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Technol., 101 3242–3245 (2010)\nWen, Z, “New Uses for Crude Glycerin from Biodiesel Production.” eXtension Farm Energy, June 18 (2012). https:\u002F\u002Farticles.extension.org\u002Fpages\u002F29264\u002Fnew-uses-for-crude-glycerin-from-biodiesel-production.\nXiao, Y, Xiao, G, Varma, A, “A Universal Procedure for Crude Glycerol Purification from Different Feedstocks in Biodiesel Production: Experimental and Simulation Study.” Ind. Eng. Chem. Res., 52 14291–14296 (2013)\nNor Hidawati, E, Mimi Sakinah, AM, “Treatment of Glycerin Pitch from Biodiesel Production.” Int. J. Chem. Environ. Eng., 2 (5) 309–313 (2011)\nLeoneti, AB, Aragão-Leoneti, V, de Oliveira, SVWB, “Glycerol as a By-Product of Biodiesel Production in Brazil: Alternatives for the Use of Unrefined Glycerol.” Renew. Energy, 45 138–145 (2012)\nYang, F, Hanna, M, Sun, R, “Value-Added Uses for Crude Glycerol—A Byproduct of Biodiesel Production.” Biotechnol. Biofuels, 5 (13) 1–10 (2012)\nTodorov, N, Todorova, D, “Utilization of PET Wastes and the Side Products of Biodiesel Production.” Int. J. Sci. Res., 6 (11) 31–32 (2017)\nHejna, A, Kosmela, P, Formela, K, Piszczyk, Ł, Haponiuk, J, “Potential Applications of Crude Glycerol in Polymer Technology—Current State and Perspectives.” Renew. Sustain. Energy Rev., 66 449–475 (2016)\nLuo, X, Ge, X, Cui, S, Li, Y, “Value-Added Processing of Crude Glycerol into Chemicals and Polymers.” Bioresour. Technol., 215 144–154 (2016)\nHu, S, Li, Y, “Polyols and Polyurethane Foams from Acid-Catalyzed Biomass Liquefaction by Crude Glycerol: Effects of Crude Glycerol Impurities.” J. Appl. Polym. Sci., 131 40739 (2014). https:\u002F\u002Fdoi.org\u002F10.1002\u002FAPP.40739\nTodorov, N, Radenkov, M, Todorova, D, “Preparation of Unsaturated Polyester Resin by Using Waste Polyethylene Terephthalate and Waste Glycerol.” Annu. Assen Zlatarov Univ., 41 (1) 86–91 (2012)\nTodorov, N, “Utilization of Waste Polyethylene Terephthalate and Crude Glycerol in the Production of Unsaturated Polyesters.” Acad. J. Ind. Technol., 3 (1) 134–140 (2016)\nTodorov, N, “Utilization of Crude Glycerol and Waste Poly(Ethylene Terephthalate) for Production of Unsatured Polyester Resins.” Int. J. Sci. Res. Environ. Sci., 5 (3) 87–89 (2016)\nTodorov, N, Radenkov, M, Todorova, D, “Obtaining and Studies on Polymer Concrete, Containing Unsaturated Polyester Resin, Based on PET Waste and Crude Glycerol.” Acad. J. Manag. Educ., 9 (6) 78–85 (2013)\nTodorov, N, Dzhundzhurova, B, Todorova, D, “Alkyd Resin Obtained from Crude Glycerol and Waste Polyethylene Terephthalate.” Int. J. Appl. Res., 2 (10) 101–103 (2016)\nTodorov, N, Radenkov, M, Todorova, D, “Utilization of Crude Glycerol and Waste Polyethylene Terephthalate for Production of Alkyd Resins.” J. Chem. Technol. Metall., 50 (3) 12–20 (2015)\nTodorov, N, “Preparation and Study of Alkyd Resins Based on Waste Polyethylene Terephthalate and Crude Glycerol.” Sci. Technol., 4 (3) 48–53 (2014)\nValerio, O, Horvath, T, Pond, C, Misra, M, Mohanty, A, “Improved Utilization of Crude Glycerol from Biodiesel Industries: Synthesis and Characterization of Sustainable Biobased Polyesters.” Ind. Crops Products, 78 141–147 (2015)\nTodorov, N, “Surface Coatings Based on Glycerol Phase and Waste Polyethylene Terephthalate.” Bulg. Chem. Commun., 51 107–112 (2019)\nTodorov, N, Georgieva, K, Denev, Y, “Alkyd Resins Based on the Glycerole Phase from the Rapid Oil Biodiesel Production.” Annu. Assen Zlatarov Univ., 47 (1) 50–54 (2018)\nHofland, A, “The Drying of Alkyd Paints.” Prospector Knowledge Center, posted on November 11, 2016. https:\u002F\u002Fknowledge.ulprospector.com\u002F5512\u002Fpc-the-drying-of-alkyd-paints\u002F\nISO 12937:2000: Petroleum Products—Determination of Water—Coulometric Karl Fischer Titration Method (2000)\nISO 3987:2000: Petroleum Products—30 Determination of Sulfated Ash in Lubricating Oil and Additives (2010)\nISO 2464:1973: Crude Glycerol for Industrial Use—Calculation of Matter (Organic) Non Glycerol (MONG) (1973), Revised 2007\nASTM D1544-04: Standard Test Method for Color of Transparent Liquids (Gardner Color Scale) (2018)\nAOCS Official Method Ca5a-40: Free Fatty Acids in Crude and Refined Fats and Oils (2017)\nISO 3961:2013: Animal and Vegetable Fats and Oils—Determination of Iodine Value (2013), Revised 2018\nISO 660:2009: Animal and Vegetable Fats and Oils—Determination of Acid Value and Acidity (2009), Confirmed 2014\nISO 6883:2017: Animal and Vegetable Fats and Oils—Determination of Conventional Mass Per Volume (2017)\nISO 9117-5:2012: Paints and Varnishes—Drying Tests—Part 5: Modified Bandow-Wolff Test (2012)\nASTM D3363-05: Standard Test Method for Film Hardness by Pencil Test (2005), Confirmed 2011\nASTM D3359-17: Standard Test Methods for Rating Adhesion by Tape Test (2017)\nISO 3251:2008: Paints, Varnishes and Plastics—Determination of Non-Volatile-Matter Content (2008)\nISO 2811-1:2016: Paints and Varnishes—Determination of Density—Part 1: Pycnometer Method (2016)\nASTM D 1647-00: Test Methods for Resistance of Dried Films of Varnishes to Water and Alkali (2000)\nIsaac, IO, Ekpa, OD, “Fatty Acid Composition of Cottonseed Oil and Its Application in Production and Evaluation of Biopolymers.” Am. 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Coat., 68 (3) 214–218 (2010)\nZeybek, B, Pekmez, NO, Kilic, E, “Electrochemical Synthesis of Bilayer Coatings of Poly(N-Methylaniline) and Poly(pyrrole) on Mild Steel and Their Corrosion Protection Performances.” Electrochim. Acta, 56 (25) 9277–9286 (2011)\nTuken, T, Tansug, G, Yazici, B, Erbil, M, “Poly(N-Methylpyrrole) and its Copolymer with Pyrrole for Mild Steel Protection.” Surf. Coat. Technol., 202 (1) 146–154 (2007)\nDuran, B, Bereket, G, “Cyclic Voltammetric Synthesis of Poly(N-Methylpyrrole) on Copper and Effects of Polymerization Parameters on Corrosion Performance.” Ind. Eng. Chem. Res., 51 (14) 5246–5255 (2012)\nSarac, AS, Sezgin, S, Ates, M, Turhan, CM, Parlak, EA, Irfanoglu, B, “Electrochemical Impedance Spectroscopy of Poly(N-Methyl Pyrrole) on Carbon Fiber Microelectrodes and Morphology.” Prog. Org. Coat., 62 (3) 331–335 (2008)\nSarac, AS, Sezgin, S, Ates, M, Turhan, CM, “Electrochemical Impedance Spectroscopy and Morphological Analyses of Pyrrole, Phenylpyrrole and Methoxyphenylpyrrole on Carbon Fiber Microelectrodes.” Surf. Coat. Technol., 202 (16) 3997–4005 (2008)\nAtes, M, “A Comparative Study of Redox Parameters and Electrochemical Impedance Spectroscopy of Polycarbazole Derivatives on Carbon Fiber Microelectrode.” Fibers Polym., 11 (8) 1094–1100 (2010)\nChen-Yang, YW, Li, JL, Wu, TL, Wang, WS, Hon, TF, “Electropolymerization and Electrochemical Properties of (N-Hydroxyalkyl)Pyrrole\u002FPyrrole Copolymers.” Electrochim. Acta, 49 (12) 2031–2040 (2004)\nSarac, AS, Dogru, E, Ates, M, Parlak, EA, “Electrochemical Synthesis of N-Methylpyrrole and N-Methylcarbazole Copolymer on Carbon Fiber Microelectrodes, and Their Characterization.” Turk. J. Chem., 30 (4) 401–418 (2006)\nRen, YJ, Zeng, CL, “Effect of Conducting Composite Polypyrrole\u002FPolyaniline Coatings on the Corrosion Resistance of Type 304 Stainless Steel for Bipolar Plates of Proton-Exchange Membrane Fuel Cells.” J. Power Sources, 182 (2) 524–530 (2008)\nEftekhari, A, Nanostructured Conducting Polymers. Wiley, New York, 2010\nMollahosseini, A, Noroozian, E, “Electrodeposition of a Highly Adherent and Thermally Stable Polypyrrole Coating on Steel from Aqueous Polyphosphate Solution.” Synth. Met., 159 (13) 1247–1254 (2009)\nZhu, RL, Li, GX, Zheng, JH, Jiang, JW, Zeng, HB, “Influence of Electrosynthesis Potential on Corrosion Performance of Polypyrrole Coated Stainless Steel and its Mechanism Research.” Surf. Eng., 25 (2) 156–162 (2009)\nPepe, A, Galliano, P, Aparicio, M, Duran, A, Cere, S, “Sol–Gel Coatings on Carbon Steel: Electrochemical Evaluation.” Surf. Coat. Technol., 200 (11) 3486–3491 (2006)\nKoene, L, Hamer, WJ, De Wit, JHW, “Electrochemical Behaviour of Poly(Pyrrole) Coatings on Steel.” J. Appl. Electrochem., 36 (5) 545–556 (2006)\nDuran, B, Turhan, MC, Bereket, G, Sarac, AS, “Electropolymerization, Characterization and Corrosion Performance of Poly(N-Ethylaniline) on Copper.” Electrochim. Acta, 55 (1) 104–112 (2009)\nDuran, B, Bereket, G, Turhan, MC, Virtanen, S, “Poly(N-Methyl Aniline) Thin Films on Copper: Synthesis, Characterization and Corrosion Protection.” Thin Solid Films, 519 (18) 5868–5874 (2011)\nYano, J, Nakatani, K, Harima, Y, Kitani, A, “Bilayer Polymer Coating Containing a Polyaniline for Corrosion Protection of Iron.” Mater. Lett., 61 (7) 1500–1503 (2007)",{"EN":539},"In this study, three sets of different bilayered composite coatings of pyrrole and N-substituted pyrroles were synthesized by a layer-by-layer approach on copper surface and corrosion performances of the synthesized materials were compared. Electrodepositions of poly(N-methylpyrrole), poly(N-phenylpyrrole), and poly(N-methoxyphenylpyrrole) were performed in nonaqueous medium on a poly(pryrrole)-coated copper surface using cyclic voltammetry. The morphologies of the resulting bilayered composite coatings of poly(pyrrole)\u002Fpoly(N-methylpyrrole), poly(pyrrole)\u002Fpoly(N-phenylpyrrole), and poly(pyrrole)\u002Fpoly(N-methoxyphenylpyrrole) were investigated by scanning electron microscopy. Stabilities of a doping-dedoping process of the composites were determined from the cyclic voltammetric study of the bilayer-coated electrodes in a monomer-free solution. Corrosion performances of the bilayer composite-coated and uncoated copper electrodes were investigated in 0.1 M H2SO4 solution using open circuit potential–time (E\n                ocp–t) curves, anodic polarization, and electrochemical impedance spectroscopy. All the investigated bilayered coatings gave significant enhancement in the corrosion resistance of copper, compared to the single poly(pyrrole) coating. Stability and corrosion tests revealed that the composite material poly(pyrrole)\u002Fpoly(N-methoxyphenylpyrrole) exhibited higher electrochemical stability and corrosion resistant behavior than the other bilayered composite coatings.",{"EN":541},"A comparative study on protective properties of electrosynthesized poly(pyrrole)\u002Fpoly(N-methylpyrrole), poly(pyrrole)\u002Fpoly(N-phenylpyrrole), poly(pyrrole)\u002Fpoly(N-methoxyphenylpyrrole) composite coatings",{"VOID":543},"10.1007\u002Fs11998-013-9529-8","https:\u002F\u002Flink.springer.com\u002Farticle\u002F10.1007\u002Fs11998-013-9529-8",[546,561],{"id":547,"sortIndex":182,"researcher":20,"roles":548,"affiliations":549,"properties":558},"703efcda-02ce-4dc9-b114-d5b6d5510b27",[233],[550],{"id":20,"sortIndex":21,"affiliation":551,"properties":20},{"id":552,"createTime":553,"updateTime":553,"relativeEntities":554,"slug":20,"properties":555,"entityType":64,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"67eb5fff-9623-4fc5-be9a-b850f02a6d08","2024-02-09T11:51:11.825+00:00",[],{"title":556},{"VI":557},"Department of Chemistry, Faculty of Science and Letters, Eskişehir Osmangazi University, Eskisehir, Turkey",{"title":559},{"VI":560},"Gözen Bereket",{"id":562,"sortIndex":21,"researcher":20,"roles":563,"affiliations":564,"properties":570},"2c05951a-3ae0-4703-be91-b9e9ac75a091",[233],[565],{"id":20,"sortIndex":21,"affiliation":566,"properties":20},{"id":552,"createTime":553,"updateTime":553,"relativeEntities":567,"slug":20,"properties":568,"entityType":64,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":569},{"VI":557},{"title":571},{"VI":572},"Berrin Duran",{"url":544,"publisher":574,"properties":602},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":575,"slug":10,"properties":576,"entityType":18,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"subjectFields":580,"manageAffiliations":581,"indexDatabases":582,"url":20,"thumbnailPath":20,"statistic":597,"gsStatistic":20,"type":20,"analyzePriority":20},[],{"issn":577,"eissn":578,"title":579},{"VOID":13},{"VOID":15},{"EN":17},[],[],[583,590],{"id":101,"indexDatabase":584,"url":116,"indexYears":20,"academicFieldIds":589,"indexDatabaseRanking":20},{"id":103,"createTime":104,"updateTime":105,"relativeEntities":585,"label":586,"description":587,"key":112,"publicationTags":588,"standard":20},[],{"EN":108,"VI":108},{"VI":110,"EN":111},[114,115],[118,119],{"id":79,"indexDatabase":591,"url":92,"indexYears":93,"academicFieldIds":596,"indexDatabaseRanking":99},{"id":81,"createTime":82,"updateTime":83,"relativeEntities":592,"label":593,"description":594,"key":89,"publicationTags":595,"standard":20},[],{"EN":86,"VI":86},{"EN":86,"VI":88},[91],[95,96,97,98],{"impactFactor":21,"impactFactorByYear":598,"i10Index":134,"i10IndexLast5Year":135,"totalPublication":136,"totalPublicationByYear":599,"totalCitation":161,"totalCitationByYear":600,"totalCitationPerPublication":183,"totalCitationPerPublicationByYear":601,"hindexLast5Year":135,"hindex":135},{"2012":122,"2013":123,"2014":124,"2015":125,"2016":126,"2017":127,"2018":128,"2019":129,"2020":130,"2021":131,"2022":132,"2023":133},{"1997":138,"1998":139,"1999":140,"2000":139,"2001":141,"2002":142,"2003":139,"2004":139,"2005":143,"2006":141,"2007":144,"2008":145,"2009":146,"2010":147,"2011":148,"2012":149,"2013":150,"2014":151