The role of 5f-orbital participation in unexpected inversion of the σ-bond metathesis reactivity trend of triamidoamine thorium(<scp>iv</scp>) and uranium(<scp>iv</scp>) alkyls

Chemical Science - Tập 5 Số 6 - Trang 2489-2497
Benedict M. Gardner1, Peter A. Cleaves1, Christos E. Kefalidis2, Jian Fang3,2, Laurent Maron2, William Lewis1, Alexander J. Blake1, Stephen T. Liddle1
1School of Chemistry, University of Nottingham, University Park, Nottingham, UK
2LPCNO, CNRS & INSA; Université Paul Sabatier; 135 Avenue de Rangueil Toulouse 31077 France
3College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, China

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