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However, it was found that the cement setting was too slow. The objective of this paper is to initially explore the effect of accelerating admixtures on the setting and hydration properties of iron-rich PAC prepared from industrial raw materials. The experimental results indicated that Al2(SO4)3 could shorten the setting time but decreased the compressive strength of the cement due to the expansion of AFt generated in cement stone. By contrast, the same content of CaCl2 had a more significant effect on promoting the cement setting. Further, 5% CaCl2 benefited the development of mechanical strength by promoting the cement hydration and improving the internal pore structure of cement stone. Consequently, this research provided guidance for regulating the working performance and promote the application of iron-rich PAC well.",{"EN":175,"VI":176},"Hydration characteristics of iron-rich phosphoaluminate cement: effect of accelerating admixtures on the setting time and compressive strength","Đặc tính hydrat hóa của xi măng phosphoaluminate giàu sắt: ảnh hưởng của phụ gia đông kết nhanh lên thời gian đông kết và cường độ chịu nén",{"VOID":178},"Liu P, Chen Y, Yu Z, Ding Z, Xing F, Lu Z, et al. Early hydration properties and performance evolution of phosphoaluminate cement concrete. Constr Build Mater. 2020;233:117318. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.conbuildmat.2019.117318.\nLi S, Wang S, Liu H, Bharath M, Zhang S. Variation in the sulfate attack resistance of iron rich-phosphoaluminate cement with mineral admixtures subjected to a Na2SO4 solution. Constr Build Mater. 2020;230:116817. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.conbuildmat.2019.116817.\nBi H, Zhang W, Xu X, Ming A, Shen Y, Wang S, et al. Chloride binding and transport characteristic of phosphoaluminate cement-based marine sand coating subjected to marine environment. Constr Build Mater. 2021;281:122505. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.conbuildmat.2021.122505.\nWang S, Zhang W, Zhang S, Lu L, Cheng X. Variation of resistance to chloride penetration of iron-rich phosphoaluminate cement with admixture materials subjected to NaCl environment. Constr Build Mater. 2020;231:117165. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.conbuildmat.2019.117165.\nLiu H, Wang S, Huang Y, Melugiri-Shankaramurthy B, Zhang S, Cheng X. Effect of SCMs on the freeze-thaw performance of iron-rich phosphoaluminate cement. Constr Build Mater. 2020;230:117012. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.conbuildmat.2019.117012.\nXu W, Dai JG, Ding Z, Wang Y. Polyphosphate-modified calcium aluminate cement under normal and elevated temperatures: Phase evolution, microstructure, and mechanical properties. Ceram Int. 2017;43:15525–36. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.ceramint.2017.08.102.\nGB 175–2007 Common portland cement. Standardization Administration of China; 2007.\nLi S, Zhang G, Zhang N, Cao W. Study of hydration activity in the aluminum-rich zone of CaO-Al2O3-P2O5 ternary system. J Chinese Ceram Soc. 1998;26:142–9.\nCheng L, Sheng G, Pi Y. Influence of phosphogypsum on setting time of portland cement. Build Mater World. 2004;26:5.\nLi J, Zhu J, Zhou W, Sun Z. Effect of phosphate slag on the setting time of silicate cement and the mechanism. 2011;32:21–3\nKamenchukov A, Yarmolinsky V, Pugachev I. Evaluation of road repair efficiency in terms of ensuring traffic quality and safety. Transp Res Procedia. 2018;36:627–33. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.trpro.2018.12.142.\nShi C, Zou X, Yang L, Wang P, Niu M. 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Cem Concr Res. 1994;24:1237–44.\nRiding K, Silva DA, Scrivener K. Early age strength enhancement of blended cement systems by CaCl2 and diethanol-isopropanolamine. Cem Concr Res. 2010;40:935–46. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.cemconres.2010.01.008.\nMakaratat N, Jaturapitakkul C, Namarak C, Sata V. Effects of binder and CaCl2 contents on the strength of calcium carbide residue-fly ash concrete. Cem Concr Compos. 2011;33:436–43. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.cemconcomp.2010.12.004.\nYum WS, Jeong Y, Yoon S, Jeon D, Jun Y, Oh JE. Effects of CaCl2 on hydration and properties of lime(CaO)-activated slag\u002Ffly ash binder. Cem Concr Compos. 2017;84:111–23. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.cemconcomp.2017.09.001.\nSteger L, Blotevogel S, Frouin L, Patapy C, Cyr M. Experimental evidence for the acceleration of slag hydration in blended cements by the addition of CaCl2. Cem Concr Res. 2021;149:2–10.\nOdler I, Abdul-Maula S. 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The influence of NaCl on the reactivity of high alumina cement in water: Pore-solution and solid phase characterization. J Mater Res. 1994;9:1533–9.\nWang Z, Zhao Y, Yang H, Zhou L, Diao G, Liu G, et al. Influence of sodium chloride on the hydration of calcium aluminate cement constantly cured at 5, 20 and 40° C. 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analysis–mass spectrometry, in situ X-ray diffraction, scanning electron microscopy and Fourier transform infrared spectroscopy were used to characterize hydromagnesite [Mg5(CO3)4(OH)2·4H2O] from Dujiali Lake in Tibet, China. This study describes the variations in the thermal decomposition mechanisms of hydromagnesite at varying heating rates and under either helium (He) or carbon dioxide (CO2) atmospheres. In a He atmosphere, only two decomposition stages were observed; the loss of the crystalline water followed by the combined dehydroxylation and decarbonation. However, under a CO2 atmosphere, the dehydroxylation and decarbonation occur separately as the inert CO2 gas prevents the decomposition of the MgCO3 component of hydromagnesite. Overall, the thermal decomposition is an endothermic process. A distinctly exothermic process occurs at about 540 °C under conditions of high partial pressure of CO2 or high heating rate and implies the crystallization of magnesite (MgCO3). We propose that the release of H2O and CO2 at different stages likely results from the complicated hydrogen bonds and different carbonate groups in the crystal structure of hydromagnesite.",{"EN":355,"VI":356},"Thermogravimetric analysis–mass spectrometry (TGA–MS) of hydromagnesite from Dujiali Lake in Tibet, China","Phân tích nhiệt trọng lượng–khối phổ (TGA–MS) của hydromagnesite từ hồ Dujiali ở Tây Tạng, Trung Quốc",{"VOID":358},"Power IM, Wilson SA, Harrison AL, Dipple GM, Mccutcheon J, Southam G, et al. A depositional model for hydromagnesite–magnesite playas near Atlin, British Columbia, Canada. Sedimentology. 2014;61:1701–33.\nPower IM, Wilson SA, Thom JM, Dipple GM, Gabites JE, Southam G. The hydromagnesite playas of Atlin, British Columbia, Canada: a biogeochemical model for CO2 sequestration. Chem Geol. 2009;260:302–16.\nLin Y, Zheng M, Ye C. Hydromagnesite precipitation in the Alkaline Lake Dujiali, central Qinghai-Tibetan Plateau: constraints on hydromagnesite precipitation from hydrochemistry and stable isotopes. Appl Geochem. 2017;78:139–48.\nBotha A, Strydom CA. Preparation of a magnesium hydroxy carbonate from magnesium hydroxide. Hydrometallurgy. 2001;62:175–83.\nBeck CW. Differential thermal analysis curves of carbonate materials. Am Miner. 1950;35:985–1013.\nSawada Y, Uematsu K, Mizutani N, Kato M. Thermal decomposition of hydromagnesite 4MgCO3—Mg(OH)2–4H2O under different partial pressures of carbon dioxide. Thermochim Acta. 1978;27:45–59.\nSawada Y, Yamaguchi J, Sakurai O, Uematsu K, Mizutani N, Kato M. Thermal decomposition of basic magnesium carbonates under high-pressure gas atmospheres. Thermochim Acta. 1979;32:277–91.\nSawada Y, Yamaguchi J, Sakurai O, Uematsu K, Mizutani N, Kato M. Isothermal differential scanning calorimetry on an exothermic phenomenon during thermal decomposition of hydromagnesite 4MgCO3—Mg(OH)2–4H2O. Thermochim Acta. 1979;34:233–7.\nTeir S, Eloneva S, Fogelholm CJ, Zevenhoven R. Fixation of carbon dioxide by producing hydromagnesite from serpentinite. Appl Energy. 2009;86:214–8.\nBotha A, Strydom CA. DTA and FT-IR analysis of the rehydration of basic magnesium carbonate. J Thermal Anal Calorim. 2003;71:987–95.\nPadeste C, Oswald HR, Reller A. The thermal behaviour of pure and nickel-doped hydromagnesite in different atmospheres. Mater Res Bull. 1991;26:1263–8.\nChoudhary VR, Pataskar SG, Gunjikar VG, Zope GB. Influence of preparation conditions of basic magnesium carbonate on its thermal analysis. Thermochim Acta. 1994;232:95–110.\nHull TR, Witkowski A, Hollingbery L. Fire retardant action of mineral fillers. Polym Degrad Stab. 2011;96:1462–9.\nVágvölgyi V, Frost RL, Hales M, Locke A, Kristóf J, Horváth E. Controlled rate thermal analysis of hydromagnesite. J Thermal Anal Calorim. 2008;92:893–7.\nHaurie L, Fernandez AI, Velasco JI, Chimenos JM, Lopez-Cuesta JM, Espiell F. Effects of milling on the thermal stability of synthetic hydromagnesite. Mater Res Bull. 2007;42:1010–8.\nKhan N, Dollimore D, Alexander K, Wilburn FW. The origin of the exothermic peak in the thermal decomposition of basic magnesium carbonate. Thermochim Acta. 2001;367–368:321–33.\nRao TR, Cholan VS. Kinetics of thermal decomposition of hydromagnesite. Chem Eng Technol. 2004;18(5):359–363.\nSawada Y, Uematsu K, Mizutani N, Kato M. Thermal decomposition of hydromagnesite 4MgCO3·Mg(OH)2·4H2O. J Inorg Nucl Chem. 1978;40:979–82.\nHollingbery LA, Hull TR. The fire retardant effects of huntite in natural mixtures with hydromagnesite. Polym Degrad Stab. 2012;97:504–12.\nHollingbery LA, Hull TR. The fire retardant behaviour of huntite and hydromagnesite—a review. Polym Degrad Stab. 2010;95(12):2213–2225.\nRealinho V, Haurie L, Antunes M, Velasco JI. Thermal stability and fire behaviour of flame retardant high density rigid foams based on hydromagnesite-filled polypropylene composites. Compos B Eng. 2014;58:553–8.\nLaoutid F, Gaudon P, Taulemesse JM, Lopez Cuesta JM, Velasco JI, Piechaczyk A. Study of hydromagnesite and magnesium hydroxide based fire retardant systems for ethylene–vinyl acetate containing organo-modified montmorillonite. Polym Degrad Stab. 2006;91:3074–82.\nHollingbery LA, Hull TR. The thermal decomposition of huntite and hydromagnesite—a review. Thermochim Acta. 2010;509:1–11.\nSawada Y, Yamaguchi J, Sakurai O, Uematsu K, Mizutani N, Kato M. Thermogravimetric study on the decomposition of hydromagnesite 4 MgCO3·Mg(OH)2·4H2O. Thermochim Acta. 1979;33:127–40.\nFrost RL, Weier ML, Erickson KL. Thermal decomposition of struvite. J Therm Anal Calorim [Internet]. 2004;76:1025–33. http:\u002F\u002Fdownload.springer.com\u002Fstatic\u002Fpdf\u002F672\u002Fart%253A10.1023%252FB%253AJTAN.0000032287.08535.b3.pdf?originUrl=http%3A%2F%2Flink.springer.com%2Farticle%2F10.1023%2FB%3AJTAN.0000032287.08535.b3&token2=exp=1497438534~acl=%2Fstatic%2Fpdf%2F672%2Fart%25253A10.1.\nCheng H, Yang J, Liu Q, He J, Frost RL. Thermogravimetric analysis–massspectrometry(TG–MS) of selected Chinese kaolinites. Thermochim Acta [Internet]. 2010;507–508:106–14. http:\u002F\u002Fwww.scopus.com\u002Finward\u002Frecord.url?eid=2-s2.0-77955470571&partnerID=tZOtx3y1.\nPaulose S, Thomas D, Jayalatha T, Rajeev R, George BK. TG–MS study on the kinetics and mechanism of thermal decomposition of copper ethylamine chromate, a new precursor for copper chromite catalyst. J Therm Anal Calorim. 2016;124:1099–108.\nJayaraman K, Kok MV, Gokalp I. Combustion properties and kinetics of different biomass samples using TG–MS technique. J Therm Anal Calorim. 2017;127:1361–70.\nÅkerblom IE, Ojwang DO, Grins J, Svensson G. A thermogravimetric study of thermal dehydration of copper hexacyanoferrate by means of model-free kinetic analysis. J Therm Anal Calorim. 2017;129:721–31.\nIngram AL, Nickels TM, Maraoulaite DK, White RL. Thermogravimetry–mass spectrometry investigations of montmorillonite interlayer water perturbations caused by aromatic acid adsorbates. J Therm Anal Calorim. 2016;126:1157–66.\nXia H, Wei K. Equivalent characteristic spectrum analysis in TG–MS system. Thermochim Acta [Internet]. 2015;602:15–21. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.tca.2014.12.019.\nAkao M, Marumo F, Iwai S. The crystal structure of hydromagnesite. Acta Crystallogr Sect B Struct Crystallogr Cryst Chem [Internet]. 1974;30:2670–2. http:\u002F\u002Fscripts.iucr.org\u002Fcgi-bin\u002Fpaper?S0567740874007771.\nAkao M, Iwai S. The hydrogen bonding of hydromagnesite. Acta Crystallogr Sect B [Internet]. 1977;33:1273–5. http:\u002F\u002Fscripts.iucr.org\u002Fcgi-bin\u002Fpaper?S0567740877005834.\nJanet CM, Viswanathan B, Viswanath RP, Varadarajan TK. Characterization and photoluminescence properties of MgO microtubes synthesized from hydromagnesite flowers. J Phys Chem C. 2007;111:10267–72.\nWang J, Li D, Gao R, Liu Q, Jing X, Wang Y, et al. Construction of superhydrophobic hydromagnesite films on the Mg alloy. Mater Chem Phys [Internet]. 2011;129:154–60. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.matchemphys.2011.03.065.\nZhang Z, Zheng Y, Ni Y, Liu Z, Chen J, Liang X. Temperature- and pH-dependent morphology and FT-IR analysis of magnesium carbonate hydrates. J Phys Chem B. 2006;110:12969–73.\nGil Kim S, Hyun Choi K, Hwan Eun J, Joon Kim H, Seung Hwang C. Effects of additives on properties of MgO thin films by electrostatic spray deposition. Thin Solid Films. 