,"2015":152,"2016":153,"2017":154,"2018":155,"2019":156,"2020":157,"2021":158,"2022":159,"2023":160,"2024":138},{"2004":163,"2005":164,"2006":165,"2007":166,"2008":167,"2009":151,"2010":168,"2011":169,"2012":170,"2013":171,"2014":172,"2015":173,"2016":174,"2017":175,"2018":176,"2019":177,"2020":178,"2021":179,"2022":180,"2023":181,"2024":182},{"2004":185,"2005":186,"2006":187,"2007":188,"2008":189,"2009":190,"2010":191,"2011":192,"2012":193,"2013":194,"2014":195,"2015":196,"2016":197,"2017":198,"2018":199,"2019":200,"2020":201,"2021":202,"2022":203,"2023":204,"2024":205},{"volume":603,"pages":605},{"VOID":604},"10",{"VOID":606},"897-907","2013-09-27",2013,{"id":610,"createTime":611,"updateTime":612,"relativeEntities":613,"slug":614,"properties":615,"entityType":225,"verifyStatus":226,"verifyTime":612,"verifyNote":227,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21,"primaryUrl":624,"fullTextUrl":20,"authors":625,"publicationType":258,"publisherRelationship":775,"citationCount":20,"citationInfo":20,"publishDate":807,"publishYear":808,"citationAnalyzeStatus":19,"lastCitationAnalyze":20,"indexDatabases":20,"openAccess":20,"references":20,"isForceReanalyzing":295},"d45af7aa-4d2b-4af6-a057-a65203cb5b2e","2023-11-18T11:51:31.293+00:00","2025-01-22T23:56:31.828+00:00",[],"Enhanced-wear-resistance-of-epoxy-coatings-on-steel-using-graphene-oxide",{"references":616,"abstract":618,"title":620,"doi":622},{"VOID":617},"Lan, P, Nunez, EE, Polycarpou, AA, “Advanced Polymeric Coatings and Their Applications: Green Tribology.” In: Encyclopedia of Renewable and Sustainable Materials, pp. 345–358. Elsevier (2020). https:\u002F\u002Fdoi.org\u002F10.1016\u002FB978-0-12-803581-8.11466-3.\nNecolau, MI, Pandele, AM, “Recent Advances in Graphene Oxide-Based Anticorrosive Coatings: An Overview.” Coatings. https:\u002F\u002Fdoi.org\u002F10.3390\u002Fcoatings10121149 (2020)\nShang, H, Shao, S, Wang, W, “Bond Behavior Between Graphene Modified Epoxy Coated Steel Bars and Concrete.” J. Build. Eng., 42 102481 (2021)\nHooda, A, Goyat, MS, Kumar, J, Kumar, A, Gupta, R, “A Review on Fundamentals, Constraints and Fabrication Techniques of Superhydrophobic Coatings.” Prog. Org. Coat., 142 105557 (2020)\nZhao, Y, Wen, J, Peyraut, F, Planche, M, Misra, S, “Porous Architecture and Thermal Properties of Thermal Barrier Coatings Deposited by Suspension Plasma Spray.” Surf. Coat. Technol., 386 125462 (2020)\nKavouras, P, et al. “Correlation of Mechanical Properties with Antifouling Efficacy of Coatings Containing Loaded Microcapsules.” Prog. Org. Coat., 136 105249 (2019)\nHung, Y, Mclandsborough, LA, Goddard, JM, Bastarrachea, LJ, “Antimicrobial Polymer Coatings with Efficacy Against Pathogenic and Spoilage Microorganisms.” LWT Food Sci. Technol., 97 546–554 (2018)\nGu, H, Ma, CGu, J, Guo, J, Yan, X, “An Overview of Multifunctional Epoxy Nanocomposites.” J. Mater. Chem. C, 4 5890–5906 (2016)\nBajat, JB, Dedíc, O, “Adhesion and Corrosion Resistance of Epoxy Primers Used in the Automotive Industry.” J. Adhes. Sci. Technol., 21 819–831 (2007)\nJin, H, et al. “Fracture Behavior of a Self-healing, Toughened Epoxy Adhesive.” Int. J. Adhes. Adhes., 44 157–165 (2013)\nEldesouki, M, Abo-Shanab, ZL, El-Shafie, M, Abo-Riya, M, El-Kholy, SA, “Fabrication and Evaluation of Novel Sulfur\u002FEpoxy Resin Composites.” Polym. Bull. https:\u002F\u002Fdoi.org\u002F10.1007\u002Fs00289-022-04641-0 (2022)\nMi, X, et al. “Toughness and Its Mechanisms in Epoxy Resins.” Prog. Mater. Sci., 130 100977 (2022)\nShokrieh, MM, Ghoreishi, SM, Esmkhani, M, Zhao, Z, “Effects of Graphene Nanoplatelets and Graphene Nanosheets on Fracture Toughness of Epoxy Nanocomposites.” Fatigue Fract. Eng. Mater. Struct., 37 1116–1123 (2014)\nDomun, N, et al. “Improving the Fracture Toughness and the Strength of Epoxy Using Nanomaterials—A Review of the Current Status.” Nanoscale, 7 10294–10329 (2015)\nBaer, DR, Burrows, PE, El-azab, AA, “Enhancing Coating Functionality Using Nanoscience and Nanotechnology.” Prog. Org. Coat., 47 342–356 (2003)\nWetzel, B, Haupert, F, Qiu, M, “Epoxy Nanocomposites with High Mechanical and Tribological Performance.” Compos. Sci. Technol., 63 2055–2067 (2003)\nAli, N, et al. “TiO2 Nanoparticles and Epoxy-TiO2 Nanocomposites: A Review of Synthesis, Modification Strategies, and Photocatalytic Potentialities.” J. Inorg. Organomet. Polym. Mater., 30 4829–4846 (2020)\nZhou, H, et al. “Fabrication of ZnO\u002FEpoxy Resin Superhydrophobic Coating on AZ31 Magnesium Alloy.” Chem. Eng. J., 368 261–272 (2019)\nAlam, MA, et al. “Influence of SiO2 Content and Exposure Periods on the Anticorrosion Behavior of Epoxy Nanocomposite Coatings.” Coatings, 10 1–14 (2020)\nTang, J, et al. “Properties of Graphene Oxide\u002FEpoxy Resin Composites.” J. Nanomater., 2014 175–180 (2014)\nMaestrelli, LMD, et al. “Role of Graphene Oxide on the Mechanical Behaviour of Polycarbonate-Urethane\u002FGraphene Oxide Composites.” Mater. Res., 24 1–14 (2021)\nMuzyka, R, Kwoka, M, Smędowski, Ł, Díez, N, Gryglewicz, G, “Oxidation of Graphite by Different Modified Hummers Methods.” Xinxing Tan Cailiao\u002FNew Carbon Mater., 32 15–20 (2017)\nAl Imran, K, Shivakumar, KN, “Enhancement of Electrical Conductivity and Assessment of Thermal and Mechanical Properties of Graphene\u002FEpoxy Nanocomposites.” In: Proceedings of the American Society for Composites 30th Technical Conference ACS 2015 (2015)\nRibeiro, H, et al. “Glass Transition Improvement in Epoxy\u002FGraphene Composites.” J. Mater. Sci., 48 7883–7892 (2013)\nRibeiro, H, et al. “Multifunctional Nanocomposites Based on Tetraethylenepentamine-Modified Graphene Oxide\u002FEpoxy.” Polym. Test., 43 182–192 (2015)\nYu, W, Sisi, L, Haiyan, Y, Jie, L, “Progress in the Functional Modification of Graphene\u002FGraphene Oxide: A Review.” R. Soc. Chem., 10 15328–15345 (2020)\nLi, Y, et al. “Additive Manufacturing High Performance Graphene-based Composites: A Review.” Compos. Part A Appl. Sci. Manuf., 124 105483 (2019)\nTaheri, NN, Ramezanzadeh, B, Mahdavian, M, “Application of Layer-by-Layer Assembled Graphene Oxide Nanosheets\u002FPolyaniline\u002FZinc Cations for Construction of an Effective Epoxy Coating Anti-corrosion System.” J. Alloys Compd., 800 532–549 (2019)\nZheng, W, et al. “Enhancing Chloride Ion Penetration Resistance Into Concrete by Using Graphene Oxide Reinforced Waterborne Epoxy Coating.” Prog. Org. Coat. 138 105389 (2020)\nHutchings, I, Shipway, P, Tribology - Friction and Wear of Engineering Materials. Elsevier (2017)\nAbdelbary, A, “Polymer Tribology.” In: Wear of Polymers and Composites. Woodhead Publishing. https:\u002F\u002Fdoi.org\u002F10.1533\u002F9781782421788.1 (2014)\nZhai, W, et al. “Recent Progress on Wear-Resistant Materials: Designs, Properties, and Applications.” Adv. Sci., 8 1–29 (2021)\nRamos, JA, Mondragon, I, Candal, R, Goyanes, S, “Influence of Filler Alignment in the Mechanical and Electrical Properties of Carbon Nanotubes\u002FEpoxy Nanocomposites.” Phys. B Condens. Matter, 407 3181–3183 (2012)\nReis, T. M. C. do, Assis, A. L. S., Castro, V. G. de & Silva, G. G. Processo de obtenção de óxido de grafeno e produto. (2020).