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Stortenbeker and H.-G. Bakhuis Roozeboom: Rec. Trav. Chim. Pays-Bas, 1908, 27, pp. 360–410 (in French).\nH.J. Bakhuis Roozeboom: “Sur le Bromure Butylique Tertiare,” Ber. Deutsch Chem. Ges., 1881, 14, pp. 2396–400 (in French).\nH.S. van Klooster: “Bakhuis Roozeboom and the Phase Rule,” J. Chem. Educ., 1954, 31, 594–97.\nH.J. Bakhuis Roozeboom: “Sur l’Hydrate de l’Acide Sulfureux,” Rec. Trav. Chim. Pays-Bas, 1884, 3, pp. 29–58 (in French).\nH.J. Bakhuis Roozeboom: “Sur l’Hydrate de Chlore,” Rec. Trav. Chim. Pays-Bas, 1884, 3, pp. 59–72 (in French).\nH.J. Bakhuis Roozeboom: “Sur l’Hydrate de Brome,” Rec. Trav. Chim. Pays-Bas, 1884, 3, pp. 73–83 (in French).\nH.J. Bakhuis Roozeboom: “Sur l’Hydrate de Gaz Chlorhydrique,” Rec. Trav. Chim. Pays-Bas, 1884, 3, pp. 84–104 (in French).\nH. Le Châtelier: “Sur la Dissociation de l’Hydrate de Chlore,” Compt. Rendu, 1884, 99, pp. 1074–77 (in French).\nH.J. Bakhuis Roozeboom: “Sur la Dissociation des Hydrates de l’Acide Sulfureux, du Chlore et du Brome,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 65–73 (in French).\nH.J. Bakhuis Roozeboom: “Solubilité de l’Acide Bromhydrique à des Températures et Sour des Pressions Différentes,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 102–07 (in French).\nH.J. Bakhuis Roozeboom: “Dissociation de l’Hydrate HBr.2H2O,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 108–24 (in French).\nJ.D. van der Waals: “Influence de la Température sur la Richese en Gaz d’une Solution et Sur l’Equilibre Entre Solutions Gazeuses et des Hydrates Solides,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 135–38 (in French).\nH.J. Bakhuis Roozeboom: “Dissociation de l’Hydrate HBr.2H2O”, Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 331–46 (in French).\nA. Smits, A. De Beteenkenis, and van J.D. van der Waals Sr.: “Voor de Chemische Wetenshap,” Faraday, 1937, 8, pp. 50–71.\nJ.W. Gibbs: “On the Equilibrium of Heterogeneous Systems, Part I,” Trans. Connecticut Acad. Sci., 1876, 3, pp. 108–248.\nJ.W. Gibbs: “On the Equilibrium of Heterogeneous Systems, Part II,” Trans. Connecticut Acad. Sci., 1878, 3, pp. 343–524.\nP.M. Duhem: “Étude Thermodynamique sur les Travaux de J. W. Gibbs,” Bull. Soc. Mathematiques [2], 1887, 11, pp. 122, 159 (in French).\nH.J. Bakhuis Roozeboom: “Sur les Conditions d’Équilibre de Deux Corps Dans Trois États, Solide, Liquide et Gazeux, d’Après M. v. d. Waals,” Rec. Trav. Chim. Pays-Bas, 1886, 5, pp. 335–50 (in French).\nH.J. Bakhuis Roozeboom: “Sur un Nouvel Hydrate de l’Acide Bromhydrique HBr.H2O,” Rec. Trav. Chim. Pays-Bas, 1886, 5, pp. 363–79 (in French).\nH.J. Bakhuis Roozeboom: “La Dissociation des Composées Liquids et la Loi de MM. Debray et Wiedemann,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 355–60 (in French).\nH.J. Bakhuis Roozeboom: “Dissociation du Composé AzH4Br.3AzH3 à l’État Solide et à l’État Liquide,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 361–78 (in French).\nH.J. Bakhuis Roozeboom: “Sur les Combinaisons du Bromure d’Ammonium Avec l’Ammoniaque,” Rec. Trav. Chim. Pays-Bas, 1886, 5, pp. 387–92 (in French).\nH.J. Bakhuis Roozeboom: “Solubilité du Chlore Dans l’Oxychlorure de Chrome,” Rec. Trav. Chim. Pays-Bas, 1885, 4, pp. 379–81 (in French).\nH.J. Bakhuis Roozeboom: “Sur les Points Quadruples Dans l’Équilibre d’un Système Formé de Deux Corps,” Rec. Trav. Chim. Pays-Bas, 1886, 5, pp. 393–413 (in French).\nH.J. Bakhuis Roozeboom: “Application de la Formule de M. v. d. Waals Aux Hydrates de SO2, Cl2, Br2, et à la Glace,” Rec. Trav. Chim. Pays-Bas, 1886, 5, pp. 380–86 (in French).\nH.J. Bakhuis Roozeboom: “Sur les Différentes Formes de l’Equilibre Chimique Hétérogène,” Rec. Trav. Chim. Pays-Bas, 1887, 6, pp. 262–303 (in French).