2000;377–378:694–8.",{"VOID":360},"10.1007\u002Fs10973-018-7197-8","2024-12-31T19:54:33.970+00:00",[186],"http:\u002F\u002Flink.springer.com\u002F10.1007\u002Fs10973-018-7197-8",[365,389,409,422],{"id":366,"sortIndex":19,"researcher":18,"roles":367,"affiliations":368,"properties":386,"displayName":388,"givenName":18,"familyName":18},"764adc08-532c-437e-9f8f-5efab9dce7fb",[192],[369,377],{"id":370,"sortIndex":19,"affiliation":371,"properties":18},"d5bbc481-3f0a-4445-8c0e-8f9212eb4d63",{"id":370,"createTime":18,"updateTime":18,"relativeEntities":372,"slug":18,"properties":373,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":376,"statistic":18},[],{"title":374},{"VI":375},"Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing, China",[],{"id":378,"sortIndex":109,"affiliation":379,"properties":385},"e79c3d63-1b57-4827-93bb-23b97d1f1d78",{"id":378,"createTime":18,"updateTime":18,"relativeEntities":380,"slug":18,"properties":381,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":384,"statistic":18},[],{"title":382},{"VI":383},"School of Earth Sciences and Resources, China University of Geosciences, Beijing, China",[],{},{"title":387},{"VI":388},"Yongjie Lin",{"id":390,"sortIndex":109,"researcher":18,"roles":391,"affiliations":392,"properties":406,"displayName":408,"givenName":18,"familyName":18},"0a448a02-50a2-4f8a-be53-54fe94fcea3f",[192],[393,399],{"id":370,"sortIndex":19,"affiliation":394,"properties":18},{"id":370,"createTime":18,"updateTime":18,"relativeEntities":395,"slug":18,"properties":396,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":398,"statistic":18},[],{"title":397},{"VI":375},[],{"id":378,"sortIndex":109,"affiliation":400,"properties":405},{"id":378,"createTime":18,"updateTime":18,"relativeEntities":401,"slug":18,"properties":402,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":404,"statistic":18},[],{"title":403},{"VI":383},[],{},{"title":407},{"VI":408},"Mianping Zheng",{"id":410,"sortIndex":222,"researcher":18,"roles":411,"affiliations":412,"properties":419,"displayName":421,"givenName":18,"familyName":18},"91ed5636-54f4-4b0b-a85f-0d447dd6f1b1",[192],[413],{"id":370,"sortIndex":19,"affiliation":414,"properties":18},{"id":370,"createTime":18,"updateTime":18,"relativeEntities":415,"slug":18,"properties":416,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":418,"statistic":18},[],{"title":417},{"VI":375},[],{"title":420},{"VI":421},"Chuanyong Ye",{"id":423,"sortIndex":236,"researcher":18,"roles":424,"affiliations":425,"properties":434,"displayName":436,"givenName":18,"familyName":18},"60535506-dab3-4d6e-b041-a639d3633c10",[192],[426],{"id":427,"sortIndex":19,"affiliation":428,"properties":18},"c6db6717-2c13-45c6-abf1-897cf4b97b75",{"id":427,"createTime":18,"updateTime":18,"relativeEntities":429,"slug":18,"properties":430,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":433,"statistic":18},[],{"title":431},{"VI":432},"Trent School of the Environment, Trent University, Peterborough, Canada",[],{"title":435},{"VI":436},"Ian M. Power",{"url":363,"publisher":438,"properties":483},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":439,"slug":10,"properties":440,"entityType":16,"verifyStatus":17,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":19,"subjectFields":443,"manageAffiliations":452,"indexDatabases":463,"url":18,"thumbnailPath":18,"statistic":478,"gsStatistic":18,"type":160,"analyzePriority":18},[],{"issn":441,"title":442},{"VOID":13},{"VOID":15},[444,448],{"id":22,"createTime":18,"updateTime":18,"relativeEntities":445,"label":446,"description":447,"parentId":18,"standard":18,"scholarHubFieldId":18},[],{"EN":25},{},{"id":28,"createTime":18,"updateTime":18,"relativeEntities":449,"label":450,"description":451,"parentId":18,"standard":18,"scholarHubFieldId":18},[],{"EN":31},{},[453,458],{"id":35,"createTime":18,"updateTime":18,"relativeEntities":454,"slug":18,"properties":455,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":457,"statistic":18},[],{"title":456},{"EN":39},[],{"id":42,"createTime":18,"updateTime":18,"relativeEntities":459,"slug":18,"properties":460,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":462,"statistic":18},[],{"title":461},{"EN":46},[48],[464,471],{"id":51,"indexDatabase":465,"url":64,"indexYears":18,"academicFieldIds":470,"indexDatabaseRanking":18},{"id":53,"createTime":18,"updateTime":18,"relativeEntities":466,"label":467,"description":468,"key":60,"publicationTags":469,"standard":18},[],{"EN":56,"VI":56},{"EN":58,"VI":59},[62,63],[66,67],{"id":69,"indexDatabase":472,"url":80,"indexYears":81,"academicFieldIds":477,"indexDatabaseRanking":85},{"id":71,"createTime":18,"updateTime":18,"relativeEntities":473,"label":474,"description":475,"key":77,"publicationTags":476,"standard":18},[],{"EN":74,"VI":74},{"EN":74,"VI":76},[79],[83,84],{"impactFactor":19,"impactFactorByYear":479,"i10Index":99,"i10IndexLast5Year":100,"totalPublication":101,"totalPublicationByYear":480,"totalCitation":122,"totalCitationByYear":481,"totalCitationPerPublication":141,"totalCitationPerPublicationByYear":482,"hindexLast5Year":159,"hindex":159},{"2012":88,"2014":89,"2015":90,"2016":91,"2017":92,"2018":93,"2019":94,"2020":95,"2021":96,"2022":97,"2023":98},{"2003":103,"2004":104,"2005":105,"2006":106,"2009":107,"2010":108,"2011":109,"2012":109,"2013":110,"2014":111,"2015":112,"2016":113,"2017":114,"2018":115,"2019":116,"2020":117,"2021":118,"2022":119,"2023":120,"2024":121},{"2003":124,"2004":125,"2005":126,"2006":127,"2010":128,"2013":129,"2014":130,"2015":131,"2016":132,"2017":133,"2018":134,"2019":135,"2020":136,"2021":137,"2022":138,"2023":139,"2024":140},{"2003":143,"2004":144,"2005":145,"2006":146,"2010":147,"2013":148,"2014":149,"2015":150,"2016":151,"2017":152,"2018":153,"2019":154,"2020":150,"2021":155,"2022":156,"2023":157,"2024":158},{"pages":484,"volume":486},{"VOID":485},"1429-1437",{"VOID":487},"133","2018-03-31",2018,[85,62],{"id":492,"createTime":493,"updateTime":494,"relativeEntities":495,"slug":496,"properties":497,"entityType":181,"verifyStatus":182,"verifyTime":507,"verifyNote":184,"languages":18,"translateLanguages":508,"viewCount":19,"primaryUrl":509,"fullTextUrl":18,"authors":510,"publicationType":289,"publisherRelationship":576,"citationCount":18,"citationInfo":18,"publishDate":627,"publishYear":628,"citationAnalyzeStatus":17,"lastCitationAnalyze":18,"indexDatabases":629,"openAccess":18,"references":18,"isForceReanalyzing":344},"53e90ae4-ec5e-4f0b-93db-64861dca927c","2024-01-16T12:57:57.177+00:00","2026-09-07T08:14:45.178+00:00",[],"Thermal-denaturation-of-%CE%B1-chymotrypsinogen-A-in-presence-of-polyols-at-pH-2-0-and-pH-3-0",{"abstract":498,"title":500,"references":503,"doi":505},{"EN":499},"Osmolytes are cosolutes that induce stabilization of the structure of proteins. Polyols are osmolytes that have importance in a wide variety of biotechnological and industrial processes. In this work, a systematic study concerning the effect of polyols of different number of methylene and hydroxyl groups on the stability of α-chymotrypsinogen A is presented. Protein thermal stability measurements in buffer, ethylene glycol, glycerol, meso-erythritol, sorbitol and inositol was followed by fluorescence measurements. Under the selected conditions, the thermal denaturation of α-chymotrypsinogen A is a reversible transition between native and unfolded state that can be well described by a two-state model. Reversibility of the transition was confirmed by DSC, circular dichroism, UV–Vis and fluorescence measurements. The change in thermal stability of the protein in the presence of ethylene glycol, glycerol, erythritol, sorbitol and inositol shows that ethylene glycol is the only polyol that presents a destabilizing effect. The other cosolutes exert stabilizing effects that increase with the number of hydroxyl groups and depend on concentration.",{"EN":501,"VI":502},"Thermal denaturation of α-chymotrypsinogen A in presence of polyols at pH 2.0 and pH 3.0","Biến tính nhiệt của α-chymotrypsinogen A khi có mặt các polyol ở pH 2,0 và pH 3,0",{"VOID":504},"Romero CM, Lozano JM, Sancho J, Giraldo GI. Thermal stability of beta-lactoglobulin in the presence of aqueous solution of alcohols and polyols. Int J Biol Macromol. 2007;40:423–8.\nXie G, Timasheff S. Mechanism of the stabilization of ribonuclease A by sorbitol: preferential hydration is greater for the denatured than for the native protein. Protein Sci. 1997;6:211–21.\nDavis-Searles PR, Saunders AJ, Erie DA, Winzor DJ, Pielak GJ. Interpreting the effects of small uncharged solutes on protein-folding equilibria. Annu Rev Biophys Biomol Struct. 2001;30:271–306.\nKaushik JK, Bhat R. Thermal stability of proteins in aqueous polyol solutions: role of the surface tension of water in the stabilizing effect of polyols. J Phys Chem. 1998;102:7058–66.\nGerlsma S. The effects of polyhydric and monohydric alcohols on the heat induced reversible denaturation of chymotrypsinogen A. Eur J Biochem. 1970;14:150–3.\nXie G, Timasheff SN. The thermodynamic mechanism of protein stabilization by trehalose. Biophys Chem. 1997;64:25–43.\nTheodore BG, Herskovits T. On the structural stability and solvent denaturation of proteins. J Biol Chem. 1970;245:2588–98.\nHartley BS. Amino-acid sequence of bovine chymotrypsinogen-A. Nature. 1964;201:1284–7.\nBrandts JF. The thermodynamics of protein denaturation i. the denaturation of chymotrypsinogen. J Am Chem Soc. 1964;86:4291–301.\nBrandts JF. The thermodynamics of protein denaturation II. A model of reversible denaturation and interpretations regarding the stability of chymotrypsinogen. J Am Chem Soc. 1964;86:4302–14.\nJackson WM, Brandts JF. Thermodynamics of protein denaturation. Calorimetric study of the reversible denaturation of chymotrypsinogen and conclusions regarding the accuracy of the two-state approximation. Biochemistry. 1970;9:2294–301.\nPoklar N, Vesnaver G, Lapanje S. Interactions of alpha-chymotrypsinogen A with alkylureas. Biophys Chem. 1996;57:279–89.\nChalikian TV, Volker J, Anafi D, Breslauer KJ. The native and the heat-induced denatured states of α-chymotrypsinogen A: thermodynamic and spectroscopic studies. J Mol Biol. 1997;274:237–52.\nRomero CM, Albis A, Lozano JM, Sancho J. Thermodynamic study of the influence of polyols and glucose on the thermal stability of holo-bovine α-lactalbumin. J Therm Anal Calorim. 2009;98:165–71.\nCooper A. Thermodynamics of protein folding and stability. Protein A Compr Treatise. 1999;2:217–70.\nBrandts JF, Hunt L. Thermodynamics of protein denaturation III. Denaturation of ribonuclease in water and in aqueous urea and aqueous ethanol mixtures. J Am Chem Soc. 1967;89:4826–38.\nHaque I, Singh R, Moosavi-Movahedi AA, Ahmad F. Effect of polyol osmolytes on ∆GD, the Gibbs energy of stabilisation of proteins at different pH values. Biophys Chem. 2005;117:1–12.\nSancho J. The stability of 2-state, 3-state and more-state proteins from simple spectroscopic techniques… plus the structure of the equilibrium intermediates at the same time. Arch Biochem Biophys. 2013;531:4–13.\nMiyawaki O, Tatsuno M. Thermodynamic analysis of alcohol effect on thermal stability of proteins. J Biosci Bioeng. 2011;111:198–203.\nGekko K, Morikawa T. Thermodynamics of polyol-induced thermal stabilization of chymotrypsinogen. J Biochem. 1981;90:51–60.\nPrivalov PL. Stability of proteins: small globular proteins. Adv Protein Chem. 1979;33:167–241.\nSturtevant JM. Biochemical applications of differential scanning calorimetry. Annu Rev Phys Chem. 1987;38:463–88.\nPrivalov PL, Khechinashvili NN. A thermodynamic approach to the problem of stabilization of globular protein structure: a calorimetric study. J Mol Biol. 1974;86:665–84.\nGreenfield NJ. Using circular dichroism spectra to estimate protein secondary structure. Nat Protoc. 2006;1:2876–90.\nGreenfield NJ, Fasman GD. Computed circular dichroism spectra for the evaluation of protein conformation. Biochemistry. 1969;8:4108–16.\nBrahms S, Brahms J. Determination of protein secondary structure in solution by vacuum ultraviolet circular dichroism. J Mol Biol. 1980;138:149–78.\nReed J, Reed TA. A set of constructed type spectra for the practical estimation of peptide secondary structure from circular dichroism. Anal Biochem. 1997;254:36–40.\nMao D, Wachter E, Wallace BA. Folding of the mitochondrial proton adenosine triphosphatase proteolipid channel in phospholipid vesicles. Biochemistry. 1982;21:4960–8.\nFreer ST, Kraut J, Robertus JD, Wright HT. Chymotrypsinogen: 2,5-Å crystal structure, comparison with α-chymotrypsin, and implications for zymogen activation. Biochemistry. 1970;9:1997–2009.\nWang D, Bode W, Huber R. Bovine chymotrypsinogen A X-ray crystal structure analysis and refinement of a new crystal form at 1.8 A resolution. J Mol Biol. 1985;185:595–624.\nKhan F, Khan RH, Muzammil S. Alcohol-induced versus anion-induced states of alpha-chymotrypsinogen A at low pH. Biochim Biophys Acta. 2000;1481:229–36.",{"VOID":506},"10.1007\u002Fs10973-014-4374-2","2025-01-02T03:32:46.294+00:00",[186],"https:\u002F\u002Flink.springer.com\u002Farticle\u002F10.1007\u002Fs10973-014-4374-2",[511,526,539,554],{"id":512,"sortIndex":19,"researcher":18,"roles":513,"affiliations":514,"properties":523,"displayName":525,"givenName":18,"familyName":18},"9cb03781-5dab-4249-bf88-31e04074d916",[192],[515],{"id":516,"sortIndex":19,"affiliation":517,"properties":18},"7c695362-b9cf-40be-aae3-5497c40afe00",{"id":516,"createTime":18,"updateTime":18,"relativeEntities":518,"slug":18,"properties":519,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":522,"statistic":18},[],{"title":520},{"VI":521},"Departamento de Química, Universidad Nacional de Colombia, Bogotá, Colombia",[],{"title":524},{"VI":525},"Carmen M. Romero",{"id":527,"sortIndex":109,"researcher":18,"roles":528,"affiliations":529,"properties":536,"displayName":538,"givenName":18,"familyName":18},"3d4a1064-595e-467a-982f-75b57c2e726b",[192],[530],{"id":516,"sortIndex":19,"affiliation":531,"properties":18},{"id":516,"createTime":18,"updateTime":18,"relativeEntities":532,"slug":18,"properties":533,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":535,"statistic":18},[],{"title":534},{"VI":521},[],{"title":537},{"VI":538},"Juan S. 