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A seven-lump kinetic model was presented for the catalytic cracking of vacuum residue, taking cognisance of diffusion resistance, which is a departure from the general norm in the literature. Also, heat transfer resistance between the fluid and solid phases was incorporated into the energy balances for instantaneous and one-dimensional vaporization of feedstock. The developed model was a set of twelve coupled, highly non-linear and stiff ordinary differential equations, ODEs, which was numerically solved with an implicit MATLAB built-in solver, ode23t, designed deliberately for handling stiff differential equations to circumvent the problem of instability associated with explicit methods. An excellent agreement was achieved between the industrial RFCCU plant data and the simulated results of this study, with average absolute deviation being \u003C ± 5% for instantaneous vaporization of feedstock in all cases investigated. Moreover, the simulated results revealed that half of the reactor was relatively redundant as this accounted for only 3% of the conversion. Hence, the findings of this study could be useful to the production practice for the Khartoum Refinery Company.",{"EN":48},"Modelling and simulation of an industrial RFCCU-riser reactor for catalytic cracking of vacuum residue",{"VOID":50},"[]",{"VOID":52},"Ahmed A, Maulud A, Ramasamy M, Lau KK, Mahadzir S (2014) 3D CFD modelling and simulation of RFCC riser hydrodynamics and kinetics. J Appl Sci 14(23):3172–3181\nPugsley S, Dalai K (2004) Two-dimensional reaction engineering model of the riser section of fluid catalytic cracking unit. Ind Eng Chem Res 43:5571–5581\nBollas GM, Lappasa AA, Iatridisa DK, Vasalos IA (2007) Five-lump kinetic model with selective catalyst deactivation for the prediction of the product selectivity in the fluid catalytic cracking process. Catal Today 127:31–43\nWeekman VW Jr (1968) A model of catalytic cracking conversion in fixed, moving, and fluid-bed reactors. Ind Eng Chem Proc Des Dev 7:90–95\nWeekman VW Jr (1969) Kinetics and dynamics of catalytic cracking selectivity in fixed beds. Ind Eng Chem Proc Des Dev 8:385–393\nLee LS, Yu SW, Cheng CT, Pan WY (1988) Fluidized-bed catalyst cracking regenerator modelling and analysis. Chem Eng Sci 40:71–82\nLee LS, Chen YW, Huang TN, Pan WY (1989) Four-lump kinetic model for fluid catalytic cracking process. Can J Chem Eng 67:615–619\nCorella J, Frances E (1991) On the kinetic equation of deactivation cracking commercial (FCC) catalysts with commercial feedstocks. Stud Surf Sci Catal 68:375–381\nDupain X, Makkee M, Moulijn JA (2006) Optimal conditions in fluid catalytic cracking: a mechanistic approach. Appl Catal A 297:198–219\nKraemer D, de Lasa HI, Larocca M (1991) Deactivation of cracking catalyst in short contact time reactors. Ind Eng Chem Res 69:355–360\nAncheyta JJ, Lopez FI, Aguilar RE (1999) 5-Lump kinetic model for gas oil catalytic cracking. Appl Catal A 177:227–235\nTakatsuka T, Sato S (1987) A reaction model for fluidized-bed catalytic cracking of residual oil. Int Chem Eng 27(1):107–116\nXiong K, Lu C, Wang Z, Gao X (2015) Kinetic study of catalytic cracking of heavy oil over an in situ crystallized FCC catalyst. Fuel 142:65–72\nXu O, Su H, Mu S, Chu J (2006) 7-lump kinetic model for residual oil catalytic cracking. J Zhejiang Univ Sci A 7(11):1932–1941\nHeydari M, AleEbrahim H, Dabir B (2010) Study of seven-lump kinetic model in the fluid catalytic cracking unit. Am J Appl Sci 7(1):71–76\nHagelberg P, Eilos I, Hiltunen J, Lipiäinen K, Niemi VM, Aittamaa J, Krause AO (2002) Kinetics of catalytic cracking with short contact times. Appl Catal A 223:73–84\nJacob SM, Gross B, Voltz SE, Weekman VW Jr (1976) A lumping and reaction scheme for catalytic cracking. AIChE J 22:701–713\nDu YP, Yang Q, Zhao H, Yang CH (2014) An integrated methodology for the modeling of fluid catalytic cracking (FCC) riser reactor. Appl Petrochem Res 4:423–433\nBarbosa AC, Lopes GC, Rosa LM, Mori M, Martignoni WP (2013) Three dimensional simulation of catalytic cracking reactions in an industrial scale riser using a 11-lump kinetic model. AIDIC Conf Ser 11:31–40\nSa Y, Liang X, Chen X, Liu J (1995) Study of 13-lump kinetic model for residual catalytic cracking. Petrochem Eng Cor 145–152\nLan X, Xu C, Wang L, Wu I, Gao J (2009) CFD modelling of gas-solid flow and cracking reaction in two-stage riser FCC reactor. Chem Eng Sci 64:3847–3858\nPitault I, Nevicato D, Forissier M, Bernard JR (1994) Kinetic model on a molecular description for catalytic cracking of vacuum gas oil. Chem Eng Sci 49(27A):4249–4262\nPinheiro CI, Fernandes JL, Domingues L, Chambel AJ, Graca I, Oliveira NM, Ribeiro FR (2011) Fluid catalytic cracking (FCC) process modeling, simulation, and control. Ind Eng Chem Res 51(1):1–29\nHu Y, Xu W, Hou W, Su H, Chu J (2005) Dynamic modelling and simulation of a commercial naphtha catalytic reforming process. Chin J Chem Eng 13:74–82\nLiu Z, Meng X, Xu C, Gao J (2007) Secondary cracking of gasoline and diesel from heavy oil catalytic pyrolysis. Chin J Chem Eng 15:309–314\nFlinger M, Schipper PH, Sapre AV, Krambeck FJ (1994) Two phase cluster in riser reactors: impact of radial density distribution on yields. Chem Eng Sci 49:5813–5818\nGupta A, Subba Rao D (2001) Model for the performance of a fluid catalytic cracking (FCC) riser reactor: effect of feed atomization. Chem Eng Sci 56:4489–4503\nNayak SV, Joshi SL, Ranade VV (2005) Modeling of vaporization and cracking of liquid oil injected in a gas–solid riser. Chem Eng Sci 60:6049–6066\nRanz WE, Marshall WR (1952) Evaporation from drops. Chem Eng Prog 48:141–146\nSmith JM (1981) Chemical engineering kinetics, 3rd edn. McGraw-Hill Book Co., Singapore\nPruski J, Pekediz A, de Lasa HI (1996) Catalytic cracking of hydrocarbons in a novel riser simulator: lump adsorption parameters under reaction conditions. Chem Eng Sci 51:1799–1806\nBidabehere CM, Sedran U (2001) Simultaneous diffusion, adsorption, and reaction in fluid catalytic cracking catalysts. Ind Eng Chem Res 40:530–535\nAli H, Rohani S (1997) Dynamic modeling and simulation of riser-type fluid catalytic cracking unit. Chem Eng Technol 20:118–130\nArandes JM, Lasa HI (1992) Simulation and multiplicity of steady states in fluidized FCCUs. Chem Eng Sci 47:2535–2540\nArbel A, Huang Z, Rinard IH, Shinnar R, Sapre AV (1995) Dynamic and control of fluidized catalytic crackers. 1. Modeling of the current generation of FCC’s. Ind Eng Chem Res 34:1228–1243\nHan IS, Chung CB (2001) Dynamic modelling and simulation of a fluidized catalytic cracking process. Part II: property estimation and simulation. Chem Eng Sci 56(5):1973–1990\nAhmed HS, Shaban SA, Menoufy MF, El Kady FY (2013) Effect of catalyst deactivation on vacuum residue hydrocracking. Egypt J Pet 22(3):367–372\nRossini F, Mair B (1958) Summary of 159 hydrocarbons isolated from one representative petroleum. Ind Eng Chem Chem Eng Data Ser 3(1):141–145\nDasila PK, Choudhury I, Saraf D, Chopra S, Dalai A (2012) Parametric sensitivity studies in a commercial FCC unit. Adv Chem Eng Sci 2:136–149\nGupta RS (2006) Modeling and simulation of fluid catalytic cracking unit. Deemed University, Patiala\nPugsley TS, Berruti F (1996) A predictive hydrodynamic model for circulating fluidized bed risers. Powder Technol 89:57–69\nMeng X, Xu C, Gao J, Li L (2007) Seven-lump kinetic model for catalytic pyrolysis of heavy oil. Cat Comm 8:1197–1201\nPatience GS, Chaouki J, Berruti F, Wong SR (1992) Scaling considerations for circulating fluidized bed risers. Powder Technol 72:31–39\nSvoboda K, Kalisz S, Miccio F, Wieczorek K, Pohorely M (2009) Simplified modeling of circulating flow of solids between a fluidized bed and a vertical pneumatic transport