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1999, The anti-inflammatory sesquiterpene lactone parthenolide inhibits NF-κB by targeting the IκB kinase complex, J Immunol, 163, 5617, 10.4049\u002Fjimmunol.163.10.5617\nDelhase, 1999, Positive and negative regulation of IκB kinase activity through IKKβ subunit phosphorylation, Science, 284, 309, 10.1126\u002Fscience.284.5412.309\nPasparakis, 2006, Dissection of the NF-kappaB signalling cascade in transgenic and knockout mice, Cell Death Differ, 13, 861, 10.1038\u002Fsj.cdd.4401870\nLiang, 2006, Inhibition of transcription factor NF-κB signaling proteins IKKβ and p65 through specific cysteine residues by epoxyquinone A monomer: Correlation with its anti-cancer cell growth activity, Biochem Pharmacol, 71, 634, 10.1016\u002Fj.bcp.2005.11.013\nSrinivasan, 2009, Structure-activity relationship studies of chalcone leading to 3-hydroxy-4, 3′, 4′, 5′- tetramethoxychalcone and its analogues as potent Nuclear Factor κB inhibitors and their anticancer activities, J Med Chem, 52, 7228, 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Bitter principles of Physalis alkekengi var. franchetii: Structure of physalin A. Tetrahedron Lett 1969; 14: 1083–1086.\nKawai, 1992, Physalins N and O from Physalis alkekengi, Phytochemistry, 31, 4299, 10.1016\u002F0031-9422(92)80462-N\nKawai, 1987, A new physalin from Physalis alkekengi: structure of physalin L., Phytochemistry, 26, 3313, 10.1016\u002FS0031-9422(00)82495-4\nRow, 1980, New physalins from Physalis angulata and Physalis lancifolia. 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Endocrinol., 154, 57, 10.1677\u002Fjoe.0.1540057\nHavlikova, 2002, Sex- and age-related changes in epitestosterone in relation to pregnenolone sulfate and testosterone in normal subjects, J. Clin. Endocrinol. Metab., 87, 2225, 10.1210\u002Fjcem.87.5.8499\nBaulieu, E.E., et al., Steroid Hormone Regulation of the Brain. Pergamon Press ed. Oxford, Wenner-Green Center International Symposium Series. vol. 34, 1981. 3–14.\nKancheva, 2011, Neuroactive steroids in periphery and cerebrospinal fluid, Neuroscience, 191, 22, 10.1016\u002Fj.neuroscience.2011.05.054\nMensah-Nyagan, 1999, Neurosteroids: expression of steroidogenic enzymes and regulation of steroid biosynthesis in the central nervous system, Pharmacol. Rev., 51, 63\nMorfin, 2001, Neurosteroid 7-hydroxylation products in the brain, Int. Rev. Neurobiol., 46, 79, 10.1016\u002FS0074-7742(01)46059-4\nKriz, 2008, Steroid sulfatase and sulfuryl transferase activities in human brain tumors, J. Steroid Biochem. Mol. Biol., 109, 31, 10.1016\u002Fj.jsbmb.2007.12.004\nKriz, 2005, Steroid sulfatase and sulfuryl transferase activity in monkey brain tissue, Steroids, 70, 960, 10.1016\u002Fj.steroids.2005.07.005\nGhosh, 2011, Cellular localization and functional significance of CYP3A4 in the human epileptic brain, Epilepsia, 52, 562, 10.1111\u002Fj.1528-1167.2010.02956.x\nStevens, 2003, Developmental expression of the major human hepatic CYP3A enzymes, J. Pharmacol. Exp. Ther., 307, 573, 10.1124\u002Fjpet.103.054841\nMiller, 2004, Stereo- and regioselectivity account for the diversity of dehydroepiandrosterone (DHEA) metabolites produced by liver microsomal cytochromes P450, Drug Metab. Dispos., 32, 305, 10.1124\u002Fdmd.32.3.305\nReddy, 2003, Pharmacology of endogenous neuroactive steroids, Crit. Rev. Neurobiol., 15, 197, 10.1615\u002FCritRevNeurobiol.v15.i34.20\nVyklicky, 2015, Block of NMDA receptor channels by endogenous neurosteroids: implications for the agonist induced conformational states of the channel vestibule, Sci. Rep., 5, 10935, 10.1038\u002Fsrep10935\nSun, 2007, Neurotransmitter modulation relates with tinnitus signal generation and management, J. Otol., 2, 2\nMarx, 2006, Clozapine markedly elevates pregnenolone in rat hippocampus, cerebral cortex, and serum: candidate mechanism for superior efficacy?, Pharmacol. Biochem. Behav., 84, 598, 