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Velázquez",{"id":555,"sortIndex":236,"researcher":18,"roles":556,"affiliations":557,"properties":573,"displayName":575,"givenName":18,"familyName":18},"15988bff-4a95-4d8b-a5a0-fe014622d72e",[192],[558,566],{"id":559,"sortIndex":19,"affiliation":560,"properties":18},"3ca271e2-0937-439e-8986-db40f1b3f74d",{"id":559,"createTime":18,"updateTime":18,"relativeEntities":561,"slug":18,"properties":562,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":565,"statistic":18},[],{"title":563},{"VI":564},"Departamento de Bioquímica y Biología Molecular y Celular, Universidad de Zaragoza, Zaragoza, 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integration of cavities designed with distinct specifications enhances the convective heat transfer, leads to improved performance of engineering systems. The current research focuses on numerical investigation of mixed convection within the cavity, which features a partially heated wall and a rotating cylinder. The cavity is filled with hybrid nanofluid comprising Al\n              \n                \n              \n              $$_{2}$$\n              \n            O\n              \n                \n              \n              $$_{3}$$\n              \n             and Cu nanoparticles suspended in water, serving as base fluid. The dimensionless governing equations were derived with a novel transformation of parameters along with consideration of the two-phase Buongiorno model. The input parameters examined included the Rayleigh number (\n              \n                \n              \n              $$10^3 \\le \\text{Ra} \\le 10^6$$\n              \n            ), the dimensionless radius of the cylinder (\n              \n                \n              \n              $$0.1 \\le R \\le 0.4$$\n              \n            ), the angular rotational velocity of the cylinder (\n              \n                \n              \n              $$0 \\le \\Omega \\le 600$$\n              \n            ), the concentration of nanoparticles (\n              \n                \n              \n              $$0.02 \\le \\phi \\le 0.05$$\n              \n            ), and the dimensionless length of partially heated wall. Utilizing COMSOL Multiphysics as a simulation platform, Galerkin’s Weighted Residual Method is used to solve the governing equations. The impact of varying parameters is analyzed through the visualization of streamlines, dimensionless temperature with isothermal lines, normalized solid volume fraction, and their influence on both local and average Nusselt numbers. The observed results indicate an indirect relationship between average Nusselt number and the length of the partially heated wall. Moreover, the careful consideration of the varying parameters discussed leads to improved heat transfer performance of the hybrid nanofluid in the cavity. The highest value of Nusselt number attained is 8.9456 at \n              \n                \n              \n              $$\\phi _{\\rm{hnf}}=0.05$$\n              \n            , \n              \n                \n              \n              $$\\Omega =250$$\n              \n             and \n              \n                \n              \n              $$R=0.2$$\n              \n            , underscoring a notable achievement that surpasses the values reported in previous works. The findings of this study offer valuable implications for optimizing convective heat transfer in applications, such as heat exchangers and electronic cooling systems.",{"EN":640,"VI":641},"Numerical investigation of multiphase flow effects on mixed convection in partially heated hybrid nanofluid-filled cavity","Nghiên cứu số về các hiệu ứng dòng chảy đa pha lên đối lưu hỗn hợp trong hốc chứa đầy chất lỏng nano lai được gia nhiệt một phần",{"EN":643},"",{"VOID":645},"Alsabery AI, Abosinnee AS, Al-Hadraawy SK, Ismael MA, Fteiti MA, Hashim I, Sheremet M, Ghalambaz M, Chamkha AJ. Convection heat transfer in enclosures with inner bodies: a review on single and two-phase nanofluid models. Renew Sustain Energy Rev. 2023;183: 113424. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.rser.2023.113424.\nCorcione M. Empirical correlating equations for predicting the effective thermal conductivity and dynamic viscosity of nanofluids. Energy Convers Manag. 2011;52(1):789–93. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.enconman.2010.06.072.\nDas SK, Putra N, Thiesen P, Roetzel W. Temperature dependence of thermal conductivity enhancement for nanofluids. J Heat Transf. 2003;125(4):567–74. https:\u002F\u002Fdoi.org\u002F10.1115\u002F1.1571080.\nMintsa HA, Roy G, Nguyen CT, Doucet D. New temperature dependent thermal conductivity data for water-based nanofluids. Int J Therm Sci. 2009;48(2):363–71. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.ijthermalsci.2008.03.009.\nHuminic G, Huminic A. The influence of hybrid nanofluids on the performances of elliptical tube: Recent research and numerical study. Int J Heat Mass Transf. 2019;129:132–43. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.ijheatmasstransfer.2018.09.107.\nMahmood Z, Khan U, Al-Zubaidi A. Nanofluid flow with slip condition over a moving surface: buoyancy and heat source effects at the separated stagnation point. J Therm Anal Calorim. 2023. https:\u002F\u002Fdoi.org\u002F10.1007\u002Fs10973-023-12721-0.\nAlqahtani AM, Rafique K, Mahmood Z, Al-Sinan BR, Khan U, Hassan AM. MHD rotating flow over a stretching surface: the role of viscosity and aggregation of nanoparticles. Heliyon. 2023;9(11):21107. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.heliyon.2023.e21107.\nMahmood Z, Duraihem FZ, Khan U, Rafique K, Ghareeb Goma H. Flow across moving plate at separated stagnation point: features of corcione’s correlation with Thompson and Troian slip and melting heat. Numer Heat Transf Part B Fundam. 2023. https:\u002F\u002Fdoi.org\u002F10.1080\u002F10407790.2023.2270155.\nÇolak AB, Shafiq A, Sindhu TN. Modeling of Darcy–Forchheimer bioconvective Powell Eyring nanofluid with artificial neural network. Chin J Phys. 2022;77:2435–53. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.cjph.2022.04.004.\nShafiq A, Çolak AB, Sindhu TN. Modeling of Soret and Dufour’s convective heat transfer in nanofluid flow through a moving needle with artificial neural network. Arab J Sci Eng. 2023;48(3):2807–20. https:\u002F\u002Fdoi.org\u002F10.1007\u002Fs13369-022-06945-9.\nShafiq A, Çolak AB, Sindhu TN, Muhammad T. Optimization of Darcy–Forchheimer squeezing flow in nonlinear stratified fluid under convective conditions with artificial neural network. Heat Transf Res. 2022;53(3):100. https:\u002F\u002Fdoi.org\u002F10.1615\u002FHeatTransRes.2021041018.\nNasir S, Sirisubtawee S, Juntharee P, Berrouk AS, Mukhtar S, Gul T. Heat transport study of ternary hybrid nanofluid flow under magnetic dipole together with nonlinear thermal radiation. Appl Nanosci. 2022;12(9):2777–88. https:\u002F\u002Fdoi.org\u002F10.1007\u002Fs13204-022-02583-7.\nNasir S, Berrouk AS. Numerical and intelligent neuro-computational modelling with Fourier’s energy and Fick’s mass flux theory of 3d fluid flow through a stretchable surface. Engineering Applications of Computational Fluid Mechanics. 2023;17(1):2270675. https:\u002F\u002Fdoi.org\u002F10.1080\u002F19942060.2023.2270675.\nMahmood Z, El-Rahman MA, Khan U, Hassan AM, Khalifa HAE-W. Entropy generation due to nanofluid flow in porous media over radiative permeable exponentially surface with nanoparticle aggregation effect. Tribol Int. 2023;188:108852. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.triboint.2023.108852.\nRafique K, Mahmood Z, Alqahtani AM, Elsiddieg AMA, Khan U, Deebani W, Shutaywi M. Impacts of thermal radiation with nanoparticle aggregation and variable viscosity on unsteady bidirectional rotating stagnation point flow of nanofluid. Mater Today Commun. 2023;36: 106735. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.mtcomm.2023.106735.\nAlqahtani AM, Rafique K, Mahmood Z, Al-Sinan BR, Khan U, Hassan AM. MHD As b rotating flow over a stretching surface: The role of viscosity and aggregation of nanoparticles. Heliyon. 2023. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.heliyon.2023.e21107.\nPutra N, Roetzel W, Das SK. Natural convection of nano-fluids. Heat Mass Transf. 2003;39(8–9):775–84. https:\u002F\u002Fdoi.org\u002F10.1007\u002Fs00231-002-0382-z.\nKhanafer K, Aithal SM. Mixed convection heat transfer in a lid-driven cavity with a rotating circular cylinder. Int Commun Heat Mass Transf. 2017;86:131–42. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.icheatmasstransfer.2017.05.025.\nJamil F, Ali HM. Applications of hybrid nanofluids in different fields. In: Hybrid Nanofluids for Convection Heat Transfer. Amsterdam: Elsevier; 2020. p. 215–54. https:\u002F\u002Fdoi.org\u002F10.1016\u002FB978-0-12-819280-1.00006-9\nManohar GR, Venkatesh P, Gireesha BJ, Madhukesh JK, Ramesh GK. Dynamics of hybrid nanofluid through a semi spherical porous fin with internal heat generation. Partial Differ Equ Appl Math. 2021;4: 100150. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.padiff.2021.100150.\nMadhukesh JK, Naveen Kumar R, Punith Gowda RJ, Prasannakumara BC, Ramesh GK, Ijaz Khan M, Ullah Khan S, Chu Y-M. Numerical simulation of aa7072–aa7075\u002Fwater-based hybrid nanofluid flow over a curved stretching sheet with Newtonian heating: A non-Fourier heat flux model approach. J Mol Liq. 2021;335: 116103. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.molliq.2021.116103.\nRamesh GK, Madhukesh JK, Ali Shah N, Yook S-J. Flow of hybrid CNTs past a rotating sphere subjected to thermal radiation and thermophoretic particle deposition. Alex Eng J. 2023;64:969–79. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.aej.2022.09.026.\nSelimefendigil F, Öztop HF. MHD mixed convection of nanofluid filled partially heated triangular enclosure with a rotating adiabatic cylinder. J Taiwan Inst Chem Eng. 2014;45(5):2150–62. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.jtice.2014.06.018.\nRoslan R, Saleh H, Hashim I. Effect of rotating cylinder on heat transfer in a square enclosure filled with nanofluids. Int J Heat Mass Transf. 2012;55(23–24):7247–56. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.ijheatmasstransfer.2012.07.051.\nSheremet MA, Pop I, Mahian O. Natural convection in an inclined cavity with time–periodic temperature boundary conditions using nanofluids: application in solar collectors. Int J Heat Mass Transf. 2018;116:751–61. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.ijheatmasstransfer.2017.09.070.\nAlsabery AI, Gedik E, Chamkha AJ, Hashim I. Impacts of heated rotating inner cylinder and two-phase nanofluid model on entropy generation and mixed convection in a square cavity. Heat Mass Transf. 2020;56(1):321–38. https:\u002F\u002Fdoi.org\u002F10.1007\u002Fs00231-019-02698-8.\nCorcione M, Cianfrini M, Quintino A. Two-phase mixture modeling of natural convection of nanofluids with temperature-dependent properties. Int J Therm Sci. 2013;71:182–95. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.ijthermalsci.2013.04.005.\nCosta V, Raimundo A. Steady mixed convection in a differentially heated square enclosure with an active rotating circular cylinder. Int J Heat Mass Transf. 2010;53(5–6):1208–19. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.ijheatmasstransfer.2009.10.007.\nLiao C-C, Lin C-A. Mixed convection of a heated rotating cylinder in a square enclosure. Int J Heat Mass Transf. 2014;72:9–22. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.ijheatmasstransfer.2013.12.081.\nSelimefendigil F, Öztop HF, Chamkha AJ. Analysis of mixed convection of nanofluid in a 3D lid-driven trapezoidal cavity with flexible side surfaces and inner cylinder. Int Commun Heat Mass Transf. 2017;87:40–51. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.icheatmasstransfer.2017.06.015.\nMohebbi R, Rashidi M. Numerical simulation of natural convection heat transfer of a nanofluid in an l-shaped enclosure with a heating obstacle. J Taiwan Inst Chem Eng. 2017;72:70–84. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.jtice.2017.01.006.\nIshak MS, Alsabery AI, Hashim I, Chamkha AJ. Entropy production and mixed convection within trapezoidal cavity having nanofluids and localised solid cylinder. Sci Rep. 2021;11(1):14700. https:\u002F\u002Fdoi.org\u002F10.1038\u002Fs41598-021-94238-w.\nAlinia M, Ganji D, Gorji-Bandpy M. Numerical study of mixed convection in an inclined two sided lid driven cavity filled with nanofluid using two-phase mixture model. Int Commun Heat Mass Transf. 2011;38(10):1428–35. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.icheatmasstransfer.2011.08.003.\nPuneeth V, Manjunatha S, Madhukesh JK, Ramesh GK. Three dimensional mixed convection flow of hybrid Casson nanofluid past a nonlinear stretching surface: a modified buongiorno’s model aspects. Chaos Solitons Fractals. 2021;152: 111428. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.chaos.2021.111428.\nMinea AA. Hybrid nanofluids based on Al\\(_2\\)O\\(_3\\), TiO\\(_2\\) and SiO\\(_2\\): numerical evaluation of different approaches. Int J Heat Mass Transf. 2017;104:852–60. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.ijheatmasstransfer.2016.09.012.\nBatchelor G. The effect of Brownian motion on the bulk stress in a suspension of spherical particles. J Fluid Mech. 1977;83(1):97–117. https:\u002F\u002Fdoi.org\u002F10.1017\u002FS0022112077001062.\nPrasher R, Song D, Wang J, Phelan P. Measurements of nanofluid viscosity and its implications for thermal applications. Appl Phys Lett. 2006;89(13): 133108. https:\u002F\u002Fdoi.org\u002F10.1063\u002F1.2356113.\nBuongiorno J. Convective transport in nanofluids. J Heat Transf. 2005;128(3):240–50. https:\u002F\u002Fdoi.org\u002F10.1115\u002F1.2150834.\nWahid NS, Arifin NM, Khashi’ie NS, Pop I, Bachok N, Hafidzuddin MEH. Hybrid nanofluid radiative mixed convection stagnation point flow past a vertical flat plate with Dufour and Soret effects. Mathematics. 2022;10(16):2966. https:\u002F\u002Fdoi.org\u002F10.3390\u002Fmath10162966.\nRafique K, Mahmood Z, Khan U. Mathematical analysis of MHD hybrid nanofluid flow with variable viscosity and slip conditions over a stretching surface. Mater Today Commun. 2023;36: 106692. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.mtcomm.2023.106692.\nAhmad S, Takana H, Ali K, Akhtar Y, Hassan AM, Ragab AE. Role of localized magnetic field in vortex generation in tri-hybrid nanofluid flow: a numerical approach. Nanotechnol Rev. 2023;12(1):20220561. https:\u002F\u002Fdoi.org\u002F10.1515\u002Fntrev-2022-0561.\nSuresh S, Venkitaraj K, Selvakumar P, Chandrasekar M. Synthesis of Al\\(_2\\)O\\(_3\\)–Cu\u002Fwater hybrid nanofluids using two step method and its thermo physical properties. Colloids Surf A. 2011;388(1–3):41–8. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.colsurfa.2011.08.005.