\nAssis, ALS, et al., Processo de Obtenção de Nanomateriais Concentrados em Polímeros via Moinho de Rolos. vol. 2 (2022)\nMedeiros, FDS, Cury, CS, de Vasconcelos, CK, Silva, GG, “Reduced Graphene Oxide as an Adhesion Enhancer of Fusion-Bonded Epoxy Coatings.” Prog. Org. Coat., 171 107057 (2022)\nASTM International, ASTM D 790:Standard Test Methods for Flexural Properties of Unreinforced and Reinforced Plastics and Electrical Insulating Materials. (2017). Doi: https:\u002F\u002Fdoi.org\u002F10.1520\u002FD0790-17.2.\nBadruddoza, AZ, Chepyala, R, Ashraf, K, “State-of-the-Art Characterization Methods for Graphene and Its Derivatives. In: Biomedical Applications of Graphene and 2D Nanomaterials, pp. 43–86 Elsevier Inc. (2019). Doi: https:\u002F\u002Fdoi.org\u002F10.1016\u002FB978-0-12-815889-0.00003-9\nRomero, A, Valverde, JL, “Comparative Study of Different Scalable Routes to Synthesize Graphene Oxide and Reduced Graphene Oxide.” Mater. Chem. Phys. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.matchemphys.2017.10.013 (2017)\nYuan, Y, Gurunathan, S, “Combination of Graphene Oxide-Silver Nanoparticle Nanocomposites and Cisplatin Enhances Apoptosis and Autophagy in Human Cervical Cancer Cells.” Int. J. Nanomed., 2017 6537–6558 (2017)\nZheng, W, et al. “Enhancing Chloride Ion Penetration Resistance into Concrete by Using Graphene Oxide Reinforced Waterborne Epoxy Coating.” Prog. Org. Coat., 138 105389 (2020)\nViana, MM, et al. “Microwave-Assisted Synthesis of Polyacrylamide-Aminated Graphene Oxide Hybrid Hydrogel with Improved Adsorption Properties.” J. Environ. Chem. Eng., 8 1–8 (2020)\nTang, LC, et al. “The Effect of Graphene Dispersion on the Mechanical Properties of Graphene\u002FEpoxy Composites.” Carbon N. Y., 60 16–27 (2013)\nWan, Y, Tang, L, Gong, L, Yan, D, Li, Y, “Grafting of Epoxy Chains Onto Graphene Oxide for Epoxy Composites with Improved Mechanical and Thermal Properties.” Carbon N. Y., 69 467–480 (2013)\nFraga, F, Vazquez, EC, Rodrígues-Núñez, E, Martínez-Ageitos, JM, “Curing Kinetics of the Epoxy System Diglycidyl Ether of Bisphenol A\u002FIsophoronediamine by Fourier Transform Infrared Spectroscopy.” Polym. Adv. Technol., 19 1623–1628. https:\u002F\u002Fdoi.org\u002F10.1002\u002Fpat (2008)\nWang, Y, Jin, B, Ye, D, Liu, Z, “Fully Recyclable Carbon Fiber Reinforced Vanillin-based Epoxy Vitrimers.” Eur. Polym. J., 162 110927 (2022)\nLi, L, Wu, Q, Li, S, Wu, P, “Study of the Infrared Spectral Features of an Epoxy Curing Mechanism.” Appl. Spectrosc., 62 1129–1136 (2008)\nMo, R, Song, L, Hu, J, Sheng, X, Zhang, X, “An Acid-Degradable Biobased Epoxy-Imine Adaptable Network Polymer for the Fabrication of Responsive Structural Color Film.” Polym. Chem., 11 974–981 (2020)\nLiu, Q, et al. “Mechanical and Thermal Properties of Epoxy Resin Nanocomposites Reinforced with Graphene Oxide Mechanical and Thermal Properties of Epoxy Resin Nanocomposites Reinforced with Graphene Oxide.” Polym. Plast. Technol. Eng., 51 252–256 (2013)\nWang, S, Tambraparni, M, Qiu, J, Tipton, J, Dean, D, “Thermal Expansion of Graphene Composites.” Macromolecules, 42 5251–5255 (2009)\nWolk, A, et al. “Graphene Oxide as Flexibilizer for Epoxy Amine Resins.” Prog. Org. Coat., 122 280–289 (2018)\nVryonis, O, Virtanen, STH, Andritsch, T, Vaughan, AS, Lewin, PL, “Understanding the Cross-Linking Reactions in Highly Oxidized Graphene\u002FEpoxy Nanocomposite Systems.” J. Mater. Sci., 54 3035–3051 (2019)\nPerdigão, NF, Castro, VG, Silva, GG, “Glass Transition Behavior in Epoxy Nanocomposites with Oxidized and Aminated Carbon Nanotubes, Graphene Oxide and Nano-Calcium Carbonate.” Thermochim. Acta, 717, 179331 (2022)\nWang, M, Li, Q, Li, X, Liu, Y, Fan, L, “Effect of Oxygen-Containing Functional Groups in Epoxy\u002FReduced Graphene Oxide Composite Coatings on Corrosion Protection and Antimicrobial Properties.” Appl. Surf. Sci., 448 351–361 (2018)\nHuang, W, \"Graphene Oxide Nanopapers.\" In: Nanopapers: From Nanochemistry and Nanomanufacturing to Advanced Applications. Elsevier Inc. (2018)\nBlanco, C, et al. “Critical Temperatures in the Synthesis of Graphene-like Materials by Thermal Exfoliation—Reduction of Graphite Oxide.” Carbon, 52 (2) 1–10 (2012)\nTegou, E, Pseiropoulos, G, Filippidou, MK, Chatzandroulis, S, “Low-Temperature Thermal Reduction of Graphene Oxide Films in Ambient Atmosphere: Infra-Red Spectroscopic Studies and Gas Sensing Applications.” Microelectron. Eng., 159 146–150 (2016)\nDolbin, AV, et al. “The Effect of the Thermal Reduction Temperature on the Structure and Sorption Capacity of Reduced Graphene Oxide Materials.” Appl. Surf. Sci., 361 213–220 (2016)\nWang, ZG, et al. “The Green Synthesis of Reduced Graphene Oxide by the Ethanol–Thermal Reaction and Its Electrical Properties.” Mater. Lett., 116 416–419 (2014)\nIqbal, A, Saeed, A, Kausar, A, Arshad, M, Mahar, J, “Synthesis and Characterization of DGEBA Composites Reinforced with Cu\u002FAg Modified Carbon Nanotubes.” Heliyon, 5 e01733 (2019)\nDeng, Z, et al. “Study on Light Aging of Anhydride-Cured Epoxy Resin Used for RGB LED Packaging Material.” Polym. Test., 80 106131 (2019)\nJi, Z, et al. “Simultaneous Aging of DGEBA\u002FMeHHPA Epoxy Resin Under Thermal Heating and Gamma Irradiation up to 1000 kGy.” Polym. Degrad. Stab., 199 109908 (2022)\nAmparo, SZSD, et al. “Microwave-Assisted Synthesis of PAM Preformed Particle Gels Reinforced with Carbon Nanomaterials for Conformance Control in Oil Recovery.” Fuel, 330 125650 (2022)\nSäckl, G, et al. “The Interaction of Waterborne Epoxy\u002FDicyandiamide Varnishes with Metal Oxides.” Polymers, 14 2226 (2022)\nNeves, JC, Multifuncionalidade em Compósitos Poliméricos de Nanotubos de Carbono de Paredes Múltiplas em Matriz Epóxi. Universidade Federal de Minas Gerais (2017)\nSchaefer, DW, Justice, RS, “How Nano are Nanocomposites?” Macromolecules, 40 8501–8517 (2007)\nGaleski, A, “Strength and Toughness of Crystalline Polymer Systems.” Prog. Polym. Sci., 28 1643–1699 (2003)\nKim, S, Hong, H, Han, TH, Kim, MO, “Early-Age Tensile Bond Characteristics of Epoxy Coatings for Underwater Applications.” Coatings, 9 1–15 (2019)\nLuévano-Cabrales, OL, et al. “Effect of Graphene Oxide on Wear Resistance of Polyester Resin Electrostatically Deposited on Steel Sheets.” Wear, 426–427 296–301 (2019)",{"EN":619},"Graphene oxide (GO) addition to epoxy can improve various properties provided that the GO features, dispersion and interaction with epoxy are optimized. Herein, the challenge of improving the hydrophobicity, flexural behavior and wear resistance of an epoxy coating on steel substrate was addressed by GO incorporation. Three GO concentrations were tested in the epoxy system (0.1, 0.25, and 0.50% m\u002Fm), and nanocomposites were prepared via roller mill. An increase in the thermal stability of the pure epoxy by 23°C was observed for the nanocomposites as a function of GO incorporation. XPS analyses were carried out to study the interaction between DGEBA and GO, and the results show that a covalent link was formed between GO and epoxy. The wettability test showed an increase of 26° in the contact angle while the behavior of the system from mechanical bending tests showed gains of 52% in the energy to fracture for the sample containing 0.5 wt.% GO with respect to the neat epoxy. The wear of the coatings showed a 31% decrease in the wear coefficient of the nanocomposite compared to the reference. The set of results reported in the present work pointed to the epoxy\u002FGO coating as promising in terms of hydrophobicity and wear properties.",{"EN":621},"Enhanced wear resistance of epoxy coatings on steel using graphene oxide",{"VOID":623},"10.1007\u002Fs11998-023-00811-5","https:\u002F\u002Flink.springer.com\u002F10.1007\u002Fs11998-023-00811-5",[626,656,671,686,701,732,752],{"id":627,"sortIndex":21,"researcher":20,"roles":628,"affiliations":629,"properties":653},"91fe8022-c1ef-4d30-8422-a991c19ab219",[233],[630,643],{"id":631,"sortIndex":21,"affiliation":632,"properties":641},"be150dec-1fd7-46d0-a886-d6954cdedf87",{"id":633,"createTime":634,"updateTime":635,"relativeEntities":636,"slug":637,"properties":638,"entityType":64,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"1f2e0e72-ceb9-4afd-8f1e-76d3f30496f9","2023-11-18T11:51:37.468+00:00","2023-12-22T16:28:10.651+00:00",[],"CTNano-Universidade-Federal-de-Minas-Gerais-Belo-Horizonte-Brazil",{"title":639},{"VI":640},"CTNano, Universidade Federal de Minas Gerais, Belo Horizonte, Brazil",{"title":642},{"VI":640},{"id":20,"sortIndex":21,"affiliation":644,"properties":20},{"id":645,"createTime":646,"updateTime":647,"relativeEntities":648,"slug":649,"properties":650,"entityType":64,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"66deb4a6-b540-40a5-aac7-f69fb22d3856","2023-11-18T11:52:17.720+00:00","2024-04-20T14:01:05.702+00:00",[],"Departamento-de-Qu%C3%ADmica-ICEx-Universidade-Federal-de-Minas-Gerais-Belo-Horizonte-Brazil",{"title":651},{"VI":652},"Departamento de Química-ICEx, Universidade Federal de Minas Gerais, Belo Horizonte, Brazil",{"title":654},{"VI":655},"Sthéfany Z. 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Medeiros",{"id":687,"sortIndex":21,"researcher":20,"roles":688,"affiliations":689,"properties":698},"e47921a1-97ba-44c5-bd01-953424185d91",[233],[690],{"id":691,"sortIndex":21,"affiliation":692,"properties":696},"216c8805-2153-4134-a8ec-9e4918531419",{"id":633,"createTime":634,"updateTime":635,"relativeEntities":693,"slug":637,"properties":694,"entityType":64,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":695},{"VI":640},{"title":697},{"VI":640},{"title":699},{"VI":700},"João L. N. Pereira",{"id":702,"sortIndex":21,"researcher":20,"roles":703,"affiliations":704,"properties":729},"b8e9bccf-05ac-4328-8a0b-a5672d865b0e",[233],[705,713,721],{"id":20,"sortIndex":21,"affiliation":706,"properties":20},{"id":707,"createTime":708,"updateTime":708,"relativeEntities":709,"slug":20,"properties":710,"entityType":64,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"6d8566c6-b7d1-45d1-a2a9-a9d3dccfef7a","2023-12-28T22:33:09.892+00:00",[],{"title":711},{"VI":712},"Departamento de Física e Química, Pontifícia Universidade Católica de Minas Gerais, Belo Horizonte, Brazil",{"id":714,"sortIndex":21,"affiliation":715,"properties":719},"5238540e-d69c-477a-b577-ef8049de3f7e",{"id":633,"createTime":634,"updateTime":635,"relativeEntities":716,"slug":637,"properties":717,"entityType":64,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":718},{"VI":640},{"title":720},{"VI":640},{"id":722,"sortIndex":21,"affiliation":723,"properties":727},"d46bfbcc-3bb2-4cdb-a327-789b3fd886e0",{"id":645,"createTime":646,"updateTime":647,"relativeEntities":724,"slug":649,"properties":725,"entityType":64,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":726},{"VI":652},{"title":728},{"VI":652},{"title":730},{"VI":731},"Claudia K. B. de Vasconcelos",{"id":733,"sortIndex":21,"researcher":20,"roles":734,"affiliations":735,"properties":749},"feefcb47-ddb0-4669-a5e0-4344c22556ce",[233],[736,744],{"id":20,"sortIndex":21,"affiliation":737,"properties":20},{"id":738,"createTime":739,"updateTime":739,"relativeEntities":740,"slug":20,"properties":741,"entityType":64,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"190be340-776c-42e4-b7fe-25810d014317","2024-01-30T16:23:06.528+00:00",[],{"title":742},{"VI":743},"Departamento de Engenharia Química, Universidade Federal de Minas Gerais, Belo Horizonte, Brazil",{"id":20,"sortIndex":21,"affiliation":745,"properties":20},{"id":633,"createTime":634,"updateTime":635,"relativeEntities":746,"slug":637,"properties":747,"entityType":64,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},[],{"title":748},{"VI":640},{"title":750},{"VI":751},"Amanda B. 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Anal. Appl. Pyrolysis, 124 130–148 (2017)\nDemir, H, Arkis, E, Balköse, D, Ülkü, S, “Synergistic Effect of Natural Zeolites on Flame Retardant Additives.” Polym. Degrad. Stab., 89 478–483 (2005)\nDequesne, S, Magnet, S, Jana, C, Delobel, R, “Thermoplastic Resins for Thin Film Intumescent Coatings—Towards a Better Understanding of Their Effect on Intumescence Efficiency.” Polym. Degrad. Stab., 88 63–69 (2005)\nBiswas, B, Kandola, BK, Horrocks, AR, Price, D, “A Quantitative Study of Carbon Monoxide and Carbon Dioxide Evolution During Thermal Degradation of Flame Retarded Epoxy Resins.” Polym. Degrad. Stab., 92 765–776 (2007)\nLi, ZS, Wang, HJ, Zhang, S, “Smoke Density Evaluation of Acrylic Resin and Intumescent Flame Retardant Coatings.” Pigment Resin Technol., 45 86–92 (2016)\nWang, B, Zhang, Y, Tao, YJ, Zhou, Z, Song, L, Jie, G, Hu, Y, “Monitoring the Degradation of Physical Properties and Fire Hazards of High-Impact Polystyrene Composite with