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Acta Enzymol., 524, 162, 10.1016\u002F0005-2744(78)90114-6",{"doi":1458},"10.1016\u002F0005-2744(78)90114-6",{"id":1460,"createTime":1461,"updateTime":1461,"relativeEntities":1462,"slug":1463,"properties":1464,"entityType":165,"verifyStatus":166,"verifyTime":1478,"verifyNote":167,"syncStatus":23,"languages":1479,"translateLanguages":24,"viewCount":25,"primaryUrl":1480,"fullTextUrl":24,"authors":1481,"publicationType":215,"publisherRelationship":1590,"citationCount":1622,"citationInfo":1623,"publishDate":1626,"publishYear":1627,"citationAnalyzeStatus":23,"lastCitationAnalyze":24,"indexDatabases":24,"openAccess":24,"references":1628,"isForceReanalyzing":483},"c4c53239-740f-4318-8e30-9ecf06773942","2024-10-07T22:10:28.459+00:00",[],"Assembly-of-Bacteriophage-into-Functional-Materials",{"mag":1465,"keywords":1467,"openalex":1468,"abstract":1470,"title":1472,"pm":1474,"doi":1476},{"VOID":1466},"1939075531",{},{"VOID":1469},"W1939075531",{"EN":1471},"\u003Cjats:title>ABSTRACT:\u003C\u002Fjats:title>\u003Cjats:p>For the last decade, the fabrication of ordered structures of phage has been of great interest as a means of utilizing the outstanding biochemical properties of phage in developing useful materials. Combined with other organic\u002Finorganic substances, it has been demonstrated that phage is a superior building block for fabricating various functional devices, such as the electrode in lithium‐ion batteries, photovoltaic cells, sensors, and cell‐culture supports. Although previous research has expanded the utility of phage when combined with genetic engineering, most improvements in device functionality have relied upon increases in efficiency owing to the compact, more densely packable unit size of phage rather than on the unique properties of the ordered nanostructures themselves. Recently, self‐templating methods, which control both thermodynamic and kinetic factors during the deposition process, have opened up new routes to exploiting the ordered structural properties of hierarchically organized phage architectures. In addition, ordered phage films have exhibited unexpected functional properties, such as structural color and optical filtering. Structural colors or optical filtering from phage films can be used for optical phage‐based sensors, which combine the structural properties of phage with target‐specific binding motifs on the phage‐coat proteins. This self‐templating method may contribute not only to practical applications, but also provide insight into the fundamental study of biomacromolecule assembly in in vivo systems under complicated and dynamic conditions.\u003C\u002Fjats:p>",{"EN":1473},"Assembly of Bacteriophage into Functional 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But flowing versions of them are new actors in the materials science landscape and in particular for energy applications. This paper presents a new way to deliver nanostructured hybrid materials for energy storage, namely, in the form of nanofluids. We present here the first example of a hybrid electroactive nanofluid (HENFs) combining capacitive and faradaic energy storage mechanisms in a single fluid material. This liquid electrode is composed of reduced graphene oxide and polyoxometalates (rGO‐POMs) forming a stable nanocomposite for electrochemical energy storage in novel Nanofluid Flow Cells. Two graphene based hybrid materials (rGO‐phosphomolybdate, rGO‐PMo\u003Cjats:sub>12\u003C\u002Fjats:sub> and rGO‐phosphotungstate, rGO‐PW\u003Cjats:sub>12\u003C\u002Fjats:sub>) were synthesized and dispersed with the aid of a surfactant in 1 M H\u003Cjats:sub>2\u003C\u002Fjats:sub>SO\u003Cjats:sub>4\u003C\u002Fjats:sub> aqueous electrolyte to yield highly stable hybrid electroactive nanofluids (HENFs) of low viscosity which were tested in a home‐made flow cell under static and continuous flowing conditions. Remarkably, even low concentration rGO‐POMs HENFs (0.025 wt%) exhibited high specific capacitances of 273 F\u002Fg(rGO‐PW\u003Cjats:sub>12\u003C\u002Fjats:sub>) and 305 F\u002Fg(rGO‐PMo\u003Cjats:sub>12\u003C\u002Fjats:sub>) with high specific energy and specific power. Moreover, rGO‐POM HENFs show excellent cycling stability (∼95 %) as well as Coulombic efficiency (∼77–79 %) after 2000 cycles. Thus, rGO‐POM HENFs effectively behave as real liquid electrodes with excellent properties, demonstrating the possible future application of HENFs for dual energy storage in a new generation of Nanofluid Flow Cells.\u003C\u002Fjats:p>",{"EN":1961},"Hybrid Graphene‐Polyoxometalates Nanofluids as Liquid Electrodes for Dual Energy Storage in Novel Flow 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The role of the perimeter interfaces of Au particles as the sites for reactions is discussed as well as the \nchange in chemical reactivity of Au clusters composed of fewer than 300 atoms. © 2003 The Japan Chemical Journal Forum and Wiley Periodicals, \nInc., Chem Rec 3: 75–87; 2003: Published online in Wiley InterScience (www.interscience.wiley.com) DOI 10.1002\u002Ftcr.10053\u003C\u002Fjats:p>",{"EN":2285},"When Gold Is Not Noble: Catalysis by 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This review provides the latest advances in the preparation of graphene supported metal nanoparticles and their application in the catalytic formation of both carbon‐carbon (C−C) and carbon‐heteroatom (C−X) bonds including the Suzuki, Heck, Hiyama, Ullmann, Buchwald and Sonogashira coupling reactions. 