\nBergman TL, Lavine AS, Incropera FP, DeWitt DP. Introduction to Heat Transfer. New York: Wiley; 2011. p. 916.",{"VOID":647},"10.1007\u002Fs10973-023-12860-4","2025-02-25T21:28:23.253+00:00",[186],"https:\u002F\u002Flink.springer.com\u002Farticle\u002F10.1007\u002Fs10973-023-12860-4",[652,675,690,711,726],{"id":653,"sortIndex":19,"researcher":18,"roles":654,"affiliations":655,"properties":672,"displayName":674,"givenName":18,"familyName":18},"2bc891fc-f51e-435f-b3f5-74c0db3e2af2",[192],[656,664],{"id":657,"sortIndex":19,"affiliation":658,"properties":18},"8d47c630-6f70-45af-a23a-378c2b3c1981",{"id":657,"createTime":18,"updateTime":18,"relativeEntities":659,"slug":18,"properties":660,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":663,"statistic":18},[],{"title":661},{"VI":662},"Department of Mathematical Sciences, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, Bangi, Malaysia",[],{"id":665,"sortIndex":19,"affiliation":666,"properties":18},"6ca34968-8b5e-4691-b408-d497084df5c8",{"id":665,"createTime":18,"updateTime":18,"relativeEntities":667,"slug":18,"properties":668,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":671,"statistic":18},[],{"title":669},{"VI":670},"Department of Basic Sciences, DHA Suffa University, Karachi, Pakistan",[],{"title":673},{"VI":674},"Muhammad Ashhad Shahid",{"id":676,"sortIndex":109,"researcher":18,"roles":677,"affiliations":678,"properties":687,"displayName":689,"givenName":18,"familyName":18},"85465273-04d1-40af-b63f-f0efd0b271fe",[192],[679],{"id":680,"sortIndex":19,"affiliation":681,"properties":18},"799277e9-f792-4a43-a6fb-b246381551df",{"id":680,"createTime":18,"updateTime":18,"relativeEntities":682,"slug":18,"properties":683,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":686,"statistic":18},[],{"title":684},{"VI":685},"Solar Energy Research Institute, Universiti Kebangsaan Malaysia, Bangi, Malaysia",[],{"title":688},{"VI":689},"Mojtaba Dayer",{"id":691,"sortIndex":222,"researcher":18,"roles":692,"affiliations":693,"properties":708,"displayName":710,"givenName":18,"familyName":18},"b47d253d-8361-4e00-a1f3-49f694be9dea",[192],[694,702],{"id":695,"sortIndex":19,"affiliation":696,"properties":18},"e668b3f3-5b9a-4573-9458-17a3114732fd",{"id":695,"createTime":18,"updateTime":18,"relativeEntities":697,"slug":18,"properties":698,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":701,"statistic":18},[],{"title":699},{"VI":700},"Nonlinear Dynamics Research Center (NDRC), Ajman University, Ajman, United Arab Emirates",[],{"id":657,"sortIndex":19,"affiliation":703,"properties":18},{"id":657,"createTime":18,"updateTime":18,"relativeEntities":704,"slug":18,"properties":705,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":707,"statistic":18},[],{"title":706},{"VI":662},[],{"title":709},{"VI":710},"Ishak Hashim",{"id":712,"sortIndex":236,"researcher":18,"roles":713,"affiliations":714,"properties":723,"displayName":725,"givenName":18,"familyName":18},"8c119cdd-c758-4d0c-90b3-fc68c42b24a6",[192],[715],{"id":716,"sortIndex":19,"affiliation":717,"properties":18},"501cc3e9-955f-4cf0-a66e-8bc536d6c40e",{"id":716,"createTime":18,"updateTime":18,"relativeEntities":718,"slug":18,"properties":719,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":722,"statistic":18},[],{"title":720},{"VI":721},"Refrigeration and Air-Conditioning Technical Engineering Department, The Islamic University, Najaf, Iraq",[],{"title":724},{"VI":725},"Ammar I. Alsabery",{"id":727,"sortIndex":250,"researcher":18,"roles":728,"affiliations":729,"properties":744,"displayName":746,"givenName":18,"familyName":18},"c1e82056-8828-45a3-9d12-b5dd2e35738f",[192],[730,738],{"id":731,"sortIndex":19,"affiliation":732,"properties":18},"c323589b-f5ef-4374-b7fe-a3f484af2ff8",{"id":731,"createTime":18,"updateTime":18,"relativeEntities":733,"slug":18,"properties":734,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":737,"statistic":18},[],{"title":735},{"VI":736},"Department of Mathematics, Faculty of Science, University of Jordan, Amman, Jordan",[],{"id":695,"sortIndex":19,"affiliation":739,"properties":18},{"id":695,"createTime":18,"updateTime":18,"relativeEntities":740,"slug":18,"properties":741,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":743,"statistic":18},[],{"title":742},{"VI":700},[],{"title":745},{"VI":746},"Shaher Momani",{"url":18,"publisher":748,"properties":18},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":749,"slug":10,"properties":750,"entityType":16,"verifyStatus":17,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":19,"subjectFields":753,"manageAffiliations":762,"indexDatabases":773,"url":18,"thumbnailPath":18,"statistic":788,"gsStatistic":18,"type":160,"analyzePriority":18},[],{"issn":751,"title":752},{"VOID":13},{"VOID":15},[754,758],{"id":22,"createTime":18,"updateTime":18,"relativeEntities":755,"label":756,"description":757,"parentId":18,"standard":18,"scholarHubFieldId":18},[],{"EN":25},{},{"id":28,"createTime":18,"updateTime":18,"relativeEntities":759,"label":760,"description":761,"parentId":18,"standard":18,"scholarHubFieldId":18},[],{"EN":31},{},[763,768],{"id":35,"createTime":18,"updateTime":18,"relativeEntities":764,"slug":18,"properties":765,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":767,"statistic":18},[],{"title":766},{"EN":39},[],{"id":42,"createTime":18,"updateTime":18,"relativeEntities":769,"slug":18,"properties":770,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":772,"statistic":18},[],{"title":771},{"EN":46},[48],[774,781],{"id":51,"indexDatabase":775,"url":64,"indexYears":18,"academicFieldIds":780,"indexDatabaseRanking":18},{"id":53,"createTime":18,"updateTime":18,"relativeEntities":776,"label":777,"description":778,"key":60,"publicationTags":779,"standard":18},[],{"EN":56,"VI":56},{"EN":58,"VI":59},[62,63],[66,67],{"id":69,"indexDatabase":782,"url":80,"indexYears":81,"academicFieldIds":787,"indexDatabaseRanking":85},{"id":71,"createTime":18,"updateTime":18,"relativeEntities":783,"label":784,"description":785,"key":77,"publicationTags":786,"standard":18},[],{"EN":74,"VI":74},{"EN":74,"VI":76},[79],[83,84],{"impactFactor":19,"impactFactorByYear":789,"i10Index":99,"i10IndexLast5Year":100,"totalPublication":101,"totalPublicationByYear":790,"totalCitation":122,"totalCitationByYear":791,"totalCitationPerPublication":141,"totalCitationPerPublicationByYear":792,"hindexLast5Year":159,"hindex":159},{"2012":88,"2014":89,"2015":90,"2016":91,"2017":92,"2018":93,"2019":94,"2020":95,"2021":96,"2022":97,"2023":98},{"2003":103,"2004":104,"2005":105,"2006":106,"2009":107,"2010":108,"2011":109,"2012":109,"2013":110,"2014":111,"2015":112,"2016":113,"2017":114,"2018":115,"2019":116,"2020":117,"2021":118,"2022":119,"2023":120,"2024":121},{"2003":124,"2004":125,"2005":126,"2006":127,"2010":128,"2013":129,"2014":130,"2015":131,"2016":132,"2017":133,"2018":134,"2019":135,"2020":136,"2021":137,"2022":138,"2023":139,"2024":140},{"2003":143,"2004":144,"2005":145,"2006":146,"2010":147,"2013":148,"2014":149,"2015":150,"2016":151,"2017":152,"2018":153,"2019":154,"2020":150,"2021":155,"2022":156,"2023":157,"2024":158},"2024-02-27",2024,[85,62],{"id":797,"createTime":798,"updateTime":799,"relativeEntities":800,"slug":801,"properties":802,"entityType":181,"verifyStatus":17,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":812,"viewCount":19,"primaryUrl":813,"fullTextUrl":18,"authors":814,"publicationType":289,"publisherRelationship":856,"citationCount":18,"citationInfo":18,"publishDate":907,"publishYear":908,"citationAnalyzeStatus":17,"lastCitationAnalyze":18,"indexDatabases":909,"openAccess":18,"references":18,"isForceReanalyzing":344},"7000721f-903c-44ab-b89d-6585dcdc3f75","2024-01-30T02:05:47.699+00:00","2026-09-04T07:50:10.761+00:00",[],"Thermodynamic-properties-of-hydroxypropyl-%CE%B2-cyclodextrin-guest-interaction-a-survey-of-recent-studies",{"abstract":803,"title":805,"references":808,"doi":810},{"EN":804},"For many years, cyclodextrins (CDs) have been the object of attention for their capability of improving the stability, solubility and bioavailability of numerous molecules of interest, including drugs and nutraceuticals. They have low toxicity and for this reason have been employed for different routes of administration, including oral, ocular, nasal and parenteral. Among them, the hydroxypropyl-β-cyclodextrin (HP-β-CD) is the least toxic. Several physicochemical methodologies have been employed for studying cyclodextrin\u002Fguest interaction, but isothermal titration calorimetry (ITC) is the only one capable of simultaneously providing the binding constant, ΔH°, ΔS°, ΔG° and the binding stoichiometry. Here, we present the state of the art of ITC studies applied to HP-β-CD\u002Fguest complexes, discussing selected publications of the last five years, highlighting the thermodynamic factors that are decisive for optimal encapsulation.",{"EN":806,"VI":807},"Thermodynamic properties of hydroxypropyl-β-cyclodextrin\u002Fguest interaction: a survey of recent studies","Các tính chất nhiệt động học của tương tác hydroxypropyl-β-cyclodextrin\u002Fkhách: khảo sát các nghiên cứu gần đây",{"VOID":809},"Tonkova A. Bacterial cyclodextrin glucanotransferase. Enzyme Microb Technol. 1998;22:678–86.\nDavis ME, Brewster ME. Cyclodextrin-based pharmaceutics: past, present and future. Nat Rev Drug Discov. 2004;3:1023–35.\nLoftsson T, Duchene D. Cyclodextrins and their pharmaceutical applications. Int J Pharm. 2007;329:1–11.\nOtero-Espinar FJ, Torres-Labandeira JJ, Alvarez-Lorenzo C, Blanco-Méndez J. Cyclodextrins in drug delivery systems. J Drug Deliv Sci Technol. 2010;20:289–301.\nKurkov SV, Loftsson T. Cyclodextrins. Int J Pharm. 2013;453:167–80.\nJansook P, Ogawa N, Loftsson T. Cyclodextrins: structure, physicochemical properties and pharmaceutical applications. Int J Pharm. 2018;535:272–84.\nMuankaew C, Loftsson T. Cyclodextrin-based formulations: a non-invasive platform for targeted drug delivery. Basic Clin Pharmacol Toxicol. 2018;122:46–55.\ndos Santos Silva Araújo L, Lazzara G, Chiappisi L. Cyclodextrin\u002Fsurfactant inclusion complexes: An integrated view of their thermodynamic and structural properties. Adv Colloid Interface Sci. 2021;289:102375.\nJambhekar SS, Breen P. Cyclodextrins in pharmaceutical formulations I: structure and physicochemical properties, formation of complexes, and types of complex. Drug Discov Today. 2016;21:356–62.\nGould S, Scott RC. 2-Hydroxypropyl-β-cyclodextrin (HP-β-CD): A toxicology review. Food Chem Toxicol. 2005;43:1451–9.\nChatziathanasiadou MV, Mavromoustakos T, Tzakos AG. Unveiling the thermodynamic aspects of drug-cyclodextrin interactions through isothermal titration calorimetry. Methods Mol Biol. 2021;2207:187–98.\nPagano B, Mattia CA, Giancola C. Applications of isothermal titration calorimetry in biophysical studies of G-quadruplexes. Int J Mol Sci. 2009;10:2935–57.\nGiancola C, Pagano B. Energetics of ligand binding to G-quadruplexes. Top Curr Chem. 2013;330:211–42.\nFotticchia I, Fotticchia T, Mattia CA, Giancola C. Chitosan-based nanoparticles studied by isothermal titration calorimetry. J Therm Anal Calorim. 2016;125:585–93.\nFotticchia I, Fotticchia T, Mattia CA, Netti PA, Vecchione R, Giancola C. Thermodynamic signature of secondary nano-emulsion formation by isothermal titration calorimetry. Langmuir. 2014;30:14427–33.\nPagano B, Fotticchia I, De Tito S, Mattia CA, Mayol L, Novellino E, et al. Selective binding of distamycin a derivative to G-quadruplex structure [d(TGGGGT)]4. J Nucleic Acids. 2010;2010:247137.\nLadbury JE. Calorimetry as a tool for understanding biomolecular interactions and an aid to drug design. Biochem Soc Trans. 2010;38:888–93.\nHipólito-Nájera AR, del Rosario M-H, Rojas-Hernández A, Gómez-Balderas R. Interaction of indomethacin–cyclodextrins in water by UV–Vis and ITC. J Incl Phenom Macrocycl Chem. 2019;95:55–62.\nUria-Canseco E, Perez-Casas S, Navarrete-Vázquez G. Thermodynamic characterization of the inclusion complexes formation between antidiabetic new drugs and cyclodextrins. J Chem Thermodyn. 2019;129:55–60.\nNavarrete-Vazquez G, Paoli P, León-Rivera I, Villalobos-Molina R, Medina-Franco JL, Ortiz-Andrade R, et al. Synthesis, in vitro and computational studies of protein tyrosine phosphatase 1B inhibition of a small library of 2-arylsulfonylaminobenzothiazoles with antihyperglycemic activity. Bioorg Med Chem. 2009;17:3332–41.\nAmaro B, Alves C, Ferreira G, Carvalho P, da Silva J, Souza C, et al. Multifunctionality of βCD\u002FOfloxacin and HPβCD\u002FOfloxacin complexes: improvement of the antimicrobial activity and apoptosis induction on lung adenocarcinoma A549 cells. J Braz Chem Soc. 2020;31:2628–37.\nCouto VM, de Oliveira-Nascimento L, Cabeça LF, Geraldes DC, Costa JSR, Riske KA, et al. Capsaicin-cyclodextrin complex enhances mepivacaine targeting and improves local anesthesia in inflamed tissues. Int J Mol Sci. 2020;21:1–17.\nGuimarães PPG, de Menezes AC, Teixeira KIR, Denadai ÂML, Fills RA, Cortés ME, et al. Enhanced efficacy against bacterial biofilms via host:guest cyclodextrin-doxycycline inclusion complexes. J Incl Phenom Macrocycl Chem. 2021. https:\u002F\u002Fdoi.org\u002F10.1007\u002Fs10847-020-01041-7.\nSachdeva V, Roy A, Bharadvaja N. Current prospects of nutraceuticals: a review. Curr Pharm Biotechnol. 2020;21:884–96.\nTian L, Cao J, Zhao T, Liu Y, Khan A, Cheng G. The bioavailability, extraction, biosynthesis and distribution of natural dihydrochalcone: phloridzin. Int J Mol Sci. 2021;22:962.\nZhang C-L, Liu J-C, Yang W-B, Chen D-L, Jiao Z-G. Experimental and molecular docking investigations on the inclusion mechanism of the complex of phloridzin and hydroxypropyl-β-cyclodextrin. Food Chem. 2017;215:124–8.\nD’Aria F, Serri C, Niccoli M, Mayol L, Quagliariello V, Iaffaioli RV, et al. Host–guest inclusion complex of quercetin and hydroxypropyl-β-cyclodextrin: a calorimetric study. J Therm Anal Calorim. 2017;130:451–6.\nXavier-Júnior FH, Tavares CT, Rabello MM, Hernandes MZ, Bezerra BP, Ayala AP, et al. Elucidation of the mechanism of complexation between oncocalyxone A and cyclodextrins by isothermal titration calorimetry and molecular modeling. J Mol Liq. 2019;274:165–72.\nda Silva RE, et al. Antimicrobial and antibiofilm activity of the benzoquinone oncocalyxone A. Microb Pathog. 2020;149:104513.\nBuko V, Zavodnik I, Palecz B, Stepniak A, Kirko S, Shlyahtun A, et al. Betulin\u002F2-hydroxypropyl-β-cyclodextrin inclusion complex: physicochemical characterization and hepatoprotective activity. J Mol Liq. 2020;309:113–8.\nAndreadelis I, Chatziathanasiadou ΜV, Ntountaniotis D, Valsami G, Papaemmanouil C, Christodoulou E, et al. Charting the structural and thermodynamic determinants in phenolic acid natural product-cyclodextrin encapsulations. J Biomol Struct Dyn. 2020;39:2642–58.\nWahl J, Furuishi T, Yonemochi E, Meinel L, Holzgrabe U. Characterization of complexes between phenethylamine enantiomers and β-cyclodextrin derivatives by capillary electrophoresis-determination of binding constants and complex mobilities. Electrophoresis. 