tube reactor connected by orifices. Powder Technol 192:65–73\nCoulson JM, Richardson JF (2002) Chemical engineering, vol. 2, 5th edn. Butterworth-Heinemann, Oxford\nRabinovich E, Kalman H (2011) Flow regime diagram for vertical pneumatic vonveying and fluidized bed systems. Powder Technol 207:119–133\nTsuo YP, Gidaspow D (1990) Computation of flow patterns in circulating fluidized beds. AIChE J 36:885–896\nGupta RK, Kumar V, Srivastava VK (2007) A new generic approach for the modelling of fluid catalytic cracking (FCC) riser reactor. Chem Eng Sci 62(17):4510–4528\nFernandes JL, Verstraete JJ, Pinheiro CI, Oliveira NM, Ribeiro FR (2007) Dynamic modelling of an industrial R2RFCC unit. Chem Eng Sci 62(4):1184–1198\nBromley LA, Wilke CR (1951) Viscosity behaviour of gases. Ind Eng Chem 43:1641–1648\nAmerican Petroleum Institute (API) (1992) Technical data book—petroleum refining, 5th edn. API, New York\nDaubert TE, Danner RP (1985) Data compilation tables of properties of pure components. American Institute of Chemical Engineers, New York\nFahim MA, Al-Sahhaf TA, Elkilani AS (2010) Fundamentals of petroleum refining. Elsevier, New York\nKonno H, Saito SJ (1969) Pneumatic conveying of solids through straight pipe. J Chem Eng 2:211–225\nNegrão CO, Baldessar F (2006) Simulation of fluid catalytic cracking risers—a six lump model. In: The 11th Brazillian congress of thermal sciences and engineering, Braz Soc of Mech Sci Eng ABCM, Curitiba, Brazil Dec 5–8\nFarah MA (2003) Fundamental calculations in process engineering. Trainees Program Report of Petrobras, Rio de Janeiro (in Portuguese)\nSinnott R, Towler G (2013) Chemical engineering design, vol 6, 5th edn. Butterworth-Heinemann (An imprint of Elsevier), Oxford\nSmith JM, Van Ness HC, Abbott MM (2001) Introduction to chemical engineering thermodynamics, 6th edn. McGraw-Hill Inc, New York\nAhari JS, Farshi A, Forsat K (2008) A mathematical modeling of the riser reactor in industrial FCC unit. Pet Coal 50:15–24\nSouza JA, Vargas JVC, Ordonez JC, Matignoni WP, von Meien OF (2011) Thermodynamic optimization of fluidized catalytic cracking (FCC) units. Int J Heat Mass Transfer 54:1187–1197\nFogler HS (2006) Elements of chemical reaction engineering, 4th edn. Pearson Education Inc., Upper Saddle River\nMissen RW, Mims CA, Saville BA (1999) Introduction to chemical reaction engineering and kinetics. Wiley, New York, pp 198–214\nGreenstein AM, Graham S, Hudiono YC, Nair S (2006) Thermal properties and lattice dynamics of polycrystalline MFI zeolite films. Nanoscale Microscale Thermophys 10(4):321–331\nCoquil T, Reitz C, Brezesinski T, Tolbert SH, Pilon L (2010) Thermal conductivity of pure silica MEL and MFI zeolite thin films. J Appl Phys. https:\u002F\u002Fdoi.org\u002F10.1063\u002F1.3462500\nAli H, Rohani S, Corriou JP (1997) Modeling and control of a riser type fluid catalytic cracking (FCC) unit. Trans Inst Chem Eng 75:380–395\nBerry TA, McKeen TR, Pugsley TS, Dalai AK (2004) Two-dimensional reaction engineering model of the riser section of a fluid catalytic cracking unit. Ind Eng Chem Res 43:5571–5581\nDerouin C, Nevicato D, Forissier M, Nild G, Bernard J (1997) Hydrodynamics of riser units and their impact on FCC operation. Ind Eng Chem Res 36:4504–4513\nKimm NK, Berruti F, Pugsley TS (1996) Modeling the hydrodynamics of down flow gas–solids reactors. Chem Eng Sci 51:2661–2666\nMartin MP, Derouin C, Turlier P, Forissier M, Wild G, Bernard J (1992) Catalytic cracking in riser reactors: core—annulus and elbow effects. Chem Eng Sci 47:2319–2327\nTheologos KN, Markatos NC (1993) Advanced modeling of fluid catalytic cracking riser-type reactors. 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J Mol Catal A Chem 394:211–216. \n                              https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.molcata.2014.07.023",{"doi":285},"10.1016\u002Fj.molcata.2014.07.023",{"id":22,"text":287,"url":22,"identifiers":288},"Amitouche D, Haouas M, Mazari T, Mouanni S, Canioni R, Rabia C, Cadot E, Marchal-Roch C (2018) The primary stages of polyoxomolybdate catalyzed cyclohexanone oxidation by hydrogen peroxide as investigated by in situ NMR. Substrate activation and evolution of the working catalyst. Appl Catal A Gen 561:104–116. \n                              https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.apcata.2018.05.017",{"doi":289},"10.1016\u002Fj.apcata.2018.05.017",{"id":22,"text":291,"url":22,"identifiers":292},"Atlamsani A, Brégeault JM, Ziyad M (1993) Oxidation of 2-methylcyclohexanone and cyclohexanone by dioxygen catalyzed by vanadium-containing heteropolyanions. 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Chem Rev 98:359. \n                              https:\u002F\u002Fdoi.org\u002F10.1021\u002Fcr960398a",{"doi":358},"10.1021\u002Fcr960398a",{"id":22,"text":360,"url":22,"identifiers":361},"Kuznetsova LI, Kuznetsova NI, Maksimovskaya RI, Koshcheeva OS, Utkin VA (2013) Catalytic properties of heteropoly compounds in 1,3-butadiene oxidation with hydrogen peroxide. Kinet Catal 54:420–430. \n                              https:\u002F\u002Fdoi.org\u002F10.1134\u002FS0023158413040071",{"doi":362},"10.1134\u002FS0023158413040071",{"id":22,"text":364,"url":22,"identifiers":365},"Leont’ev AV, Fomicheva OA, Proskurnina MV, Zefirov NS (2001) Modern chemistry of nitrous oxide. Russ Chem Rev 70:91–104. \n                              https:\u002F\u002Fdoi.org\u002F10.1070\u002FRC2001v070n02ABEH000631",{"doi":366},"10.1070\u002FRC2001v070n02ABEH000631",{"id":22,"text":368,"url":22,"identifiers":369},"Li H, She Y, Fu H, Cao M, Wang J, Wang T (2015) Synergistic effect of co-reactant promotes one-step oxidation of cyclohexane into adipic acid catalyzed by manganese porphyrins. Can J Chem 93:696–701. \n                              https:\u002F\u002Fdoi.org\u002F10.1139\u002Fcjc-2014-0515",{"doi":370},"10.1139\u002Fcjc-2014-0515",{"id":22,"text":372,"url":22,"identifiers":373},"Luo J, Huang Y, Ding B, Wang P, Geng X, Zhang J, Wei Y (2018) Single-atom Mn active site in a triol-stabilized β-Anderson manganohexamolybdate for enhanced catalytic activity towards adipic acid production. Catalysts 8:121. \n                              https:\u002F\u002Fdoi.org\u002F10.3390\u002Fcatal8030121",{"doi":374},"10.3390\u002Fcatal8030121",{"id":22,"text":376,"url":22,"identifiers":377},"Maksimovskaya RI (2013) Molybdophosphate heteropoly blues: electron-transfer reactions in aqueous solutions as studied by NMR. Polyhedron 65:54–59. \n                              https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.poly.2013.08.014",{"doi":378},"10.1016\u002Fj.poly.2013.08.014",{"id":22,"text":380,"url":22,"identifiers":381},"Mazari T, Benadji S, Tahar A, Dermeche L, Rabia C (2013) Simple and green liquid-phase synthesis of adipic acid using Keggin-type phosphomolybdates catalysts. J Mat Sci Eng B 3:146–152. \n                              https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.molcata.2014.07.023",{"doi":285},{"id":22,"text":383,"url":22,"identifiers":384},"Mazari T, Marchal-Roch C, Hocine S, Salhi N, Rabia C (2009) Oxidation of propane over substituted Keggin phosphomolybdate salts. J Nat Gas Chem 18:319–324. \n                              https:\u002F\u002Fdoi.org\u002F10.1016\u002FS1003-9953(08)60111-5",{"doi":385},"10.1016\u002FS1003-9953(08)60111-5",{"id":22,"text":387,"url":22,"identifiers":388},"Mouanni S, Mazari T, Benadji S, Dermeche L, Marchal-Roch C, Rabia C (2018) Simple and green adipic acid synthesis from cyclohexanone and\u002For cyclohexanol oxidation with efficient (NH4)xHyMzPMo12O40 (M: Fe Co, Ni) catalysts. BREC 13:386–391",{},{"id":22,"text":390,"url":22,"identifiers":391},"Mouanni S, Mazari T, Amitouche D, Benadji S, Dermeche L, Roch-Marchal C, Rabia