methanol fuel cell. J Power Sources. 2002, 106: 173-177.\nYoon SR, Hwang GH, Cho WI, Oh IH, Hong SA, Ha HY: Modification of polymer electrolyte membranes for DMFCs using Pd films formed by sputtering. J Power Sources. 2001, 106: 215-223.\nMa ZQ, Cheng P, Zhao TS: A palladium-alloy deposited Nafion membrane for direct methanol fuel cells. J Membr Sci. 2003, 215: 327-336.\nChoi WC, Kim JD, Woo SI: Modification of proton conducting membrane for reducing methanol crossover in a direct-methanol fuel cell. J Power Sources. 2001, 96: 411-414.\nKim YS, Hickner MA, Dong L, Pivovar BS, McGrath JE: Sulfonated poly(arylene ether sulfone) copolymer proton exchange membranes: Composition and morphology effects on the methanol permeability. J Membr Sci. 2004, 243: 317-326.\nJung DH, Cho SY, Peck DH, Shin DR, Kim JS: Preparation and performance of a Nafion®\u002Fmontmorillonite nanocomposite membrane for direct methanol fuel cell. J Power Sources. 2003, 118: 205-211.\nSmit EA, Ocampo AL, Espinosa-Medina MA, Sebastian PJ: A modified Nafion membrane with in situ polymerized polypyrrole for the direct methanol fuel cell. J Power Sources. 2003, 124: 59-64.\nShao ZG, Wang X, Hsing IM: Composite Nafion\u002Fpolyvinyl alcohol membranes for the direct methanol fuel cell. J Membr Sci. 2002, 210: 147-153.\nZhou X, Weston J, Chalkova E, Hofmann MA, Ambler CM, Allcock HR, Lvov SN: High temperature transport properties of polyphosphazene membranes for direct methanol fuel cells. Electrochim Acta. 2003, 48: 2173-2180.\nGuo Q, Pintauro PN, Tang H, O’Connor S: Sulfonated and crosslinked polyphosphazene-based proton-exchange membranes. J Membr Sci. 1999, 154: 175-181.\nArico AS, Baglio V, Blasi AD, Creti P, Antonucci PL, Antonucci V: Influence of the acid–base characteristics of inorganic fillers on the high temperature performance of composite membranes in direct methanol fuel cells. Solid State Ion. 2003, 161: 251-265.\nAntonucci PL, Arico AS, Creti P, Ramunni E, Antonucci V: Investigation of a direct methanol fuel cell based on a composite Nafion-silica electrolyte for high temperature operation. Solid State Ion. 1999, 125: 431-437.\nPivovar BS, Wang Y, Cussler EL: Pervaporation membranes in direct methanol fuel cells. J Membr Sci. 1999, 154: 155-162.\nJones DJ, Rozière J, Marrony M: High temperature DMFC stack operating with non-fluorinated membranes. Fuel Cells Bulletin. 2005\nBauer F, Porada MW: Microstructural characterization of Zr-phosphate-Nafion® membranes for direct methanol fuel cell (DMFC) applications. J Membr Sci. 2004, 233: 141-149.\nNunes SP, Ruffmann B, Rikowski E, Vetter S, Richau K: Inorganic modification of proton conductive polymer membranes for direct methanol fuel cells. J Membr Sci. 2002, 203: 215-225.\nCohen SG, Wolosinski HT, Scheuer PJ: α, β, β-trifluorostyrene and α-chloro-β, β-difluorostyrene. J Am Chem Soc. 1949, 71: 3439-3440.\nLin CW, Thangamuthu R, Yang CJ: Proton-conducting membranes with high selectivity from phosphotungstic acid-doped poly(vinyl alcohol) for DMFC applications. J Membr Sci. 2005, 253: 23-31.\nProber M: The synthesis and polymerization of some fluorinated styrenes. J Am Chem Soc. 1953, 75: 968-973.\nXu W, Liu C, Xue X, Su Y, Lv Y, Xing W, Lu T: New proton exchange membranes based on poly (vinyl alcohol) for DMFCs. Solid State Ion. 2004, 171: 121-127.\nTevlina AS, Ivankin AN, Korshak VV, Baranova NP, Nikitina TS, Rokhlin EM: Copolymerization of a, b, b-trifluorostyrene with some vinyl monomers. Viniti. 1981, 12: 127-181.\nKarthikeyan CS, Nunes SP, Prado LASA, Ponce ML, Silva H, Ruffmann B, Schulte K: Polymer nanocomposite membranes for DMFC application. J Membr Sci. 2005, 254: 139-146.