Different Ageing Time in Natural Environments.” J. Hazard. Mater., 352 92–100 (2018)\nHassan, MA, Kozlowski, R, Obidzinski, B, Shehata, AB, Abdel Aziz, F, “The Effect of New Flame Retardant Systems Containing Montmorillonite-Butyl Acrylate Nanoclay on the Flammability Properties of Polyurethane Polymer.” Polym. Plast. Technol. Eng., 46 521–527 (2007)\nBourbigot, S, Samyn, F, Turf, T, Duquesne, S, “Nanomorphology and Reaction to Fire of Polyurethane and Polyamide Nanocomposites Containing Flame Retardants.” Polym. Degrad. Stab., 95 320–326 (2010)\nAlongi, J, Han, Z, Bourbigot, S, “Intumescence: Tradition Versus Novelty. A Comprehensive Review.” Prog. Polym. Sci., 51 28–73 (2015)\nChuang, CS, Tsai, KC, Wang, MK, Ko, CH, Shiau, IL, “Impact of the Intumescent Formulation of Styrene Acrylic-Based Coatings on the Fire Performance of Thin Painted Red Lauan (Parashorea spp.) Plywood.” Eur. J. Wood Prod., 67 407–415 (2009)\nGao, M, Sun, CY, Wang, CX, “Thermal Degradation of Wood Treated with Flame Retardants.” J. Therm. Anal. Calorim., 85 765–769 (2006)\nChinese National Standard CNS 6532, Method of Test for the Fire-Resistibility of Internal Decorative Material of Building. National Standard Bureau, Taipei, Taiwan (1993)\nChinese National Standard CNS 14705-1, Method of Test for Heat Release Rate for Building Materials-Part 1: Cone Calorimeter Method. National Standard Bureau, Taipei, Taiwan (2013)\nChuang, CS, Tsai, KC, Yang, TH, Ko, CH, Wang, MK, “Effects of Adding Organo-Clays for Acrylic-Based Intumescent Coating on Fire-Retardancy of Painted Thin Plywood.” Appl. Clay Sci., 53 709–715 (2011)\nRibeiro, SPS, Estevao, LRM, Nascimento, RSV, “Effect of Clay on the Fire Retardant Properties of a Polyethylenic Copolymer Containing Intumescent Formulation.” Sci. Technol. Adv. Mater., 9 1–7 (2008)\nCamino, G, Costa, L, Martinasso, G, “Intumescent Fire-Retardant Systems.” Polym. Degrad. Stab., 23 359–376 (1989)\nPimenta, JT, Concalves, C, Hiliou, L, Coelho, JFJ, Magalhars, FD, “Effect of Binder on Performance of Intumescent Coatings.” J. Coat. Technol. Res., 13 227–238 (2016)\nAnees, SM, Dasari, A, “A Review on the Environmental Durability of Intumescent Coatings for Steel.” J. Mater. Sci., 53 124–145 (2018)\nDasari, A, Yu, ZZ, Cai, GP, Mai, YW, “Recent Developments in the Fire Retardancy of Polymeric Materials.” Prog. Polym. Sci., 38 1357–1387 (2013)\nCamino, G, Costa, L, Trossarelli, L, Costanzi, F, Pagliari, A, “Study of the Mechanism of Intumescence in Fire Retardant Polymers: Part VI-Mechanism of Ester Formation in Ammonium Polyphosphate–Pentaerythritol Mixtures.” Polym. Degrad. Stab., 12 213–228 (1985)\nPuri, RG, Khanna, AS, “Intumescent Coatings: A Review on Recent Progress.” J. Coat. Technol. Res., 14 1–20 (2017)\nChozhan, CK, Rajasekaran, R, Alagar, M, Gnanasundaram, P, “Thermomechanical Behavior of Vinyl Ester Oligomer-Toughened Epoxy-Clay Hybrid Nanocomposites.” Int. J. Polym. Mater., 57 319–337 (2008)\nShiralizadeh, S, Nasr-Isfahani, H, Keivanloo, A, Bakherad, M, “Radiopaque Nanocomposites Based on Biocompatible Iodinated N-phenyl Amide-Modified Methyl Methacrylate\u002FAcrylic Acid Copolymer.” J. Polym. Res., 24 186 (2017)\nSong, L, Hu, Y, Tang, Y, Zhang, R, Chen, ZY, Fan, WC, “Study on the Properties of Flame Retardant Polyurethane\u002FOrganoclay Nanocomposite.” Polym. Degrad. Stab., 87 111–116 (2005)\nLiu, X, Hao, JW, Gaan, S, “Recent Studies on the Decomposition and Strategies of Smoke and Toxicity Suppression for Polyurethane Based Materials.” RSC Adv., 6 74742–74756 (2016)\nChen, XL, Song, WK, Liu, JB, Jiao, CM, Qian, Y, “Synergistic Flame-Retardant Effects Between Aluminum Hypophosphite an Expandable Graphite in Silicon Rubber Composite.” J. Therm. Anal. Calorim., 120 1819–1826 (2015)\nYang, Z, Cai, J, Zhou, CG, Zhou, D, Chen, BF, Yang, H, Cheng, RS, “Effects of the Content of Silane Coupling Agent KH-560 on the Properties of LLDPE\u002FMagnesium Hydroxide Composites.” J. Appl. Polym. Sci., 118 2634–2641 (2010)\nGao, L, Zheng, G, Zhou, Y, Hu, L, Feng, G, Xie, Y, “Synergistic Effects of Expandable Graphite, Melamine Polyphosphate and Layered Double Hydroxide on Improving the Fire Behavior of Rosin-Based Rigid Polyurethane Foam.” Ind. Crops Prod., 50 638–647 (2013)\nWladyka-Przbylak, M, Kozlowski, R, “The Thermal Characteristics of Different Intumescent Coatings.” Fire Mater., 23 33–43 (1999)\nLe Bras, M, Bourbigot, S, Revel, B, “Comprehensive Study of the Degradation of an Intumescent EVA-Based Material During Combustion.” J. Mater. Sci., 34 5777–5782 (1999)\nBaljinder, KK, Horrocks, AR, “Complex Char Formation in Flame-Retarded Fire-Intumescent Combinations–II. Thermal Analytical Studies.” Polym. Degrad. Stab., 54 289–303 (1996)\nLindsay, CI, Hill, SB, Hearn, M, Manton, G, Everall, N, Bunn, A, Heron, J, Fletcher, I, “Mechanisms of Action of Phosphorus Based Flame Retardants in Acrylic Polymers.” Polym. Int., 49 1183–1192 (2000)\nDrevelle, C, Duquesne, S, Le Bras, M, Lefebvre, J, Delobel, R, Castrovinci, A, Magniez, C, Vouters, M, “Influence of Ammonium Polyphosphate on the Mechanism of Thermal Degradation of an Acrylic Binder Resin.” J. Appl. Polym. Sci., 94 717–729 (2004)\nBourbigot, S, Le Bras, M, Duquesne, S, Rochery, M, “Recent Advances for Intumescent Polymers.” Macromol. Mater. Eng., 289 499–511 (2004)\nBourbigot, S, Le Bras, M, Dabrowski, F, Gilman, JW, Kashiwagi, T, “PA-6 Clay Nanocomposite Hybrid as Char Forming Agent in Intumescent Formulations.” Fire Mater., 24 201–208 (2000)\nLookman, R, Grobet, P, Merckx, R, Vlassak, K, “Phosphate Sorption by Synthetic Amorphous Aluminum Hydroxides: A 27Al and 31P Solid-State MASS NMR Spectroscopy Study.” Eur. J. Soil Sci., 45 37–44 (1994)\nBourbigot, S, Le Bras, M, Delobel, R, Decressaing, R, Amourex, JP, “Synergistic Effect of Zeolite in an Intumescent Process: Study of the Carbonaceous Structures Using Solid-State NMR.” J. Chem. Soc. Faraday Trans., 92 149–158 (1996)\nDuncan, TM, Douglass, DC, “On the 31P Chemical Shift Anisotropy in Condensed Phosphates.” Chem. Phys., 87 339–349 (1984)",{"EN":819},"Coating plywood with intumescent paint is an effective approach to ensure fire safety in materials. This study investigated the effects of applying an intumescent coating with nanoclay and different amounts of Cloisite 15A (1%, 3%, 5%, and 10%) on 4-mm plywood panels. The nanoclay coating had a lower total heat release and peak heat release rate than other approaches, and it significantly enhanced the fire retardancy of painted plywood. In addition, nanoclay treated with an organic modifier has better flame retardancy than unmodified nanoclay. Another critical