C (2019) Preparation and characterization of H3−2\n                           (x+y)MnxCoyPMo12O40 heteropolysalts. Application to adipic acid green synthesis from cyclohexanone oxidation with hydrogen peroxide. C R Chim. \n                              https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.crci.2019.01.003",{"doi":392},"10.1016\u002Fj.crci.2019.01.003",{"id":22,"text":394,"url":22,"identifiers":395},"Moudjahed M, Dermeche L, Benadji S, Mazari T, Rabia C (2016) Dawson-type polyoxometalates as green catalysts for adipic acid synthesis. Mol Catal A Chem 414:72–77. \n                              https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.molcata.2015.12.014",{"doi":396},"10.1016\u002Fj.molcata.2015.12.014",{"id":22,"text":398,"url":22,"identifiers":399},"Mouheb L, Dermeche L, Mazari T, Benadji S, Essayem N, Rabia C (2018) Clean adipic acid synthesis from liquid-phase oxidation of cyclohexanone and cyclohexanol using (NH4)xAyPMo12O40 (A: Sb, Sn, Bi) mixed heteropolysalts and hydrogen peroxide in free solvent. J Catal Lett 148:612–620. \n                              https:\u002F\u002Fdoi.org\u002F10.1007\u002Fs10562-017-2263-6",{"doi":400},"10.1007\u002Fs10562-017-2263-6",{"id":22,"text":402,"url":22,"identifiers":403},"Nomiya K, Miwa M, Sugaya Y (1984) Catalysis by heteropolyacid-VII. Catalytic oxidation of cyclohexanol by dodecamolybdate. 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Appl Catal B Environ 44:117–151. \n                              https:\u002F\u002Fdoi.org\u002F10.1016\u002FS0926-3373(03)00026-2",{"doi":412},"10.1016\u002FS0926-3373(03)00026-2",{"id":22,"text":414,"url":22,"identifiers":415},"Piyali B, Kajari G, Safikul I, Astam KP, Manirul I, Asim B (2016) New hybrid iron phosphonate material as an efficient catalyst for the synthesis of adipic acid in air and water. ACS Sustain 4:7147–7157. \n                              https:\u002F\u002Fdoi.org\u002F10.1021\u002Facssuschemeng.6b02023",{"doi":416},"10.1021\u002Facssuschemeng.6b02023",{"id":22,"text":418,"url":22,"identifiers":419},"Rocchiccioli-Deltcheff C, Fournier M, Franck R, Thouvenot R (1984) Vibrational investigations of polyxometalates. 4. Valence force fields of anions related to the lindqvist structure. J Mol Struct 114:49–56. \n                              https:\u002F\u002Fdoi.org\u002F10.1016\u002FS0022-2860(84)87202-6",{"doi":420},"10.1016\u002FS0022-2860(84)87202-6",{"id":22,"text":422,"url":22,"identifiers":423},"Renz M, Blasco T, Corma A, Fornes V, Jensen R, Nemeth L (2002) Selective and shape-selective Baeyer–Villiger oxidations of aromatic aldehydes and cyclic ketones with Sn-beta zeolites and H2O2. Chem Eur J 8:20",{"doi":424},"10.1002\u002F1521-3765(20021018)8:20\u003C4708::AID-CHEM4708>3.0.CO;2-U",{"id":22,"text":426,"url":22,"identifiers":427},"Strukul G, Varagnolo A, Pinna F (1997) New (old) hydroxo complexes of platinum(II) as catalysts for the Baeyer–Villiger oxidation of ketones with hydrogen peroxide. J Mol Catal A Chem 17:413–423. \n                              https:\u002F\u002Fdoi.org\u002F10.1016\u002FS1381-1169(96)00246-4",{"doi":428},"10.1016\u002FS1381-1169(96)00246-4",{"id":22,"text":430,"url":22,"identifiers":431},"Tahar A, Benadji S, Mazari T, Dermeche L, Marchal-Roch C, Rabia C (2015) Preparation, characterization and reactivity of Keggin type phosphomolybdates, H3−2xNixPMo12O40 and (NH4)3−2xNixPMo12O40, for adipic acid synthesis. Catal Lett 145:569–575. \n                              https:\u002F\u002Fdoi.org\u002F10.1007\u002Fs10562-014-1373-7",{"doi":432},"10.1007\u002Fs10562-014-1373-7",{"id":22,"text":434,"url":22,"identifiers":435},"Terent’ev AO, Platonov MM, Kashin AS, INikishin GI (2008) Oxidation of cycloalkanones with hydrogen peroxide: an alternative route to the Baeyer–Villiger reaction. Synthesis of dicarboxylic acid esters. Tetrahedron 64:7944–7948. \n                              https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.tet.2008.06.027",{"doi":436},"10.1016\u002Fj.tet.2008.06.027",{"id":22,"text":438,"url":22,"identifiers":439},"Xu S, Wang Z, Zhang X, Zhang X, Ding K (2008) Chiral Brønsted acid catalyzed asymmetric Baeyer–Villiger reaction of 3-substituted cyclobutanones by using aqueous H2O2. J Angew Chem 120:2882–2885. \n                              https:\u002F\u002Fdoi.org\u002F10.1002\u002Fange.200705932",{"doi":440},"10.1002\u002Fange.200705932",{"id":442,"createTime":443,"updateTime":444,"relativeEntities":445,"slug":446,"properties":447,"entityType":55,"verifyStatus":56,"verifyTime":456,"verifyNote":58,"languages":22,"translateLanguages":22,"viewCount":23,"primaryUrl":457,"fullTextUrl":22,"authors":458,"publicationType":134,"publisherRelationship":524,"citationCount":22,"citationInfo":22,"publishDate":544,"publishYear":545,"citationAnalyzeStatus":21,"lastCitationAnalyze":444,"indexDatabases":546,"openAccess":22,"references":547,"isForceReanalyzing":159},"19380ad3-5c66-4b83-805e-ea5035b4ad84","2024-01-14T08:47:42.608+00:00","2025-07-12T20:28:13.894+00:00",[],"Utilization-of-exhausted-dust-from-FCC-flue-gas-as-material-for-FCC-catalyst-preparation",{"abstract":448,"title":450,"gsPaper":452,"doi":454},{"EN":449},"In this paper, new matrix and corresponding fluidized catalytic cracking (FCC) catalysts were prepared by reutilizing the exhausted dust which was derived from fluidized catalytic cracking flue gas. The results showed that the new matrix has wider mesopore size distribution than pseudo-boehmite binder. With the increase of the additional amount of this new matrix, FCC catalyst possessed increased micro-activity test conversion of vacuum gas oil (VGO) from 68 % to 71 %. The catalytic cracking performance on a fixed fluidized bed unit showed that compared with CAT-1, the conversion of VGO on CAT-5 increased by 1.19 %, heavy oil yield and coke yield decreased by 2.16 and 1.65 %, respectively. Besides, the total liquid yield and light oil yield increased by 2.27 and 2.26 %, respectively. The reaction performance of CAT-3 and CAT-5 is obviously superior to CAT-1. The appropriate pore structures and crystallized Y zeolite component on this new matrix improve the cracking ability of FCC catalysts.",{"EN":451},"Utilization of exhausted dust from FCC flue gas as material for FCC catalyst preparation",{"VOID":453},"[\"5199894711732644608\"]",{"VOID":455},"10.1007\u002Fs13203-015-0126-x","2024-05-06T10:31:06.338+00:00","https:\u002F\u002Flink.springer.com\u002Farticle\u002F10.1007\u002Fs13203-015-0126-x",[459,483,498,511],{"id":460,"sortIndex":23,"researcher":22,"roles":461,"affiliations":462,"properties":480,"displayName":482,"givenName":22,"familyName":22},"243acb66-96a7-4d14-b789-13b12018990b",[64],[463,471],{"id":464,"sortIndex":23,"affiliation":465,"properties":22},"111ae558-64dd-43bf-8585-ed6547749cab",{"id":464,"createTime":22,"updateTime":22,"relativeEntities":466,"slug":22,"properties":467,"entityType":22,"verifyStatus":22,"verifyTime":22,"verifyNote":22,"languages":22,"translateLanguages":22,"viewCount":22,"url":22,"parentIds":470,"statistic":22},[],{"title":468},{"VI":469},"State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao, China",[],{"id":472,"sortIndex":29,"affiliation":473,"properties":479},"321762ae-6d3f-407f-9742-96575bd7f99a",{"id":472,"createTime":22,"updateTime":22,"relativeEntities":474,"slug":22,"properties":475,"entityType":22,"verifyStatus":22,"verifyTime":22,"verifyNote":22,"languages":22,"translateLanguages":22,"viewCount":22,"url":22,"parentIds":478,"statistic":22},[],{"title":476},{"VI":477},"The Refinery of Zhongyuan Oilfield Company, SINOPEC, Puyang, China",[],{},{"title":481},{"VI":482},"Zejun