\nPołtarzewski Z, Wieczorek W, Przyłuski J, Antonucci V: Novel proton conducting composite electrolytes for application in methanol fuel cells. Solid State Ion. 1999, 119: 301-304.\nSilva VS, Ruffmann B, Silva H, Gallego YA, Mendes A, Madeira LM, Nunes SP: Proton electrolyte membrane properties and direct methanol fuel cell performance: I. Characterization of hybrid sulfonated poly(ether ether ketone)\u002Fzirconium oxide membranes. J Power Sources. 2005, 140: 34-40.\nWu H, Wang Y, Wang S: A methanol barrier polymer electrolyte membrane in direct methanol fuel cells. J New Mat Electr Sys. 2002, 5: 251-254.\nManea C, Mulder M: New polymeric electrolyte membranes based on proton donorproton acceptor properties for direct methanol fuel cells. Desalination. 2002, 147: 179-l 82.\nWoo Y, Oh SY, Kang YS, Jung B: Synthesis and characterization of sulfonated polyimide membranes for direct methanol fuel cell. J Membr Sci. 2003, 220: 31-45.\nZhang X, Filho LP, Torras C, Valls RG: Experimental and computational study of proton and methanol permeabilities through composite membranes. J Power Sources. 2005, 145: 223-230.\nChakrabarty T, Kumar M, Shahi VK: Chitosan based membranes for separation, pervaporation and fuel cell applications Recent developments. biopolymers. Edited by: Elnashar MM. 2010, India: Sciyo, 201-226.\nYamada M, Honma I: Anhydrous proton conductive membrane consisting of chitosan. Electrochim Acta. 2005, 50: 2837-2841.\nLewandowski A, Skorupska K, Malinska J: Novel poly(vinyl alcohol)– KOH–H2O alkaline polymer electrolyte. Solid State Ion. 2000, 133: 265-271.\nXiong Y, Liu QL, Zhang QG, Zhu AM: Synthesis and characterization of cross-linked quaternized poly(vinyl alcohol)\u002Fchitosan composite anion exchange membranes for fuel cells. J Power Sources. 2008, 183: 447-453.\nWan Y, Creber KAM, Peppley B, Tam Bui V: Ionic conductivity of chitosan membranes. Polymer. 2003, 44: 1057-1065.\nWan Y, Creber KAM, Peppley B, Tam Bui V: Structure and ionic conductivity of a series of di-o-butyrylchitosan membranes. J Appl Polym Sci. 2004, 94: 2309-2323.\nWan Y, Creber KAM, Peppley B, Tam Bui V: Ionic conductivity and related properties of cross-linked chitosan membranes. J Appl Polym Sci. 2003, 89: 306-317.\nWan Y, Creber KAM, Peppley B, Tam Bui V: Synthesis, characterization and ionic conductive properties of phosphorylated chitosan membranes. Macromol Chem Phys. 2003, 204: 850-858.\nWang J, He R, Che Q: Anion exchange membranes based on semi interpenetrating polymer network of quaternized chitosan and polystyrene. J Colloid Interface Sci. 2011, 361: 219-225.\nMukoma P, Jooste BR, Vosloo HCM: Synthesis and characterization of cross-linked chitosan membranes for application as alternative proton exchange membrane materials in fuel cells. J Power Sources. 2004, 136: 16-23.\nDu J, Bai Y, Chu W, Qiao L: The structure and electric characters of proton conducting chitosan membranes with various ammonium salts as complexant. J Polym Sci Part B: Polym Phys. 2010, 48: 880-885.\nNg LS, Mohamad AA: Protonic battery based on a plasticized chitosan–NH4NO3 solid polymer electrolyte. J Power Sources. 2006, 163: 382-385.\nLópez-Chávez E, Oviedo-Roa R, Contreras-Pérez G, Martínez-Magadán JM, Castillo-Alvarado FL: Theoretical studies of ionic conductivity of cross-linked chitosan membranes. Int J Hydrogen Energy. 2010, 35: 12141-12146.\nSmitha B, Sridhar S, Khan AA: Chitosan–poly (vinyl pyrrolidone) blends as membranes for direct methanol fuel cell applications. J Power Sources. 2006, 159: 846-854.\nChoudhury NA, Ma J, Sahai Y, Buchheit RG: High performance polymer chemical hydrogel-based electrode binder materials for direct borohydride fuel cells. J Power Sources. 