10.1016\u002Fj.pbb.2006.07.026\nKancheva, 2010, Peripheral neuroactive steroids may be as good as the steroids in the cerebrospinal fluid for the diagnostics of CNS disturbances, J. Steroid Biochem. Mol. Biol., 119, 35, 10.1016\u002Fj.jsbmb.2009.12.006\nNaylor, 2008, Cerebrospinal fluid dehydroepiandrosterone levels are correlated with brain dehydroepiandrosterone levels, elevated in Alzheimer’s disease, and related to neuropathological disease stage, J. Clin. Endocrinol. Metab., 93, 3173, 10.1210\u002Fjc.2007-1229\nTrygg, 2007, Chemometrics in metabonomics, J. Proteome Res., 6, 469, 10.1021\u002Fpr060594q\nTrygg, 2002, Orthogonal projections to latent structure, J. Chemom., 16, 119, 10.1002\u002Fcem.695\nMadsen, 2010, Chemometrics in metabolomics–a review in human disease diagnosis, Anal. Chim. Acta, 659, 23, 10.1016\u002Fj.aca.2009.11.042\nCzech, 2012, Metabolite profiling of Alzheimer’s disease cerebrospinal fluid, PLoS ONE, 7, e31501, 10.1371\u002Fjournal.pone.0031501\nParizek, 2016, A comprehensive evaluation of steroid metabolism in women with intrahepatic cholestasis of pregnancy, PLoS ONE, 11, e0159203, 10.1371\u002Fjournal.pone.0159203\nHill, 2010, Steroid metabolome in plasma from the umbilical artery, umbilical vein, maternal cubital vein and in amniotic fluid in normal and preterm labor, J. Steroid Biochem. Mol. Biol., 121, 594, 10.1016\u002Fj.jsbmb.2009.10.012\nHill, 2010, Effects of valproate and carbamazepine monotherapy on neuroactive steroids, their precursors and metabolites in adult men with epilepsy, J. Steroid Biochem. Mol. 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Metab., 82, 2396, 10.1210\u002Fjcem.82.8.4160\nBrochu, 1987, Effects of flutamide and aminoglutethimide on plasma 5 alpha-reduced steroid glucuronide concentrations in castrated patients with cancer of the prostate, J. Steroid Biochem., 28, 619, 10.1016\u002F0022-4731(87)90388-8\nTokushige, 2013, Serum metabolomic profile and potential biomarkers for severity of fibrosis in nonalcoholic fatty liver disease, J. Gastroenterol., 48, 1392, 10.1007\u002Fs00535-013-0766-5\nMeng, 1997, Progesterone metabolites and bile acids in serum of patients with intrahepatic cholestasis of pregnancy: effect of ursodeoxycholic acid therapy, Hepatology, 26, 1573, 10.1002\u002Fhep.510260627\nAbu-Hayyeh, 2013, Intrahepatic cholestasis of pregnancy levels of sulfated progesterone metabolites inhibit farnesoid X receptor resulting in a cholestatic phenotype, Hepatology, 57, 716, 10.1002\u002Fhep.26055\nGuennoun, 2015, Progesterone and allopregnanolone in the central nervous system: response to injury and implication for neuroprotection, J. Steroid Biochem. Mol. Biol., 146, 48, 10.1016\u002Fj.jsbmb.2014.09.001\nMelcangi, 2014, Levels and actions of progesterone and its metabolites in the nervous system during physiological and pathological conditions, Prog. 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10.1016\u002FS0015-0282(16)48320-2\nDiani, 1992, Hair growth effects of oral administration of finasteride, a steroid 5a-reductase inhibitor alone and in combination with topical minoxidil in the balding stumptail macaque, J Clin Endocrinol Metab, 74, 45, 10.1210\u002Fjc.74.2.345\nLabrie, 1992, Structure of human type II 5a-reductase gene, Endocrinology, 131, 1571, 10.1210\u002Fen.131.3.1571\nSingh, 1991, Heterosteroids and drug research, Prog Med Chem, 28, 233, 10.1016\u002FS0079-6468(08)70366-7\nLourdusamy, 1997, Synthesis and in vitro study of 17β-[N-ureylene-N,N′-disubstituted]-4-methyl-4-aza-5α-androstan-3-ones as selective inhibitors of type I 5α-reductase, Bioorg Med Chem, 5, 305, 10.1016\u002FS0968-0896(96)00241-6\nStrachan, 1964, Synthesis of 2′-(2,4-dieno[3,2-c]pyrazole, J Med Chem, 7, 355, 10.1021\u002Fjm00333a024\nHirschmann, 1964, Synthesis of pregn-4-eno[3,2-c]pyrazoles related to 9-alpha-fluoro-16-alpha-methylcortisol, J Med Chem, 7, 352, 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