Zuo",{"id":484,"sortIndex":29,"researcher":22,"roles":485,"affiliations":486,"properties":495,"displayName":497,"givenName":22,"familyName":22},"10d2f9fe-a88a-4973-9474-564b1005bdd2",[64],[487],{"id":488,"sortIndex":23,"affiliation":489,"properties":22},"2da7e5f5-9d03-40c5-b2cd-b4329c82a0e7",{"id":488,"createTime":22,"updateTime":22,"relativeEntities":490,"slug":22,"properties":491,"entityType":22,"verifyStatus":22,"verifyTime":22,"verifyNote":22,"languages":22,"translateLanguages":22,"viewCount":22,"url":22,"parentIds":494,"statistic":22},[],{"title":492},{"VI":493},"Qingdao Huicheng Petrochemical Technology Co., Ltd, Qingdao, China",[],{"title":496},{"VI":497},"Lingling Lv",{"id":499,"sortIndex":92,"researcher":22,"roles":500,"affiliations":501,"properties":508,"displayName":510,"givenName":22,"familyName":22},"8f654cec-0a9a-473a-a15d-ffdf0ca1794a",[64],[502],{"id":464,"sortIndex":23,"affiliation":503,"properties":22},{"id":464,"createTime":22,"updateTime":22,"relativeEntities":504,"slug":22,"properties":505,"entityType":22,"verifyStatus":22,"verifyTime":22,"verifyNote":22,"languages":22,"translateLanguages":22,"viewCount":22,"url":22,"parentIds":507,"statistic":22},[],{"title":506},{"VI":469},[],{"title":509},{"VI":510},"Chenguang Liu",{"id":512,"sortIndex":106,"researcher":22,"roles":513,"affiliations":514,"properties":521,"displayName":523,"givenName":22,"familyName":22},"1340c7d1-1c25-4f0d-99aa-6e2f60101084",[64],[515],{"id":488,"sortIndex":23,"affiliation":516,"properties":22},{"id":488,"createTime":22,"updateTime":22,"relativeEntities":517,"slug":22,"properties":518,"entityType":22,"verifyStatus":22,"verifyTime":22,"verifyNote":22,"languages":22,"translateLanguages":22,"viewCount":22,"url":22,"parentIds":520,"statistic":22},[],{"title":519},{"VI":493},[],{"title":522},{"VI":523},"Xingong Zhang",{"url":457,"publisher":525,"properties":539},{"id":6,"createTime":7,"updateTime":8,"relativeEntities":526,"slug":10,"properties":527,"entityType":20,"verifyStatus":21,"verifyTime":22,"verifyNote":22,"languages":22,"translateLanguages":22,"viewCount":23,"subjectFields":531,"manageAffiliations":532,"indexDatabases":533,"url":22,"thumbnailPath":22,"statistic":534,"gsStatistic":22,"type":33,"analyzePriority":22},[],{"issn":528,"title":529,"eissn":530},{"VOID":15},{"EN":17},{"VOID":13},[],[],[],{"impactFactor":23,"impactFactorByYear":535,"i10Index":23,"i10IndexLast5Year":23,"totalPublication":29,"totalPublicationByYear":536,"totalCitation":23,"totalCitationByYear":537,"totalCitationPerPublication":23,"totalCitationPerPublicationByYear":538,"hindexLast5Year":23,"hindex":23},{},{"2011":29},{},{},{"pages":540,"volume":542},{"VOID":541},"215-220",{"VOID":543},"5","2015-07-29",2015,[],[548,554,560,563,566,572,575],{"id":549,"text":550,"url":551,"identifiers":552},"4c68646b-0035-4279-8000-0006b275d4fa","Kulkarni P, Chellam S, Fraser MP (2007) Tracking petroleum refinery emission events using lanthanum and lanthanides as elemental markers for Pm2.5[J]. Environ Sci Technol 41(19):6748–6754","https:\u002F\u002Flink.springer.com\u002F10.1007\u002Fs10440-022-00541-7",{"doi":553},"10.1007\u002Fs10440-022-00541-7",{"id":555,"text":556,"url":557,"identifiers":558},"05a37a10-c2a8-4763-b0c1-9135e2705715","Bozlaker A, Buzcu-Güven B, Fraser MP et al (2013) Insights into Pm10 sources in Houston, Texas: role of petroleum refineries in enriching lanthanoid metals during episodic emission events[J]. Atmos Environ 69:109–117","https:\u002F\u002Fwww.sciencedirect.com\u002Fscience\u002Farticle\u002Fpii\u002FS1352231012011491",{"doi":559},"10.1016\u002Fj.atmosenv.2012.11.068",{"id":22,"text":561,"url":22,"identifiers":562},"Chen Junwu, Cao Hanchang (2005) Engineering and technology of fluid catalytic cracking [M]. Sinopec press, Beijing",{},{"id":549,"text":564,"url":551,"identifiers":565},"Basaldella EI, Torres Sánchez RM, Conconi MS (2009) Conversion of exhausted fluid cracking catalysts into zeolites by alkaline fusion[J]. Appl Clay Sci 42(3–4):611–614",{"doi":553},{"id":567,"text":568,"url":569,"identifiers":570},"fd751ef3-f5c8-4bb3-8a8c-a6f8704cf514","Elena IB, Julio CP, Mariana S et al (2006) Exhausted fluid catalytic cracking catalysts as raw materials for zeolite synthesis[J]. Appl Catal B 66(3):186–191","https:\u002F\u002Fwww.sciencedirect.com\u002Fscience\u002Farticle\u002Fpii\u002FS0926337306001019",{"doi":571},"10.1016\u002Fj.apcatb.2006.03.013",{"id":549,"text":573,"url":551,"identifiers":574},"Liu X, Liang H, Li L et al (2010) Preparation of ultrafine y zeolite from spent fluid catalytic cracking catalyst powders[J]. Chin J Catal 31(7):833–838",{"doi":553},{"id":549,"text":576,"url":551,"identifiers":577},"Brunauer S, Emmett PH, Teller E (1938) Adsorption of gases in multimolecular layers[J]. J Am Chem Soc 60(2):309–319",{"doi":553},{"id":579,"createTime":580,"updateTime":581,"relativeEntities":582,"slug":583,"properties":584,"entityType":55,"verifyStatus":56,"verifyTime":581,"verifyNote":58,"languages":22,"translateLanguages":22,"viewCount":23,"primaryUrl":593,"fullTextUrl":22,"authors":594,"publicationType":134,"publisherRelationship":678,"citationCount":22,"citationInfo":22,"publishDate":697,"publishYear":156,"citationAnalyzeStatus":21,"lastCitationAnalyze":22,"indexDatabases":698,"openAccess":22,"references":22,"isForceReanalyzing":159},"04c0a129-c2ab-4b87-b520-c3a5860227f2","2024-01-19T08:17:21.365+00:00","2025-02-26T20:34:57.830+00:00",[],"Study-of-dual-phase-drive-synchronization-method-and-temperature-measurement-algorithm-for-measuring-external-surface-temperatures-of-ethylene-cracking-furnace-tubes",{"abstract":585,"title":587,"references":589,"doi":591},{"EN":586},"Currently, the manual method using hand-held infrared temperature measurement instruments for measuring temperatures on the external surfaces of ethylene cracking furnace tubes is highly subjective and is affected by a number of prominent issues, such as the high temperature working environments, which leads to low efficiency and poor measurement accuracy. Hence, an automatic temperature measurement system based on infrared light is designed and realized. In the system, a dual-phase drive synchronization method is proposed to rotate the thermodetector during horizontal movements, thus realizing automatic batch temperature measurements of the furnace tubes. Moreover, a temperature processing algorithm is developed to automatically identify furnace wall and tube surface temperatures, filter out abnormal temperatures and select only high-quality temperature measurements prior to calculating the final result. Real temperature measurement experiments demonstrated that the dual-phase drive temperature measurement system and temperature processing method are effective and efficient. Compared with the traditional manual way, temperatures obtained using the proposed system are more stable and accurate.",{"EN":588},"Study of dual-phase drive synchronization method and temperature measurement algorithm for measuring external surface temperatures of ethylene cracking furnace tubes",{"VOID":590},"Khodamorad SH, Fatmehsari DH, Rezaie H, Sadeghipour A (2012) Analysis of ethylene cracking furnace tubes. Eng Fail Anal 21:1–8\nPregowski P, Goleniewski G, Komosa W, Zwolenik S (2005) Applications of dynamic IR thermography in studying operation of heaters. Proc SPIE 5782:83–92\nNishiyama Y, Semba H, Ogawa K, Sawaragi Y, Yamadera Y, Kinomura S (2002) A new carburization resistant alloy for ethylene cracking furnace tubes. In: Conference: CORROSION 2002, 7-11 April. Denver, Colorado\nGeng LY, Gong JM, Qin XY, Shen LM (2012) Modeling of carburization and thermal stress analysis for ethylene cracking furnace tube. Mater Sci Forum 704:1136–1140\nHan Y, Geng Z, Wang Z, Mu P (2016) Performance analysis and optimal temperature selection of ethylene cracking furnaces: a data envelopment analysis cross-model integrated analytic hierarchy process. J Anal Appl