2017;38:1188–200.\nLiu M, Zheng Y, Wang C, Xie J, Wang B, Wang Z, et al. Improved stability of (+)-catechin and (−)-epicatechin by complexing with hydroxypropyl-β-cyclodextrin: Effect of pH, temperature and configuration. Food Chem. 2016;196:148–54.\nMaurya PK, Rizvi SI. Protective role of tea catechins on erythrocytes subjected to oxidative stress during human aging. Nat Prod Res. 2009;23:1072–9.\nNagarajan S, Nagarajan R, Braunhut S, Bruno F, McIntosh D, Samuelson L, et al. Biocatalytically oligomerized epicatechin with potent and specific anti-proliferative activity for human breast cancer cells. Molecules. 2008;13:2704–16.\nUsacheva T, Kabirov D, Beregova D, Gamov G, Sharnin V, Biondi M, et al. Thermodynamics of complex formation between hydroxypropyl-β-cyclodextrin and quercetin in water–ethanol solvents at T = 298.15 K. J Therm Anal Calorim. 2019;138:417–24.\nCai C, Liu M, Yan H, Zhao Y, Shi Y, Guo Q, et al. A combined calorimetric, spectroscopic and molecular dynamic simulation study on the inclusion complexation of (E)-piceatannol with hydroxypropyl-β-cyclodextrin in various alcohol + water cosolvents. J Chem Thermodyn. 2019;132:341–51.\nKabirov D, Silvestri T, Niccoli M, Usacheva T, Mayol L, Biondi M, et al. Phase solubility and thermoanalytical studies of the inclusion complex formation between curcumin and hydroxypropyl-β-cyclodextrin in hydroalcoholic solutions. J Therm Anal Calorim. 2020;1–7.\nPaul BK, Ghosh N, Mukherjee S. Interaction of bile salts with β-cyclodextrins reveals nonclassical hydrophobic effect and enthalpy–entropy compensation. J Phys Chem B. 2016;120:3963–8.\nSchönbeck C, Holm R. Exploring the origins of enthalpy–entropy compensation by calorimetric studies of cyclodextrin complexes. J Phys Chem B. 2019;123:6686–93.\nGrunwald E, Steel C. Solvent reorganization and thermodynamic enthalpy–entropy compensation. J Am Chem Soc. 1995;117:5687–92.\nBreiten B, Lockett MR, Sherman W, Fujita S, Al-Sayah M, Lange H, et al. Water networks contribute to enthalpy\u002Fentropy compensation in protein-ligand binding. J Am Chem Soc. 2013;135:15579–84.\nDragan AI, Read CM, Crane-Robinson C. Enthalpy–entropy compensation: the role of solvation. Eur Biophys J. 2017;46:301–8.\nWalker CH. The hydrophobic effect: formation of micelles and biological membranes. FEBS Lett. 1981;124:127–127.\nSandilya AA, Natarajan U, Priya MH. Molecular view into the cyclodextrin cavity: structure and hydration. ACS Omega. 2020;5:25655–67.",{"VOID":811},"10.1007\u002Fs10973-021-10958-1",[186],"https:\u002F\u002Flink.springer.com\u002Farticle\u002F10.1007\u002Fs10973-021-10958-1",[815,830,843],{"id":816,"sortIndex":19,"researcher":18,"roles":817,"affiliations":818,"properties":827,"displayName":829,"givenName":18,"familyName":18},"2b7b2630-0ca1-471a-80c0-94079784e01e",[192],[819],{"id":820,"sortIndex":19,"affiliation":821,"properties":18},"a6ec7a25-bab7-4dc9-8357-7646389d851b",{"id":820,"createTime":18,"updateTime":18,"relativeEntities":822,"slug":18,"properties":823,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":826,"statistic":18},[],{"title":824},{"EN":825},"Department of Pharmacy, University of Naples “Federico II”, Naples, Italy",[],{"title":828},{"VI":829},"Federica D’Aria",{"id":831,"sortIndex":109,"researcher":18,"roles":832,"affiliations":833,"properties":840,"displayName":842,"givenName":18,"familyName":18},"09b52af3-6ed6-47be-9576-3bd3b057632b",[192],[834],{"id":820,"sortIndex":19,"affiliation":835,"properties":18},{"id":820,"createTime":18,"updateTime":18,"relativeEntities":836,"slug":18,"properties":837,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":839,"statistic":18},[],{"title":838},{"EN":825},[],{"title":841},{"VI":842},"Bruno 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of the V2O5–SrO system allowed final confirmation of formation of four compounds of the following stoichiometric formulas: Sr(VO3)2, Sr2V2O7, Sr3(VO4)2 and Sr4V2O9. The results presented permitted solving literature controversies regarding low- and high-temperature polymorphs of strontium metavanadate(V), i.e. Sr(VO3)2-I and Sr(VO3)2-II. The polymorphic transformation of both varieties that crystallize in the orthorhombic system was proved to be reversible and take place at 530 °C. Strontium metavanadate(V) was found to melt incongruently at 670 °C with deposition of solid Sr2V2O7. Both polymorphic forms of Sr(VO3)2 were studied by IR and SEM methods. According to the results of tests using the UV-Vis-DRS method, both polymorphs Sr(VO3)2 belong to the semiconductor class. Thermal stabilities of Sr2V2O7, Sr3(VO4)2 and Sr4V2O9 were verified. The powder diffractogram of Sr4V2O9 was indexed.",{"EN":920},"Reinvestigation of thermal and other properties of compounds from the V2O5–SrO system",{"VOID":922},"[]",{"VOID":924},"Kaur P, Khanna A. Structural, electrical and luminescence properties of M2V2O7 (M = Mg, Ca, Sr, Ba, Zn). J Mater Sci: Mater Electron. 2021;32:21813–23.\nSharma A, Varshney M, Chae K-H, Won SO. Electronic structure and luminescence assets in white-light emitting Ca2V2O7, Sr2V2O7 and Ba2V2O7 pyro-vanadates: X-ray absorption spectroscopy investigations. RSC Adv. 2018;8:26423–31.\nBedyal AK, Kumar V, Swart HC. Charge compensated derived enhanced red emission from Sr3(VO4)2:Eu3+ nanophosphors for white light emitting diodes and flat panel displays. J Alloys Compd. 2017;109:362–72.\nLi L, Wang W, Pan Y, Zhu Y, Liu X, Noh HM, Moon BK, Choi BC, Jeong JH. Preferential occupancy of Eu3+ and energy transfer in Eu3+ doped Sr2V2O7, Sr9Gd(VO4)7 and Sr2V2O7\u002F Sr9Gd(VO4)7 phosphors. RSC Adv. 2018;8:1191–202.\nSawala NS, Koparkar KA, Bajaj NS, Omanwar SK. Near-infrared spectral downshifting in Sr(3–x)(VO4)2:xNd3+ phosphor. Bull Mater Sci. 2016;39:1625–9.\nMachida M, Ikematsu A, Nur ASM, Yoshida H. Catalytic SO3 decomposition activity of SiO2-supported alkaline earth vanadates for solar thermochemical water splitting cycles. ACS Appl Energy Mater. 2021;4:1696–703.\nZhou Y, Kang S-Z, Qin L, Li X. Boosting charge separation and nitrogen vacancies in graphitic carbon nitride by implanted strontium vanadate for highly efficient photocatalytic reduction of hexavalent chromium. RSC Adv. 2021;11:16034–9.\nKarthik R, Kumar JV, Chen S-M, Kumar PS, Selvam V, Muthuraj V. A selective electrochemical sensor for caffeic acid and photocatalyst for metronidazole drug pollutant - a dual role by rod-like SrV2O6. Sci Rep. 2017;7:1–12.\nChen J, Li C, Xiang H, Tang Y, Fang L. SrV2O6: an ultralow-firing microwave dielectric ceramic for LTCC applications. Mater Res Bull. 2018;100:377–81.\nFotiev AA, Makarov VA. Crystal optics of strontium vanadates and phase diagram of V2O5-SrO system. Sov Phys – Crystallogr. 1970;14:621–3.\nSolacolu S, Dinescu R, Zaharescu M. Thermal phase equilibrium of the strontium oxide-vanadium pentoxide system. Rev Roum Chim. 1972;17:311–7.\nBrown JJ Jr. Phase equilibria in the system SrO–CdO–V2O5. J Am Ceram Soc. 1972;55:500–3.\nFotiev AA, Bazuev GV. Phase relations in the lanthanum oxide-vanadium pentoxide-strontium oxide system. Zh Neorg Khim. 1984;29:1337–40.\nZhuravlev VD, Velikodnyi YuA, Kristallov LV. Phase equilibrium in the copper monoxide-strontium oxide-vanadium pentoxide system. Zh Neorg Khim. 1987;32:3060–3.\nFotiev AA, Slobodin BV, Khodos MYa. Vanadates. Composition, synthesis, structure, properties. Moskva: Nauka; 1988.\nUnnimaya AN, Suresh EK, Ratheesh. Crystal structure and microwave dielectric properties of new alkaline earth vanadate A4V2O9 (A = Ba, Sr, Ca, Mg and Zn) ceramics for LTCC applications. Mater Res Bull. 2017;88:174–81.\nZhu YN, Zheng GH, Dai ZX, Zhang LY, Li YQ, Mu JJ. Luminescent properties of Sr4V2O9:Eu3+, Ba2+ phosphors prepared by a solvothermal method. Mater Res Bull. 2015;70:222–8.\nMi L, Huang Y, Liu X, Qin L, Seo HJ. Improvement of self-activated luminescence from introduced cation disorder in Sr6V2O11. J Am Ceram Soc. 2018;101:2987–95.\nMaeda H, Zhang PX, Watanabe K, Matsushita T, Otabe ES. Fabrication and properties of Ag-sheathed Bi2223 tapes with Sr6V2O11 oxide barriers between filaments. Phys C. 2000;335:35–8.\nTeixeira MM, Gouveia AF, de Sousa AG, da Silva LF, de Oliveira RC, San-Miguel MA, Li MS, Longo E. Unraveling the photoluminescence properties of the Sr10V6O25 structure through experimental and theoretical analyses. J Phys Chem C. 2020;124:14446–58.\nYan Y, Yu Y, Wu D, Yang Y, Cao Y. TiO2\u002Fvanadate (Sr10V6O25, Ni3V2O8, Zn2V2O7) heterostructured photocatalysts with enhanced photocatalytic activity for photoreduction of CO2 into CH4. Nanoscale. 2016;8:949–58.\nSuresh EK, Prasad K, Arun NS, Ratheesh R. Synthesis and microwave dielectric properties of A16V18O61 (A = Ba, Sr and Ca) ceramics for LTCC applications. J Electron Mater. 2016;45:2996–3002.\nSchnuriger B, Enjalbert R, Savariault JM, Galy J. Synthesis and crystal structure of β-SrV2O6. J Solid State Chem. 1991;95:397–402.\nGlazyrin MP, Ivakin AA, Alyamovskii SI. Phase diagrams of magnesium metavanadate-potassium metavanadate, magnesium metavanadate-strontium metavanadate, and calcium metavanadate-strontium metavanadate pseudobinary systems. Zh Neorg Khim. 1975;20:1081–4.\nZabara OA, Krasnenko TI, Zhilyaev VA. Occurrence of the Hedwall effect during solid-state synthesis of strontium metavandanate. Izv Akad Nauk SSSR, Neorg Mater. 1991;27:1032–5.\nKarpov OG, Simonov MA, Krasnenko TI, Zabara OA. Crystal structure of α-strontium vanadate (SrV2O6). Kristallografiya. 1989;34:1392–5.\nKrasnenko TI, Zabara OA, Zolotukhina LV. Crystal-chemical analysis of structural transformations in a morphotropic series of divalent metal metavanadates. Zh Neorg Khim. 2001;46:641–5.\nKristallov LV, Perelyaeva LA, Vovkotrub EG, Kiseleva NV. Vibrational spectra of isostructural strontium and lead metavanadates. Zh Neorg Khim. 1991;36:2141–7.\nLi Z-A, Yang H-X, Tian H-F, Zhang Y, Li J-Q. Fabrication and characterization of micro-pattern dandelion-like and nanobelts of β-SrV2O6 via hydrothermal process. Chin J Chem Phys. 2007;20:727–32.\nBlonska-Tabero A, Bosacka M, Filipek E, Piz M, Kochmanski P. High-temperature synthesis and unknown properties of M3Cr4(PO4)6, where M = Zn or Mg and a new solid solution Zn1.5Mg1.5Cr4(PO4)6. J Therm Anal Calorim. 2020;140:2625–31.\nPiotrowska D, Szczygieł I. Phase equilibria in the ErPO4-KPO3-Er(PO3)3 partial system. J Therm Anal Calorim. 2022;147:1621–9.\nTabero P, Filipek E, Piz M. Reactivity of T-Nb2O5 or H-Nb2O5 towards V2O5. Synthesis in the solid state and properties of V4Nb18O55. Cent Eur J Chem. 2009;7:222–7.\nBouloux J-C, Galy J, Hagenmuller P. Calcium, strontium, or barium oxide-vanadium(V) oxide-vanadium(IV) oxide ternary systems. Rev Chim Miner. 1974;11:48–70.\nJordan BD, Calvo C. Crystal structure of lead metavanadate, PbV2O6. Can J Chem. 1974;52:2701–4.\nYao T, Oka Y, Yamamoto N. Structure refinement of barium metavanadate BaV2O6. Inorganica Chim Acta. 1995;238:165–8.\nDimitrov V, Dimitriev Y. Structure of glasses in PbO–V2O5 system. J Non-Cryst Solids. 1990;122:133–8.\nAlagna L, Endregard M, Prosperi T, Tomlinson AAG. X-ray absorption spectroscopic study of the binary semiconducting glass PbV2O6. J Mater Chem. 1994;4:943–7.\nKristallov LV, Tsvetkova MP, Fotiev AA. Vibrational spectra of alkaline earth metavanadates. Zh Neorg Khim. 1984;29:1723–8.\nBusca G, Ricchiardi G, Siew Hew Sam D, Volta J-C. Spectroscopic characterization of magnesium vanadate catalysts. J Chem Soc Faraday Trans. 1994;90:1161–70.\nDąbrowska G, Filipek E, Piz M. A new ceramic continuous solid solution in the CrSnSbO6–FeSnSbO6 system and some of its properties. Ceram Int. 2015;41:12560–7.",{"VOID":926},"10.1007\u002Fs10973-022-11363-y","2024-09-05T07:41:08.667+00:00","https:\u002F\u002Flink.springer.com\u002F10.1007\u002Fs10973-022-11363-y",[930,945,958,971],{"id":931,"sortIndex":19,"researcher":18,"roles":932,"affiliations":933,"properties":942,"displayName":944,"givenName":18,"familyName":18},"b92b87fd-f4ba-48fd-8ec5-58a44f3a4322",[192],[934],{"id":935,"sortIndex":19,"affiliation":936,"properties":18},"7f190eae-a97e-4e7a-95b9-4d3abceda519",{"id":935,"createTime":18,"updateTime":18,"relativeEntities":937,"slug":18,"properties":938,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":941,"statistic":18},[],{"title":939},{"VI":940},"Faculty of Chemical Technology and Engineering, Department of Inorganic and Analytical Chemistry, West Pomeranian University of Technology, Szczecin, Szczecin, Poland",[],{"title":943},{"VI":944},"Anna 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with increasing energy consumption, global warming, and many problems caused by weather conditions, the tendency to use novel methods of energy generation with high efficiency and low cost that reduce environmental pollution has increased. This study investigates the feasibility of using gas pressure energy recovery in natural gas pressure reduction stations by turboexpanders for cogeneration of power and refrigeration. Turboexpanders and compression refrigeration cycles are employed to recover the energy from natural gas pressure reduction stations. Then, natural gas along with the compressed air enters the Brayton power generation cycle and its waste heat is used in the carbon dioxide (CO2) power generation plant, multistage Rankine cycle, and multi-effect thermal desalination unit. This integrated structure generates 105.6 MW of power, 2.960 MW of refrigeration, and 34.73 kg s−1 of freshwater. The electrical efficiencies of the Rankine power generation cycle, CO2 power generation plant, and the whole integrated structure are 0.4101, 0.4120, and 0.4704, respectively. The exergy efficiency and irreversibility of the developed integrated structure are 60.59% and 68.17 MW, respectively. The exergy analysis of the integrated structure shows that the highest rates of exergy destruction are related to the combustion chamber (59.68%), heat exchangers (14.70%), and compressors (14.46%). The annualized cost of the system (ACS) is used to evaluate the developed hybrid system. The economic analysis of the integrated structure indicated the period of return, the prime cost of the product, and capital cost are 2.565 years, 0.0430 US$ kWh−1, and 372.3 MMUS$, respectively. The results reveal that the period of return is highly sensitive to the electricity price, such that the period of return in the developed integrated structure is less than 5 years for the electricity price of 0.092 US$ kWh−1 and more. Also, the period of return is less than 5 years for the initial investment cost of 632.9 MMUS$ and less, which is economically viable.",{"EN":1049},"Exergetic and economic evaluation of a novel integrated system for trigeneration of power, refrigeration and freshwater using energy recovery in natural gas pressure reduction stations",{"VOID":1051},"[\"1885592833019404321\"]",{"VOID":1053},"Farzaneh-Gord M, Faramarzi M, Ahmadi MH, Sadi M, Shamshirband S, Mosavi A, et al. Numerical simulation of pressure pulsation effects of a snubber in a CNG station for increasing measurement accuracy. Engineering Applications of Computational Fluid Mechanics. 