parameter in this study was the concentration of organoclay added to the intumescent coating. Cloisite 15A at a concentration of 1% further enhanced the fire retardancy of plywood. A higher organoclay concentration can reduce CO emissions; however, it also increases CO2 emissions during combustion. The intumescent char layers containing 1% and 3% organoclay had the most extensive phosphocarbonaceous structures according to Fourier-transform IR spectroscopy and 27Al and 31P nuclear magnetic resonance analyses. Regarding the mechanism of fire performance and CO\u002FCO2 emissions, the addition of 1% and 3% Cloisite 15A to intumescent coatings is recommended; it achieved superior performance to Cloisite 15A at a higher concentration (i.e., 10%).",{"EN":821},"Effects of added nanoclay for styrene-acrylic resin on intumescent fire retardancy and CO\u002FCO2 emission",{"VOID":823},"10.1007\u002Fs11998-019-00246-x","https:\u002F\u002Flink.springer.com\u002Farticle\u002F10.1007\u002Fs11998-019-00246-x",[826,841],{"id":827,"sortIndex":182,"researcher":20,"roles":828,"affiliations":829,"properties":838},"738f9d61-fc64-41b8-b924-66a34bb702fe",[233],[830],{"id":20,"sortIndex":21,"affiliation":831,"properties":20},{"id":832,"createTime":833,"updateTime":833,"relativeEntities":834,"slug":20,"properties":835,"entityType":64,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"aaf7ed01-3cde-4d4c-8226-6e89985a8716","2024-01-16T04:36:55.226+00:00",[],{"title":836},{"VI":837},"Institute of Applied Mechanics, National Taiwan University, Taipei, Taiwan, ROC",{"title":839},{"VI":840},"Horn-Jiunn 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X, Ishida, H, “Phenolic Materials Via Ring-Opening Polymerization Synthesis and Characterization of Bisphenol-A Based Benzoxazines and Their Polymers.” J. Polym. Sci. Part A Polym. Chem., 32 1121–1129 (1994)\nIshida, H, Allen, DJ, “Physical and Mechanical Characterization of Near-Zero Shrinkage Polybenzoxazines.” J. Polym. Sci. Part B Polym. Phys., 34 1019–1030 (1996)\nLiu, J, Lu, X, Xin, Z, Zhou, CL, “Synthesis and Surface Properties of Low Surface Free Energy Silane-Functional Polybenzoxazine Films.” Langmuir, 29 (1) 411–416 (2013)\nWang, CF, Chen, HY, Kuo, SW, Lai, YS, Yang, PF, “Rapid, Low Temperature Microwave Synthesis of Durable, Superhydrophobic Carbon Nanotube–Polybenzoxazine Nanocomposites.” RSC Adv., 3 (25) 9764–9769 (2013)\nKumar, RS, Ariraman, M, Alagar, M, “Design of Lamellar Structured POSS\u002FBPZ Polybenzoxazine Nanocomposites as a Novel Class of Ultra Low-k Dielectric Materials.” RSC Adv., 4 (37) 19127–19136 (2014)\nSelvi, M, Vengatesan, MR, Devaraju, S, Kumar, M, Alagar, M, “In Situ Sol–Gel Synthesis of Silica Reinforced Polybenzoxazine Hybrid Materials with Low Surface Free Energy.” RSC Adv., 4 (17) 8446–8452 (2014)\nWang, CF, Wang, TF, Liao, CS, Kuo, S-W, Lin, HC, “Using Pencil Drawing to Pattern Robust Superhydrophobic Surfaces to Control the Mobility of Water Droplets.” J. Phys. Chem. C, 115 (33) 16495–16500 (2011)\nShang, YW, Si, Y, Raza, A, Yang, LP, Mao, X, Ding, B, Yu, JY, “An In Situ Polymerization Approach for the Synthesis of Superhydrophobic and Superoleophilic Nanofibrous Membranes for Oil–Water Separation.” Nanoscale, 4 (24) 7847–7854 (2012)\nYang, LP, Raza, A, Si, Y, Mao, X, Shang, YW, Ding, B, Yu, JY, Al-Deyab, SS, “Synthesis of Superhydrophobic Silica Nanofibrous Membranes with Robust Thermal Stability and Flexibility Via In Situ Polymerization.” Nanoscale, 4 (20) 6581–6587 (2012)\nZhang, WF, Lu, X, Xin, Z, Zhou, CL, “A Self-Cleaning Polybenzoxazine\u002FTiO2 Surface with Superhydrophobicity and Superoleophilicity for Oil\u002FWater Separation.” Nanoscale, 7 (46) 19476–19483 (2015)\nZhou, CL, Lu, X, Xin, Z, Liu, J, “Corrosion Resistance of Novel Silane-Functional Polybenzoxazine Coating on Steel.” Corros. Sci., 70 145–151 (2013)\nLu, X, Liu, Y, Zhou, CL, Zhang, WF, Xin, Z, “Corrosion Protection of Hydrophobic Bisphenol A-Based Polybenzoxazine Coatings on Mild Steel.” RSC Adv., 6 (7) 5805–5811 (2016)\nEscobar, J, Poorteman, M, Dumas, L, Bonnaud, L, Dubois, P, Olivier, M-G, “Thermal Curing Study of Bisphenol A Benzoxazine for Barrier Coating Applications on 1050 Aluminum Alloy.” Prog. Org. Coat., 79 53–61 (2015)\nPoorteman, M, Renaud, A, Escobar, J, Dumas, L, Bonnaud, L, Dubois, P, Olivier, MG, “Thermal Curing of Para-Phenylenediamine Benzoxazine for Barrier Coating Applications on 1050 Aluminum Alloys.” Prog. Org. Coat., 97 99–109 (2016)\nBalanuca, B, Raicopol, M, Maljusch, A, Garea, S, Hanganu, A, Schuhmann, W, Andronescu, C, “Phenolated Oleic Acid Based Polybenzoxazine Derivatives as Corrosion Protection Layers.” ChemPlusChem, 80 (7) 1170–1177 (2015)\nRaicopol, M, Balanuca, B, Sliozberg, K, Schlueter, B, Garea, SA, Chira, N, Schuhmann, W, Andronescu, C, “Vegetable Oil-Based Polybenzoxazine Derivatives Coatings on Zn–Mg–Al Alloy Coated Steel.” Corros. Sci., 100 386–395 (2015)\nAgag, T, Geiger, S, Alhassan, SM, Qutubuddin, S, Ishida, H, “Low-Viscosity Polyether-Based Main-Chain Benzoxazine Polymers: Precursors for Flexible Thermosetting Polymers.” Macromolecules, 43 (17) 7122–7127 (2010)\nTakeichi, T, Kano, T, Agag, T, “Synthesis and Thermal Cure of High Molecular Weight Polybenzoxazine Precursors and the Properties of the Thermosets.” Polymer, 46 (26) 12172–12180 (2005)\nLiu, J, Agag, T, Ishida, H, “Main-Chain Benzoxazine Oligomers A New Approach for Resin Transfer Moldable Neat Benzoxazines for High Performance Applications.” Polymer, 51 (24) 5688–5694 (2010)\nLin, CH, Chang, SL, Shen, TY, Shih, YS, Lin, HT, Wang, CF, “Flexible Polybenzoxazine Thermosets with High Glass Transition Temperatures and Low Surface Free Energies.” Polym. Chem., 3 (4) 935–945 (2012)\nWang, MW, Jeng, RJ, Lin, CH, “Study on the Ring-Opening Polymerization of Benzoxazine Through Multisubstituted Polybenzoxazine Precursors.” Macromolecules, 48 (3) 530–535 (2015)\nSudo, A, Hirayama, S, Endo, T, “Highly Efficient Catalysts-Acetylacetonato Complexes of Transition Metals in the 4th Period for Ring-Opening Polymerization of 1,3-Benzoxazine.” J. Polym. Sci. Part A Polym. Chem., 48 (2) 479–484 (2010)\nRan, QC, Zhang, DX, Zhu, RQ, Gu, Y, “The Structural Transformation During Polymerization of Benzoxazine\u002FFeCl3 and the Effect on the Thermal Stability.” Polymer, 53 (19) 4119–4127 (2012)\nArnebold, A, Schorsch, O, Stelten, J, Hartwig, A, “Resorcinol-Based Benzoxazine with Low Polymerization Temperature.” J. Polym. Sci. Part A Polym. Chem., 52 (12) 1693–1699 (2014)\nRen, ST, Yang, X, Zhao, XJ, Zhang, Y, Huang, W, “An m-Phenylenediamine-Based Benzoxazine with Favorable Processability