2011, 196: 5817-5822.\nKlotzbach T, Watt M, Ansari Y, Minteer SD: Effects of hydrophobic modification of chitosan and Nafion on transport properties, ion-exchange capacities, and enzyme immobilization. J Membr Sci. 2006, 282: 276-283.\nKlotzbach TL, Watt M, Ansari Y, Minteer SD: Improving the microenvironment for enzyme immobilization at electrodes by hydrophobically modifying chitosan and Nafion® polymers. J Membr Sci. 2008, 311: 81-88.\nWu B, Zhang Y, Kuang Y, Yu Y, Zhang X, Chen J: Chitosanfunctionalized carbon nanotubes as support for the high dispersion of PtRu nanoparticles and their electrocatalytic oxidation of methanol. Chem Asian J. 2012, 7: 190-195.\nWang D, Lu S, Xiang Y, Jiang SP: Self-assembly of HPW on Pt\u002FC nanoparticles with enhanced electrocatalysis activity for fuel cell applications. Appl Catal B-Environ. 2011, 103: 311-317.\nDeng L, Shang L, Wen D, Zhai J, Dong S: A membraneless biofuel cell powered by ethanol and alcoholic beverage. Biosens Bioelectron. 2010, 26: 70-73.\nFalk B, Garramone S, Shivkumar S: Diffusion coefficient of paracetamol in a chitosan hydrogel. Mater Lett. 2004, 58: 3261-3265.\nLiu Y, Wang M, Zhao F, Xu Z, Dong S: The direct electron transfer of glucose oxidase and glucose biosensor based on carbon nanotubes\u002Fchitosan matrix. Biosens Bioelectron. 2005, 21: 984-988.\nWei X, Cruz J, Gorski W: Integration of enzymes and electrodes: Spectroscopic and electrochemical studies of chitosan enzyme films. Anal Chem. 2002, 74: 5039-5046.\nCooney MJ, Lau C, Windmeisser M, Liaw BY, Klotzbach T, Minteer SD: Design of chitosan gel pore structure: Towards enzyme catalyzed flowthrough electrodes. J Mater Chem. 2008, 18: 667-674.\nHiggins SR, Foerster D, Cheung A, Lau C, Bretschger O, Minteer SD: Fabrication of macroporous chitosan scaffolds doped with carbon nanotubes and their characterization in microbial fuel cell operation. Enzyme Microb Tech. 2011, 48: 458-465.\nHiggins SR, Lau C, Atanassov P, Minteer SD, Cooney MJ: Hybrid biofuel cell: Microbial fuel cell with an enzymatic air-breathing cathode. ACS Catal. 2011, 1: 994-997.\nKaturi K, Luisa Ferrer M, Gutierrez MC, Jimenez R, Monte F, Leech D: Three-dimensional microchanelled electrodes in flow-through configuration for bioanode formation and current generation. Energy Environ Sci. 2011, 4: 4201-4210.\nLiu X, Sun X, Huang Y, Sheng G, Wang S, Yu H: Carbon nanotube\u002F chitosan nanocomposite as a biocompatible biocathode material to enhance the electricity generation of a microbial fuel cell. Energy Environ Sci. 2011, 4: 1422-1427.",{"EN":860},"Fuel cells are electrochemical devices which convert chemical energy into electrical energy. Fuel cells have attracted attention due to their potential as a promising alternative to traditional power sources. More recently, efficient and environmentally benign biopolymer “chitosan” have been extensively investigated as a novel material for its application in fuel cells. This biopolymer can be used in both membrane electrolyte and electrode in various fuel cells such as alkaline polymer electrolyte fuel cells, direct methanol fuel cells and biofuel cells. This review provides an overview of main available fuel cells following by application of chitosan as novel biopolymer in fuel cells technology. Recent achievements are included and recommendations are also given for areas of future research.",{"EN":862},"Recent advances in application of chitosan in fuel