Pyrol 122:35–44\nJin YK, Li JL, Du WL, Wang ZL, Qian F (2013) Outlet temperature correlation and prediction of transfer line exchanger in an industrial steam ethylene pyrolysis process. Chinese J Chem Eng 21(4):388–394\nZhou HC, Han SD (2003) Simultaneous reconstruction of temperature distribution, absorptivity of wall surface and absorption coefficient of medium in a 2-D furnace system. Int J Heat Mass Tran 46:2645–2653\nMasoumi ME, Sadrameli SM, Towfighi J, Niaei A (2006) Simulation, optimization and control of a thermal cracking furnace. Energy 31(4):516–527\nLou C, Li WH, Zhou HC, Salinas CT (2011) Experimental investigation on simultaneous measurement of temperature distributions and radiative properties in an oil-fired tunnel furnace by radiation analysis. Int J Heat Mass Tran 54:1–8\nCheng Q, Zhang X, Wang Z, Zhou H (2014) Simultaneous measurement of three-dimensional temperature distributions and radiative properties based on radiation image processing technology in a gas-fired pilot tubular furnace. Heat Transfer Eng 35(6–8):770–779\nZheng S, Zhang X, Qi C, Zhou H (2015) Modeling of heat transfer and pyrolysis reactions in ethylene cracking furnace based on 3-D combustion monitoring. Int J Therm Sci 94:28–36\nPeng ZP (2015) Temperature discrimination method and measuring device of the furnace tube surface and the furnace wall. China Patent no 201410666748.5",{"VOID":592},"10.1007\u002Fs13203-018-0205-x","https:\u002F\u002Flink.springer.com\u002Farticle\u002F10.1007\u002Fs13203-018-0205-x",[595,610,623,638,651,664],{"id":596,"sortIndex":23,"researcher":22,"roles":597,"affiliations":598,"properties":607,"displayName":609,"givenName":22,"familyName":22},"5abd3e02-1da5-4cea-bc05-2ff9cfe8148e",[64],[599],{"id":600,"sortIndex":23,"affiliation":601,"properties":22},"9aa99041-465b-4edd-9cdc-dbd83fb6b99e",{"id":600,"createTime":22,"updateTime":22,"relativeEntities":602,"slug":22,"properties":603,"entityType":22,"verifyStatus":22,"verifyTime":22,"verifyNote":22,"languages":22,"translateLanguages":22,"viewCount":22,"url":22,"parentIds":606,"statistic":22},[],{"title":604},{"VI":605},"College of Computer and Electronic Information, Guangdong University of Petrochemical Technology, Maoming, China",[],{"title":608},{"VI":609},"Zhiping 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J Anal Appl Pyrolysis 86(1):215–220",{"doi":837},"10.1016\u002Fj.jaap.2009.06.008",{"id":22,"text":839,"url":22,"identifiers":840},"Gbolahan I, Folorunsho H, Umaru A (2018) Catalytic pyrolysis of waste polypropylene using Ahoko kaolin from Nigeria. Appl Petrochem Res 8:203–210",{"doi":841},"10.1007\u002Fs13203-018-0207-8",{"id":22,"text":843,"url":22,"identifiers":844},"Hamidi N, Tebyanian F, Massoudi R, Whitesides L (2013) Pyrolysis of household plastic wastes. Br J Appl Sci Technol 3(3):417–439",{"doi":845},"10.9734\u002FBJAST\u002F2014\u002F1984",{"id":22,"text":847,"url":22,"identifiers":848},"Sethi B (2016) Recycling of polymers in the presence of nanocatalysts: a green approach towards sustainable environment. Int J Environ Ecol Eng 10(5):472–478",{},{"id":22,"text":850,"url":22,"identifiers":851},"Gumula T, Paluszkiewicz C, Blazewicz S (2009) Study on thermal decomposition processes of polysiloxane polymers-From polymer to nanosized silicon carbide. J Anal Appl Pyrolysis 86(2):375–380",{"doi":852},"10.1016\u002Fj.jaap.2009.09.001",{"id":22,"text":854,"url":22,"identifiers":855},"Sarker M, Rashid MM, Rahman S, Molla M (2012) Conversion of low density polyethylene (LDPE) and polypropylene (PP) waste plastics into liquid fuel using thermal cracking process. Br J Environ Clim Change 2(1):1–11",{"doi":856},"10.9734\u002FBJECC\u002F2012\u002F994",{"id":22,"text":858,"url":22,"identifiers":859},"Sarker M, Mamunor Rashid M, Molla M (2012) First waste plastic conversion into liquid fuel by using muffle furnace through reactor. Int J Energy Eng 2(6):293–303",{"doi":860},"10.5923\u002Fj.ijee.20120206.04",{"id":22,"text":862,"url":22,"identifiers":863},"Sonawane YB, Shindikar M, Khaladkar M (2015) Use of catalyst in pyrolysis of polypropylene waste into liquid fuel. Int Res J Environ Sci 4(7):24–28",{},{"id":22,"text":865,"url":22,"identifiers":866},"Kumar S, Panda AK, Singh RK (2011) A review on tertiary recycling of high-density polyethylene to fuel. Resour Conserv Recycl 55(11):893–910",{"doi":867},"10.1016\u002Fj.resconrec.2011.05.005",{"id":22,"text":869,"url":22,"identifiers":870},"Seo YH, Lee KH, Shin DH (2003) Investigation of catalytic degradation of high-density polyethylene by hydrocarbon group type analysis. J Anal Appl Pyrolysis 70(2):383–398",{"doi":871},"10.1016\u002FS0165-2370(02)00186-9",{"id":22,"text":835,"url":22,"identifiers":873},{"doi":837},{"id":22,"text":875,"url":22,"identifiers":876},"Nishino J, Itoh M, Fujiyoshi H, Uemichi Y (2008) Catalytic degradation of plastic waste into petrochemicals using Ga-ZSM-5. Fuel 87(17–18):3681–3686",{"doi":877},"10.1016\u002Fj.fuel.2008.06.022",{"id":22,"text":879,"url":22,"identifiers":880},"Zhang Y, Huang J, Williams PT (2017) Fe-Ni-MCM-41 catalysts for hydrogen-rich syngas production from waste plastics by pyrolysis-catalytic steam reforming. Energy Fuels 31(8):8497–8504",{"doi":881},"10.1021\u002Facs.energyfuels.7b01368",{"id":22,"text":883,"url":22,"identifiers":884},"Sun K, Xia H, Hensen E, Van Santen R, Li C (2006) Chemistry of N2O decomposition on active sites with different nature: effect of high-temperature treatment of Fe\u002FZSM-5. J Catal 238:186–195",{"doi":885},"10.1016\u002Fj.jcat.2005.12.013",{"id":22,"text":887,"url":22,"identifiers":888},"Jaroniec M, Kruk M, Sayari A (2000) Recent advances in adsorption characterization of mesoporous molecular sieves. Stud Surf Sci Catal 129:587–596",{"doi":889},"10.1016\u002FS0167-2991(00)80261-X",{"id":22,"text":891,"url":22,"identifiers":892},"Saito A, Foley HC (1991) Curvature and parametric sensitivity in models for adsorption in micropores. AIChE J 37(3):429–436",{"doi":893},"10.1002\u002Faic.690370312",{"id":22,"text":895,"url":22,"identifiers":896},"Khoshbin R, Karimzadeh R (2017) The beneficial use of ultrasound in free template synthesis of nanostructured ZSM-5 zeolite from rice husk ash used in catalytic cracking of light naphtha: effect of irradiation power. Adv Powder Technol 28:973–982",{"doi":897},"10.1016\u002Fj.apt.2017.01.001",{"id":22,"text":899,"url":22,"identifiers":900},"Aziz A, Kim S, Kim KS (2016) Fe\u002FZSM-5 zeolites for organic-pollutant removal in the gas phase: effect of the iron source and loading. J Environ Chem Eng 4(3):3033–3040",{"doi":901},"10.1016\u002Fj.jece.2016.06.021",{"id":22,"text":903,"url":22,"identifiers":904},"Calsavara V, Luciano M (2008) Transformation of ethanol into hydrocarbons on ZSM-5 zeolites modified with iron in different ways. Fuel 87:1628–1636",{"doi":905},"10.1016\u002Fj.fuel.2007.08.006",{"id":22,"text":907,"url":22,"identifiers":908},"Zhao T, Zhang H, Li F, Yang C, Zong B (2005) Synthesis and characterization of ZSM-5\u002Fβ co-crystalline zeolite. J Nat Gas Chem 14:95–100",{},{"id":22,"text":910,"url":22,"identifiers":911},"Figueiredo AL et al (2016) Catalytic cracking of LDPE over nanocrystalline HZSM-5 zeolite prepared by seed-assisted synthesis from an organic-template-free system. J Anal Appl Pyrolysis 117:132–140",{"doi":912},"10.1016\u002Fj.jaap.2015.12.005",{"id":22,"text":914,"url":22,"identifiers":915},"Iliopoulou EF et al (2014) Pilot-scale validation of Co-ZSM-5 catalyst performance in the catalytic upgrading of biomass pyrolysis vapours. Green Chem 16(2):662–674",{"doi":916},"10.1039\u002FC3GC41575A",{"id":22,"text":918,"url":22,"identifiers":919},"Agullo J et al (2007) Catalytic pyrolysis of low density polyethylene over H-β, H-Y, H-Mordenite, and H-Ferrierite zeolite catalysts: influence of