2019;13(1):642–63.\nDeymi-Dashtebayaz M, Dadpour D, Khadem J. Using the potential of energy losses in gas pressure reduction stations for producing power and fresh water. Desalination.497:114763.\nYao S, Zhang Y, Deng N, Yu X, Dong S. Performance research on a power generation system using twin-screw expanders for energy recovery at natural gas pressure reduction stations under off-design conditions. Appl Energy. 2019;236:1218–30.\nCascio EL, Von Friesen MP, Schenone C. Optimal retrofitting of natural gas pressure reduction stations for energy recovery. Energy. 2018;153:387–99.\nLi C, Zheng S, Li J, Zeng Z. Optimal design and thermo-economic analysis of an integrated power generation system in natural gas pressure reduction stations. Energy Convers Manag. 2019;200:112079.\nPajączek K, Kostowski W, Stanek W. Natural gas liquefaction using the high-pressure potential in the gas transmission system. Energy. 2020;202:117726.\nGolchoobian H, Taheri MH, Saedodin S. Thermodynamic analysis of turboexpander and gas turbine hybrid system for gas pressure reduction station of a power plant. Case StudTherm Eng. 2019;14:100488.\nDiao A, Wang Y, Guo Y, Feng M. Development and application of screw expander in natural gas pressure energy recovery at city gas station. Appl Therm Eng. 2018;142:665–73.\nCascio EL, Borelli D, Devia F, Schenone C. Key performance indicators for integrated natural gas pressure reduction stations with energy recovery. Energy Convers Manag. 2018;164:219–29.\nAndrei I, Valentin T, Cristina T, Niculae T. Recovery of wasted mechanical energy from the reduction of natural gas pressure. Procedia Eng. 2014;69:986–90.\nAshouri E, Veysi F, Shojaeizadeh E, Asadi M. The minimum gas temperature at the inlet of regulators in natural gas pressure reduction stations (CGS) for energy saving in water bath heaters. J Nat Gas Sci Eng. 2014;21:230–40.\nJedlikowski A, Englart S, Cepiński W, Badura M, Sayegh MA. Reducing energy consumption for electrical gas preheating processes. Therm Sci Eng Progress. 2020;19:100600.\nCascio EL, Ma Z, Schenone C. Performance assessment of a novel natural gas pressure reduction station equipped with parabolic trough solar collectors. Renew Energy. 2018;128:177–87.\nNeseli MA, Ozgener O, Ozgener L. Thermo-mechanical exergy analysis of Marmara Eregli natural gas pressure reduction station (PRS): an application. Renew Sustain Energy Rev. 2017;77:80–8.\nNami H, Mahmoudi S, Nemati A. Exergy, economic and environmental impact assessment and optimization of a novel cogeneration system including a gas turbine, a supercritical CO2 and an organic Rankine cycle (GT-HRSG\u002FSCO2). Appl Therm Eng. 2017;110:1315–30.\nEl Saie MA, El Saie YMA, El Gabry H. Techno-economic study for combined cycle power generation with desalination plants at Sharm El Sheikh. Desalination. 2003;153(1–3):191–8.\nShakib SE, Amidpour M, Aghanajafi C. Simulation and optimization of multi effect desalination coupled to a gas turbine plant with HRSG consideration. Desalination. 2012;285:366–76.\nShakib SE, Hosseini SR, Amidpour M, Aghanajafi C. Multi-objective optimization of a cogeneration plant for supplying given amount of power and fresh water. Desalination. 2012;286:225–34.\nGhorbani B, Mehrpooya M, Ghasemzadeh H. Investigation of a hybrid water desalination, oxy-fuel power generation and CO2 liquefaction process. Energy. 2018;158:1105–19.\nGhorbani B, Miansari M, Zendehboudi S, Hamedi M-H. Exergetic and economic evaluation of carbon dioxide liquefaction process in a hybridized system of water desalination, power generation, and liquefied natural gas regasification. Energy Convers Manag. 2020;205:112374.\nCalise F, d’Accadia MD, Piacentino A. A novel solar trigeneration system integrating PVT (photovoltaic\u002Fthermal collectors) and SW (seawater) desalination: dynamic simulation and economic assessment. Energy. 2014;67:129–48.\nVakilabadi MA, Bidi M, Najafi A, Ahmadi MH. Exergy analysis of a hybrid solar-fossil fuel power plant. Energy Sci Eng. 2019;7(1):146–61.\nShaygan M, Ehyaei M, Ahmadi A, Assad MEH, Silveira JL. Energy, exergy, advanced exergy and economic analyses of hybrid polymer electrolyte membrane (PEM) fuel cell and photovoltaic cells to produce hydrogen and electricity. J Clean Prod. 2019;234:1082–93.\nAhmadi A, Jamali D, Ehyaei M, Assad MEH. Energy, exergy, economic and exergoenvironmental analyses of gas and air bottoming cycles for production of electricity and hydrogen with gas reformer. J Clean Prod. 2020;259:120915.\nEhyaei M, Ahmadi A, Assad MEH, Rosen MA. Investigation of an integrated system combining an organic rankine cycle and absorption chiller driven by geothermal energy: energy, exergy, and economic analyses and optimization. J Clean Prod. 2020;258:120780.\nJavadi MA, Ahmadi MH, Khalaji M. Exergetic, economic, and environmental analyses of combined cooling and power plants with parabolic solar collector. Environ Progress Sustain Energy. 2020;39(2):e13322.\nGhorbani B, Javadi Z, Zendehboudi S, Amidpour M. Energy, exergy, and economic analyses of a new integrated system for generation of power and liquid fuels using liquefied natural gas regasification and solar collectors. Energy Convers Manag. 2020;219:112915.\nAmidpour M, Hamedi M, Mafi M, Ghorbani B, Shirmohammadi R, Salimi M. Sensitivity analysis, economic optimization, and configuration design of mixed refrigerant cycles by NLP techniques. J Nat Gas Sci Eng. 2015;24:144–55.\nAhmadi MH, Banihashem SA, Ghazvini M, Sadeghzadeh M. Thermo-economic and exergy assessment and optimization of performance of a hydrogen production system by using geothermal energy. Energy Environ. 2018;29(8):1373–92.\nMirzaei M, Ahmadi MH, Mobin M, Nazari MA, Alayi R. Energy, exergy and economics analysis of an ORC working with several fluids and utilizes smelting furnace gases as heat source. Thermal Science and Engineering Progress. 2018;5:230–7.\nAshouri M, Ahmadi MH, Pourkiaei SM, Astaraei FR, Ghasempour R, Ming T, et al. Exergy and exergo-economic analysis and optimization of a solar double pressure organic Rankine cycle. Therm Sci Eng Progress. 2018;6:72–86.\nNoroozian A, Mohammadi A, Bidi M, Ahmadi MH. Energy, exergy and economic analyses of a novel system to recover waste heat and water in steam power plants. Energy Convers Manage. 2017;144:351–60.\nGhorbani B, Shirmohammadi R, Amidpour M, Inzoli F, Rocco M. Design and thermoeconomic analysis of a multi-effect desalination unit equipped with a cryogenic refrigeration system. Energy Convers Manag. 2019;202:112208.\nGhorbani B, Ebrahimi A, Moradi M, Ziabasharhagh M. Energy, exergy and sensitivity analyses of a novel hybrid structure for generation of Bio-Liquefied natural Gas, desalinated water and power using solar photovoltaic and geothermal source. Energy Convers Manag. 2020;222:113215.\nAhmadi M, Sadaghiani M, Pourfayaz F, Ghazvini M, Mahian O, Mehrpooya M, et al. Energy and exergy analyses of a solid oxide fuel cell-gas turbine-organic Rankine cycle power plant with liquefied natural gas as heat sink. Entropy. 2018;20(7):484.\nEbrahimi A, Ghorbani B, Lohrasbi H, Ziabasharhagh M. Novel integrated structure using solar parabolic dish collectors for liquid nitrogen production on offshore gas platforms (exergy and economic analysis). Sustain Energy Technol Assessments. 2020;37:100606.\nReyhani HA, Meratizaman M, Ebrahimi A, Pourali O, Amidpour M. Thermodynamic and economic optimization of SOFC-GT and its cogeneration opportunities using generated syngas from heavy fuel oil gasification. Energy. 2016;107:141–64.\nWang Y, Lior N. Performance analysis of combined humidified gas turbine power generation and multi-effect thermal vapor compression desalination systems—Part 1: The desalination unit and its combination with a steam-injected gas turbine power system. Desalination. 2006;196(1–3):84–104.\nPiadehrouhi F, Ghorbani B, Miansari M, Mehrpooya M. Development of a new integrated structure for simultaneous generation of power and liquid carbon dioxide using solar dish collectors. Energy. 2019;179:938–59.\nKhanmohammadi S, Azimian AR, Khanmohammadi S. Exergy and exergo–economic evaluation of Isfahan steam power plant. Int J Exergy. 2013;12(2):249–72.\nAhmadi G, Toghraie D, Akbari OA. Solar parallel feed water heating repowering of a steam power plant: A case study in Iran. Renew Sustain Energy Rev. 2017;77:474–85.\nMehrpooya M, Ghorbani B, Sadeghzadeh M. Hybrid solar parabolic dish power plant and high-temperature phase change material energy storage system. Int J Energy Res. 2019;43(10):5405–20.\nMohammadi A, Ashouri M, Ahmadi MH, Bidi M, Sadeghzadeh M, Ming T. Thermoeconomic analysis and multiobjective optimization of a combined gas turbine, steam, and organic Rankine cycle. Energy Sci Eng. 2018;6(5):506–22.\nMohammadi A, Ahmadi MH, Bidi M, Ghazvini M, Ming T. Exergy and economic analyses of replacing feedwater heaters in a Rankine cycle with parabolic trough collectors. Energy Rep. 2018;4:243–51.\nAhmadi MH, Alhuyi Nazari M, Sadeghzadeh M, Pourfayaz F, Ghazvini M, Ming T, et al. Thermodynamic and economic analysis of performance evaluation of all the thermal power plants: A review. Energy Sci Eng. 2019;7(1):30–65.\nMehrpooya M, Ghorbani B. Introducing a hybrid oxy-fuel power generation and natural gas\u002Fcarbon dioxide liquefaction process with thermodynamic and economic analysis. J Clean Prod. 2018;204:1016–33.\nMehrpooya M, Taromi M, Ghorbani B. Thermo-economic assessment and retrofitting of an existing electrical power plant with solar energy under different operational modes and part load conditions. Energy Rep. 2019;5:1137–50.\nNouri M, Miansari M, Ghorbani B. Exergy and economic analyses of a novel hybrid structure for simultaneous production of liquid hydrogen and carbon dioxide using photovoltaic and electrolyzer systems. J Clean Prod. 2020;259:120862.\nNiasar MS, Ghorbani B, Amidpour M, Hayati R. Developing a hybrid integrated structure of natural gas conversion to liquid fuels, absorption refrigeration cycle and multi effect desalination (exergy and economic analysis). Energy. 2019;189:116162.",{"VOID":1055},"10.1007\u002Fs10973-021-10607-7","2024-06-26T18:00:37.249+00:00","https:\u002F\u002Flink.springer.com\u002Farticle\u002F10.1007\u002Fs10973-021-10607-7",[1059,1076,1091],{"id":1060,"sortIndex":19,"researcher":18,"roles":1061,"affiliations":1062,"properties":1071,"displayName":1073,"givenName":18,"familyName":18},"bd21ad48-d20b-48a8-a556-c0fb510f9a6c",[192],[1063],{"id":1064,"sortIndex":19,"affiliation":1065,"properties":18},"158c61cc-bff9-4b62-9a8b-1c7c7a9e32da",{"id":1064,"createTime":18,"updateTime":18,"relativeEntities":1066,"slug":18,"properties":1067,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":1070,"statistic":18},[],{"title":1068},{"VI":1069},"Faculty of Mechanical Engineering, Semnan University, Semnan, Iran",[],{"title":1072,"gsAuthor":1074},{"VI":1073},"Hooman 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Flow of hybrid nanofluid through Darcy–Forchheimer porous space with variable characteristics. Alex Eng J. 2021;60(3):3047–56. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.aej.2021.01.021.",{"doi":1320},"10.1016\u002Fj.aej.2021.01.021",{"id":18,"text":1322,"url":18,"identifiers":1323},"Shoaib M, Raja MAZ, Sabir MT, et al. Numerical investigation for rotating flow of MHD hybrid nanofluid with thermal radiation over a stretching sheet. Sci Rep. 2020. https:\u002F\u002Fdoi.org\u002F10.1038\u002Fs41598-020-75254-8.",{"doi":1324},"10.1038\u002Fs41598-020-75254-8",{"id":18,"text":1326,"url":18,"identifiers":1327},"Yashkun U, Zaimi K, Abu Bakar NA, Ishak A, Pop I. MHD hybrid nanofluid flow over a permeable stretching\u002Fshrinking sheet with thermal radiation effect. Int J Numer Meth Heat Fluid Flow. 2020;31(3):1014–31. https:\u002F\u002Fdoi.org\u002F10.1108\u002Fhff-02-2020-0083.",{"doi":1328},"10.1108\u002Fhff-02-2020-0083",{"id":18,"text":1330,"url":18,"identifiers":1331},"Khan AS, Xu H-Y, Khan W. Magnethydrodynamic Hybrid Nanofluid flow past an exponentially stretching sheet with slip conditions. Mathematics. 2021;9(24):3291. https:\u002F\u002Fdoi.org\u002F10.3390\u002Fmath9243291.",{"doi":1332},"10.3390\u002Fmath9243291",{"id":18,"text":1334,"url":18,"identifiers":1335},"Venkateswarlu B, Narayana PVS. Cu-Al2O3\u002FH2O hybrid nanofluid flow past a porous stretching sheet due to temperatue-dependent viscosity and viscous dissipation. Heat Transf. 2021;50:432–49. https:\u002F\u002Fdoi.org\u002F10.1002\u002Fhtj.21884.",{"doi":1336},"10.1002\u002Fhtj.21884",{"id":18,"text":1338,"url":18,"identifiers":1339},"Vishalakshi AB, Mahabaleshwar US, Sarris IE. An MHD fluid flow over a porous stretching\u002Fshrinking sheet with slips and mass transpiration. Micromachines. 2022;13(1):116. https:\u002F\u002Fdoi.org\u002F10.3390\u002Fmi13010116.",{"doi":1340},"10.3390\u002Fmi13010116",{"id":18,"text":1342,"url":18,"identifiers":1343},"Khan U, Zaib A, Abu Bakar S, Ishak A. Stagnation-point flow of a hybrid nanoliquid over a non-isothermal stretching\u002Fshrinking sheet with characteristics of inertial and microstructure. Case Stud Thermal Eng. 2021;26:101150. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.csite.2021.101150.",{"doi":1344},"10.1016\u002Fj.csite.2021.101150",{"id":18,"text":1346,"url":18,"identifiers":1347},"Rajesh V, Sheremet MA, Öztop HF. Impact of hybrid nanofluids on MHD flow and heat transfer near a vertical plate with ramped wall temperature. Case Stud Therm Eng. 2021;28:101557. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.csite.2021.101557.",{"doi":1348},"10.1016\u002Fj.csite.2021.101557",{"id":18,"text":1350,"url":18,"identifiers":1351},"Roşca NC, Pop I. Hybrid nanofluids flows determined by a permeable power-law stretching\u002Fshrinking sheet modulated by orthogonal surface Shear. Entropy. 