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fundamental equation of state for the Helmholtz free energy of R 134a (1,1,1,2-tetrafluoroethane) is presented which is valid for temperatures between 170 K and 455 K and pressures up to 70 MPa. It is based on the most accurate measurements of pressure-density-temperature (p,ρ,T), speed of sound, heat capacity, and vapor pressure which are currently available. A linear regression analysis and a nonlinear least squares fitting technique, based on the selected measurements, were used to determine the structure of the fundamental equation of state and the values of its 21 coefficients. The equation represents nearly all selected experimental data within their estimated accuracy with the exception of heat capacities and speed of sound in the region close to the critical point. Typical accuracies are ±0.05% for density, ±0.02% for the vapor pressure, or ±0.5 and ±1% for the heat capacity. 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energy levels of the iron atom in all of its stages of ionization, as derived from the analyses of atomic spectra, have been compiled. 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the present paper an assessment of experimental and theoretical data on the structure and molecular vibrations of all the LnX3 lanthanide trihalides (X=F,Cl,Br,I) is presented. 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Những dữ liệu này đã hỗ trợ việc xác nhận các xu hướng đã được đề xuất trước đây về các tính chất phân tử của các hợp chất có tiêu đề và ước lượng đáng tin cậy về dữ liệu của các phân tử LnX3 ít được nghiên cứu hơn. Dựa trên các dữ liệu đã thu thập, một phân tích so sánh giữa kết quả thực nghiệm và tính toán đã được thực hiện. Điều này phục vụ để đánh giá khả năng của các phương pháp lý thuyết gần đây đối với các tính chất phân tử nêu trên.\u003C\u002Fjats:p>",{"EN":992,"VI":993},"Structure and Vibrations of Lanthanide Trihalides: An Assessment of Experimental and Theoretical Data","Cấu trúc và Dao động của Các Halogen ba Niken: Đánh Giá Dữ Liệu Thực Nghiệm và Lý Thuyết",{"VI":505},{"VOID":996},"10.1063\u002F1.1595651","2024-12-17T13:32:48.408+00:00",[155],[519],"https:\u002F\u002Fpubs.aip.org\u002Fjpr\u002Farticle\u002F33\u002F1\u002F377\u002F241998\u002FStructure-and-Vibrations-of-Lanthanide-Trihalides",[1002,1021],{"id":1003,"sortIndex":25,"researcher":24,"roles":1004,"affiliations":1005,"properties":1014,"displayName":1018,"givenName":24,"familyName":24},"d1a08921-0737-45db-a23e-69dcf6941aac",[],[1006],{"id":1007,"sortIndex":25,"affiliation":1008,"properties":24},"2dcb0f16-9283-450a-81f3-5f167ff73152",{"id":1007,"createTime":24,"updateTime":24,"relativeEntities":1009,"slug":24,"properties":1010,"entityType":24,"verifyStatus":24,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":24,"url":24,"parentIds":1013,"statistic":24},[],{"title":1011},{"VI":1012},"European Commission Joint Research Centre Institute for Transuranium Elements, P.O. 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The dependence of the molar refraction on wavelength, temperature, and density is shown over an extended range. Based upon the electromagnetic theory of light an equation for the refractive index of water with wavelength, temperature, and density as independent variables is constructed. Its coefficients are directly deduced from all available experimental data by least-squares fit. The range of validity of wavelength is restricted by the theory for normal dispersion to 182 nm≤λ≤2770 nm. The range of temperature and density is given by the available experimental data. Interpolations between the single measured points are possible and the following range of validity can be recommended: for temperature −10 °C≤T≤500 °C and for density 0.0028 kg\u002Fm3 ≤ρ≤1045 kg\u002Fm3. Good agreement exists between the new relation, the available experimental data, and several existing equations.