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Entropy, which is one of the most \nmacroscopic concepts but which has a clear microscopic meaning, provides crucial microscopic information for complex \nsystems for which a microscopic description is hard to establish. Starting from structural implication by absolute \n(third‐law) entropy for crystalline solids, the existence of successive phase transitions caused \nby the successive conformational melting of alkyl chains in discotic mesogens is explained. An experimental basis \nis given for the “quasi‐binary picture” of thermotropic liquid crystals, i.e., the highly disordered \nalkyl chains behave like a second component (solvent). A novel entropy transfer between the \n“components” of a molecule and the resulting “alkyl chains as entropy reservoir” mechanism are \nexplained for cubic mesogens. © 2003 The Japan Chemical Journal Forum and Wiley Periodicals, Inc., Chem Rec 3: \n29–39; 2003: Published online in Wiley InterScience (www.interscience.wiley.com) \nDOI 10.1002\u002Ftcr.10046\u003C\u002Fjats:p>",{"EN":3617},"Alkyl chains acting as entropy reservoir in liquid crystalline 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of MXenes (Ti\u003Cjats:sub>3\u003C\u002Fjats:sub>C\u003Cjats:sub>2\u003C\u002Fjats:sub>T\u003Cjats:sub>x\u003C\u002Fjats:sub>), which belongs to the family of two‐dimensional transition metal nitrides and carbides by encompassing unique combination of metallic conductivity and hydrophilicity, is receiving tremendous attention, since its discovery as energy material in 2011. Owing to its precursor selective chemical etching, and unique intrinsic characteristics, the MXene surface properties are further classified into highly chemically active compound, which further produced different surface functional groups i. e., oxygen, fluorine or hydroxyl groups. However, the role of surface functional groups doesn't not only have a significant impact onto its electrochemical and hydrophilic characteristics (i. e., ion adsorption\u002Fdiffusion), but also imparting a noteworthy effect onto its conductivity, work function, electronic structure and properties. Henceforth, such kind of inherent chemical nature, robust electrochemistry and high hydrophilicity ultimately increasing the MXene application as a most propitious material for overall environment‐remediation, electrocatalytic sensors, energy conversion and storage application. Moreover, it is well documented that the role of MXenes in all kinds of research fields is still on a progress stage for their further improvement, which is not sufficiently summarized in literature till now. The present review article is intended to critically discuss the different chemical aptitudes and the diversity of MXenes and its derivates (i. e., hybrid composites) in all aforesaid application with special emphasis onto the improvement of its surface characteristics for the multidimensional application. However, this review article is anticipated to endorse MXenes and its derivates hybrid configuration, which is discussed in detail for emerging environmental decontamination, electrochemical use, and pollutant detection via electrocatalytic sensors, photocatalysis, along with membrane distillation and the adsorption application. Finally, it is expected, that this review article will open up new window for the effective use of MXene in a broad range of environmental remediation, energy conversion and storage application as a novel, robust, multidimensional and more proficient materials.\u003C\u002Fjats:p>",{"EN":3927},"Recent Advancement in Rational Design Modulation of MXene: A Voyage from Environmental Remediation to Energy Conversion and Storage",{"VOID":3929},"36103617",{"VOID":3931},"10.1002\u002Ftcr.202200097","2024-08-30T17:40:45.278+00:00",[169],"https:\u002F\u002Fonlinelibrary.wiley.com\u002Fdoi\u002F10.1002\u002Ftcr.202200097",[3936,3958,3991,4013,4034,4057,4079,4101,4118,4137,4159,4181,4198,4220],{"id":3937,"sortIndex":1625,"researcher":24,"roles":3938,"affiliations":3939,"properties":3951},"987b87bb-900a-4dca-91d2-8def034f8b40",[],[3940],{"id":3941,"sortIndex":25,"affiliation":3942,"properties":24},"8d1604dc-e969-4b67-a6d7-be82fee00204",{"id":3943,"createTime":3944,"updateTime":3945,"relativeEntities":3946,"slug":3947,"properties":3948,"entityType":84,"verifyStatus":23,"verifyTime":24,"verifyNote":24,"syncStatus":23,"languages":24,"translateLanguages":24,"viewCount":25},"a2c9d19d-9fc2-43df-a4c7-303143a35ea1","2023-12-06T18:47:37.230+00:00","2024-08-30T17:41:09.257+00:00",[],"Energy-Technology-Program-Department-of-Specialized-Engineering-Faculty-of-Engineering-Prince-of-Songkla-University-15-Karnjanavanich-Rd-Hat-Yai-Songkhla-90110-Thailand",{"title":3949},{"VI":3950},"Energy Technology Program, Department of Specialized Engineering, Faculty of Engineering, Prince of Songkla University, 15 Karnjanavanich Rd., Hat Yai, Songkhla 90110, Thailand",{"openalex":3952,"orcid":3954,"title":3956},{"VOID":3953},"A5051602102",{"VOID":3955},"https:\u002F\u002Forcid.org\u002F0000-0003-0503-5301",{"EN":3957},"M.S. 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Converging growth of two hemispherical gold deposits on two adjacent platinum microelectrodes (both 100 µm diameter in glass, ca. 45 µm gap) followed by careful etching in aqueous chloride solution was employed. During growth both gold hemispheres “connect” and during etching “disconnection” is evident in a drop in current. Gold‐gold junctions with sub‐micron gaps are formed and applied for the electroanalytical detection of sub‐micromolar concentrations of hydroquinone in 0.1 M phosphate buffer pH 7 (\u003Cjats:italic>E\u003C\u002Fjats:italic>\u003Cjats:sub>rev\u003C\u002Fjats:sub> = 0.04 V vs. SCE) and sub‐micromolar concentration of dopamine in 0.1 M phosphate buffer pH 7 (\u003Cjats:italic>E\u003C\u002Fjats:italic>\u003Cjats:sub>rev\u003C\u002Fjats:sub> = 0.14 V vs. SCE). 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