cells",{"VOID":864},"10.1186\u002F2043-7129-1-16","https:\u002F\u002Fsustainablechemicalprocesses.springeropen.com\u002Farticles\u002F10.1186\u002F2043-7129-1-16",[867,884,901,913],{"id":868,"sortIndex":21,"researcher":20,"roles":869,"affiliations":870,"properties":881},"04247d85-93ee-4677-96ff-f32e12616a7d",[62],[871],{"id":20,"sortIndex":21,"affiliation":872,"properties":20},{"id":873,"createTime":874,"updateTime":875,"relativeEntities":876,"slug":877,"properties":878,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"5ed467f7-a1e5-4a41-926f-e45f4a626cf9","2024-01-27T02:24:18.522+00:00","2024-10-08T07:43:22.293+00:00",[],"Department-of-Chemical-Engineering-Sahand-University-of-Technology-Tabriz-Iran",{"title":879},{"VI":880},"Department of Chemical Engineering, Sahand University of Technology, Tabriz, Iran",{"title":882},{"VI":883},"Hamideh Vaghari",{"id":885,"sortIndex":111,"researcher":20,"roles":886,"affiliations":887,"properties":898},"89852f70-d76a-48ba-93bd-8462656ebc94",[62],[888],{"id":20,"sortIndex":21,"affiliation":889,"properties":20},{"id":890,"createTime":891,"updateTime":892,"relativeEntities":893,"slug":894,"properties":895,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"b7122d61-5355-4bce-81d8-d37a97752f48","2024-01-12T18:40:43.640+00:00","2025-01-30T08:57:22.876+00:00",[],"School-of-Chemical-and-Biomolecular-Engineering-The-University-of-Sydney-Sydney-Australia",{"title":896},{"VI":897},"School of Chemical and Biomolecular Engineering, The University of Sydney, Sydney, Australia",{"title":899},{"VI":900},"Aydin Berenjian",{"id":902,"sortIndex":60,"researcher":20,"roles":903,"affiliations":904,"properties":910},"71284369-e346-4803-9964-98dfb145019b",[62],[905],{"id":20,"sortIndex":21,"affiliation":906,"properties":20},{"id":873,"createTime":874,"updateTime":875,"relativeEntities":907,"slug":877,"properties":908,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":909},{"VI":880},{"title":911},{"VI":912},"Hoda 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Anarjan",{"url":865,"publisher":931,"properties":945},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":932,"slug":10,"properties":933,"entityType":18,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"subjectFields":937,"manageAffiliations":938,"indexDatabases":939,"url":20,"thumbnailPath":20,"statistic":940,"gsStatistic":20,"type":34,"analyzePriority":20},[],{"issn":934,"title":935,"url":936},{"VOID":13},{"EN":15},{"VOID":17},[],[],[],{"impactFactor":21,"impactFactorByYear":941,"i10Index":21,"i10IndexLast5Year":21,"totalPublication":27,"totalPublicationByYear":942,"totalCitation":21,"totalCitationByYear":943,"totalCitationPerPublication":21,"totalCitationPerPublicationByYear":944,"hindexLast5Year":21,"hindex":21},{},{"2013":29,"2014":29,"2015":30,"2016":31},{},{},{"volume":946,"pages":947},{"VOID":478},{"VOID":948},"1-12","2013-09-11",{"id":951,"createTime":952,"updateTime":953,"relativeEntities":954,"slug":955,"properties":956,"entityType":54,"verifyStatus":281,"verifyTime":953,"verifyNote":282,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"primaryUrl":965,"fullTextUrl":20,"authors":966,"publicationType":122,"publisherRelationship":1026,"citationCount":20,"citationInfo":20,"publishDate":1044,"publishYear":482,"citationAnalyzeStatus":19,"lastCitationAnalyze":20,"indexDatabases":20,"openAccess":20,"references":20,"isForceReanalyzing":145},"84cfa47c-3e9b-40b7-8c7b-d30e9067e07a","2023-12-18T12:07:19.461+00:00","2024-12-20T20:49:07.902+00:00",[],"Thermochemical-processes-for-biofuels-production-from-biomass",{"references":957,"abstract":959,"title":961,"doi":963},{"VOID":958},"Shen 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Fuel Process Technol. 2012, 97: 79-84.