2021;23(7):813. https:\u002F\u002Fdoi.org\u002F10.3390\u002Fe23070813.",{"doi":1352},"10.3390\u002Fe23070813",{"id":18,"text":1354,"url":18,"identifiers":1355},"Wahid NS, Arifin NM, Khashi’ie NS, Pop I. Hybrid nanofluid slip flow over an exponentially stretching shrinking permeable sheet with heat generation. Mathematics. 2020;9(1):30. https:\u002F\u002Fdoi.org\u002F10.3390\u002Fmath9010030",{"doi":1356},"10.3390\u002Fmath9010030",{"id":18,"text":1358,"url":18,"identifiers":1359},"Nabwey HA, Mahdy A. Transient flow of micropolar dusty hybrid nanofluid loaded with Fe3O4-Ag nanoparticles through a porous stretching sheet. Res Phys. 2021;21:103777. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.rinp.2020.103777.",{"doi":1360},"10.1016\u002Fj.rinp.2020.103777",{"id":18,"text":1362,"url":18,"identifiers":1363},"Saba F, Ahmed N, Khan U, Mohyud-Din ST. A novel coupling of (CNT-Fe3O4\u002FH2O) hybrid nanofluid for improvements in heat transfer for flow in an asymmetric channel with dilating\u002Fsqueezing walls. Int J Heat Mass Transf. 2019;136:186–95. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.ijheatmasstransfer.2019.02.097.",{"doi":1364},"10.1016\u002Fj.ijheatmasstransfer.2019.02.097",{"id":18,"text":1366,"url":18,"identifiers":1367},"Abbas N, Saleem S, Nadeem S, Alderremy AA, Khan AU. On stagnation point flow of a micropolar nanofluid past a circular cylinder with velocity and thermal slip. Res Phys. 2018;9:1224–32. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.rinp.2018.04.017.",{"doi":1368},"10.1016\u002Fj.rinp.2018.04.017",{"id":18,"text":1370,"url":18,"identifiers":1371},"Waqas H, Raza Shah Naqvi SM, Alqarni MS, Muhammad T. Thermal transport in the magnetized flow of hybrid nanofluids over a vertical stretching cylinder. Case Stud Therm Eng. 2021;27:101219. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.csite.2021.101219",{"doi":1372},"10.1016\u002Fj.csite.2021.101219",{"id":18,"text":1374,"url":18,"identifiers":1375},"Kumar TS. Hybrid nanofluid slip flow and heat transfer over a stretching surface. Partial Differ Equ Appl Math. 2021;4:100070. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.padiff.2021.100070.",{"doi":1376},"10.1016\u002Fj.padiff.2021.100070",{"id":18,"text":1378,"url":18,"identifiers":1379},"Mohanty B, Jena S, Pattnaik PK. MHD nanofluid flow over stretching\u002Fshrinking surface in the presence of heat radiation using numerical method. Int J Emerg Technol. 2019;10:119–25.",{},{"id":18,"text":1381,"url":18,"identifiers":1382},"Mishra S, Mahanthesh B, Mackolil J, Pattnaik PK. Nonlinear radiation and cross-diffusion effects on the micropolar nanoliquid flow past a stretching sheet with an exponential heat source. Heat Transf. 2020;50(4):3530–46. https:\u002F\u002Fdoi.org\u002F10.1002\u002Fhtj.22039.",{"doi":1383},"10.1002\u002Fhtj.22039",{"id":18,"text":1385,"url":18,"identifiers":1386},"Pattnaik PK, Biswal T. Analytical solution of MHD free convective flow through porous media with time dependent temperature and concentration. Walailak J Sci Technol. 2015;12:749–762. https:\u002F\u002Fdoi.org\u002F10.14456\u002F1130",{"doi":1387},"10.14456\u002F1130",{"id":18,"text":1389,"url":18,"identifiers":1390},"Mishra AK, Pattnaik PK, Mishra SR, Senapati N. Dissipative heat energy on Cu and Al2O3 ethylene–glycol-based nanofluid flow over a heated semi-infinite vertical plate. J Therm Anal Calorim. 2020;145(1):129–37. https:\u002F\u002Fdoi.org\u002F10.1007\u002Fs10973-020-09666-z.",{"doi":1391},"10.1007\u002Fs10973-020-09666-z",{"id":18,"text":1393,"url":18,"identifiers":1394},"Barik AK, Mishra SK, Mishra SR, Pattnaik PK. Multiple slip effects on MHD nanofluid flow over an inclined, radiative, and chemically reacting stretching sheet by means of FDM. Heat Transf-Asian Res. 2019;49(1):477–501. https:\u002F\u002Fdoi.org\u002F10.1002\u002Fhtj.21622.",{"doi":1395},"10.1002\u002Fhtj.21622",{"id":18,"text":1397,"url":18,"identifiers":1398},"Seyyedi SM, Dogonchi AS, Hashemi-Tilehnoee M, Ganji DD, Chamkha AJ. Second law analysis of magneto-natural convection in a nanofluid filled wavy-hexagonal porous enclosure. Int J Numer Meth Heat Fluid Flow. 2020;30(11):4811–36. https:\u002F\u002Fdoi.org\u002F10.1108\u002Fhff-11-2019-0845.",{"doi":1399},"10.1108\u002Fhff-11-2019-0845",{"id":18,"text":1401,"url":18,"identifiers":1402},"Chamkha A, Dogonchi AS, Ganji DD. Magnetohydrodynamic nanofluid natural convection in a cavity under thermal radiation and shape factor of nanoparticles impacts: a numerical study using CVFEM. Appl Sci. 2018;8(12):2396. https:\u002F\u002Fdoi.org\u002F10.3390\u002Fapp8122396.",{"doi":1403},"10.3390\u002Fapp8122396",{"id":18,"text":1405,"url":18,"identifiers":1406},"Dogonchi AS, Waqas M, Afshar, et al. Investigation of magnetohydrodynamic fluid squeezed between two parallel disks by considering Joule heating, thermal radiation, and adding different nanoparticles. Int J Numer Methods Heat Fluid Flow. 2019;30(2):659–80. https:\u002F\u002Fdoi.org\u002F10.1108\u002Fhff-05-2019-0390.",{"doi":1407},"10.1108\u002Fhff-05-2019-0390",{"id":18,"text":1409,"url":18,"identifiers":1410},"Dogonchi AS, Mishra SR, Chamkha AJ, Ghodrat M, Elmasry Y, Alhumade H. Thermal and entropy analyses on buoyancy-driven flow of nanofluid inside a porous enclosure with two square cylinders: finite element method. Case Stud Therm Eng. 2021;27:101298. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.csite.2021.101298.",{"doi":1411},"10.1016\u002Fj.csite.2021.101298",{"id":18,"text":1413,"url":18,"identifiers":1414},"Tayebi T, SattarDogonchi A, Karimi N, Ge-JiLe H, Chamkha AJ, Elmasry Y. Thermo-economic and entropy generation analyses of magnetic natural convective flow in a nanofluid-filled annular enclosure fitted with fins. Sustain Energy Technol Assess. 2021;46:101274. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.seta.2021.101274.",{"doi":1415},"10.1016\u002Fj.seta.2021.101274",{"id":18,"text":1417,"url":18,"identifiers":1418},"Mondal S, Dogonchi AS, Tripathi, et al. A theoretical nanofluid analysis exhibiting hydromagnetics characteristics employing CVFEM. J Braz Soc Mech Sci Eng. 2019. https:\u002F\u002Fdoi.org\u002F10.1007\u002Fs40430-019-2103-2.",{"doi":1419},"10.1007\u002Fs40430-019-2103-2",{"id":18,"text":1421,"url":18,"identifiers":1422},"Khashi’ie NS, Arifin NM, Pop I, Nazar R, Hafidzuddin EH, Wahi N. Three-dimensional hybrid nanofluid flow and heat transfer past a permeable stretching\u002Fshrinking sheet with velocity slip and convective condition. Chin J Phys. 2020;66:157–71. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.cjph.2020.03.032.",{"doi":1423},"10.1016\u002Fj.cjph.2020.03.032",{"id":18,"text":1425,"url":18,"identifiers":1426},"Jusoh R, Nazar R, Pop I. Flow and heat transfer of magnetohydrodynamic three-dimensional Maxwell nanofluid over a permeable stretching\u002Fshrinking surface with convective boundary conditions. Int J Mech Sci. 2017;124–125:166–73. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.ijmecsci.2017.02.022.",{"doi":1427},"10.1016\u002Fj.ijmecsci.2017.02.022",{"id":18,"text":1429,"url":18,"identifiers":1430},"Hayat T, Ashraf B, Shehzad SA, Abouelmagd E. Three-dimensional flow of Eyring Powell nanofluid over an exponentially stretching sheet. Int J Numer Meth Heat Fluid Flow. 2015;25(3):593–616. https:\u002F\u002Fdoi.org\u002F10.1108\u002Fhff-05-2014-0118.",{"doi":1431},"10.1108\u002Fhff-05-2014-0118",{"id":18,"text":1433,"url":18,"identifiers":1434},"Pattnaik PK, Pattnaik J, Mishra SR, Ali B. A comparative note on the free convection of micropolar nanofluid due to the interaction of buoyancy and the disspative heat energy. Heat Transf. 2021;50(7):7020–41.",{"doi":1435},"10.1002\u002Fhtj.22215",{"id":18,"text":1437,"url":18,"identifiers":1438},"Aladdin NAL, Bachok N, Pop I. Cu-Al2O3\u002Fwater hybrid nanofluid flow over a permeable moving surface in presence of hydromagnetic and suction effects. Alex Eng J. 2020;59(2):657–66.",{"doi":1439},"10.1016\u002Fj.aej.2020.01.028",{"id":1441,"createTime":1442,"updateTime":1443,"relativeEntities":1444,"slug":1445,"properties":1446,"entityType":181,"verifyStatus":182,"verifyTime":1456,"verifyNote":184,"languages":18,"translateLanguages":18,"viewCount":19,"primaryUrl":1457,"fullTextUrl":18,"authors":1458,"publicationType":289,"publisherRelationship":1489,"citationCount":18,"citationInfo":18,"publishDate":1540,"publishYear":628,"citationAnalyzeStatus":1036,"lastCitationAnalyze":1541,"indexDatabases":1542,"openAccess":18,"references":18,"isForceReanalyzing":344},"1dd7678d-9b7e-4b3b-9dea-57c181557ce0","2023-12-25T17:42:11.891+00:00","2026-08-18T03:20:59.980+00:00",[],"Synthesis-growth-thermal-optical-and-mechanical-studies-on-2-amino-6-methylpyridinium-4-hydroxybenzoate",{"abstract":1447,"title":1449,"gsPaper":1451,"references":1452,"doi":1454},{"EN":1448},"\nThe novel organic nonlinear optical single crystals of 2-amino-6-methylpyridinium 4-hydroxybenzoate (2A6MP4HB) were grown from methanol solvent using isothermal solvent evaporation technique. The 2A6MP4HB was found to crystallize in monoclinic system with centrosymmetric space group P21\u002Fc. The microanalyses confirmed the stoichiometric compositions of 2A6MP4HB. The thermal stability and decomposition of newly identified 2A6MP4HB have been explored by thermogravimetric\u002Fdifferential thermal analysis and differential scanning calorimetric analysis. The temperature dependence specific heat capacity of title compound has been analysed through modulated differential calorimetric analysis (MDSC). The MDSC study suggested that 2A6MP4HB could possess high optical damage threshold, which is an essential requirements for optical devices. The UV–Vis–NIR spectral study indicates that newly obtained 2A6MP4HB single crystal has the transparency window 350–1100 nm, which is useful for optoelectronic applications. From Z-scan technique, the nonlinear refractive index, nonlinear absorption coefficient and third-order nonlinear susceptibility of newly designed 2A6MP4HB single crystal are found to be −5.6166 × 10−12 cm2 W−1, 5.0887 × 10−6 cm W−1 and 8.3551 × 10−10 esu, respectively. The room temperature mechanical behaviours of 2A6MP4HB have been tested using Vickers microhardness tester, and the results showed that the title compound belongs to soft material category. All these studies have been performed for the first time and aimed to explore the useful and safe region of thermal, optical and mechanical properties to enhance its usefulness for device fabrications.",{"EN":1450},"Synthesis, growth, thermal, optical and mechanical studies on 2-amino-6-methylpyridinium 4-hydroxybenzoate",{"VOID":922},{"VOID":1453},"Brahadeeswaran S, Venkataramanan V, Sherwood JN, Bhat HL. Crystal growth and characterization of semiorganic nonlinear optical material: sodium p-nitrophenolate dehydrate. 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Growth and characterization of 2-amino-4-picolinium 4-aminobenzoate single crystals. Spectrochim Acta Part A. 2010;75:1223–7.\nBrahadeeswaran S, Onduka S, Takagi M, Takahashi Y, Adachi H, Kamimura T, Yoshimura M, Mori Y, Yoshida K, Sasaki T. Twin-free and high-quality DAST crystals—effected through solutions of lower supersaturation coupled with isothermal solvent evaporation. Cryst Growth Des. 2006;6:2463–8.\nSuthan T, Rajesh NP, Mahadevan CK, Sajan D, Bhagavannarayana G. Growth and characterization of organic material 2-hydroxypyridine single crystal by modified vertical Bridgman technique. Mater Chem Phys. 2011;130:915–20.\nDhanaraj PV, Rajesh NP, Bhagavannarayan G. Synthesis, crystal growth and characterization of an organic NLO material: Bis(2-aminopyridinium) maleate. Phys B. 2010;405:3441–5.\nPandi P, Peramaiyan G, Krishna Kumar M, Mohan Kumar R, Jayavel R. Synthesis, structural, optical and thermal studies of an organic nonlinear optical 4-aminopyridinium maleate single crystal. Spectrochim Acta Part A. 2012;88:77–8.\nChen T, Sun Z, Li L, Wang S, Wang Y, Luo J, Hong M. Growth and characterization of a nonlinear optical crystal. 2, 6-diaminopyridinium 4-nitrophenolate 4-nitrophenol (DAPNP). J Cryst Growth. 2012;338:157–61.\nKannan V, Sugumar P, Brahadeeswaran S, Ponnuswamy MN. 2-Amino-6-methylpyridinium 4-hydroxybenzoate. Acta Crystallogr Sect E. 2013;69:o610–7.\nBoyd RW. Nonlinear optics. Amsterdam: Academic Press; 2003.\nSrinivasan P, Nooraldeen AY, Dhinaa AN, Palanisamy PK, Gopalakrishnan R. Z-scan determination of the third-order optical nonlinearity of l-asparaginium picrate (LASP) crystal. Laser Phys. 2008;18:790–3.\nSheik-Bahae M, Said AA, VanStryl EW. High-sensitivity, single-beam n2 measurements. Opt Lett. 1989;14:955–7.\nVan Stryland EW, Sheik-Bahae M. Z-scan measurements of optical nonlinearities; 1998.\nSudharsana N, Keerthana B, Nagalakshmi R, Krishnakumar V, Guru Prasad L. Growth and characterization of hydroxyethylammonium picrate single crystals for third-order nonlinear optical applications. Mater Chem Phys. 2012;134:736–46.\nMERCURY 1.3. Cambridge: Cambridge Crystallographic Data Centre, CCDC Software Limited; 2004.\nShanmugam G, Thirupugalmani K, Rakhikrishna R, Philip J, Brahadeeswaran S. Thermophysical, mechanical and dielectric studies on piperidinium p-hydroxybenzoate: a novel organic NLO single crystal. J Therm Anal Calorim. 2013;114:1245.\nSrinivasan P, Kanagasekaran T, Vijayan N, Bhagavannarayana G, Gopalakrishnan R, Ramasamy P. Studies on the growth, optical, thermal and dielectric aspects, of a proton transfer complex—dimethyl amino pyridinium 4-nitrophenolate 4-nitrophenol (DMAPNP) crystals for non-linear optical applications. Opt Mater. 2007;30:553–64.\nGlass AJ, Guenther AH. Laser induced damage of optical elements—a status report. Appl Opt. 1973;12:637–49.\nSun ZH, Xu D, Wang XQ, Zhang GH, Yu G, Zhu LY, Fan HL. Growth and characterization of the nonlinear optical single crystal: l-lysinium trifluoroacetate. Mater Res Bull. 2009;44:925–30.\nVerdonck E, Schaap K, Thomas LC. A discussion of the principles and applications of modulated temperature DSC (MTDSC). Int J Pharm. 1999;192:3–20.\nPhilip J, Manjusha MV. Thermal transport across incommensurate phases in potassium selenate: photopyroelectric and calorimetric measurements. J Phys Condens Matter. 2009;21:45901–7.