acidity and structures. Kinet Catal 48(4):535–540",{"doi":920},"10.1134\u002FS002315840704009X",{"id":22,"text":922,"url":22,"identifiers":923},"Syamsiro M, Cheng S, Hu W, Saptoadi H, Syamsiro M (2015) Liquid and gaseous fuel from waste plastics by sequential pyrolysis and catalytic reforming processes over Indonesian natural zeolite catalysts fulltext refbacks. Waste Technol 2:1–3",{},{"id":22,"text":925,"url":22,"identifiers":926},"Miandad R, Barakat MA, Aburiazaiza AS, Rehan M, Nizami AS (2016) Catalytic pyrolysis of plastic waste: a review. Process Saf Environ Prot 102:822–838",{"doi":927},"10.1016\u002Fj.psep.2016.06.022",{"id":929,"createTime":930,"updateTime":931,"relativeEntities":932,"slug":933,"properties":934,"entityType":55,"verifyStatus":56,"verifyTime":931,"verifyNote":58,"languages":22,"translateLanguages":22,"viewCount":29,"primaryUrl":943,"fullTextUrl":22,"authors":944,"publicationType":134,"publisherRelationship":1023,"citationCount":22,"citationInfo":22,"publishDate":1042,"publishYear":156,"citationAnalyzeStatus":21,"lastCitationAnalyze":22,"indexDatabases":1043,"openAccess":22,"references":22,"isForceReanalyzing":159},"bbc9948f-bd5e-4137-b51b-300e9cd6d46e","2024-02-13T10:41:28.010+00:00","2025-02-26T17:40:58.796+00:00",[],"Heat-strengthening-of-double-field-coupling-demulsification-of-industrial-waste-oil-emulsion",{"abstract":935,"title":937,"references":939,"doi":941},{"EN":936},"Demulsification of highly aqueous waste oil is difficult to complete by a single process efficiently. The dewatering-type hydrocyclone is used as the unit body and includes the high-voltage electrode to realize demulsification and dewatering ability of the coupling of high-voltage electric and swirling centrifugal fields in waste oil emulsion efficiently. This study considers the influence of heating temperature on demulsification in coupled field. Thus, a heat-strengthening double-field demulsification process is proposed. Specifically, the effect of heat strengthening on demulsification, dewatering, and separation of double-field coupled by numerical simulation and experimental methods was investigated. The temperatures of heat-strengthening were 60 °C, 65 °C, 70 °C, and 75 °C. The results show that the separation efficiency predicted by numerical simulation are in good agreement with the experimental results. And the heat-strengthening can effectively enhance the separation effect of two fields and improve the efficiency of the oil–water separation of industrial waste oil. When the heating temperature is raised from 60 to 65 °C, and from 65 to 70 °C, the separation efficiency increases by approximately 4.1% and 6.7%, respectively.",{"EN":938},"Heat strengthening of double-field coupling demulsification of industrial waste oil emulsion",{"VOID":940},"Praporgescu G, Mihalescu S (2011) Study the environmental impact of lubricants used in mechanical systems. Ann Univ Petroşani Mech Eng 13:131–136\nSu SL, Liew RK, Jusoh A, Cheng TC, Ani FN, Chase HA (2016) Progress in waste oil to sustainable energy, with emphasis on pyrolysis techniques. Renew Sustain Energy Rev 53:741–753\nYi H, Zhong CH, Zhang WD, Xiang SU, Wang XX (2015) Research status and prospects of waste lubricating oil combined technology. Mod Chem Ind 35:19–22\nRincon J, Canizares P, Garcia MT (2005) Regeneration of used lubricant oil by polar solvent extraction. Ind Eng Chem Res 44:4373–4379\nGu G, Liu G, Chen B, Tian M, Wu HY (2015) Research progress of physical demulsification technologies and equipment about W\u002FO emulsions. Chem Ind Eng Prog 34:319–324\nGong H, Zhang X, Peng Y, Shang HH, Wang JS (2016) Three-field coupled procedure and equipment for demulsification and dehydration of waste oil. Mod Chem Ind 36:164–167\nPan S, Zhang X, Wu F (2010) The study of demulsification in oil water emulsion. J Chongqing Technol Bus Univ (Nat Sci Ed) 27:158–163\nEow JS, Ghadiri M, Sharif AO, Williams TJ (2001) Electrostatic enhancement of coalescence of water droplets in oil: a review of the current understanding. Chem Eng J 85:357–368\nBailes PJ (1992) Electrically augmented settlers and coalescers for solvent extraction. Hydrometallurgy 30:417–430\nEow JS, Ghadiri M (2001) Electro-mechanical coalescer-separators for the separation of aqueous-in-oil dispersions, UK Patent GB 2377397A, publ. date January 15, 2001\nEow JS, Ghadiri M (2002) Electrocoalesce-separators for the separation of aqueous drops from a flowing dielectric viscous liquid. Sep Purif Technol 29:63–77\nYang X (2009) Drop dynamic of W\u002FO emulsion under the combination of centrifugal field and pulsed electric field. China University of Petroleum, Beijing\nWang J (2009) Study of the rule of emulsion’s concentration and sedimentation under the combination of high frequency-pulse electric and centrifugal fields. China University of Petroleum, Beijing\nLi Q, Chen J, Meng L, Pan Z, Wang K (2014) Investigation of water separation from water-in-oil emulsion using high frequency pulsed AC electric field by new equipment. J Dispers Sci Technol 36:918–923\nMhatre S, Vivacqua V, Ghadiri M, Abdullah AM, Al-Marri MJ, Hassanpour A, Hewakandamby B, Azzopardi B, Kermani B (2015) Electrostatic phase separation: a review. Chem Eng Res Des 96:177–195\nZolfaghari R, Fakhru’L-Razi A, Abdullah LC, Elnashaie SSEH, Pendashteh A (2016) Demulsification techniques of water-in-oil and oil-in-water emulsions in petroleum industry. Sep Purif Technol 170:377–407\nSun L (2009) Study of the rule of emulsion’s concentration and sedimentation under the combination of high frequency-pulse electric and centrifugal fields. China University of Petroleum, Beijing\nZhang Y, Liu Y, Ji R, Wang F, Cai B, Li H (2011) Application of variable frequency technique on electrical dehydration of water-in-oil emulsion. Colloids Surf A 386:185–190\nCao Y, Jin Y, Li J, Zou D, Chen X (2016) Demulsification of the phosphoric acid–tributyl phosphate (W\u002FO) emulsion by hydrocyclone. Sep Purif Technol 158:387–395\nEow JS, Ghadiri M, Sharif AO (2002) Electrostatic and hydrodynamic separation of aqueous drops in a flowing viscous oil. Chem Eng Process 41:649–657\nEow JS, Ghadiri M, Sharif AO (2007) Electro-hydrodynamic separation of aqueous drops from flowing viscous oil. J Pet Sci Eng 55:146–155\nYang D, Xu M, He L, Luo X, Lu Y, Yan H, Tian C (2015) The influence and optimisation of electrical parameters for enhanced coalescence under pulsed DC electric field in a cylindrical electrostatic coalescer. Chem Eng Sci 138:71–85\nMurthy YR, Bhaskar KU (2012) Parametric CFD studies on hydrocyclone. Powder Technol 230:36–47\nAhmed MA, Nadia GK, Mahmoud RN (2011) Functions of demulsifiers in the petroleum industry. Sep Sci Technol 46:1144–1163\nHosseini M, Shahavi MH (2012) Electrostatic enhancement of coalescence of oil droplets (in nanometer scale) in water emulsion. Chin J Chem Eng 20:654–658\nKwon WT, Park K, Han SD, Yoon SM, Kim JY, Bae W, Rhee YW (2010) Investigation of water separation from water-in-oil emulsion using electric field. J Ind Eng Chem 16:684–687\nZhang Y (2012) Dehydration efficiency of water-in-model oil emulsions in high frequency pulsed DC electrical field: effect of physical and chemical properties of the emulsions. J Dispers Sci Technol 33:1574–1581\nPeng Y, Liu T, Gong H, Wang J, Zhang X (2015) Effect of pulsed electric field with variable frequency on coalescence of drops in oil. RSC Adv 5:31318–31323\nMousavichoubeh M, Ghadiri M, Shariaty-Niassar M (2011) Electro-coalescence of an aqueous droplet at an oil–water interface. Chem Eng Process 50:338–344\nMotin A (2015) Theoretical and numerical study of swirling flow separation device for oil-water mixtures. Michigan State University, East Lansing\nSchutz S, Gorbach G, Piesche M (2009) Modeling fluid behavior and droplet