\nH.J. Bakhuis Roozeboom: “Erstarrungspunkte der Mischkrystalle Zweier Stoffe. Umwandlungspunkte vei Mischkrystallen,” Zeit. Phys. Chem., 1899, 30, pp. 385–412 (in German).\nH.J. Bakhuis Roozeboom: Heterogene Gleichgewichte vom Standpunkte Phasenlehre (Heterogeneous Equilibrium from the Standpoint of the Phase Rule), Braunsweig volume 1, 1901, volume 2, 1904 (in German).\nH.J. Bakhuis Roozeboom: “Iron and Steel From the Point of View of the Phase Doctrine,” J. Iron Steel Institute, 1900, 2, 311–16. (Also published verbatim in The Metallographist, 1900, 3, pp. 293–300.)\nH. Le Châtelier: “Fer et Acier au Point de Vue de la Doctrine des Phases,” Bull. Soc. Enc. Ind. Nationale, 1900, 6, pp. 661–70 (in French).\nW.C. Roberts-Austen: Procedures of the 4th Report to the Alloys Research Committee of the Institute of Mechanical Engineers, February 1897.\nW.C. Roberts-Austen: Procedures of the 5th Report to the Alloys Research Committee of the Institute of Mechanical Engineers, February 1899.",{"EN":46},"Hendrik-Willem Bakhuis Roozeboom (1854–1907) is well known for his applications of the phase rule to the study of heterogeneous equilibrium and its representation using the projection of the P-T-x space into the P-T and T-x planes. Together with van der Waals, he put Gibbs’ abstract studies of phase equilibrium in a language that any chemist could understand and use. The graphical representation of the phenomena of equilibrium had a profound influence in the study of the phase rule and the variety of its applications. With its help, Bakhuis Roozeboom was able to improve significantly the original phase diagram for the system iron-carbon presented by Roberts-Austen. 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Nishizawa and K. Ishida: “The Co-Cu (Cobalt-Copper) System,” Bull. Alloy Phase Diagrams, 1984, 5(2), pp. 161–65.\nT. Nishizawa and K. Ishida: “The Co-Fe (Cobalt-Iron),” Bull. Alloy Phase Diagrams, 1984, 5(3), pp. 250–59.\nK.C. Hari Kumar and V. Raghavan: “BCC-FCC Equilibrium in Ternary Iron Alloys—III,” J. Alloy Phase Diagrams, 1989, 5(3), pp. 201–20.\nV. Raghavan: “The Co-Cu-Fe (Cobalt-Copper-Iron) System,” Phase Diagrams of Ternary Iron Alloys, Part 6, Ind. Inst. Metals, Calcutta, 1992, pp. 597–99.\nL.J. Swartzendruber: “Cu-Fe (Copper-Iron),” Phase Diagrams of Binary Iron Alloys, ASM International, Materials Park, OH, 1993, pp. 131–37.\nH. Ohtani, H. Suda, and K. Ishida: “Solid\u002FLiquid Equilibria in Fe-Cu Based Ternary Systems,” ISIJ Int., 1997, 37(3), pp. 207–16.\nS. Bein, C. Colinet, and M. Durand-Charre: “CVM Calculation of the Ternary System Co-Cu-Fe,” J. Alloys Compd., 2000, 313, pp. 133–43.\nD.I. Kim and R. Abbaschian: “The Metastable Liquid Miscibility Gap in Cu-Co-Fe Alloys,” J. Phase Equilibria, 2000, 21(1), pp. 25–31.\nD.I. Kim and R. Abbaschian: “The Metastable Liquid Miscibility Gap in Cu-Co-Fe Alloys,” Taehan Kumsok Hakhoechi, 2000, 38(2), pp. 227–33 (in Korean).\nJ. Kubista and J. Vrestal: “Thermodynamics of the Liquid Co-Cu System and Calculation of Phase Diagram,” J. Phase Equilibria, 2000, 21(2), pp. 125–29.\nA. Antoni-Zdziobek and C. Colinet: “CVM Calculations of Phase Equilibria in the Fe-Cu-Co System Including Both Chemical and Magnetic Interactions,” Scand. J. Metall., 2001, 30, pp. 265–72.\nC.P. Wang, X.J. Liu, I. Ohnuma, R. Kainuma, and K. Ishida: “Phase Equilibria in Fe-Cu-X (X: Co, Cr, Si, V) Ternary Systems,” J. 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Petzow: IEEE Trans. Magn., 1992, vol. 28 (5), part 2, pp. 2832–34.\nC.D. Fuerst, F.E. Pinkerton, and J.F. Herbst: J. Appl. Phys., 1994, vol. 76 (10), part 2, pp. 6144–46.\nG.V. Ivanova, G.M. Malkarova, Y.V. Shcherbakova, and Y.V. Belozenov: J. Alloys Compounds, 1995, vol. 224 (1), pp. 29–32.