\nDhanaraj G, Srinivasan MR, Bhat HL, Jayanna HS, Subramanyam SV. Thermal and electrical properties of the novel organic nonlinear crystal l-arginine phosphate monohydrate. J Appl Phys. 1992;72:3464–7.\nVanishri S, Babureddy JN, Bhat HL, Ghosh S. Laser damage studies in nonlinear optical crystal sodium p-nitrophenolate dehydrate. Appl Phys B Laser Opt. 2007;88:457–61.\nDhanuskodi S, Manivannan S, Kirschbaum K, Philip J, Selladurai S. Structural, thermal and dielectric studies on a new solution grown 4-dimethylaminopyridinium dihydrogen phosphate crystal. J Cryst Growth. 2006;290:548–53.\nZhang HJ, Jiang HD, Wang JY, Hu XB, Yu GW, Yu WT, Gao L, Liu JA, Zhang SJ, Jiang MH. Growth and characterization of LaCa4O (BO3)3 crystal. Appl Phys A. 2004;78:889–93.\nSharma YR. Elementary organic spectroscopy. 4th ed. New Delhi: S. Chand; 2007.\nKannan V, Brahadeeswaran S. Investigations on influence of coloration on growth of high quality hydrazonium l-tartrate single crystal. J Cryst Growth. 2013;374:71–8.\nTauc JC. Optical properties of solids. Amsterdam: North-Holland; 1972. p. 372.\nShettigar S, Umesh G, Chandrasekharan K, Kalluraya B. Third order nonlinear optical properties and two photon absorption in newly synthesized phenyl sydnone doped polymer. Synth Met. 2007;157(3):142–6.\nZhou YS, Wang EB, Peng J, Liu J, Hu CW, Huang RD, You X. Synthesis and the third-order optical nonlinearities of two novel charge-transfer complexes of a heteropoly blue type (C9H7NO)4 H7PMo12O40·3H2O (C9H7NO = quinolin-8-ol) and (phen)3 H7PMo12O40·CH3CN·H2O (phen = 1,10-phenanthroline). Polyhedron. 1999;18(10):1419–23.\nGupte SS, Marcano OA, Pradhan RD, Desai CF, Melikechi N. Pump-probe thermal lens near-infrared spectroscopy and Z-scan study of zinc (tris) thiourea sulphate. J Appl Phys. 2001;89(9):4939–43.\nZong R, Zhou J, Li Q, Li L, Wang W, Chen Z. Linear and nonlinear optical properties of Ag nanorods\u002FAAM composite films. Chem Phys Lett. 2004;398(1–3):224–7.\nDhanaraj PV, Rajesh NP, Vinitha G, Bhagavannarayana G. Crystal structure and characterization of a novel organic optical crystal: 2-aminopyridinium trichloroacetate. Mater Res Bull. 2011;46(5):726–73.\nRajesh Kumar T, Jerald Vijay R, Jeyasekaran R, Selvakumar S, Antony Arockiaraj M, Sagayaraj P. Growth, linear and nonlinear optical and, laser damage threshold studies of organometallic crystal of MnHg(SCN)4. Opt Mater. 2011;33:1654–60.\nVenugopal Rao S, Naga Srinivas NKM, Narayana Rao D, Giribabu L, Maiya BG, Philip R, Ravindra Kumar G. Studies of third-order optical nonlinearity and nonlinear absorption in tetra tolyl porphyrins using degenerate four wave mixing and Z-scan. Opt Commun. 2000;182(1–3):255–64.\nMajles Ara MH, Salmani S, Esmaeilzadeh M, Mousavi SH, Koushki E, Shakouri K. Optical characterization of Erioglaucine using z-scan technique, beam radius variations and diffraction pattern in far-field. Curr Appl Phys. 2009;9(5):885–9.\nKulagin LA, Ganeev RA, Tugushev RI, Ryasnyansky AI, Usmanov T. Components of the third-order nonlinear susceptibility tensors in KDP, DKDP and LiNbO3 nonlinear optical crystals. Quantum Electron. 2004;34(7):657–62.\nVodchits AI, Orlovich VA, Apanasevich PA. Nonlinear refractive index of vanadate crystals in the near IR region. J Appl Spectrosc. 2012;78(6):918–21.\nBanerjee PP. Nonlinear optics. New York: Marcell Dekker Inc.; 2004.\nGaneev RA, Kulagin IA, Ryasnyansky AI, Tugushev RI, Usmanov T. Characterization of nonlinear optical parameters of KDP, LiNbO3 and BBO crystals. Opt Commun. 2004;229(1–6):403–12.\nLawn BR, Fuller ER. Equilibrium penny-like cracks in indentation fracture. J Mater Sci. 1975;10:2016–24.\nSangwal K. Microhardness of as-grown and annealed lead sulphide crystals. J Mater Sci. 1989;24:1128–32.\nOnitsch EM. Over the microhardness of the metal. Microskopie. 1947;2:131–51.",{"VOID":1455},"10.1007\u002Fs10973-015-5174-z","2025-01-18T21:54:44.659+00:00","https:\u002F\u002Flink.springer.com\u002Farticle\u002F10.1007\u002Fs10973-015-5174-z",[1459,1474],{"id":1460,"sortIndex":19,"researcher":18,"roles":1461,"affiliations":1462,"properties":1471,"displayName":1473,"givenName":18,"familyName":18},"6b2ad7b6-28a8-4218-8950-9ecc80b1cd89",[192],[1463],{"id":1464,"sortIndex":19,"affiliation":1465,"properties":18},"d0ce67a6-f870-4602-82a0-a54564ee9b0f",{"id":1464,"createTime":18,"updateTime":18,"relativeEntities":1466,"slug":18,"properties":1467,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":1470,"statistic":18},[],{"title":1468},{"VI":1469},"Department of Physics, M.A.M. School of Engineering, Tiruchirappalli, India",[],{"title":1472},{"VI":1473},"V. Kannan",{"id":1475,"sortIndex":109,"researcher":18,"roles":1476,"affiliations":1477,"properties":1486,"displayName":1488,"givenName":18,"familyName":18},"77d0c64b-221d-4e72-959c-ab22c75079cb",[192],[1478],{"id":1479,"sortIndex":19,"affiliation":1480,"properties":18},"e4dcebc6-e9b0-4ba5-b814-358c4c5128c7",{"id":1479,"createTime":18,"updateTime":18,"relativeEntities":1481,"slug":18,"properties":1482,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":1485,"statistic":18},[],{"title":1483},{"VI":1484},"Department of Physics, Anna University Chennai, BIT Campus, Tiruchirappalli, India",[],{"title":1487},{"VI":1488},"S. 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Depending on the storage and\u002For heating conditions, gums and insoluble organic particulates may be formed in liquid phase by oxidation. To contribute to the evaluation of this oxidized heavier components formation in liquid phase, a new thermal analysis quantitative method was developed by the authors, which was applied to diesel oil\u002Fsoybean biodiesel blends having from 5 to 20 vol% of the latter. The method consists on obtaining differential thermogravimetric curves (DIFTG), subtracting the TG curve obtained in inert atmosphere from the TG curve of the same sample obtained in air, which, actually, shows how and how much accumulated oxidized mass is being formed in liquid phase during analysis. Corresponding thermal effects are quantified by differential DTA (DIFDTA) curves, subtracting respective DTA curves in N2 from those in air. The results show that, as the biodiesel content is increased, a higher amount of heavy oxidized products remains in liquid phase of the blend, up to the respective much higher decomposition temperatures. This fact is confirmed by estimating the activation energies as a function of the mass loss conversion degree, which shows that the higher is the formation rate of the liquid phase oxidized mass in a blend, the higher is the activation energy needed for its decomposition and the higher is the blend ignition temperature, which is a polynomial function of second order of the biodiesel content.",{"EN":1553},"Liquid phase oxidation quantitative analysis of biodiesel\u002Fdiesel blends by differential TG and DTA",{"VOID":1555},"[\"661568811467421082\"]",{"VOID":1557},"Andrade RDA. Calor de combustão de blendas do tipo diesel\u002Fbiodiesel e diesel\u002Fbio-óleo [Calorific power of Diesel\u002FBiodiesel and Diesel\u002FBio-oil blends]. Master’s Dissertation. 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Storage, handling, and transport of oils and fats. In: Shahidi F, editor. bailey’s industrial oil and fats products. 6th ed. Hoboken: Wiley; 2005.\nLo KM, Cheung PCK. Antioxidant activity of extracts from the fruiting bodies of Agrocybe awgerita var. Alba. Food Chem. 2005;89(4):533–9.\nMonyem A, Gerpen JHV. The effect of biodiesel oxidation on engine performance and emissions. Biomass Bioenergy. 2001;20:317–25.\nValle MLM, Leonardo RS, Dweck J. Comparative study of biodiesel oxidation stability using Rancimat, PetroOXY, and low P-DSC. J Therm Anal Calorim. 2014;116:113–8. https:\u002F\u002Fdoi.org\u002F10.1007\u002Fs10973-014-3706-6.\nKnothe G. Some aspects of biodiesel oxidative stability: a review. Fuel Process Technol. 2007;88:669–77.\nKowalski B, Gruczynska E, Maciaszek K. Kinectis of repassed oil oxidation by pressure differential sanning calorimetry measurements. Eur J Lipid Sci Techonol. 2000;102(5):337–41.\nKaravalakis G, Stournas S, Karonis D. Evaluation of the oxidation stability of diesel. Biodiesel Blends. 2010;89(9):2483–9. https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.fuel.2010.03.041.\nMc Cormick RL, Westbrook SR. Storage stability of biodiesel and blends. Energy Fuels. 2010;24:690–8.\nLeonardo RS, Valle MLM, Dweck J. The thermal processing in air of ethylic soybean biodiesel after accelerated aging, with and without antioxidant. J Therm Anal Calorim. 2017. https:\u002F\u002Fdoi.org\u002F10.1007\u002Fs10973-017-6314-4.\nDoyle CD. Estimating isothermal life from thermogravimetric data. J Appl Polym Sci. 1962;42(6):639–42.\nLeiva CRM, Crnkovic PM, Santos AM. The use of thermogravimetry to determinate the activation energy of combustible oil combustion processes. Quim Nova. 2006;29(5):940–6.\nSoares RW, Menezes VJ, Fonseca MVA, Dweck J. Characterization of carbonaceous products by TG and DTA. J Therm Anal. 1997;49:657–61.\nMorais LC, Dweck J, Campos V, Rosa AH, Fraceto LF, Büchler PM. Combustion and pyrolysis of a sludge from wastewater treatment plant. Mat Sci Forum. 2010;660–661:1009–14.\nSbirrazzuoli N, Vecchio S, Catalani A. Isoconversional kinetics study of alachlor and metolachlor vaporization by thermal analysis. Int J Chem Kinet. 2004;3:74–80.\nOzawa T. Kinectic analysis of derivate curves in thermal analysis. J Therm Anal. 1970;2:301–24.\nFlynn JH, Wall A. General treatment of thermogravimetry of polymers. J Res Nat Bur Stand. 1966;70 A:487–523.\nASTM International, E1641—16 method, Standard Test Method for Decomposition Kinetics by Thermogravimetry Using the Ozawa\u002FFlynn\u002FWall Method, 2016.\nPereira FMM. Estudo da degradação do óleo lubrificante em motores alimentados com biodiesel B100 [A study on lubricant oil degradation in engines feeded with B100 biodiesel]. Master’s Dissertation.Universidade Tecnológica Federal do Paraná, 2015 (in portuguese).",{"VOID":1559},"10.1007\u002Fs10973-018-7298-4","2024-06-24T10:41:06.930+00:00","https:\u002F\u002Flink.springer.com\u002Farticle\u002F10.1007\u002Fs10973-018-7298-4",[1563,1578],{"id":1564,"sortIndex":19,"researcher":18,"roles":1565,"affiliations":1566,"properties":1575,"displayName":1577,"givenName":18,"familyName":18},"b6005b4f-5d5e-43eb-802b-be92789e0c9f",[192],[1567],{"id":1568,"sortIndex":19,"affiliation":1569,"properties":18},"f4624569-b88c-4731-b958-06ef4658090d",{"id":1568,"createTime":18,"updateTime":18,"relativeEntities":1570,"slug":18,"properties":1571,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":1574,"statistic":18},[],{"title":1572},{"VI":1573},"Thermal Analysis Laboratory, School of Chemistry, Rio de Janeiro Federal University, Rio de Janeiro, Brazil",[],{"title":1576},{"VI":1577},"Tatiana Fernandes de Oliveira",{"id":1579,"sortIndex":109,"researcher":18,"roles":1580,"affiliations":1581,"properties":1588,"displayName":1590,"givenName":18,"familyName":18},"f7888592-2641-47bb-8b65-c3897df5f550",[192],[1582],{"id":1568,"sortIndex":19,"affiliation":1583,"properties":18},{"id":1568,"createTime":18,"updateTime":18,"relativeEntities":1584,"slug":18,"properties":1585,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":1587,"statistic":18},[],{"title":1586},{"VI":1573},[],{"title":1589,"gsAuthor":1591},{"VI":1590},"Jo Dweck",{"VOID":1592},"[\"CiZoMrMAAAAJ\"]",{"url":1561,"publisher":1594,"properties":1639},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":1595,"slug":10,"properties":1596,"entityType":16,"verifyStatus":17,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":19,"subjectFields":1599,"manageAffiliations":1608,"indexDatabases":1619,"url":18,"thumbnailPath":18,"statistic":1634,"gsStatistic":18,"type":160,"analyzePriority":18},[],{"issn":1597,"title":1598},{"VOID":13},{"VOID":15},[1600,1604],{"id":22,"createTime":18,"updateTime":18,"relativeEntities":1601,"label":1602,"description":1603,"parentId":18,"standard":18,"scholarHubFieldId":18},[],{"EN":25},{},{"id":28,"createTime":18,"updateTime":18,"relativeEntities":1605,"label":1606,"description":1607,"parentId":18,"standard":18,"scholarHubFieldId":18},[],{"EN":31},{},[1609,1614],{"id":35,"createTime":18,"updateTime":18,"relativeEntities":1610,"slug":18,"properties":1611,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":1613,"statistic":18},[],{"title":1612},{"EN":39},[],{"id":42,"createTime":18,"updateTime":18,"relativeEntities":1615,"slug":18,"properties":1616,"entityType":18,"verifyStatus":18,"verifyTime":18,"verifyNote":18,"languages":18,"translateLanguages":18,"viewCount":18,"url":18,"parentIds":1618,"statistic":18},[],{"title":1617},{"EN":46},[48],[1620,1627],{"id":51,"indexDatabase":1621,"url":64,"indexYears":18,"academicFieldIds":1626,"indexDatabaseRanking":18},{"id":53,"createTime":18,"updateTime":18,"relativeEntities":1622,"label":1623,"description":1624,"key":60,"publicationTags":1625,"standard":18},[],{"EN":56,"VI":56},{"EN":58,"VI":59},[62,63],[66,67],{"id":69,"indexDatabase":1628,"url":80,"indexYears":81,"academicFieldIds":1633,"indexDatabaseRanking":85},{"id":71,"createTime":18,"updateTime":18,"relativeEntities":1629,"label":1630,"description":1631,"key":77,"publicationTags":1632,"standard":18},[],{"EN":74,"VI":74},{"EN":74,"VI":76},[79],[83,84],{"impactFactor":19,"impactFactorByYear":1635,"i10Index":99,"i10IndexLast5Year":100,"totalPublication":101,"totalPublicationByYear":1636,"totalCitation":122,"totalCitationByYear":1637,"totalCitationPerPublication":141,"totalCitationPerPublicationByYear":1638,"hindexLast5Year":159,"hindex":159},{"2012":88,"2014":89,"2015":90,"2016":91,"2017":92,"2018":93,"2019":94,"2020":95,"2021":96,"2022":97,"2023":98},{"2003":103,"2004":104,"2005":105,"2006":106,"2009":107,"2010":108,"2011":109,"2012":109,"2013":110,"2014":111,"2015":112,"2016":113,"2017":114,"2018":115,"2019":116,"2020":117,"2021":118,"2022":119,"2023":120,"2024":121},{"2003":124,"2004":125,"2005":126,"2006":127,"2010":128,"2013":129,"2014":130,"2015":131,"2016":132,"2017":133,"2018":134,"2019":135,"2020":136,"2021":137,"2022":138,"2023":139,"2024":140},{"2003":143,"2004":144,"2005":145,"2006":146,"2010":147,"2013":148,"2014":149,"2015":150,"2016":151,"2017":152,"2018":153,"2019":154,"2020":150,"2021":155,"2022":156,"2023":157,"2024":158},{"pages":1640,"volume":1642},{"VOID":1641},"1953-1963",{"VOID":1643},"134",{"total":19,"publishYear":489,"statisticByYear":1645},{},"2018-04-23","2026-08-17T10:41:35.909+00:00",[85,62]]