interactions during liquid-liquid separation hydrocyclones. Chem Eng Sci 64:3935–3952\nTian J, Ni L, Song T, Olson J, Zhao J (2018) An overview of operating parameters and conditions in hydrocyclones for enhanced separations. Sep Purif Technol 206:268–285\nPeng Y, Liu T, Gong H, Zhang XM (2016) Dehydration of waste lubricating oil by three fields: swirl centrifugal field, pulse electric field and vacuum temperature field. Appl Petrochem Res 6:389–395\nHuang X (1995) The method of Maxwell stress tensor and its application. J Nanjing Norm Univ 14:41–43\nAtten P (1993) Electro-coalescence of water droplets in an insulating liquid. J Electrost 30:259–270\nFluent AN (2013) ANSYS fluent theory guide. ANSYS Inc, Canonsburg\nFluent AN (2013) ANSYS fluent UDF manual. ANSYS Inc, Canonsburg\nNoroozi S, Hashemabadi SH (2011) CFD analysis of inlet chamber body profile effects on de-oiling hydrocyclone efficiency. Chem Eng Res Des 89:968–977\nAta S, Pugh RJ, Jameson GJ (2011) The influence of interfacial ageing and temperature on the coalescence of oil droplets in water. Colloids Surf A 374:96–101\nLi Y, Gong H, Dong M, Liu Y (2016) Separation of water-in-heavy oil emulsions using porous particles in a coalescence column. Sep Sci Technol 166:148–156\nBinner ER, Robinson JP, Silvester SA, Kingman SW, Lester EH (2014) Investigation into the mechanisms by which microwave heating enhances separation of water-in-oil emulsions. Fuel 116:516–521\nGong H, Yu B, Dai F, Peng Y, Shao J (2018) Simulation on performance of a demulsification and dewatering device with coupling double fields: swirl centrifugal field and high-voltage electric field. Sep Purif Technol 207:124–132",{"VOID":942},"10.1007\u002Fs13203-018-0221-x","https:\u002F\u002Flink.springer.com\u002Farticle\u002F10.1007\u002Fs13203-018-0221-x",[945,969,984,997,1010],{"id":946,"sortIndex":23,"researcher":22,"roles":947,"affiliations":948,"properties":966,"displayName":968,"givenName":22,"familyName":22},"71f41e15-f988-4909-8004-d30ab26f36fa",[64],[949,957],{"id":950,"sortIndex":23,"affiliation":951,"properties":22},"67826e5a-c499-4375-b77b-0c99c8af2421",{"id":950,"createTime":22,"updateTime":22,"relativeEntities":952,"slug":22,"properties":953,"entityType":22,"verifyStatus":22,"verifyTime":22,"verifyNote":22,"languages":22,"translateLanguages":22,"viewCount":22,"url":22,"parentIds":956,"statistic":22},[],{"title":954},{"VI":955},"School of Mechanical Engineering, Chongqing Technology and Business University, Chongqing, 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Wiley, New York",{},{"id":22,"text":1162,"url":22,"identifiers":1163},"Plunkett RJ (1941) Tetrafluoroethylene polymers, US Patent 2230654",{},{"id":22,"text":1165,"url":22,"identifiers":1166},"Ameduri B (2004) Well- architectured fluoropolymers: synthesis. Properties and Applications Elsevier Science, San Diego",{},{"id":22,"text":1168,"url":22,"identifiers":1169},"Sharma B, Verma R, Baur C, Bykova J, Mabry JM, Smith DW Jr (2013) Ultra low dielectric, self-cleansing and highly oleophobic POSS-PFCP aryl ether polymer composites. J Mater Chem C 1:7222",{"doi":1170},"10.1039\u002Fc3tc31161a",{"id":22,"text":1172,"url":22,"identifiers":1173},"Wood K (2002) The effect of fluoropolymer architecture on the exterior weathering of coatings. Macromol Symp 187:469",{"doi":1174},"10.1002\u002F1521-3900(200209)187:1\u003C469::AID-MASY469>3.0.CO;2-M",{"id":22,"text":1176,"url":22,"identifiers":1177},"Head RA, Johnson S (1988) Coating compositions for optical fibers, Eur Patent Appl 260842 (assigned to Imperial Chem. Industries PLC, UK)",{},{"id":22,"text":1179,"url":22,"identifiers":1180},"Barraud J, Gervat S, Ratovelomanana V, Boutevin B, Parisi JP, cahuzac A, Octeur RJ (1992) Cladding compositions for optical fibres. French Patent 9204222 (assigned to Alcatel)",{},{"id":22,"text":1182,"url":22,"identifiers":1183},"Schuman PD (1996) Fiber cladding compositions. PCT Int Appl, WO 9603609",{},{"id":22,"text":1185,"url":22,"identifiers":1186},"Youngblood JP, Andruzzi L, Ober CK, Hexemer A, Kramer EJ, Callow JA, Finlay JA, Callow ME (2003) Coatings based on side-chain ether-linked poly(ethylene glycol) and fluorocarbon polymers for the control of marine biofouling. Biofouling 19:91",{"doi":1187},"10.1080\u002F0892701021000053381",{"id":22,"text":1189,"url":22,"identifiers":1190},"Améduri B, Boutevin B, Kostov G (2001) Fluoroelastomers: synthesis, properties and applications. Prog Polym Sci 26:105",{"doi":1191},"10.1016\u002FS0079-6700(00)00044-7",{"id":22,"text":1193,"url":22,"identifiers":1194},"Pabon M, Corpart JM (2002) Fluorinated surfactants: synthesis, properties, effluent treatment. J Fluor Chem 114:149",{"doi":1195},"10.1016\u002FS0022-1139(02)00038-6",{"id":22,"text":1197,"url":22,"identifiers":1198},"Kissa E (1994) Fluorinated surfactants: synthesis, preparations, applications. Marcel Dekker, New York",{},{"id":22,"text":1200,"url":22,"identifiers":1201},"Ober CK, Douki K, Vohra VR, Kwark Y-J, Liu X-Q, Conley W, Miller D, Zimmerman P (2002) New strategies for high resolution photoresists. J Photopolym Sci Technol 15:603",{"doi":1202},"10.2494\u002Fphotopolymer.15.603",{"id":22,"text":1204,"url":22,"identifiers":1205},"Toriumi M, Shida N, Watanabe H, Yamazaki T, Ishikawa S, Itani T (2002) Fluoropolymer resists for 157-nm lithography. Proc. SPIE 4690:191",{"doi":1206},"10.1117\u002F12.474218",{"id":22,"text":1208,"url":22,"identifiers":1209},"Feiring AE, Crawford MK, Farnham WB, Feldman J, French RH, Leffew KW, Petrov VA, Schadt Iii FL, Wheland RC, Zumsteg FC (2003) Design of very transparent fluoropolymer resists for semiconductor manufacture at 157 nm. J Fluor Chem 122:11",{"doi":1210},"10.1016\u002FS0022-1139(03)00075-7",{"id":22,"text":1212,"url":22,"identifiers":1213},"Krebs FC, Jensen T (2003) Fluorinated molecules relevant to conducting polymer research. J Fluor Chem 120:77",{"doi":1214},"10.1016\u002FS0022-1139(02)00289-0",{"id":22,"text":1216,"url":22,"identifiers":1217},"Krafft MP, Riess JG (1998) Highly fluorinated amphiphiles and colloidal systems, and their applications in the biomedical field—A contribution. Biochimie 80:489",{"doi":1218},"10.1016\u002FS0300-9084(00)80016-4",{"id":22,"text":1220,"url":22,"identifiers":1221},"Krafft MP (2003) Fluorinated colloids and interfaces. Curr Opin Colloids Interface Sci 8:213",{"doi":1222},"10.1016\u002FS1359-0294(03)00057-8",{"id":22,"text":1224,"url":22,"identifiers":1225},"Scheirs J (1997) Modern fluoropolymers: high performance polymers for diverse applications. Wiley, New York",{},{"id":22,"text":1227,"url":22,"identifiers":1228},"Babb DA, Ezzell BR, Clement KS, Richey WF, Kennedy AP (1993) Perfluorocyclobutane aromatic ether polymers. J Polym Sci Part A Polym Chem 31:3465",{"doi":1229},"10.1002\u002Fpola.1993.080311336",{"id":22,"text":1231,"url":22,"identifiers":1232},"Iacono ST, Budy SM, Jin J, Smith DW Jr (2007) Science and technology of perfluorocyclobutyl aryl ether polymers. J Polym Sci Part A Polym Chem 45:5705",{"doi":1233},"10.1002\u002Fpola.22390",{"id":22,"text":1235,"url":22,"identifiers":1236},"Iacono ST, Budy SM, Ewald D, Smith DW Jr (2006) Facile preparation of fluorovinylene aryl ether telechelic polymers with dual functionality for thermal chain extension and tandem crosslinking. Chem Commun 46:4844",{"doi":1237},"10.1039\u002Fb610157g",{"id":22,"text":1239,"url":22,"identifiers":1240},"Sharon CK, Lund BR, Smith DW Jr, Iacono ST (2012) In advances in fluorine-containing polymers. Am Chem Soc 1106:9",{},{"id":22,"text":1242,"url":22,"identifiers":1243},"Moody JD, VanDerveer D, Smith DW Jr, Iacono ST (2011) Synthesis of internal fluorinated alkenesvia facile aryloxylation of substituted phenols with aryl trifluorovinyl ethers. Org Biomol Chem 