\nZ. Liu and Z. Jin: Z. Metallkd., 1997, vol. 88 (2), pp. 174–77.\nL.F.S. Dumitrescu, M. Hillert, and N. Saunders: J. 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Corenzwit, Beta Wolfram Structure of Compounds between Transition Elements and Al, Ga, Sb, Acta Crystallogr., Vol 2 (No. 9), 1958, p 604\nH. Boller and E. Parthé, On the Possibility of Forming “Pseudosilicides,” Acta Crystallogr., Vol 16, 1963, p 830–833\nH. Boller and H. Nowotny, Crystal-Chemical Investigations in the Systems (Ti, Nb, Ta, Mo, W)-(As, Sb), Monatsh. Chemie., Vol 95, 1964, p 1272–1282 (in German)\nS. Furuseth and A. Kjekshus, On the Arsenides and Antimonides of Niobium, Acta Chem. Scand., Vol 18, 1964, p 1180–1195\nS. Furuseth and A. Kjekshus, The Crystal Structure of NbAs2 and NbSb2, Acta Crystallogr., Vol 18, 1965, p 320–324\nL.F. Myzenkova, V.V. Baron, and Y.M. Savitsky, Constitution Diagram of the Niobium-Antimony System, Russ. Metall., TR: Izv. Akad. Nauk SSSR, Metally, (No. 2), 1966, p 89–91\nF.J. Bachner, J.B. Goodenough, and H.C. Gatos, Superconducting Transition Temperature And Electronic Structure in the Pseudobinaries Nb3Al-Nb3Sn and Nb3Sn-Nb3Sb, J. Phys. 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In contrast to earlier claims for the existence of five binary phases, Nb3Sb, Nb3Sb2, NbSb, Nb5Sb4 (or Nb4Sb3), and NbSb2, the authors observed only three binary compounds: Nb3Sb, Nb5Sb4, and NbSb2. These compounds are essentially line compounds at their stoichiometric composition and without a significant homogeneity region at 600 °C. All compounds are formed by peritectic reactions: L+(Nb)↔Nb3Sb (1750±25 °C, (L℞55 at.% Sb), L+Nb3Sb↔Nb5Sb4 (1320±10 °C, L℞71 at.% Sb), and L+Nb5Sb4↔NbSb2 (1180±10 °C, L℞88 at.% Sb). 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Nozaki, M. Shimoji, and K. Niwa, “Thermodynamic Properties of Silver-Tin and Silver-Antimony Liquid Alloys,”Ber. Bunsenges.,88, 207–214(1966).",{"doi":828},"10.1002\u002Fbbpc.19660700220",{"id":19,"text":830,"url":19,"identifiers":831},"G.R.B. Elliot and J.F. Lemons, “Activities of Molten Tin Alloys from emf Measurements,”J. Electrochem. Soc.,114, 935–937 (1967).",{"doi":832},"10.1149\u002F1.2426782",{"id":19,"text":834,"url":19,"identifiers":835},"K. Itagaki and A. Yazawa, “Measurements of Heats of Mixing in Liquid Silver Binary Alloys,”Nippon Kinzoku Gakkai-Shi, 32, 1294–1300 (1968).",{},{"id":19,"text":837,"url":19,"identifiers":838},"R. Castanet, Y. Claire, and M. Laffitte,J. Chim. Phy.,66, 1276 (1969).",{"doi":839},"10.1051\u002Fjcp\u002F196966s21276",{"id":19,"text":841,"url":19,"identifiers":842},"P.J. Roy Chowdury and A. Ghosh,Metall. Trans.,2, 2171 (1971).",{"doi":843},"10.1007\u002FBF02917546",{"id":19,"text":845,"url":19,"identifiers":846},"C.W. Kubaschewski and C.B. Alcock, “Thermodynamic Prop-erties of Ag+SnAUoys,”J. Chem. Thermodyn.,4, 259–266 (1972).",{"doi":847},"10.1016\u002F0021-9614(72)90065-1",{"id":19,"text":849,"url":19,"identifiers":850},"T. Yamaji and E. Kata, “Mass Spectrometric Study of the Ther-modynamic Properties of the Ag-Sn System,”Metall. Trans.,3, 1002–1004 (1972).",{"doi":851},"10.1007\u002FBF02647679",{"id":19,"text":853,"url":19,"identifiers":854},"R. Hultgren et al.,Selected Values of the Thermodynamic Properties of Binary Alloys, ASM, Metals Park, OH (1973).",{},{"id":19,"text":856,"url":19,"identifiers":857},"R. Boom, “Heat of Solution of Metals in Liquid Tin,”Scr. Metall.,8, 1277–1281 (1974).",{"doi":858},"10.1016\u002F0036-9748(74)90345-7",{"id":19,"text":860,"url":19,"identifiers":861},"K. Okajima and H. Sakao, “TIE Measurements of the Activities of the Silver-Antimony, Silver-Lead and Silver-Tin Molten Alloys,”Trans. Jpn. Inst. 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