\nNeves D, Thunmanb H, Matos A, Tarelhoa L, Gómez-Bareac A: Characterization and prediction of biomass pyrolysis products. Progress Energy Combustion Sci-ence. 2011, 37: 611-630. 10.1016\u002Fj.pecs.2011.01.001.\nMohan D, Pittman CU, Steele PH: Pyrolysis of wood\u002Fbiomass for bio-oil: acritical review. J Energy Fuels. 2006, 20: 848-889. 10.1021\u002Fef0502397.\nGoyal HB, Seal D, Saxena RC: Bio-fuels from thermochemical conversion of renewable resources: a review. Renew Sustain Energy Rev. 2008, 12: 504-517. 10.1016\u002Fj.rser.2006.07.014.\nBasu P: Biomass gasification and pyrolysis: practical design and theory. 2010, Burlington, USA: Elsevier Inc, 1\nHindsgaul C, Schramm J, Gratz L, Henriksen U, Dall Bentzen J: Physical and chemical characterization of particles in producer gas from wood chips. 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J Anal Appl Pyrolysis. 2008, 81: 72-79. 10.1016\u002Fj.jaap.2007.09.002.\nHitchingham Jacqueline R, White Lloyd R: Pretreatment of biomass feed for gasification. 2012, United States Patent Application 2012\u002F0266531 A1\nShigeru M: Surface inspection method and surface inspection apparatus. 2012, : US United States Patent Application 2012\u002F176611 A1\nHogendoorn J, Kersten S, Meesala L, De Miguel F: Process for catalytic hydrotreatment of a pyrolysis oil. 2011, WO Patent Application 2011\u002F064172 A1\nBartek R, Cordle R: Method and apparatus for pyrolysis of a biomass. 2012, WO International Patent Application 2012\u002F012191 A1\nHuang X, Hwang J: Method and apparatus for coproduction of pig iron and high quality syngas. 2012, WO International Patent Application 2012\u002F018394 A3\nAradi AA, Roos JW, Tze-chi: Nanoparticle catalysts and method of using the same for biomass gasification. 2011, : US United States Patent Application 2011\u002F0315931 A1\nKeskinen Kari I, Koskinen, Jukka, Aittamaa, Juhani, Pettersson, Marianne: Method of purifying a gas. 2012, US United States Patent Application 2012\u002F0202897 A1\nXianqi P, Deren S, Chuangzhi W, Xiuli Y, Zhaoqiu Z: Procédé et dispositif pour la gazéification de type à écoulements mélangés d’une biomasse. 2012, US United States Patent Application 2012\u002F159469 A1\nSascha AC, Bradford SF: Method and apparatus for sealing a wellbore. 2013, WO International Patent Application 2012\u002F025767 A3: WO International Patent Application 2012\u002F025767 A3\nPaul S: Procédé et système pour la gazéification et\u002Fou la combustion de biomasse et\u002Fou de charbon avec une séparation de dioxyde de Carbone au moins partielle. 2012, WO International Patent Application 2012\u002F103997 A1\nFoster AA: Production of stable biomass pyrolysis oils using fractional catalytic pyrolysis. 2010, United States Patent Application 2010\u002F0212215 A1\nIgor WF: Equipment and method for generating biofuel based on rapid pyrolysis of biomass. 2011, US United States Patent Application 2011\u002F0219680 A1\nBowie GK MB, Brian GS, Edson NG: Sorption enhanced methanation of biomass. 2013, US United States Patent Application 2013\u002F0017460 A1\nTang H, Zhang Y, Chen Y: Method and apparatus for pyrolysis and gasification of biomass. 2013, US United States Patent Application 2013\u002F0125465 A1\nMerola R: Reactor for pyrolysis of biomass. 