and Its High-Performance Thermoset.” J. Appl. Polym. Sci., 133 (18) 43368 (2016)\nWang, P, Zhang, D, Lu, Z, “Advantage of Super-Hydrophobic Surface as a Barrier Against Atmospheric Corrosion Induced by Salt Deliquescence.” Corros. Sci., 90 23–32 (2015)\nQian, M, McIntosh Soutar, A, Tan, XH, Zeng, XT, Wijesinghe, SL, “Two-Part Epoxy-Siloxane Hybrid Corrosion Protection Coatings for Carbon Steel.” Thin Solid Films, 517 (17) 5237–5242 (2009)\nAnsari, F, Naderi, R, Dehghanian, C, “Improvement in the Corrosion Resistance of Stainless Steel 304L in Sodium Chloride Solution by a Nanoclay Incorporated Silane Coating.” RSC Adv., 5 (1) 706–716 (2015)\nDong, HJ, Xin, Z, Lu, X, Lv, YH, “Effect of N-Substituents on the Surface Characteristics and Hydrogen Bonding Network of Polybenzoxazines.” Polymer, 52 (4) 1092–1101 (2011)\nQu, L, Xin, Z, “Preparation and Surface Properties of Novel Low Surface Free Energy Fluorinated Silane-Functional Polybenzoxazine Films.” Langmuir, 27 (13) 8365–8370 (2011)",{"EN":898},"Bisphenol A\u002Fdiaminodiphenylmethane (BA-ddm)-based polybenzoxazine precursor was synthesized from 4,4′-diaminodiphenylmethane, bisphenol A, and paraformaldehyde. The curing behavior of BA-ddm was studied by using differential scanning calorimeter and Fourier transform infrared spectrometer techniques. To verify the anticorrosion property, cured polybenzoxazine (PBA-ddm) coatings were prepared on mild steel (MS) through dip-coating and thermal curing methods. The surface properties of cured PBA-ddm coatings were characterized by microscopy and contact angle measurement. The electrochemical measurements were carried out to investigate the corrosion properties of PBA-ddm-coated MS. The results showed that PBA-ddm-coated MS samples exhibited high anticorrosive performance with the corrosion current reduced by two orders of magnitude than that of pristine MS.",{"EN":900},"Crosslinked main-chain-type polybenzoxazine coatings for corrosion protection of mild steel",{"VOID":902},"10.1007\u002Fs11998-016-9902-5","http:\u002F\u002Flink.springer.com\u002F10.1007\u002Fs11998-016-9902-5",[905,920,932,944,957,969],{"id":906,"sortIndex":21,"researcher":20,"roles":907,"affiliations":908,"properties":917},"fa4a11bd-e0f7-465e-8fd3-f6f13ebc0708",[233],[909],{"id":20,"sortIndex":21,"affiliation":910,"properties":20},{"id":911,"createTime":912,"updateTime":912,"relativeEntities":913,"slug":20,"properties":914,"entityType":64,"verifyStatus":19,"verifyTime":20,"verifyNote":20,"syncStatus":19,"languages":20,"translateLanguages":20,"viewCount":21},"a66420fc-b247-4c53-9db3-e82629763769","2023-12-01T04:04:47.755+00:00",[],{"title":915},{"VI":916},"Shanghai Key Laboratory of Multiphase 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JC, “The Development of Advanced Gas Turbines: The Technical and Economic Development.” In: Cputsouradis, D et al (eds.) Materials for Advanced Power Engineering, p. 1831. Kluwer Academic, The Netherlands (1994)\nI Gurrappa, AK Gogia, Oxidation Behavior of Titanium Alloy IMI 834 at Elevated Temperatures, Proceedings of the 5th National Convention on Corrosion, New Delhi, India, NACE International India Section, November (1999), pp. 210–219\nI Gurrappa (2002) On the Degradation Mechanism of Titanium Aalloy IMI 834 in Oxidizing Atmospheres at Elevated Temperatures, Corr. Prev. & Control, 49, 79\nI Gurrappa (2003) Mechanism of Degradation of Ttitanium Aalloy IMI 834 and Its Protection Under Hot Corrosion Conditions, Oxid. Met., 59, 321\nZ Yao, Z Jiang, F Wang, G Hao (2007) Oxidation Behavior of Ceramic Coatings on Ti-6Al-4V by Micro-Plasma Oxidation, J. Mater. Process. Tech., 190, 117\nH Zhou, F Li, B He, J Wang, B Sun (2007) Wang and B. Sun, Air Plasma Sprayed Thermal Barrier Coatings on Titanium Alloy Substrates, Surf. Coat. Tech., 202, 7360\nRiviere, JP, Pichon, L, Drouet, M, Poquillon, D, Galdikas, A, “Silicon Based Coatings Deposited by Dynamic Ion Mixing for Oxidation Protection of a Ti6242 Aalloy.” Surf. Coat. Tech., 201 8343 (2007)\nR Siab, G Bonnet, JM Brossard, J Balmain, JF Dinhut (2007) Effect of An Electrodeposited Yttrium Containing Thin Film on the High Temperature Oxidation Behavior of TA6V alloy, Appl. Surf. Sci., 253, 3425\nI Gurrappa, D Manova, JW Gerlach, S Mandl, B Rauchenbach (2006) Effect of an Electrodeposited Yttrium Containing Thin Film on the High Temperature Oxidation Behavior of TA6V Alloy, J. Alloys. Comp., 426, 375\nM Froehlich, R Braun, C Leyens (2006) Oxidation Resistant Coatings in Combination with Thermal Barrier Coatings on γ–TiAl Alloys for High Temperature Applications, Surf. Coat. Tech., 201, 3911\nH P Xiong, W Mao, WL Ma, YH Xie, Y Feng, H Yuan, XH Li (2006) Liquid-Phase Aluminizing and Siliconizing at the Surface of a Ti60 Alloy and Improvement in Oxidation Resistance, Mater. Sci.Eng., A433, 108\nH Li, C Costil, V Barnier, R Oltra, O Heintz, C Coddet (2006) Surface Modifications Induced by Nanosecond Pulsed Nd:YAG Laser Irradiation of Metallic Substrates, Surf. Coat. Tech., 201, 1383\nFox-Rabinovich GS, Wilkinson DS, Veldhuis SC, Dosboneva GK, Weatherly GC (2006) Oxidation Resistant Ti–Al–Cr Alloy for Protective Coating Applications, Intermetallics, 14, 189. doi:10.1016\u002Fj.intermet.2005.05.011\nI Gurrappa, D Manova, JW Gerlach, S Mandl, B Rauchenbach (2006) Influence of Nitrogen Implantation on the High Temperature Oxidation of Titanium-Based Alloys, Surf. Coat. Tech., 201, 3536\nHN Lee, ZM Park, MH Oh, KY Kim, DM Wee (1999) Oxidation Behavior and Mechanical Properties of Yttrium-Doped L12 (Al,Cr)3 Ti Coating on TiAl Alloys, Script Met., 41, 1073\nI Gurrappa (2001) Platinum Aluminide Coatings for Oxidation Resistance of Titanium Alloys, Platinum Metals Rev., 45, 124\nI Gurrappa (2001) Effect of Aluminizing on the Oxidation Behavior of the Titanium Alloy IMI 834, Oxid. Metals, 56, 73",{"EN":1026},"The present article explains the efforts made in developing new protective coatings based on palladium, tantalum, and aluminum with considerably improved oxidation resistance for effective protection of titanium alloy IMI 834. Systematic characterization was carried out on as-prepared as well as oxidized coatings and these results are presented. The performance of new coatings was evaluated by generating weight-gain data as a function of time followed by detailed characterization in order to confirm the ability of the coatings to prevent oxidation and alpha-case formation. The results showed that tantalum aluminide and simple aluminide coatings exhibit improved oxidation resistance when compared to palladium aluminide. 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