9:4842",{"doi":1244},"10.1039\u002Fc1ob05041a",{"id":22,"text":1246,"url":22,"identifiers":1247},"Smith DW Jr, Chen S, Kumar SM, Ballato J, Topping C, Shah HV, Foulger SH (2002) Perfluorocyclobutyl copolymers for microphotonics. Adv Mater 14:1585",{"doi":1248},"10.1002\u002F1521-4095(20021104)14:21\u003C1585::AID-ADMA1585>3.0.CO;2-S",{"id":22,"text":1250,"url":22,"identifiers":1251},"Dei DK, Lund BR, Wu J, Simon D, Ware T, Voit WE, MacFarlane D, Liff SM, Smith DW Jr (2013) High performance and multipurpose triarylamine-enchained semifluorinated polymers. ACS Macro Letter 2:35",{"doi":1252},"10.1021\u002Fmz300532z",{"id":22,"text":1254,"url":22,"identifiers":1255},"Cracowski JM, Sharma B, Brown DK, Christensen K, Lund BR, Smith DW Jr (2012) Perfluorocyclopentenyl (PFCP) aryl ether polymers via polycondensation of octafluorocyclopentene with bisphenols. Macromolecules 45:766–771",{"doi":1256},"10.1021\u002Fma2024599",{"id":22,"text":1258,"url":22,"identifiers":1259},"Sharma B, Hill SC, Liff SM, Pennington WT, Smith DW Jr (2014) Perfluorocyclohexenyl aryl ether polymers via polycondensation of decafluorocyclohexene with bisphenols. J Polym Sci Part A Polym Chem 52:232–238",{"doi":1260},"10.1002\u002Fpola.26995",{"id":22,"text":1262,"url":22,"identifiers":1263},"Budy SM, Suresh S, Spraul BK, Smith DW Jr (2008) High-temperature chromophores and perfluorocyclobutyl copolymers for electro-optic applications. J Phys Chem C 112:8099–8104",{"doi":1264},"10.1021\u002Fjp8010475",{"id":22,"text":1266,"url":22,"identifiers":1267},"Chambers RD (1992) In synthetic fluorine chemistry. In: Chambers RD, Prakash GKS (eds) Olah G. Wiley, New York, pp 359–380",{},{"id":22,"text":1269,"url":22,"identifiers":1270},"Sharma B, VanDerveer DG, Liff SM, Smith DW Jr (2013) Bis-perfluorocycloalkenyl (PFCA) aryl ether monomers towards a versatile class of semi-fluorinated aryl ether polymers. Tetrahedron Lett 54:3609–3612",{"doi":1271},"10.1016\u002Fj.tetlet.2013.04.087",{"id":22,"text":1273,"url":22,"identifiers":1274},"Timperley CM (2004) Fluoroalkene chemistry: part 1. Highly-toxic fluorobutenes and their mode of toxicity: reactions of perfluoroisobutene and polyfluorinated cyclobutenes with thiols. J Fluorine Chem 125:685–693",{"doi":1275},"10.1016\u002Fj.jfluchem.2003.11.021",{"id":22,"text":1277,"url":22,"identifiers":1278},"Smith DW Jr, Jin J, Shah HV, Xie Y, DesMarteau DD (2004) Anomalous crystallinity in a semi-fluorinated perfluorocyclobutyl (PFCB) polymer containing the hexafluoro-i-propylidene (6F) linkage. Polymer 45:5755",{"doi":1279},"10.1016\u002Fj.polymer.2004.06.011",{"id":22,"text":1281,"url":22,"identifiers":1282},"Zengin H, Zengin G, Topping CM, Smith DW Jr (2007) Synthesis and characterization of a bis-(4-trifluoromethanesulfonyloxyphenyl)phenylamine monomer and its polymer for light-emitting applications. Polym Sci Part A Polym Chem 45:1860",{"doi":1283},"10.1002\u002Fpola.21950",{"id":22,"text":1285,"url":22,"identifiers":1286},"Guo M, Hayakawa T, Kakimoto MA, Goodson T (2011) Organic macromolecular high dielectric constant materials: synthesis, characterization, and applications. 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Chem Eur J 15:10554",{"doi":1303},"10.1002\u002Fchem.200901508",{"id":1305,"createTime":1306,"updateTime":1307,"relativeEntities":1308,"slug":1309,"properties":1310,"entityType":55,"verifyStatus":56,"verifyTime":1319,"verifyNote":58,"languages":22,"translateLanguages":22,"viewCount":23,"primaryUrl":1320,"fullTextUrl":22,"authors":1321,"publicationType":134,"publisherRelationship":1352,"citationCount":22,"citationInfo":22,"publishDate":1372,"publishYear":545,"citationAnalyzeStatus":21,"lastCitationAnalyze":22,"indexDatabases":1373,"openAccess":22,"references":22,"isForceReanalyzing":159},"afe9fcac-19d5-4b14-b48b-a59999b1c149","2024-01-16T19:49:18.777+00:00","2025-02-25T16:50:47.906+00:00",[],"Simulation-of-hydrodesulfurization-unit-for-natural-gas-condensate-with-high-sulfur-content",{"abstract":1311,"title":1313,"references":1315,"doi":1317},{"EN":1312},"The natural gas condensates are composed of various components of hydrocarbons and some contaminants such as hydrogen sulfide, thiols (mercaptans), and aromatics. Thus, the natural gas condensates could be considered as a fuel resource. This study concerned the simulation of an Ultra-Deep Hydrodesulfurization (UDHDS) unit plus a distillation section to treat a combination of gas condensate and disulfide oils (DSO) and produce clean fuel cuts. Gas condensate of South Pars field of Iran with high sulfur content was applied to obtain clean fuel cuts. In order to reduce the sulfur content of this stream to less than 10 ppmw as sulfur, a UDHDS unit was simulated using Aspen HYSYS software package. The clean gas condensate leaving the UDHDS unit (with sulfur content \u003C10 ppmw) contains complex mixtures of hydrocarbon components called petroleum cuts which are identified by their boiling points ranges. To obtain the narrow fractions of butane, light naphtha, heavy naphtha, kerosene, and gasoil, a fractional distillation system was simulated. The simulation results revealed that the top products of distillation column, namely butane, light naphtha, and heavy naphtha were sulfur free and the sulfur contents of kerosene and gasoil cuts were 12 and 27 ppmw as sulfur, respectively.",{"EN":1314},"Simulation of hydrodesulfurization unit for natural gas condensate with high sulfur content",{"VOID":1316},"Manning FS, Thompson RE (1991). Oilfield Processing of Petroleum (Volume One:Natural Gas). Pennwell Books. ISBN 0-87814-343-2\nMedde M The Ph.D. thesis in ingegneria industriale università degli studi di cagliari, “experimental analysis and modelling of gasoil hydrotreatment process”\nSadighi S, Seif Mohaddecy SR, Ghabouli O, Bahmani M (2009) Revamp of naphtha hydrotreating process in an iranian refinery. Pet Coal J 51(1):45–50\nGheni SA, Jada’a WA (2012) Inhibitory study for joint reactions of hydrodesulphurization and hydrodenitrogenation during hydrotreating of vacuum gas oil. In: Proceedings of the world congress on engineering and computer science 2012, vol II. WCECS, San Francisco, USA\nKabe T, Ishihara A, Qian W (1999) Hydrodesulphurization and Hydrodenitrogenation. Kodansha Ltd., Tokyo, WILEY-VCH Verlag GmbH, Weinheim\nBabich IV, Moulijn JA (2003) Science and technology of novel processes for deep desulfurization of oil refinery streams. Fuel J 82(6):607–740\nRang H, Kann J, Oja V (2006) Advances in desulfurization research. Oil Shale 23(2):164–176\nBilal S, Mohammed Dabo IA, Mujahid AU, Kasim SA, Nuhu M, Mohammed A, Abubakar HM, Yahaya UB, Habib A, Abubakar B, Aminu YZ (2013) Simulation of hydrodesulphurization (HDS) unit of Kaduna Refining and Petrochemical Company Limited. Chem Process Eng Res 13:29–35\nJiménez F, Kafarov V, Nuñez M (2006) Computer-aided modeling for hydrodesulfurization, hydrodenitrogenation and hydrodearomatization simultaneous reactions in a hydrotreating industrial process. Comput Aided Chem Eng 21:651–657\nArce-Medina E, Paz-Paredesb JI (2009) Artificial neural network modeling techniques applied to the hydrodesulfurization process. Math Comput Modelling J 49:207–214\nTechnical Recommendation Study Report for HQCEC Company\nMorgott D, Lewis C, Bootman J, Banton M (2014) Disulfide oil hazard assessment using categorical analysis and a mode of action determination. Int J Toxicol 33:181S–198S. doi:10.1177\u002F1091581813504227\nAl-Assady Q (2009) Characterization of petroleum fractions. Iraqi J Mech Mater Eng 9(2):223–238\nRefinery Feedstocks and Products- Properties and Specifications, Colorado School of Mines, Page: 21, http:\u002F\u002Finside.mines.edu\u002F~jjechura\u002FRefining\u002F02_Feedstocks_&_Products.pdf\nOil Refinery Processes page: 40, 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