\u003C\u002Fjats:p>","\u003Cjats:p>Một cuộc khảo sát về dữ liệu thí nghiệm hiện có và các phương trình hiện có cho chỉ số khúc xạ của nước đã được thực hiện. Sự phụ thuộc của khúc xạ mol trên bước sóng, nhiệt độ và mật độ được trình bày trên một phạm vi mở rộng. Dựa trên lý thuyết điện từ về ánh sáng, một phương trình cho chỉ số khúc xạ của nước với bước sóng, nhiệt độ và mật độ là các biến độc lập đã được xây dựng. Các hệ số của nó được suy diễn trực tiếp từ tất cả dữ liệu thí nghiệm hiện có bằng phương pháp bình phương nhỏ nhất. Phạm vi hợp lệ của bước sóng bị giới hạn bởi lý thuyết cho phân tán bình thường là 182 nm≤λ≤2770 nm. Phạm vi của nhiệt độ và mật độ được cung cấp bởi dữ liệu thí nghiệm hiện có. Việc nội suy giữa các điểm đo đơn lẻ là khả thi và phạm vi hợp lệ tiếp theo có thể được khuyến nghị: đối với nhiệt độ −10 °C≤T≤500 °C và đối với mật độ 0.0028 kg\u002Fm3 ≤ρ≤1045 kg\u002Fm3. Sự phù hợp tốt tồn tại giữa mối quan hệ mới, dữ liệu thí nghiệm hiện có và một số phương trình hiện có.\u003C\u002Fjats:p>",{"EN":1115,"VI":1116},"Refractive Index of Water and Its Dependence on Wavelength, Temperature, and Density","Chỉ số khúc xạ của nước và sự phụ thuộc của nó vào bước sóng, nhiệt độ và mật độ",{"VI":505},{"VOID":1119},"10.1063\u002F1.555743",[155],[519],"https:\u002F\u002Fpubs.aip.org\u002Fjpr\u002Farticle\u002F14\u002F4\u002F933\u002F241382\u002FRefractive-Index-of-Water-and-Its-Dependence-on",[1124,1141,1156],{"id":1125,"sortIndex":25,"researcher":24,"roles":1126,"affiliations":1127,"properties":1136,"displayName":1138,"givenName":24,"familyName":24},"fdf01b1f-9e9d-4d95-8e7c-e647d83595f4",[],[1128],{"id":1129,"sortIndex":25,"affiliation":1130,"properties":24},"40e04a1b-cd18-43e1-ab1e-411a5b52dab0",{"id":1129,"createTime":24,"updateTime":24,"relativeEntities":1131,"slug":24,"properties":1132,"entityType":24,"verifyStatus":24,"verifyTime":24,"verifyNote":24,"languages":24,"translateLanguages":24,"viewCount":24,"url":24,"parentIds":1135,"statistic":24},[],{"title":1133},{"EN":1134},"Lehrstuhl A für Thermodynamik, Technische Universität München, Arcisstr. 21, D-8000 München 2, Federal Republic of Germany",[],{"title":1137,"openalex":1139},{"EN":1138},"I. 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data (through mid-1996) concerning the gas-phase reactions of alkanes and alkenes (including isoprene and monoterpenes) leading to their first generation products are reviewed and evaluated for tropospheric conditions. The recommendations of the most recent IUPAC evaluation [J. Phys. Chem. Ref. Data, 26, No. 3 (1997)] are used for the ⩽C3 organic compounds, unless more recent data necessitates reevaluation. The most recent review and evaluation of Atkinson [J. Phys. Chem. Ref. Data, Monograph 2, 1 (1994)] concerning the kinetics of the reactions of OH radicals, NO3 radicals, and O3 is also updated for these two classes of volatile organic compounds.\u003C\u002Fjats:p>","\u003Cjats:p>Dữ liệu tài liệu (đến giữa năm 1996) liên quan đến các phản ứng pha khí của các alkan và alken (bao gồm isoprene và monoterpen) dẫn đến các sản phẩm thế hệ đầu tiên của chúng được xem xét và đánh giá cho các điều kiện trong tầng đối lưu. Các khuyến nghị từ đánh giá gần đây nhất của IUPAC [J. Phys. Chem. Ref. Data, 26, Số 3 (1997)] được sử dụng cho các hợp chất hữu cơ ⩽C3, trừ khi có dữ liệu gần đây hơn cần phải đánh giá lại. Đánh giá và xem xét gần đây nhất của Atkinson [J. Phys. Chem. Ref. Data, Monograph 2, 1 (1994)] liên quan đến động học của các phản ứng của các gốc OH, gốc NO3, và O3 cũng được cập nhật cho hai loại hợp chất hữu cơ bay hơi này.\u003C\u002Fjats:p>",{"EN":1252,"VI":1253},"Gas-Phase Tropospheric Chemistry of Volatile Organic Compounds: 1. Alkanes and Alkenes","Hóa học khí quyển tầng đối lưu của các hợp chất hữu cơ bay hơi: 1. 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