2011, WO International Patent Application 2011\u002F034409 A1\nAgblevor F: Production of pyrolysis oil. 2011, WO International Patent Application 2011\u002F103313 A2",{"EN":960},"The contribution of biomass to the world’s energy supply is presently estimated to be around 10% to 14%. The conversion of biomass to biofuels can be achieved primarily via biochemical and thermochemical processes. Recently, the use of thermochemical processes as pyrolysis and gasification has received great attention. The biomass composition and form of process conduction can affect greatly the efficiency of conversion for both gasification and pyrolysis. This review compiles recent thermochemical studies using several kinds of biomass to obtain biofuels and, additionally, it presents a brief description of main gasification and pyrolysis processes employed. Publications in Patent database also were reported and compiled.",{"EN":962},"Thermochemical processes for biofuels production from biomass",{"VOID":964},"10.1186\u002F2043-7129-1-22","https:\u002F\u002Fsustainablechemicalprocesses.springeropen.com\u002Farticles\u002F10.1186\u002F2043-7129-1-22",[967,979,991,1003,1015],{"id":968,"sortIndex":60,"researcher":20,"roles":969,"affiliations":970,"properties":976},"95d3e083-62ac-4793-84e9-d0bffda32326",[62],[971],{"id":20,"sortIndex":21,"affiliation":972,"properties":20},{"id":66,"createTime":67,"updateTime":67,"relativeEntities":973,"slug":20,"properties":974,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":975},{"VI":71},{"title":977},{"VI":978},"Juliana F Soares",{"id":980,"sortIndex":111,"researcher":20,"roles":981,"affiliations":982,"properties":988},"1ca60622-521c-4134-b171-24fcd6e11273",[62],[983],{"id":20,"sortIndex":21,"affiliation":984,"properties":20},{"id":66,"createTime":67,"updateTime":67,"relativeEntities":985,"slug":20,"properties":986,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":987},{"VI":71},{"title":989},{"VI":990},"Chayene G Anchieta",{"id":992,"sortIndex":21,"researcher":20,"roles":993,"affiliations":994,"properties":1000},"8ea10277-3f34-4ebf-a71f-395ecdc5c8d1",[62],[995],{"id":20,"sortIndex":21,"affiliation":996,"properties":20},{"id":66,"createTime":67,"updateTime":67,"relativeEntities":997,"slug":20,"properties":998,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":999},{"VI":71},{"title":1001},{"VI":1002},"Nicholas Canabarro",{"id":1004,"sortIndex":85,"researcher":20,"roles":1005,"affiliations":1006,"properties":1012},"2f0223fd-c50b-42e2-8cf1-93f503624367",[62],[1007],{"id":20,"sortIndex":21,"affiliation":1008,"properties":20},{"id":66,"createTime":67,"updateTime":67,"relativeEntities":1009,"slug":20,"properties":1010,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":1011},{"VI":71},{"title":1013},{"VI":1014},"Camila S Kelling",{"id":1016,"sortIndex":98,"researcher":20,"roles":1017,"affiliations":1018,"properties":1024},"1a9949d7-bff7-48c4-9e15-9bdd48037132",[62],[1019],{"id":20,"sortIndex":21,"affiliation":1020,"properties":20},{"id":66,"createTime":67,"updateTime":67,"relativeEntities":1021,"slug":20,"properties":1022,"entityType":72,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":1023},{"VI":71},{"title":1025},{"VI":108},{"url":965,"publisher":1027,"properties":1041},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":1028,"slug":10,"properties":1029,"entityType":18,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"subjectFields":1033,"manageAffiliations":1034,"indexDatabases":1035,"url":20,"thumbnailPath":20,"statistic":1036,"gsStatistic":20,"type":34,"analyzePriority":20},[],{"issn":1030,"title":1031,"url":1032},{"VOID":13},{"EN":15},{"VOID":17},[],[],[],{"impactFactor":21,"impactFactorByYear":1037,"i10Index":21,"i10IndexLast5Year":21,"totalPublication":27,"totalPublicationByYear":1038,"totalCitation":21,"totalCitationByYear":1039,"totalCitationPerPublication":21,"totalCitationPerPublicationByYear":1040,"hindexLast5Year":21,"hindex":21},{},{"2013":29,"2014":29,"2015":30,"2016":31},{},{},{"volume":1042,"pages":1043},{"VOID":478},{"VOID":480},"2013-11-20"]